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    Process for Producing Cl-C4 Alkyl Nitrite
    4.
    发明申请
    Process for Producing Cl-C4 Alkyl Nitrite 有权
    生产Cl-C4烷基亚硝酸盐的方法

    公开(公告)号：US20110257425A1

    公开(公告)日：2011-10-20

    申请号：US13088253

    申请日：2011-04-15

    申请人： Juntao Liu ,  Siqin Li ,  Lei Li ,  Linna Zhang

    发明人： Juntao Liu ,  Siqin Li ,  Lei Li ,  Linna Zhang

    IPC分类号： C07C203/00

    CPC分类号： C07C201/04 ,  C07C203/00

    摘要： The present invention relates to a process for producing C1-C4 alkyl nitrite, comprising loading a resin catalyst layer and/or a porous filler layer into a reactor, passing nitrogen oxide, oxygen and C1-C4 alkanol as raw materials through the resin catalyst layer and/or porous filler layer in a counter current, parallel current or cross current manner, reacting under the conditions including a reaction temperature of from 0 to 150° C., a reaction pressure of from −0.09 to 1.5 MPa, a molar ratio of C1-C4 alkanol/nitrogen oxide of 1-100:1, a molar ratio of nitrogen oxide/oxygen of 4-50:1, to obtain an effluent containing C1-C4 alkyl nitrite, wherein said nitrogen oxide is NO, or a mixed gas containing NO and one or more selected from N2O3 and NO2.

    摘要翻译： 本发明涉及一种生产C1-C4烷基亚硝酸盐的方法，包括将树脂催化剂层和/或多孔填料层装入反应器中，使氮氧化物，氧和C1-C4链烷醇作为原料通过树脂催化剂层 和/或多孔填料层，以相对电流，并联电流或交叉电流方式，在0〜150℃的反应温度，-0.09〜1.5MPa的反应压力，-0.09〜1.5MPa的反应压力， C1-C4链烷醇/氮氧化物为1-100:1，氮氧化物/氧摩尔比为4-50:1，得到含有C 1 -C 4烷基亚硝酸盐的流出物，其中所述氮氧化物为NO，或混合 含有NO和选自N 2 O 3和NO 2中的一种或多种的气体。

    METHOD FOR IMPROVING THE QUALITY OF ETHYLENE GLYCOL PRODUCTS
    5.
    发明申请
    METHOD FOR IMPROVING THE QUALITY OF ETHYLENE GLYCOL PRODUCTS 有权
    改善乙二醇产品质量的方法

    公开(公告)号：US20130331618A1

    公开(公告)日：2013-12-12

    申请号：US14000878

    申请日：2012-02-24

    申请人： Juntao Liu ,  Yuhong Zhang ,  Wanmin Wang

    发明人： Juntao Liu ,  Yuhong Zhang ,  Wanmin Wang

    IPC分类号： C07C29/149

    CPC分类号： C07C29/149 ,  C07C29/90 ,  Y02P20/52 ,  C07C31/202

    摘要： A method for improving the quality of ethylene glycol products, which mainly solves the technical problem of low UV-light transmittance of the ethylene glycol products present in the prior art. The method successfully solves the problem by use of the technical solution wherein the ethylene glycol raw material and hydrogen are passed through a rotating packed bed reactor loaded with solid oxide catalyst at a temperature of about 20 to about 280 ° C., a pressure of about 0.1 to about 4.0 MPa, a space velocity of about 0.2 to about 100.0 hr−1 and a molar ratio of hydrogen to ethylene glycol of from about 0.01 to 40:1, and ethylene glycol is obtained after the reaction. The solid oxide catalyst is at least one of copper-based, nickel-based and palladium-based catalysts, and the rotation rate of the rotating packed bed reactor is about 300 to about 5000 rpm.

    摘要翻译： 一种改善乙二醇产品质量的方法，其主要解决了现有技术中存在的乙二醇产品的紫外光透射率低的技术问题。 该方法通过使用技术方案成功地解决了该问题，其中乙二醇原料和氢气通过装有固体氧化物催化剂的旋转填充床反应器在约20至约280℃的温度下进行，压力约为 0.1至约4.0MPa，空间速度为约0.2至约100.0小时-1，氢与乙二醇的摩尔比为约0.01至40:1，反应后获得乙二醇。 固体氧化物催化剂是铜基，镍基和钯基催化剂中的至少一种，并且旋转填充床反应器的旋转速率为约300至约5000rpm。

    PROCESS FOR SELECTIVE OXIDATIVE DEHYDROGENATION OF A HYDROGEN-CONTAINING CO MIXED GAS
    6.
    发明申请
    PROCESS FOR SELECTIVE OXIDATIVE DEHYDROGENATION OF A HYDROGEN-CONTAINING CO MIXED GAS 有权
    含氢混合气体的选择性氧化脱氢方法

    公开(公告)号：US20110263726A1

    公开(公告)日：2011-10-27

    申请号：US13087798

    申请日：2011-04-15

    申请人： Juntao Liu ,  Siqin Li ,  Linna Zhang ,  Lei Li ,  Jun Kuai

    发明人： Juntao Liu ,  Siqin Li ,  Linna Zhang ,  Lei Li ,  Jun Kuai

    IPC分类号： C07C27/00

    CPC分类号： B01J35/0006 ,  B01J23/44 ,  B01J23/63 ,  B01J29/46 ,  B01J29/48 ,  C10K3/04

    摘要： A process for selective oxidative dehydrogenation of a hydrogen-containing CO mixed gas, comprising contacting a hydrogen-containing CO mixed gas raw material with at least one catalyst entity having an increased activity gradient disposed in a reactor under at least one reaction condition chosen from a reaction temperature ranging from 100 to 300° C., a volume space velocity ranging from 100 to 10000 h−1, and a reaction pressure ranging from −0.08 to 5.0 MPa, wherein the molar ratio of oxygen to hydrogen in the raw material ranges from 0.5:1 to 5:1.

    摘要翻译： 一种用于含氢CO混合气体的选择性氧化脱氢的方法，包括使含氢CO混合气体原料与设置在反应器中的活化梯度增加的至少一个催化剂实体在至少一个反应条件下接触，所述反应条件选自 反应温度为100〜300℃，体积空间速度为100〜10000h -1，反应压力为-0.08〜5.0MPa，原料中氧与氢的摩尔比为 0.5：1至5：1。

    PROCESS OF PRODUCING OXALATE BY CO GAS PHASE METHOD
    7.
    发明申请
    PROCESS OF PRODUCING OXALATE BY CO GAS PHASE METHOD 有权
    通过气相法制备氧化铝的方法

    公开(公告)号：US20130197265A1

    公开(公告)日：2013-08-01

    申请号：US13641457

    申请日：2011-04-13

    申请人： Juntao Liu ,  Fengxia Sun ,  Jun Kuai

    发明人： Juntao Liu ,  Fengxia Sun ,  Jun Kuai

    IPC分类号： C07C67/18

    CPC分类号： C07C67/18 ,  B01J21/04 ,  B01J21/063 ,  B01J23/6562 ,  B01J23/8926 ,  B01J23/894 ,  B01J23/8946 ,  B01J23/8973 ,  C07C67/36 ,  C07C69/38

    摘要： The present invention relates to a process of producing oxalate by CO gas phase method for chiefly solving the technical problem of the low utilization efficiency of nitrogen oxides or nitrous acid esters in the prior art. The present invention solves the problem in a better way by using the following steps including: a gas phase stream V containing NO and methanol and oxygen enter a supergravity rotating bed reactor II and are subjected to the oxidative esterification reaction to produce an effluent VI containing methyl nitrite; a methyl nitrite effluent VII obtained from separating said effluent VI together with a CO gas II enter a coupling reactor II and is contacted with a catalyst II to react to form a dimethyl oxalate effluent VIII and a gas phase effluent IX containing NO; the resultant dimethyl oxalate effluent VIII is separated to obtain a dimethyl oxalate product I; optionally, the gas phase effluent IX containing NO is returned to the step above so as to be mixed with the gas phase stream V containing NO for being recycled. Therefore, the process is applicable to the industrial production of oxalate by CO gas phase method.

    摘要翻译： 本发明涉及一种通过CO气相法生产草酸盐的方法，主要解决现有技术中氮氧化物或亚硝酸酯利用率低的技术问题。 本发明通过使用以下步骤更好地解决了该问题，包括：含有NO和甲醇和氧的气相流V进入超重力旋转床反应器II，并进行氧化酯化反应以产生含有甲基 亚硝酸盐 通过将CO 2气体II与所述流出物VI分离而获得的亚硝酸甲酯流出物VII进入偶联反应器II，并与催化剂II接触以进行反应以形成草酸二乙酯流出物VIII和含有NO的气相流出物IX; 将得到的草酸二甲酯流出物VIII分离得到草酸二甲酯产物I; 任选地，将含有NO的气相流出物IX返回到上述步骤，以与含有NO的气相物流V混合以进行再循环。 因此，该方法适用于CO气相法工业生产草酸盐。

    Method for selective hydrogenation of phenylacetylene using composite bed in the presence of styrene
    8.
    发明授权
    Method for selective hydrogenation of phenylacetylene using composite bed in the presence of styrene 有权
    在苯乙烯存在下使用复合床选择性氢化苯乙炔的方法

    公开(公告)号：US08916736B2

    公开(公告)日：2014-12-23

    申请号：US13140645

    申请日：2009-12-17

    申请人： Siqin Li ,  Juntao Liu ,  Zhiyan Zhu ,  Junhua Zhu ,  Jun Kuai

    发明人： Siqin Li ,  Juntao Liu ,  Zhiyan Zhu ,  Junhua Zhu ,  Jun Kuai

    IPC分类号： C07C5/11 ,  C07C7/167

    CPC分类号： C07C7/167 ,  C07C15/46

    摘要： The present invention discloses a process for the selective hydrogenation of phenylacetylene in the presence of styrene conducted in a combined bed, which process comprises under hydrogenation reaction conditions, passing a hydrocarbon fraction feedstock containing phenylacetylene and styrene through a combined bed reactor containing a catalyst A and a catalyst B to contact the feedstock with the catalyst A and the catalyst B in turn, wherein the catalyst A is a nickel-based catalyst, the catalyst B is at least one selected from the group consisting of palladium-based catalysts and copper-based catalysts, and a weight ratio of the catalyst A loaded to the catalyst B loaded is from 0.5:1 to 5:1.

    摘要翻译： 本发明公开了在合并床中进行苯乙烯选择性氢化的方法，该方法包括在氢化反应条件下，将含有苯基乙炔和苯乙烯的烃馏分原料通过含有催化剂A和 依次将原料与催化剂A和催化剂B接触的催化剂B，其中催化剂A是镍基催化剂，催化剂B是选自钯基催化剂和铜基催化剂中的至少一种 催化剂，负载催化剂B的催化剂A的重量比为0.5:1〜5:1。

    Process for selective oxidative dehydrogenation of a hydrogen-containing CO mixed gas
    9.
    发明授权
    Process for selective oxidative dehydrogenation of a hydrogen-containing CO mixed gas 有权
    含氢CO混合气的选择性氧化脱氢方法

    公开(公告)号：US08574522B2

    公开(公告)日：2013-11-05

    申请号：US13087798

    申请日：2011-04-15

    申请人： Juntao Liu ,  Siqin Li ,  Linna Zhang ,  Lei Li ,  Jun Kuai

    发明人： Juntao Liu ,  Siqin Li ,  Linna Zhang ,  Lei Li ,  Jun Kuai

    IPC分类号： C01B17/16 ,  C07C7/152

    CPC分类号： B01J35/0006 ,  B01J23/44 ,  B01J23/63 ,  B01J29/46 ,  B01J29/48 ,  C10K3/04

    摘要： A process for selective oxidative dehydrogenation of a hydrogen-containing CO mixed gas, comprising contacting a hydrogen-containing CO mixed gas raw material with at least one catalyst entity having an increased activity gradient disposed in a reactor under at least one reaction condition chosen from a reaction temperature ranging from 100 to 300° C., a volume space velocity ranging from 100 to 10000 h−1, and a reaction pressure ranging from −0.08 to 5.0 MPa, wherein the molar ratio of oxygen to hydrogen in the raw material ranges from 0.5:1 to 5:1.

    摘要翻译： 一种用于含氢CO混合气体的选择性氧化脱氢的方法，包括使含氢CO混合气体原料与设置在反应器中的活化梯度增加的至少一个催化剂实体在至少一个反应条件下接触，所述反应条件选自 反应温度为100〜300℃，体积空间速度为100〜10000h -1，反应压力为-0.08〜5.0MPa，原料中氧与氢的摩尔比为 0.5：1至5：1。

    Process for producing Cl-C4 alkyl nitrite
    10.
    发明授权
    Process for producing Cl-C4 alkyl nitrite 有权
    制备C1-C4烷基亚硝酸盐的方法

    公开(公告)号：US08722918B2

    公开(公告)日：2014-05-13

    申请号：US13088253

    申请日：2011-04-15

    申请人： Juntao Liu ,  Siqin Li ,  Lei Li ,  Linna Zhang

    发明人： Juntao Liu ,  Siqin Li ,  Lei Li ,  Linna Zhang

    IPC分类号： C07C201/04

    CPC分类号： C07C201/04 ,  C07C203/00

    摘要： The present invention relates to a process for producing C1-C4 alkyl nitrite, comprising loading a resin catalyst layer and/or a porous filler layer into a reactor, passing nitrogen oxide, oxygen and C1-C4 alkanol as raw materials through the resin catalyst layer and/or porous filler layer in a counter current, parallel current or cross current manner, reacting under the conditions including a reaction temperature of from 0 to 150° C., a reaction pressure of from −0.09 to 1.5 MPa, a molar ratio of C1-C4 alkanol/nitrogen oxide of 1-100:1, a molar ratio of nitrogen oxide/oxygen of 4-50:1, to obtain an effluent containing C1-C4 alkyl nitrite, wherein said nitrogen oxide is NO, or a mixed gas containing NO and one or more selected from N2O3 and NO2.

    摘要翻译： 本发明涉及一种生产C1-C4烷基亚硝酸盐的方法，包括将树脂催化剂层和/或多孔填料层装入反应器中，使氮氧化物，氧和C1-C4链烷醇作为原料通过树脂催化剂层 和/或多孔填料层，以相对电流，并联电流或交叉电流方式，在0〜150℃的反应温度，-0.09〜1.5MPa的反应压力，-0.09〜1.5MPa的反应压力， C1-C4链烷醇/氮氧化物为1-100:1，氮氧化物/氧摩尔比为4-50:1，得到含有C 1 -C 4烷基亚硝酸盐的流出物，其中所述氮氧化物为NO，或混合 含有NO和选自N 2 O 3和NO 2中的一种或多种的气体。