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    Method for selective hydrogenation of phenylacetylene using composite bed in the presence of styrene
    1.
    发明授权
    Method for selective hydrogenation of phenylacetylene using composite bed in the presence of styrene 有权
    在苯乙烯存在下使用复合床选择性氢化苯乙炔的方法

    公开(公告)号：US08916736B2

    公开(公告)日：2014-12-23

    申请号：US13140645

    申请日：2009-12-17

    申请人： Siqin Li ,  Juntao Liu ,  Zhiyan Zhu ,  Junhua Zhu ,  Jun Kuai

    发明人： Siqin Li ,  Juntao Liu ,  Zhiyan Zhu ,  Junhua Zhu ,  Jun Kuai

    IPC分类号： C07C5/11 ,  C07C7/167

    CPC分类号： C07C7/167 ,  C07C15/46

    摘要： The present invention discloses a process for the selective hydrogenation of phenylacetylene in the presence of styrene conducted in a combined bed, which process comprises under hydrogenation reaction conditions, passing a hydrocarbon fraction feedstock containing phenylacetylene and styrene through a combined bed reactor containing a catalyst A and a catalyst B to contact the feedstock with the catalyst A and the catalyst B in turn, wherein the catalyst A is a nickel-based catalyst, the catalyst B is at least one selected from the group consisting of palladium-based catalysts and copper-based catalysts, and a weight ratio of the catalyst A loaded to the catalyst B loaded is from 0.5:1 to 5:1.

    摘要翻译： 本发明公开了在合并床中进行苯乙烯选择性氢化的方法，该方法包括在氢化反应条件下，将含有苯基乙炔和苯乙烯的烃馏分原料通过含有催化剂A和 依次将原料与催化剂A和催化剂B接触的催化剂B，其中催化剂A是镍基催化剂，催化剂B是选自钯基催化剂和铜基催化剂中的至少一种 催化剂，负载催化剂B的催化剂A的重量比为0.5:1〜5:1。

    PROCESS FOR SELECTIVE OXIDATIVE DEHYDROGENATION OF A HYDROGEN-CONTAINING CO MIXED GAS
    2.
    发明申请
    PROCESS FOR SELECTIVE OXIDATIVE DEHYDROGENATION OF A HYDROGEN-CONTAINING CO MIXED GAS 有权
    含氢混合气体的选择性氧化脱氢方法

    公开(公告)号：US20110263726A1

    公开(公告)日：2011-10-27

    申请号：US13087798

    申请日：2011-04-15

    申请人： Juntao Liu ,  Siqin Li ,  Linna Zhang ,  Lei Li ,  Jun Kuai

    发明人： Juntao Liu ,  Siqin Li ,  Linna Zhang ,  Lei Li ,  Jun Kuai

    IPC分类号： C07C27/00

    CPC分类号： B01J35/0006 ,  B01J23/44 ,  B01J23/63 ,  B01J29/46 ,  B01J29/48 ,  C10K3/04

    摘要： A process for selective oxidative dehydrogenation of a hydrogen-containing CO mixed gas, comprising contacting a hydrogen-containing CO mixed gas raw material with at least one catalyst entity having an increased activity gradient disposed in a reactor under at least one reaction condition chosen from a reaction temperature ranging from 100 to 300° C., a volume space velocity ranging from 100 to 10000 h−1, and a reaction pressure ranging from −0.08 to 5.0 MPa, wherein the molar ratio of oxygen to hydrogen in the raw material ranges from 0.5:1 to 5:1.

    摘要翻译： 一种用于含氢CO混合气体的选择性氧化脱氢的方法，包括使含氢CO混合气体原料与设置在反应器中的活化梯度增加的至少一个催化剂实体在至少一个反应条件下接触，所述反应条件选自 反应温度为100〜300℃，体积空间速度为100〜10000h -1，反应压力为-0.08〜5.0MPa，原料中氧与氢的摩尔比为 0.5：1至5：1。

    Process for selective oxidative dehydrogenation of a hydrogen-containing CO mixed gas
    3.
    发明授权
    Process for selective oxidative dehydrogenation of a hydrogen-containing CO mixed gas 有权
    含氢CO混合气的选择性氧化脱氢方法

    公开(公告)号：US08574522B2

    公开(公告)日：2013-11-05

    申请号：US13087798

    申请日：2011-04-15

    申请人： Juntao Liu ,  Siqin Li ,  Linna Zhang ,  Lei Li ,  Jun Kuai

    发明人： Juntao Liu ,  Siqin Li ,  Linna Zhang ,  Lei Li ,  Jun Kuai

    IPC分类号： C01B17/16 ,  C07C7/152

    CPC分类号： B01J35/0006 ,  B01J23/44 ,  B01J23/63 ,  B01J29/46 ,  B01J29/48 ,  C10K3/04

    摘要： A process for selective oxidative dehydrogenation of a hydrogen-containing CO mixed gas, comprising contacting a hydrogen-containing CO mixed gas raw material with at least one catalyst entity having an increased activity gradient disposed in a reactor under at least one reaction condition chosen from a reaction temperature ranging from 100 to 300° C., a volume space velocity ranging from 100 to 10000 h−1, and a reaction pressure ranging from −0.08 to 5.0 MPa, wherein the molar ratio of oxygen to hydrogen in the raw material ranges from 0.5:1 to 5:1.

    摘要翻译： 一种用于含氢CO混合气体的选择性氧化脱氢的方法，包括使含氢CO混合气体原料与设置在反应器中的活化梯度增加的至少一个催化剂实体在至少一个反应条件下接触，所述反应条件选自 反应温度为100〜300℃，体积空间速度为100〜10000h -1，反应压力为-0.08〜5.0MPa，原料中氧与氢的摩尔比为 0.5：1至5：1。

    Process for Producing Cl-C4 Alkyl Nitrite
    4.
    发明申请
    Process for Producing Cl-C4 Alkyl Nitrite 有权
    生产Cl-C4烷基亚硝酸盐的方法

    公开(公告)号：US20110257425A1

    公开(公告)日：2011-10-20

    申请号：US13088253

    申请日：2011-04-15

    申请人： Juntao Liu ,  Siqin Li ,  Lei Li ,  Linna Zhang

    发明人： Juntao Liu ,  Siqin Li ,  Lei Li ,  Linna Zhang

    IPC分类号： C07C203/00

    CPC分类号： C07C201/04 ,  C07C203/00

    摘要： The present invention relates to a process for producing C1-C4 alkyl nitrite, comprising loading a resin catalyst layer and/or a porous filler layer into a reactor, passing nitrogen oxide, oxygen and C1-C4 alkanol as raw materials through the resin catalyst layer and/or porous filler layer in a counter current, parallel current or cross current manner, reacting under the conditions including a reaction temperature of from 0 to 150° C., a reaction pressure of from −0.09 to 1.5 MPa, a molar ratio of C1-C4 alkanol/nitrogen oxide of 1-100:1, a molar ratio of nitrogen oxide/oxygen of 4-50:1, to obtain an effluent containing C1-C4 alkyl nitrite, wherein said nitrogen oxide is NO, or a mixed gas containing NO and one or more selected from N2O3 and NO2.

    摘要翻译： 本发明涉及一种生产C1-C4烷基亚硝酸盐的方法，包括将树脂催化剂层和/或多孔填料层装入反应器中，使氮氧化物，氧和C1-C4链烷醇作为原料通过树脂催化剂层 和/或多孔填料层，以相对电流，并联电流或交叉电流方式，在0〜150℃的反应温度，-0.09〜1.5MPa的反应压力，-0.09〜1.5MPa的反应压力， C1-C4链烷醇/氮氧化物为1-100:1，氮氧化物/氧摩尔比为4-50:1，得到含有C 1 -C 4烷基亚硝酸盐的流出物，其中所述氮氧化物为NO，或混合 含有NO和选自N 2 O 3和NO 2中的一种或多种的气体。

    Processes for producing an oxalate by coupling of CO
    6.
    发明授权
    Processes for producing an oxalate by coupling of CO 有权
    通过CO的偶联生产草酸盐的方法

    公开(公告)号：US08269036B2

    公开(公告)日：2012-09-18

    申请号：US12642590

    申请日：2009-12-18

    申请人： Juntao Liu ,  Zhiyan Zhu ,  Wanmin Wang ,  Lei Li

    发明人： Juntao Liu ,  Zhiyan Zhu ,  Wanmin Wang ,  Lei Li

    IPC分类号： C07C67/36

    CPC分类号： C07C67/36 ,  C07C69/36

    摘要： Provided are processes for producing an oxalate by coupling of CO in the presence of a nitrite, wherein two or more reaction zones in series are used, and at least a portion of the oxalate as reaction product is separated between the reaction zones, and/or the nitrite is fed stagewise. The processes described herein can effectively enhance the selectivity to the oxalate and the single-pass conversion of the feedstock.

    摘要翻译： 本发明提供了在亚硝酸盐存在下偶联CO的方法，其中使用两个或更多个串联的反应区，并且至少一部分草酸盐作为反应产物在反应区之间分离，和/或 亚硝酸盐逐步进料。 本文所述的方法可以有效地提高对草酸盐的选择性和原料的单程转化。

    Process for producing Cl-C4 alkyl nitrite
    8.
    发明授权
    Process for producing Cl-C4 alkyl nitrite 有权
    制备C1-C4烷基亚硝酸盐的方法

    公开(公告)号：US08722918B2

    公开(公告)日：2014-05-13

    申请号：US13088253

    申请日：2011-04-15

    申请人： Juntao Liu ,  Siqin Li ,  Lei Li ,  Linna Zhang

    发明人： Juntao Liu ,  Siqin Li ,  Lei Li ,  Linna Zhang

    IPC分类号： C07C201/04

    CPC分类号： C07C201/04 ,  C07C203/00

    摘要： The present invention relates to a process for producing C1-C4 alkyl nitrite, comprising loading a resin catalyst layer and/or a porous filler layer into a reactor, passing nitrogen oxide, oxygen and C1-C4 alkanol as raw materials through the resin catalyst layer and/or porous filler layer in a counter current, parallel current or cross current manner, reacting under the conditions including a reaction temperature of from 0 to 150° C., a reaction pressure of from −0.09 to 1.5 MPa, a molar ratio of C1-C4 alkanol/nitrogen oxide of 1-100:1, a molar ratio of nitrogen oxide/oxygen of 4-50:1, to obtain an effluent containing C1-C4 alkyl nitrite, wherein said nitrogen oxide is NO, or a mixed gas containing NO and one or more selected from N2O3 and NO2.

    摘要翻译： 本发明涉及一种生产C1-C4烷基亚硝酸盐的方法，包括将树脂催化剂层和/或多孔填料层装入反应器中，使氮氧化物，氧和C1-C4链烷醇作为原料通过树脂催化剂层 和/或多孔填料层，以相对电流，并联电流或交叉电流方式，在0〜150℃的反应温度，-0.09〜1.5MPa的反应压力，-0.09〜1.5MPa的反应压力， C1-C4链烷醇/氮氧化物为1-100:1，氮氧化物/氧摩尔比为4-50:1，得到含有C 1 -C 4烷基亚硝酸盐的流出物，其中所述氮氧化物为NO，或混合 含有NO和选自N 2 O 3和NO 2中的一种或多种的气体。

    METHOD FOR PRODUCING ETHYLENE GLYCOL FROM OXALATE THROUGH THE FLUIDIZED BED CATALYTIC REACTION
    9.
    发明申请
    METHOD FOR PRODUCING ETHYLENE GLYCOL FROM OXALATE THROUGH THE FLUIDIZED BED CATALYTIC REACTION 有权
    通过流化床催化反应从氧化铝生产乙烯甘油的方法

    公开(公告)号：US20130331617A1

    公开(公告)日：2013-12-12

    申请号：US14000876

    申请日：2012-02-24

    申请人： Weimin Yang ,  Juntao Liu ,  Wanmin Wang ,  Jun Kuai

    发明人： Weimin Yang ,  Juntao Liu ,  Wanmin Wang ,  Jun Kuai

    IPC分类号： C07C29/149

    CPC分类号： C07C29/149 ,  B01J23/83 ,  B01J23/84 ,  B01J23/8437 ,  B01J23/888 ,  B01J29/48 ,  Y02P20/52 ,  C07C31/202

    摘要： A process for producing ethylene glycol includes contacting an oxalate with a fluidized bed catalyst under the following conditions: a reaction temperature of from about 170 to about 270° C., a weight space velocity of oxalate of from about 0.2 to about 7 hours−1, a hydrogen/ester molar ratio of about 20˜200:1, a reaction pressure of from about 1.5 to about 10 MPa, and a reaction temperature difference T of from about 1 to about 15° C. The fluidized bed catalyst includes: a) from about 5 to about 80 parts by weight of copper and the oxide thereof, b) from about 10 to about 90 parts by weight of at least one carrier selected from silica, molecular sieve or alumina, c) from about 0.01 to about 30 parts by weight of bismuth and tungsten metallic elements or the oxides thereof, or cerium and niobium metallic elements or the oxides thereof.

    摘要翻译： 制备乙二醇的方法包括在以下条件下使草酸盐与流化床催化剂接触：反应温度为约170至约270℃，草酸的重量空间速度为约0.2至约7小时-1 氢/酯摩尔比为约20〜200:1，反应压力为约1.5〜10MPa，反应温度差T为约1〜约15℃。流化床催化剂包括： ）约5至约80重量份的铜及其氧化物，b）约10至约90重量份的至少一种选自二氧化硅，分子筛或氧化铝的载体，c）约0.01至约30 铋和钨金属元素或其氧化物或铈和铌金属元素或其氧化物的重量份。

    PROCESS OF PRODUCING OXALATE BY CO GAS PHASE METHOD
    10.
    发明申请
    PROCESS OF PRODUCING OXALATE BY CO GAS PHASE METHOD 有权
    通过气相法制备氧化铝的方法

    公开(公告)号：US20130197265A1

    公开(公告)日：2013-08-01

    申请号：US13641457

    申请日：2011-04-13

    申请人： Juntao Liu ,  Fengxia Sun ,  Jun Kuai

    发明人： Juntao Liu ,  Fengxia Sun ,  Jun Kuai

    IPC分类号： C07C67/18

    CPC分类号： C07C67/18 ,  B01J21/04 ,  B01J21/063 ,  B01J23/6562 ,  B01J23/8926 ,  B01J23/894 ,  B01J23/8946 ,  B01J23/8973 ,  C07C67/36 ,  C07C69/38

    摘要： The present invention relates to a process of producing oxalate by CO gas phase method for chiefly solving the technical problem of the low utilization efficiency of nitrogen oxides or nitrous acid esters in the prior art. The present invention solves the problem in a better way by using the following steps including: a gas phase stream V containing NO and methanol and oxygen enter a supergravity rotating bed reactor II and are subjected to the oxidative esterification reaction to produce an effluent VI containing methyl nitrite; a methyl nitrite effluent VII obtained from separating said effluent VI together with a CO gas II enter a coupling reactor II and is contacted with a catalyst II to react to form a dimethyl oxalate effluent VIII and a gas phase effluent IX containing NO; the resultant dimethyl oxalate effluent VIII is separated to obtain a dimethyl oxalate product I; optionally, the gas phase effluent IX containing NO is returned to the step above so as to be mixed with the gas phase stream V containing NO for being recycled. Therefore, the process is applicable to the industrial production of oxalate by CO gas phase method.

    摘要翻译： 本发明涉及一种通过CO气相法生产草酸盐的方法，主要解决现有技术中氮氧化物或亚硝酸酯利用率低的技术问题。 本发明通过使用以下步骤更好地解决了该问题，包括：含有NO和甲醇和氧的气相流V进入超重力旋转床反应器II，并进行氧化酯化反应以产生含有甲基 亚硝酸盐 通过将CO 2气体II与所述流出物VI分离而获得的亚硝酸甲酯流出物VII进入偶联反应器II，并与催化剂II接触以进行反应以形成草酸二乙酯流出物VIII和含有NO的气相流出物IX; 将得到的草酸二甲酯流出物VIII分离得到草酸二甲酯产物I; 任选地，将含有NO的气相流出物IX返回到上述步骤，以与含有NO的气相物流V混合以进行再循环。 因此，该方法适用于CO气相法工业生产草酸盐。