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公开(公告)号：US07229548B2
公开(公告)日：2007-06-12
申请号：US10677697
申请日：2003-10-02
申请人： Kenneth L. Riley , Stuart L. Soled , Sabato Miseo , Frans L. Plantenga , Marinus Bruce Cerfontain , Sonja Eijsbouts , Eelko Brevoord
发明人： Kenneth L. Riley , Stuart L. Soled , Sabato Miseo , Frans L. Plantenga , Marinus Bruce Cerfontain , Sonja Eijsbouts , Eelko Brevoord
CPC分类号： C10G65/12 , B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G2400/10 , C10G2400/14 , C08F240/00
摘要： A method for upgrading a naphtha feed to a naphtha product containing less than about 10 wppm of nitrogen and less than about 15 wppm sulfur, the method comprising contacting said naphtha feed with hydrogen in the presence of a bulk multimetallic catalyst under effective reactor conditions to hydrodesulfurize and hydrodenitrogenize said naphtha feed to produce said naphtha product, wherein said bulk multimetallic catalyst comprises at least one Group VIII non-noble metal and at least two Group VIB metals.
摘要翻译： 一种将石脑油进料升级成含有小于约10wppm氮和小于约15wppm硫的石脑油产品的方法，所述方法包括在有效反应器条件下在大量多金属催化剂存在下使所述石脑油进料与氢气接触以加氢脱硫 并且对所述石脑油进料进行加氢脱氮以产生所述石脑油产品，其中所述本体多金属催化剂包含至少一种第VIII族非贵金属和至少两种VIB族金属。
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公开(公告)号：US08067331B2
公开(公告)日：2011-11-29
申请号：US12091322
申请日：2006-10-25
申请人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Marinus Bruce Cerfontain , Frans L. Plantenga , Eelco Titus Carel Vogt , Jacobus Nicolaas Louwen , Stuart Leon Soled , Sabato Miseo , Kenneth L. Riley
发明人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Marinus Bruce Cerfontain , Frans L. Plantenga , Eelco Titus Carel Vogt , Jacobus Nicolaas Louwen , Stuart Leon Soled , Sabato Miseo , Kenneth L. Riley
IPC分类号： C10G45/04
CPC分类号： B01J23/888 , B01J23/002 , B01J35/002 , B01J37/0009 , B01J37/03 , B01J37/10 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/202 , B01J2523/69 , B01J2523/847 , B01J2523/68 , B01J2523/56
摘要： The invention relates to a nickel tungsten bulk catalyst, to a process for the manufacture of said catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock. The catalyst comprises nickel tungsten metal oxidic particles obtainable by a process comprising forming a slurry of a first solid metal compound comprising Group VNI metal nickel and a second solid metal compound comprising Group VIB metal tungsten in a protic liquid, reacting the first and second solid metal compounds at elevated temperature whereby the first and second solid metal compounds remain at least partly in the solid state during the entire reaction to form the nickel tungsten oxidic bulk catalyst.
摘要翻译： 本发明涉及镍钨体积催化剂，制备所述催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。 该催化剂包括可通过以下工艺获得的镍钨金属氧化物颗粒，所述方法包括在质子液体中形成包含VNI族金属镍的第一固体金属化合物和包含第VIB族金属钨的第二固体金属化合物的浆料，使第一和第二固体金属 化合物在高温下由此第一和第二固体金属化合物在整个反应期间保持至少部分为固体状态以形成镍钨氧化物本体催化剂。
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公开(公告)号：US20090127165A1
公开(公告)日：2009-05-21
申请号：US12091322
申请日：2006-10-25
申请人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Marinus Bruce Cerfontain , Frans L. Plantenga , Eelco Titus Carel Vogt , Jacobus Nicolaas Louwen , Stuart Leon Soled , Sabato Miseo , Kenneth L. Riley
发明人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Marinus Bruce Cerfontain , Frans L. Plantenga , Eelco Titus Carel Vogt , Jacobus Nicolaas Louwen , Stuart Leon Soled , Sabato Miseo , Kenneth L. Riley
IPC分类号： C10G45/04 , B01J23/888
CPC分类号： B01J23/888 , B01J23/002 , B01J35/002 , B01J37/0009 , B01J37/03 , B01J37/10 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/202 , B01J2523/69 , B01J2523/847 , B01J2523/68 , B01J2523/56
摘要： The invention relates to a nickel tungsten bulk catalyst, to a process for the manufacture of said catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock. The catalyst comprises nickel tungsten metal oxidic particles obtainable by a process comprising forming a slurry of a first solid metal compound comprising Group VNI metal nickel and a second solid metal compound comprising Group VIB metal tungsten in a protic liquid, reacting the first and second solid metal compounds at elevated temperature whereby the first and second solid metal compounds remain at least partly in the solid state during the entire reaction to form the nickel tungsten oxidic bulk catalyst.
摘要翻译： 本发明涉及镍钨体积催化剂，制备所述催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。 该催化剂包括可通过以下工艺获得的镍钨金属氧化物颗粒，所述方法包括在质子液体中形成包含VNI族金属镍的第一固体金属化合物和包含第VIB族金属钨的第二固体金属化合物的浆料，使第一和第二固体金属 化合物在高温下由此第一和第二固体金属化合物在整个反应期间保持至少部分为固体状态以形成镍钨氧化物本体催化剂。
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公开(公告)号：US08062508B2
公开(公告)日：2011-11-22
申请号：US11586398
申请日：2006-10-25
IPC分类号： C10G45/00
CPC分类号： B01J23/883 , B01J35/002 , B01J37/0009 , B01J37/03 , B01J37/08 , C10G45/04 , C10G45/08 , C10G65/04 , C10G65/12
摘要： The invention relates to a process for upgrading hydrocarbonaceous feedstreams by hydroprocessing using bulk bimetallic catalysts. More particularly, the invention relates to a catalytic hydrotreating process for the removal of sulfur and nitrogen from a hydrocarbon feed such as a fuel or a lubricating oil feed. The catalyst is a bulk catalyst containing a Group VIII metal and a Group VIB metal.
摘要翻译： 本发明涉及通过使用大量双金属催化剂的加氢处理来改质含烃原料流的方法。 更具体地说，本发明涉及一种用于从诸如燃料或润滑油进料的烃进料中除去硫和氮的催化加氢处理方法。 催化剂是含有VIII族金属和VIB族金属的本体催化剂。
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5.发明授权Bulk bimetallic catalysts, method of making bulk bimetallic catalysts and hydroprocessing using bulk bimetallic catalysts 有权散装双金属催化剂，制造块状双金属催化剂的方法和使用散装双金属催化剂的加氢处理公开(公告)号：US07648941B2
公开(公告)日：2010-01-19
申请号：US11586399
申请日：2006-10-25
CPC分类号： C10G45/08 , B01J23/883 , B01J23/888 , B01J23/8885 , B01J35/1014 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/038 , B01J37/20
摘要： The invention relates to a process for upgrading hydrocarbonaceous feedstreams by hydroprocessing using bulk bimetallic catalysts. More particularly, the invention relates to a catalytic hydrotreating process for the removal of sulfur and nitrogen from a hydrocarbon feed such as a fuel or a lubricating oil feed. The catalyst is a bulk catalyst comprising a Group VIII metal and a Group VIB metal.
摘要翻译： 本发明涉及通过使用大量双金属催化剂的加氢处理来改质含烃原料流的方法。 更具体地说，本发明涉及一种用于从诸如燃料或润滑油进料的烃进料中除去硫和氮的催化加氢处理方法。 该催化剂是包含VIII族金属和VIB族金属的本体催化剂。
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6.发明授权公开(公告)号：US07686943B2
公开(公告)日：2010-03-30
申请号：US11586397
申请日：2006-10-25
CPC分类号： B01J23/888 , B01J23/002 , B01J23/85 , B01J35/002 , B01J37/0072 , B01J37/0236 , B01J37/03 , B01J37/10 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G47/04 , C10G2300/202 , C10G2300/207 , C10G2400/04 , C10G2400/10 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/56
摘要： The invention relates to a process for upgrading hydrocarbonaceous feedstreams by hydroprocessing using bulk bimetallic catalysts. More particularly, the invention relates to a catalytic hydrotreating process for the removal of sulfur and nitrogen from a hydrocarbon feed such as a fuel or a lubricating oil feed. The catalyst is a bulk catalyst containing at leas one Group VIII metal and at least one Group VIB metal. The catalyst is prepared hydrothermally.
摘要翻译： 本发明涉及通过使用大量双金属催化剂的加氢处理来改质含烃原料流的方法。 更具体地说，本发明涉及一种用于从诸如燃料或润滑油进料的烃进料中除去硫和氮的催化加氢处理方法。 该催化剂是含有一种Ⅷ族金属和至少一种ⅥB族金属的大量催化剂。 催化剂水热制备。
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7.发明授权公开(公告)号：US06635599B1
公开(公告)日：2003-10-21
申请号：US09482811
申请日：2000-01-13
申请人： Sonja Eijsbouts , Bob Gerardus Oogjen , Hermannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
发明人： Sonja Eijsbouts , Bob Gerardus Oogjen , Hermannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
IPC分类号： B01J2300
CPC分类号： B01J23/8885 , B01J23/85 , B01J23/883 , B01J37/0009 , B01J37/0236 , B01J37/031 , B01J37/082 , B01J37/20 , C10G45/08 , C10G49/04
摘要： The present invention relates to a process for the preparation of a hydroprocessing catalyst, to the catalyst composition obtainable by said process, and to the use of said catalyst composition in hydroprocessing applications. The process comprises the steps of combining and reacting at least one Group VIII non-noble metal component in solution and at least two Group VIB metal components in solution in a reaction mixture to obtain an oxygen-stable precipitate, and sulfiding the precipitate.
摘要翻译： 本发明涉及一种制备加氢处理催化剂的方法，可通过所述方法获得的催化剂组合物以及所述催化剂组合物在加氢处理应用中的用途。 该方法包括以下步骤：将至少一种溶液中的第VIII族非贵金属组分和至少两种VIB族金属组分混合并在反应混合物中溶解，得到氧稳定的沉淀物，并使沉淀物硫化。
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公开(公告)号：US06534437B2
公开(公告)日：2003-03-18
申请号：US09836101
申请日：2001-04-17
申请人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
发明人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
IPC分类号： B01J27043
CPC分类号： B01J35/002 , B01J23/85 , B01J23/8885 , B01J35/0053 , B01J35/008 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0236 , B01J37/031 , B01J37/20 , C10G49/04
摘要： The invention pertains to a process for preparing a catalyst composition comprising bulk catalyst particles comprising at least one Group VIII non-noble metal and at least two Group VIB metals. The process comprises combining and reacting at least one Group VIII non-noble metal component with at least two Group VIB metal components in the presence of a protic liquid, with at least one of the metal components remaining at least partly in the solid state during the entire process. The Group VIII and Group VIB metals comprise from about 50 wt. % to about 100 wt. %, calculated as oxides, of the total weight of said bulk catalyst particles, with the solubility of those of the metal components which are at least partly in the solid state during the reaction being less than 0.05 mol/100 ml water at 18° C. The invention also covers a catalyst composition made by that process and a process for the hydroprocessing of a hydrocarbon feedstock by contacting the feedstock with that catalyst at hydroprocessing conditions.
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公开(公告)号：US20050040080A1
公开(公告)日：2005-02-24
申请号：US10677697
申请日：2003-10-02
申请人： Kenneth Riley , Stuart Soled , Sabato Miseo , Frans Plantenga , Marinus Cerfontain , Sonja Eijsbouts , Eelko Brevoord
发明人： Kenneth Riley , Stuart Soled , Sabato Miseo , Frans Plantenga , Marinus Cerfontain , Sonja Eijsbouts , Eelko Brevoord
IPC分类号： B01J23/00 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/888 , B01J37/03 , B01J37/08 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G47/12 , C10G49/04 , C10G65/02 , C10G65/04 , C10G65/08 , C10G65/12 , C10G67/04 , C10G45/00
CPC分类号： C10G65/12 , B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G2400/10 , C10G2400/14 , C08F240/00
摘要： A method for upgrading a naphtha feed to a naphtha product containing less than about 10 wppm of nitrogen and less than about 15 wppm sulfur, the method comprising contacting said naphtha feed with hydrogen in the presence of a bulk multimetallic catalyst under effective reactor conditions to hydrodesulfurize and hydrodenitrogenize said naphtha feed to produce said naphtha product, wherein said bulk multimetallic catalyst comprises at least one Group VIII non-noble metal and at least two Group VIB metals.
摘要翻译： 一种将石脑油进料升级成含有小于约10wppm氮和小于约15wppm硫的石脑油产品的方法，所述方法包括在有效反应器条件下在大量多金属催化剂存在下使所述石脑油进料与氢气接触以加氢脱硫 并且对所述石脑油进料进行加氢脱氮以产生所述石脑油产品，其中所述本体多金属催化剂包含至少一种第VIII族非贵金属和至少两种VIB族金属。
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公开(公告)号：US06652738B2
公开(公告)日：2003-11-25
申请号：US10346018
申请日：2003-01-16
申请人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
发明人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
IPC分类号： C10G4504
CPC分类号： B01J35/002 , B01J23/85 , B01J23/8885 , B01J35/0053 , B01J35/008 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0236 , B01J37/031 , B01J37/20 , C10G49/04
摘要： The invention pertains to a process for the hydroprocessing of a hydrocarbon feedstock wherein said feedstock is contacted at hydroprocessing conditions with a catalyst composition which comprises bulk catalyst particles which comprise at least one Group VIII non-noble metal and at least two Group VIB metals. The Group VIII and Group VIB metals comprise from about 50 wt. % to about 100 wt. %, calculated as oxides, of the total weight of the bulk catalyst particles. The metals are present in the catalyst composition in their oxidic and/or sulfidic state. The catalyst composition has an X-ray diffraction pattern in which the characteristic full width at half maximum does not exceed 2.5° when the Group VIB metals are molybdenum, tungsten, and, optionally, chromium, or does not exceed 4.0° when the Group VIB metals are molybdenum and chromium or tungsten and chromium.
摘要翻译： 本发明涉及烃原料的加氢处理方法，其中所述原料在加氢处理条件下与催化剂组合物接触，所述催化剂组合物包含包含至少一种VIII族非贵金属和至少两种VIB族金属的本体催化剂颗粒。 VIII族和VIB族金属包含约50wt。 ％至约100重量％ 以体积催化剂颗粒的总重量计算的氧化物％。 金属以其氧化和/或硫化态存在于催化剂组合物中。 催化剂组合物具有X射线衍射图，其中当VIB族金属为钼，钨和任选的铬时，半峰的特征全宽度不超过2.5°，当VIB族VIB金属为不超过4.0°时 金属是钼和铬或钨和铬。
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