Thermoplastic polyurethane elastomers
    1.
    发明授权
    Thermoplastic polyurethane elastomers 失效
    热塑性聚氨酯弹性体

    公开(公告)号:US06417312B1

    公开(公告)日:2002-07-09

    申请号:US08655783

    申请日:1996-05-31

    IPC分类号: C08G1810

    摘要: A process for the production of thermoplastic polyurethane elastomer is disclosed. The process entails (a) introducing and homogeneously mixing in a first static mixer (A) an isocyanate and (B) a mixture of compounds having an average of 1.8 to 3.0 Zerewitinoff active hydrogen atoms having a molecular weight of 400 to 10000 with and chain extenders having an average of 1.8 to 3.0 Zerewitinoff active hydrogen atoms and a molecular weight of 62 to 400 and optional auxiliaries to form a substantially unreacted mixture and (b) reacting said substantially unreacted mixture in a second static mixer to form thermoplastic polyurethane elastomer. The elastomer thus produced has improved mechanical properties and is suitable for the production of moldings.

    摘要翻译: 公开了一种生产热塑性聚氨酯弹性体的方法。 该方法需要(a)在第一静态混合器(A)中引入并均匀混合异氰酸酯和(B)具有平均1.8至3.0的分子量为400至10000的齐来维诺活性氢原子的化合物与链和 具有平均1.8-3.0的Zerewitinoff活性氢原子和分子量为62-400的增量剂和任选的助剂以形成基本上未反应的混合物,和(b)使所述基本上未反应的混合物在第二静态混合器中反应形成热塑性聚氨酯弹性体。 由此制造的弹性体具有改善的机械性能,并且适于制造模制品。

    Thermoplastic polyurethaneurea elastomers
    2.
    发明授权
    Thermoplastic polyurethaneurea elastomers 失效
    热塑性聚氨酯脲弹性体

    公开(公告)号:US5739252A

    公开(公告)日:1998-04-14

    申请号:US657852

    申请日:1996-05-31

    摘要: Thermoplastic polyurethaneurea elastomers prepared from organic polyisocyanates (A) and a mixture (B) containing Zerewitinoff active hydrogen atoms are disclosed. The mixture (B) is prepared from 1) 40 to 85 equivalent-% (relative to isocyanate groups in (A)) of one or more compounds having an average of at least 1.8 Zerewitinoff active hydrogen atoms and a number average molecular weight of 400 to 10,000, 2) 10 to 60 equivalent-% (relative to isocyanate groups in (A)) of water and 3) 0 to 45 equivalent-% (relative to isocyanate groups in (A)) of one or more chain extenders having an average of at least 1.8 Zerewitinoff active hydrogen atoms and a molecular weight of 62 to 400. The preparation process comprise mixing (A) and (B) in a static mixer under conditions in which no reaction occurs between (A) and (B), and reacting the mixture in a second static mixer. The resulting polyurethaneurea elastomer is useful for the production of moldings.

    摘要翻译: 公开了由有机多异氰酸酯(A)和含有Zerewitinoff活性氢原子的混合物(B)制备的热塑性聚氨酯脲弹性体。 混合物(B)由1)40至85当量%(相对于(A)中的异氰酸酯基团)制备的平均具有至少1.8兹列维诺夫活性氢原子和数均分子量为400的一种或多种化合物 至10,000,2)10至60当量%(相对于(A)中的异氰酸酯基团))和3)0至45当量%(相对于(A)中的异氰酸酯基团))的一种或多种扩链剂,其具有 平均为至少1.8兹列维诺夫活性氢原子,分子量为62至400.制备方法包括在(A)和(B)之间不发生反应的条件下,在静态混合器中混合(A)和(B) 并在第二静态混合器中使混合物反应。 所得的聚氨酯脲弹性体可用于制造模制品。

    OLIGOMERIC COMPOUNDS WHICH FORM A SEMICONDUCTOR LAYER
    5.
    发明申请
    OLIGOMERIC COMPOUNDS WHICH FORM A SEMICONDUCTOR LAYER 审中-公开
    形成半导体层的低分子化合物

    公开(公告)号:US20090283723A1

    公开(公告)日:2009-11-19

    申请号:US12441153

    申请日:2007-09-11

    IPC分类号: H01B1/12 C07D333/06

    摘要: Oligomeric compounds of the general formula (M), mixtures thereof and electronic components containing the same: wherein L represents a linear conjugated oligomeric chain; wherein each RA and each RB independently represents a moiety selected from the group consisting of linear or branched C2-C20-alkylene radicals, C3-C8-cycloalkylene radicals, mono- or polyunsaturated C2-C20-alkenylene radicals, C2-C20-oxyalkylene radicals, C2-C20-aralkylene radicals or C2-C20-oligo- or C2-C20-polyether radicals; wherein XA and XB each independently represents a moiety selected from optionally substituted vinyl groups, chlorine, iodine, hydroxyl, alkoxy groups having 1 to 3 carbon atoms, alkoxysilyl groups, silyl groups, chlorosilyl groups, siloxane groups, carboxyl groups, methyl or ethyl carbonate groups, aldehyde groups, methylcarbonyl groups, amino groups, amido groups, sulphone groups, sulphonic acid groups, halosulphonyl groups, sulphonate groups, phosphonic acid groups, phosphonate groups, trichloromethyl, tribromomethyl, cyanate groups, isocyanate groups, thiocyanate groups, isothiocyanate groups, cyano groups, nitro groups and H; wherein each Y independently represents a moiety selected from an optionally substituted alkoxysilylene group, silylene group, chlorosilylene group, methylene group, dichloromethylene group, dibromomethylene group, divalent siloxane group, disiloxane group, carboxyl group, carbonate group, amino group, amido group, sulphate group, phosphonate group, phosphate group, borate group, S and O; and wherein n represents an integer of 1 to 10.

    摘要翻译: 通式(M)的低聚化合物,其混合物和含有它们的电子组分:其中L代表线性共轭低聚链; 其中每个RA和每个RB独立地表示选自直链或支链C 2 -C 20 - 亚烷基,C 3 -C 8 - 亚环烷基,单或多不饱和C 2 -C 20亚烯基,C 2 -C 20 - 氧亚烷基 ,C 2 -C 20 - 亚芳基或C 2 -C 20 - 低聚或C 2 -C 20 - 聚醚基团; 其中XA和XB各自独立地表示选自任选取代的乙烯基,氯,碘,羟基,具有1至3个碳原子的烷氧基,烷氧基甲硅烷基,甲硅烷基,氯甲硅烷基,硅氧烷基,羧基,甲基或碳酸乙酯的部分 基团,醛基,甲基羰基,氨基,酰胺基,砜基,磺酸基,卤磺酰基,磺酸酯基,膦酸基,膦酸酯基,三氯甲基,三溴甲基,氰酸酯基,异氰酸酯基,硫氰酸酯基,异硫氰酸酯基, 氰基,硝基和H; 其中每个Y独立地表示选自任选取代的烷氧基亚芳基,亚甲硅烷基,氯亚甲硅基,亚甲基,二氯亚甲基,二溴亚甲基,二价硅氧烷基,二硅氧烷基,羧基,碳酸酯基,氨基,酰胺基,硫酸根 膦酸酯基,磷酸酯基,硼酸酯基,S和O; 并且其中n表示1至10的整数。

    Process for the production of linear organic thiophene-phenylene oligomers
    8.
    发明申请
    Process for the production of linear organic thiophene-phenylene oligomers 失效
    生产线性有机噻吩 - 亚苯基低聚物的方法

    公开(公告)号:US20050098777A1

    公开(公告)日:2005-05-12

    申请号:US10984513

    申请日:2004-11-09

    摘要: The invention relates to a novel process for the production of linear organic thiophene-phenylene oligomers represented by the following general formula (I), The process involves reacting (e.g., by means of a Suzuki coupling reaction) a compound represented by the following general formula (II), with a formula represented by the following general formula (III), YArmY   (III) The reaction may be conducted optionally in the presence of catalysts, optionally in a solution and/or optionally at elevated temperature. The linear organic thiophene-phenylene oligomers of the present invention may be used to form semi-conductive coatings.

    摘要翻译: 本发明涉及一种制备由以下通式(I)表示的线型有机噻吩 - 亚苯基低聚物的新方法:该方法包括使(如通过Suzuki偶联反应)使由以下通式 (II)表示的化合物,具有下列通式(III)表示的式:<?in-line-formula description =“In-line Formulas”end =“lead”?>YAr Y(III)<?in-line-formula description =“In-line Formulas”end =“tail”?>反应可以任选地在催化剂存在下,任选地在溶液中和/或任选地在升高的温度下进行 。 本发明的线性有机噻吩 - 亚苯基低聚物可用于形成半导体涂层。