Aqueous dispersions of polyamides
    1.
    发明授权
    Aqueous dispersions of polyamides 失效
    聚酰胺的水分散体

    公开(公告)号:US5948880A

    公开(公告)日:1999-09-07

    申请号:US852967

    申请日:1997-05-08

    摘要: A process is provided for preparing a dispersion of a polyamide in water, said process comprising:forming a solution of a polyamide having an acid value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of said polyamide during said dissolving, said solution further comprising a surfactant, wherein at least a portion of the acid value of said polyamide is neutralized,adding sufficient water to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, andremoving at least a major amount of said organic solvent from said oil-in-water dispersion. The resulting dispersion is useful in preparing a coating of the polyamide, which coating is useful as an adhesive.

    摘要翻译: 提供了一种制备聚酰胺在水中的分散体的方法,所述方法包括:在有机溶剂中形成具有大于约2的酸值的聚酰胺的溶液以形成所述聚酰胺在所述溶剂中的溶液,所述聚酰胺 并且所述溶剂在所述溶解期间处于低于所述聚酰胺的软化点的温度下,所述溶液还包含表面活性剂,其中所述聚酰胺的至少一部分酸值被中和,向所述溶液中加入足够的水,混合形成 水包油分散体,所述溶液的温度和所述水在所述添加期间低于所述聚酰胺的软化点,以及从所述水包油分散体中除去至少大量的所述有机溶剂。 得到的分散体可用于制备聚酰胺的涂层,该涂层可用作粘合剂。

    Aqueous dispersions of polyamides
    2.
    发明授权
    Aqueous dispersions of polyamides 失效
    聚酰胺的水分散体

    公开(公告)号:US5886135A

    公开(公告)日:1999-03-23

    申请号:US853311

    申请日:1997-05-08

    摘要: A process is provided for preparing a dispersion of a polyamide in water, said process comprising:dissolving a polyamide having an amine value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of said polyamide during said dissolving, said solution further comprising a surfactant and an inorganic alkaline material,adding sufficient water containing an acid to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, the amount of said acid being sufficient to neutralize a portion of said inorganic alkaline material, but insufficient to coagulate said polyamide from the resulting oil-in-water dispersion, andremoving at least a major amount of said organic solvent from said oil-in-water dispersion. The resulting dispersion is useful in preparing a coating of the polyamide, which coating is useful as an adhesive.

    摘要翻译: 提供了一种制备聚酰胺在水中的分散体的方法,所述方法包括:将具有大于约2的胺值的聚酰胺溶解在有机溶剂中以形成所述聚酰胺在所述溶剂中的溶液,所述聚酰胺和所述溶剂 在所述溶解期间在低于所述聚酰胺的软化点的温度下,所述溶液还包含表面活性剂和无机碱性材料,在混合下向所述溶液中加入足够的含有酸的水以形成水包油分散体,所述温度 的所述溶液,并且所述水在所述添加期间低于所述聚酰胺的软化点,所述酸的量足以中和一部分所述无机碱性材料,但不足以使所述聚酰胺从所得水包油分散体中凝结 ,并从所​​述水包油分散体中除去至少大量的所述有机溶剂。 得到的分散体可用于制备聚酰胺的涂层,该涂层可用作粘合剂。

    Aqueous dispersions of polyamides

    公开(公告)号:US5723538A

    公开(公告)日:1998-03-03

    申请号:US738425

    申请日:1996-10-25

    IPC分类号: C08J3/07 C09J177/00 C08K3/00

    摘要: A process is provided for preparing a dispersion of a polyamide in water, said process comprising: dissolving a polyamide having an amine value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of said polyamide during said dissolving, said solution further comprising a surfactant and an inorganic alkaline material, adding sufficient water containing an acid to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, the amount of said acid being sufficient to neutralize a portion of said inorganic alkaline material, but insufficient to coagulate said polyamide from the resulting oil-in-water dispersion, and removing at least a major amount of said organic solvent from said oil-in-water dispersion. The resulting dispersion is useful in preparing a coating of the polyamide, which coating is useful as an adhesive.

    Aqueous dispersions of polymers
    6.
    发明授权
    Aqueous dispersions of polymers 失效
    聚合物的水分散体

    公开(公告)号:US06225398B1

    公开(公告)日:2001-05-01

    申请号:US09045133

    申请日:1998-03-20

    IPC分类号: C08J300

    摘要: A method for formulating an aqueous dispersion of a polymer includes dissolving a polymer such as an acrylic polyol in a solvent to form a polymer solution. A surfactant is added to the polymer solution, and water is then added with mixing sufficient to dispersed the polymer in the water. The resulting aqueous dispersion can be mixed with a water dispersible polyisocyanate to produce coating materials which can be cured to form tough films and coatings.

    摘要翻译: 用于配制聚合物的水性分散体的方法包括将聚合物如丙烯酸多元醇溶解在溶剂中以形成聚合物溶液。 向聚合物溶液中加入表面活性剂,然后加入足以将聚合物分散在水中的混合物。 所得到的水分散体可以与水分散性多异氰酸酯混合以产生可固化以形成韧性膜和涂层的涂料。

    Aqueous thickener composition and process for making same
    7.
    发明授权
    Aqueous thickener composition and process for making same 失效
    水性增稠剂组合物及其制备方法

    公开(公告)号:US5663263A

    公开(公告)日:1997-09-02

    申请号:US676710

    申请日:1996-07-08

    CPC分类号: C08F220/12

    摘要: A water retention aid/thickener composition containing: (a) from about 40 to about 75% by weight of a C.sub.1 -C.sub.8 alkyl acrylate; (b) from about 60 to about 25% by weight of methacrylic acid; and (c) from about 0.1 to about 5% by weight of an alkoxylated acrylate or methacrylate monomer containing at least three vinyl moieties, all weights being based on the weight of the composition.

    摘要翻译: 一种保水助剂/增稠剂组合物,其包含:(a)约40至约75重量%的丙烯酸C1-C8烷基酯; (b)约60至约25重量%的甲基丙烯酸; 和(c)约0.1至约5重量%的含有至少三个乙烯基部分的烷氧基化丙烯酸酯或甲基丙烯酸酯单体,所有重量均基于组合物的重量。

    Methods of preparing inorganic pigment dispersions
    8.
    发明授权
    Methods of preparing inorganic pigment dispersions 失效
    制备无机颜料分散体的方法

    公开(公告)号:US06197879B1

    公开(公告)日:2001-03-06

    申请号:US08713314

    申请日:1996-09-13

    IPC分类号: C08L3506

    摘要: A polymer useful as an inorganic pigment dispersant is provided. The polymer is derived from monomers consisting essentially of an ethylenically unsaturated aromatic monomer, an ethylenically unsaturated dicarboxylic acid monomer, and an ethylenically unsaturated monocarboxylic acid monomer. The total amount of said ethylenically unsaturated acid monomers is sufficient to permit said polymer to associate with an inorganic pigment in an aqueous medium in a manner which disperses said inorganic pigment in said aqueous medium to form a stable aqueous dispersion of said inorganic pigment, and the amount of said ethylenically unsaturated aromatic monomer is sufficient to reduce the water sensitivity of a dried coating of a latex paint comprised of said stable aqueous dispersion of said inorganic pigment. A process of preparing a polymer useful as an inorganic pigment dispersant and a method of preparing an inorganic pigment dispersion useful in the preparation of latex paints are also provided.

    摘要翻译: 提供了可用作无机颜料分散剂的聚合物。 聚合物衍生自主要由烯属不饱和芳族单体,烯键式不饱和二羧酸单体和烯属不饱和单羧酸单体组成的单体。 所述烯属不饱和酸单体的总量足以允许所述聚合物以水性介质中的无机颜料与分散所述无机颜料在所述水性介质中以形成所述无机颜料的稳定水分散体的方式缔合, 所述烯属不饱和芳族单体的量足以降低由所述稳定的所述无机颜料的水性分散体组成的乳胶漆的干燥涂层的水敏感性。 还提供了可用作无机颜料分散剂的聚合物的制备方法和制备用于制备乳胶漆的无机颜料分散体的方法。

    Polymeric thickeners for aqueous compositions
    10.
    发明授权
    Polymeric thickeners for aqueous compositions 失效
    含水组合物的聚合增稠剂

    公开(公告)号:US6002049A

    公开(公告)日:1999-12-14

    申请号:US873773

    申请日:1997-06-12

    摘要: Latexes are thickened by compounds of the formula ##STR1## wherein R.sup.1 is an aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical having a valence of from 2 to 8; each of B.sub.1 -B.sub.8 is independently an ester, amide, amine, ether, sulfide, disulfide, thiocarbamate, urea, thiourea, urethane, sulfate, phosphate, carbonyl, methylene, thioamide, carbonate, or imide linkage; each of X.sup.1 -X.sup.8 is independently --A.sub.1 --R.sup.2 --A.sub.2 -- or --A.sub.1 -- wherein each of A.sub.1 and A.sub.2 is independently an ester, amide, amine, ether, sulfide, disulfide, urethane, thiocarbamate, urea, thiourea, sulfate, phosphate, carbonyl, methylene, thioamide, carbonate, or imide linkage and R.sup.2 is a divalent aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical with the proviso that only one of B.sub.1 -B.sub.8 is urethane and that when one of B.sub.1 -B.sub.8 is urethane, one of A.sub.1 and A.sub.2 is not urethane; each of d, g, j, m, p, s, v, y is independently 0 or 1, each of c, f, i, l, o, r, u, x is independently any integer or non-integer from 0 to about 200; each of J, K, L, M, N, P, Q, S is 0 or 1; each of e, h, k, n, q, t, w, z is independently any integer or non-integer from 0 to about 200; each of R.sup.3 -R.sup.10 is independently an aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical having from 1 to about 50 carbon atoms; each of AG and AO is independently an ethyleneoxy, 1,2-propyleneoxy, 1,2-butyleneoxy unit or combinations thereof.

    摘要翻译: 乳化剂由下式化合物增稠,其中R1是2至8价的脂族,取代的脂族,芳族或取代的芳族基团; 每个B1-B8独立地是酯,酰胺,胺,醚,硫化物,二硫化物,硫代氨基甲酸酯,脲,硫脲,氨基甲酸酯,硫酸酯,磷酸酯,羰基,亚甲基,硫代酰胺,碳酸酯或酰亚胺键; X1-X8各自独立地为-A1-R2-A2-或-A1-,其中A1和A2各自独立地为酯,酰胺,胺,醚,硫醚,二硫化物,氨基甲酸酯,硫代氨基甲酸酯,脲,硫脲,硫酸酯,磷酸酯 ,羰基,亚甲基,硫代酰胺,碳酸酯或酰亚胺键,R 2是二价脂族,取代的脂族,芳族或取代的芳族基团,条件是B1-B8中只有一个是氨基甲酸酯,当B1-B8中的一个是氨基甲酸酯时 A1和A2之一不是氨基甲酸酯; d,g,j,m,p,s,v,y中的每一个独立地为0或1,c,f,i,l,o,r,u,x中的每一个独立地为0以上的整数或非整数 至约200; J,K,L,M,N,P,Q,S中的每一个为0或1; e,h,k,n,q,t,w,z中的每一个独立地为0至约200的任何整数或非整数; 每个R 3 -R 10独立地是具有1至约50个碳原子的脂族,取代的脂族,芳族或取代的芳族基团; AG和AO各自独立地为亚乙氧基,1,2-亚丙氧基,1,2-亚丁基氧基单元或其组合。