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    Bulk Hydroprocessing Catalyst Comprising A Group VIII Metal And Molybdenum, Preparation And Use Thereof
    7.
    发明申请
    Bulk Hydroprocessing Catalyst Comprising A Group VIII Metal And Molybdenum, Preparation And Use Thereof 有权
    包含VIII族金属和钼的大量加氢催化剂，其制备和使用

    公开(公告)号：US20090139904A1

    公开(公告)日：2009-06-04

    申请号：US12091328

    申请日：2006-10-25

    申请人： Sona Eijsbouts-Spickova ,  Jacobus Nicolaas Louwen ,  Frans L. Plantenga ,  Robertus Gerardus Leliveld ,  Sabato Miseo ,  Stuart Leon Soled

    发明人： Sona Eijsbouts-Spickova ,  Jacobus Nicolaas Louwen ,  Frans L. Plantenga ,  Robertus Gerardus Leliveld ,  Sabato Miseo ,  Stuart Leon Soled

    IPC分类号： C10G45/04 ,  B01J23/883 ,  B01J23/882

    CPC分类号： B01J23/88 ,  B01J23/883 ,  B01J23/8877 ,  B01J23/8885 ,  B01J35/002 ,  B01J37/03 ,  B01J37/20 ,  C10G45/08 ,  C10G45/12 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2400/04

    摘要： The invention relates to a bulk catalyst comprising at least 60 wt % metal oxidic particles comprising one or more Group VIII metals and Group VIB metal molybdenum, comprising less than 10 mole % of a second Group VIB metal (relative to the total amount of Group VIB metals) and comprising a Group V metal in an amount less than 10 mole % (relative to the total of the Group VIB metals), which bulk catalyst has been calcined at a temperature below a temperature where the hexagonal metastable crystal structure changes to an inactive crystalline structure, preferably below 450° C. and which bulk catalyst has a metastable hexagonal phase characterized by an X-ray diffraction pattern having reflections at 33-35 and 58-61° 2θ. Preferably, the main reflections have a full width at half maximum (FWHM) of less than 2.5. The invention further relates to a process for the manufacture of the bulk catalyst, to the corresponding sulphided bulk catalyst and to the use of said catalyst or sulphided catalyst in the hydroprocessing, in particular the hydrodesulphurisation and hydrodenitrogenation, of a hydrocarbon feedstock.

    摘要翻译： 本发明涉及一种本体催化剂，其包含至少60重量％的包含一种或多种第VIII族金属和VIB族金属钼的金属氧化物颗粒，其包含小于10摩尔％的第二族VIB金属（相对于VIB族的总量） 金属），并且包含少于10摩尔％（相对于第VIB族金属的总量）的第V族金属，该体积催化剂在低于六方晶系亚稳晶体结构变为不活泼的温度的温度下被煅烧 晶体结构，优选低于450℃，并且该体积催化剂具有亚稳态六方晶相，其特征在于具有在33-35和58-61°2θ之间的反射的X射线衍射图。 优选地，主反射具有小于2.5的半高宽（FWHM）。 本发明还涉及一种用于制造本体催化剂的方法，相应的硫化体积催化剂以及所述催化剂或硫化催化剂在烃原料的加氢处理，特别是加氢脱硫和加氢脱氮中的用途。

    Bulk catalyst comprising metal oxidic particles and a process for the manufacture thereof
    8.
    发明授权
    Bulk catalyst comprising metal oxidic particles and a process for the manufacture thereof 有权
    包含金属氧化物颗粒的散装催化剂及其制造方法

    公开(公告)号：US08394263B2

    公开(公告)日：2013-03-12

    申请号：US12091327

    申请日：2006-10-25

    申请人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Stuart Leon Soled ,  Sabato Miseo

    发明人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Stuart Leon Soled ,  Sabato Miseo

    IPC分类号： B01J23/755

    CPC分类号： B01J37/20 ,  B01J23/85 ,  B01J23/8885 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/10 ,  C10G45/08 ,  C10G2300/202

    摘要： The invention relates to a bulk catalyst having improved activity in hydrodesulphurization, in particular in relatively low Group VIII over Group VIB metal molar ratios. The bulk catalyst comprises metal oxidic particles comprising one or more Group VIB metals and one or more-Group VIII metals which metal oxidic particles are obtainable by a process comprising the steps of reacting the compounds comprising one or more Group VIB metals and compounds comprising one or more Group VIII metals in hydrothermal conditions at a reaction temperature above the boiling temperature of the protic liquid, preferably in an autoclave at a reaction pressure above atmospheric pressure and. The invention also relates to the corresponding sulphided catalyst, to a process for the manufacture of said bulk catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurization and hydrodenitrogenation of hydrocarbon feedstock.

    摘要翻译： 本发明涉及具有改进的加氢脱硫活性的本体催化剂，特别是在VIB族金属摩尔比相对较低的第VIII族。 本体催化剂包含包含一种或多种VIB族金属和一种或多种VIII族金属的金属氧化物颗粒，该金属氧化物颗粒可通过包括以下步骤的方法获得，所述方法包括使包含一种或多种VIB族金属的化合物与包含一种或多种 反应温度高于质子液体沸点温度的水热条件下，优选在反应压力高于大气压的高压釜中。 本发明还涉及相应的硫化催化剂，制备所述本体催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。

    Bulk hydroprocessing catalyst comprising a group VIII metal and molybdenum, preparation and use thereof
    9.
    发明授权
    Bulk hydroprocessing catalyst comprising a group VIII metal and molybdenum, preparation and use thereof 有权
    包含第VIII族金属和钼的本体加氢处理催化剂，其制备和用途

    公开(公告)号：US08486259B2

    公开(公告)日：2013-07-16

    申请号：US12091328

    申请日：2006-10-25

    申请人： Sona Eijsbouts-Spickova ,  Jacobus Nicolaas Louwen ,  Frans L. Plantenga ,  Robertus Gerardus Leliveld ,  Sabato Miseo ,  Stuart Leon Soled

    发明人： Sona Eijsbouts-Spickova ,  Jacobus Nicolaas Louwen ,  Frans L. Plantenga ,  Robertus Gerardus Leliveld ,  Sabato Miseo ,  Stuart Leon Soled

    IPC分类号： C10G45/08 ,  B01J23/88

    CPC分类号： B01J23/88 ,  B01J23/883 ,  B01J23/8877 ,  B01J23/8885 ,  B01J35/002 ,  B01J37/03 ,  B01J37/20 ,  C10G45/08 ,  C10G45/12 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2400/04

    摘要： The invention relates to a bulk catalyst comprising at least 60 wt % metal oxidic particles comprising one or more Group VIII metals and Group VIB metal molybdenum, comprising less than 10 mole % of a second Group VIB metal (relative to the total amount of Group VIB metals) and comprising a Group V metal in an amount less than 10 mole % (relative to the total of the Group VIB metals), which bulk catalyst has been calcined at a temperature below a temperature where the hexagonal metastable crystal structure changes to an inactive crystalline structure, preferably below 450° C. and which bulk catalyst has a metastable hexagonal phase characterized by an X-ray diffraction pattern having reflections at 33-35 and 58-61° 2θ. Preferably, the main reflections have a full width at half maximum (FWHM) of less than 2.5. The invention further relates to a process for the manufacture of the bulk catalyst, to the corresponding sulphided bulk catalyst and to the use of said catalyst or sulphided catalyst in the hydroprocessing, in particular the hydrodesulphurisation and hydrodenitrogenation, of a hydrocarbon feedstock.

    摘要翻译： 本发明涉及一种本体催化剂，其包含至少60重量％的包含一种或多种第VIII族金属和VIB族金属钼的金属氧化物颗粒，其包含小于10摩尔％的第二族VIB金属（相对于VIB族的总量） 金属），并且包含少于10摩尔％（相对于第VIB族金属的总量）的第V族金属，该体积催化剂在低于六方晶系亚稳晶体结构变为不活泼的温度的温度下被煅烧 晶体结构，优选低于450℃，并且该体积催化剂具有亚稳态六方晶相，其特征在于具有在33-35和58-61°2θ之间的反射的X射线衍射图。 优选地，主反射具有小于2.5的半高宽（FWHM）。 本发明还涉及一种用于制造本体催化剂的方法，相应的硫化体积催化剂以及所述催化剂或硫化催化剂在烃原料的加氢处理，特别是加氢脱硫和加氢脱氮中的用途。

    Bulk Catalyst Comprising Metal Oxidic Particles And A Process For The Manufacture Thereof
    10.
    发明申请
    Bulk Catalyst Comprising Metal Oxidic Particles And A Process For The Manufacture Thereof 有权
    包含金属氧化物颗粒的散装催化剂及其制造方法

    公开(公告)号：US20090211945A1

    公开(公告)日：2009-08-27

    申请号：US12091327

    申请日：2006-10-25

    申请人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Stuart Leon Soled ,  Sabato Miseo

    发明人： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Stuart Leon Soled ,  Sabato Miseo

    IPC分类号： B01J23/755 ,  B01J27/049 ,  C10G45/00

    CPC分类号： B01J37/20 ,  B01J23/85 ,  B01J23/8885 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/10 ,  C10G45/08 ,  C10G2300/202

    摘要： The invention relates to a bulk catalyst having improved activity in hydrodesulphurisation, in particular in relatively low Group VIII over Group VIB metal molar ratios. The bulk catalyst comprises metal oxidic particles comprising one or more Group VIB metals and one or more-Group VIII metals which metal oxidic particles are obtainable by a process comprising the steps of reacting the compounds comprising one or more Group VIB metals and compounds comprising one or more Group VIII metals in hydrothermal conditions at a reaction temperature above the boiling temperature of the protic liquid, preferably in an autoclave at a reaction pressure above atmospheric pressure and. The invention also relates to the corresponding sulphided catalyst, to a process for the manufacture of said bulk catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock.

    摘要翻译： 本发明涉及具有改进的加氢脱硫活性的本体催化剂，特别是在VIB族金属摩尔比相对较低的第VIII族。 本体催化剂包含包含一种或多种VIB族金属和一种或多种VIII族金属的金属氧化物颗粒，该金属氧化物颗粒可通过包括以下步骤的方法获得，所述方法包括使包含一种或多种VIB族金属的化合物与包含一种或多种 反应温度高于质子液体沸点温度的水热条件下，优选在反应压力高于大气压的高压釜中。 本发明还涉及相应的硫化催化剂，制备所述本体催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。