公开(公告)号：US4070390A

公开(公告)日：1978-01-24

申请号：US732361

申请日：1976-10-14

申请人： Sumio Umemura ,  Kyoji Ohdan ,  Tokuo Matsuzaki ,  Taizo Uda ,  Mikio Hidaka ,  Yasuo Nakamura ,  Masao Tsuruoka

发明人： Sumio Umemura ,  Kyoji Ohdan ,  Tokuo Matsuzaki ,  Taizo Uda ,  Mikio Hidaka ,  Yasuo Nakamura ,  Masao Tsuruoka

IPC分类号： C07B61/00 ,  B01J23/00 ,  B01J23/88 ,  B01J23/887 ,  B01J27/00 ,  B01J27/057 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  C07C120/14

CPC分类号： C07C253/26 ,  B01J23/8877 ,  B01J27/0576 ,  B01J2523/00 ,  Y02P20/52

摘要： Acrylonitrile can be produced in a high yield by the catalytical ammoxidation of propylene at an elevated temperature, preferably of 330.degree. to 470.degree. C, in the presence of a new type of catalyst consisting of an oxide composition of the empirical formula: Mo.sub.a Co.sub.b Fe.sub.c Bi.sub.d X.sub.e O.sub.f wherein X denotes at least one atom of an element selected from vanadium and tellurium and wherein the ratio a:b:c:d:e:f is in a range of 10:3 to 10:1 to 7:0.1 to 0.7:0.01 to 1:34.6 to 54.1, said catalyst being prepared by providing an aqueous mixture containing molybdenum-, cobalt- and iron-containing compounds, bismuth-containing compound, and vanadium-or tellurium-containing compound, converting the aqueous mixture into a dried solid mixture and calcining the solid mixture at a temperature of at least 500.degree. C.

摘要翻译： 丙烯腈可以通过在升高的温度下，优选在330℃至470℃的丙烯的催化氨氧化反应，在新型催化剂的存在下，由经验式的氧化物组合物：MoaCobFecBidXeOf，其中X 表示选自钒和碲中的元素的至少一个原子，其中a:b:c:d:e:f的比率在10:3至10:1至7:0.1至0.7:0.01至1的范围内 ：34.6至54.1，所述催化剂通过提供含有含钼，钴和铁的化合物，含铋化合物和含钒或碲化合物的水性混合物制备，将含水混合物转化成干燥的固体混合物， 在至少500℃的温度下煅烧固体混合物

公开(公告)号：US4205010A

公开(公告)日：1980-05-27

申请号：US718513

申请日：1976-08-30

申请人： Sumio Umemura ,  Kyoji Ohdan ,  Taizo Uda ,  Tokuo Matsuzaki ,  Mikio Hidaka ,  Yasuo Nakamura ,  Masao Tsuruoka

发明人： Sumio Umemura ,  Kyoji Ohdan ,  Taizo Uda ,  Tokuo Matsuzaki ,  Mikio Hidaka ,  Yasuo Nakamura ,  Masao Tsuruoka

IPC分类号： C07B61/00 ,  B01J23/00 ,  B01J23/88 ,  B01J23/882 ,  B01J27/19 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  C07C120/14

CPC分类号： C07C253/26 ,  B01J23/882 ,  B01J27/19 ,  Y02P20/52

摘要： Acrylonitrile can be catalytically produced with a high yield by bringing, at an elevated temperature, preferably of 300.degree. to 470.degree. C., a reaction feed containing propylene, ammonia and molecular oxygen into contact with a catalyst consisting of an oxide composition of the empirical formula: Mo.sub.a Co.sub.b Fe.sub.c X.sub.d O.sub.e wherein X denotes at least one atom of an element selected from phosphorus, arsenic, antimony and bismuth and wherein the ratio a:b:c:d:e is in a range of 12:4 to 9:1 to 5:0.01 to 0.07:39.5 to 52.7, said catalyst being prepared by providing an aqueous mixture containing molybdenum-, cobalt- and iron-containing compounds and a phosphorus-, arsenic-, antimony- or bismuth-containing compound, converting the aqueous mixture into a dried solid mixture and calcining the solid mixture at a temperature of at least 550.degree. C.

摘要翻译： 丙烯腈可以通过在升高的温度，优选在300-470℃下，使含有丙烯，氨和分子氧的反应进料与由经验的氧化物组成的催化剂接触而以高产率催化制备 式：MoaCobFecXdOe其中X表示选自磷，砷，锑和铋中的元素的至少一个原子，其中a:b:c:d:e的比率在12:4至9:1至5:1的范围内。 0.01至0.07：39.5至52.7，所述催化剂通过提供含有含钼，钴和铁的化合物和含磷，砷，锑或铋的化合物的含水混合物制备，将含水混合物转化为 干固体混合物并在至少550℃的温度下煅烧固体混合物

公开(公告)号：US4097518A

公开(公告)日：1978-06-27

申请号：US733771

申请日：1976-10-19

申请人： Sumio Umemura ,  Kyoji Ohdan ,  Taizo Uda ,  Tokuo Matsuzaki ,  Mikio Hidaka ,  Yasuo Nakamura ,  Tsuruoka, Masao

发明人： Sumio Umemura ,  Kyoji Ohdan ,  Taizo Uda ,  Tokuo Matsuzaki ,  Mikio Hidaka ,  Yasuo Nakamura ,  Tsuruoka, Masao

IPC分类号： B01J23/882 ,  C07C120/14

CPC分类号： C07C253/26 ,  B01J23/882 ,  Y02P20/52

摘要： High-yield catalytic production of acrylonitrile at an elevated temperature, from a reaction mixture containing propylene, ammonia and molecular oxygen, utilizing a catalyst comprising an oxide composition having the empirical formula Mo.sub.a Co.sub.b Fe.sub.c X.sub.d O.sub.e wherein X denotes at least one atom of an element selected from among calcium, tungsten, chromium, zirconium, titanium, zinc, manganese, and tin and the atomic ratio a:b:c:d:e is in the range of 12:4 to 10:1 to 6:0 to 1.0:40 to 70, said catalyst being prepared by providing an aqueous mixture containing compounds of the elements, drying the aqueous mixture, and calcining the dried solid product at a temperature of at least 500.degree. C.

摘要翻译： 使用包含具有经验式MoaCobFecXdOe的氧化物组合物的催化剂，从含有丙烯，氨和分子氧的反应混合物高温催化生产丙烯腈，其中X表示选自钙的元素的至少一个原子 ，钨，铬，锆，钛，锌，锰和锡，原子比a:b:c:d:e在12:4至10:1至6:0至1.0:40至70的范围内 所述催化剂通过提供含有元素化合物的水性混合物，干燥含水混合物和在至少500℃的温度下煅烧干燥的固体产物来制备。

公开(公告)号：US4290922A

公开(公告)日：1981-09-22

申请号：US134053

申请日：1980-03-26

申请人： Sumio Umemura ,  Kyoji Ohdan ,  Mikio Hidaka ,  Toshio Kurafuji

发明人： Sumio Umemura ,  Kyoji Ohdan ,  Mikio Hidaka ,  Toshio Kurafuji

IPC分类号： B01J23/88 ,  C07B61/00 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J21/06 ,  B01J23/24

CPC分类号： B01J23/8872 ,  B01J23/8876 ,  B01J23/8877 ,  B01J23/8878 ,  C07C253/26 ,  Y02P20/52

摘要： A catalyst for the ammoxidation of propylene to prepare acrylonitrile with a high yield thereof comprising an oxide composition of the empirical formula (I)Mo.sub.a Co.sub.b Ni.sub.c Fe.sub.d Bi.sub.e V.sub.f Ca.sub.g K.sub.h X.sub.i Si.sub.j O.sub.k (I)wherein X is zirconium and/or chromium, the subscripts a, b, c, d, e, f, g, h, i and j respectively denote the number of the respective atoms of the elements, when a=10, b=0 to 8, c=0 to 8, (b+c)=2 to 10, d=0.3 to 7, e=0.01 to 3, f=0.01 to 2, g=0.01 to 5, h=0.05 to 0.5, i=0 to 2, j=10 to 50, and the subscript k denotes the number of oxygen atoms which satisfies the average valency of the elements other than oxygen and the ratio a:k being in a range of 10:30 to 80, which catalyst is prepared by preparing an aqueous slurry containing respective element-containing compounds, by spray drying the aqueous slurry to prepare a dried solid precursory catalyst and, finally, by calcining the precursory catalyst as a temperature of from 500.degree. to 750.degree. C. to provide an activated catalyst.

摘要翻译： 用于丙烯氨氧化以制备丙烯腈的高产率的催化剂，其包含经验式（I）的氧化物组合物，其中X是锆和/或铬，下标a，b，c，d，e的MoaCobNicFedBieVfCagKhXiSijOk（I） 当a = 10，b = 0〜8，c = 0〜8，（b + c）= 2〜10时，f，g，h，i，j分别表示各元素的原子数，d = 0.3〜7，e = 0.01〜3，f = 0.01〜2，g = 0.01〜5，h = 0.05〜0.5，i = 0〜2，j = 10〜50，下标k表示氧数 原子，其满足除氧之外的元素的平均化合价，a:k的比例在10:30至80的范围内，该催化剂通过制备含有各含元素化合物的含水浆料，通过喷雾干燥水溶液 浆料以制备干燥的固体前体催化剂，最后通过在500℃至750℃的温度下煅烧前体催化剂以提供活化的催化剂。

公开(公告)号：US5885917A

公开(公告)日：1999-03-23

申请号：US880388

申请日：1997-06-23

申请人： Kyoji Ohdan ,  Tokuo Matsuzaki ,  Mikio Hidaka

发明人： Kyoji Ohdan ,  Tokuo Matsuzaki ,  Mikio Hidaka

IPC分类号： B01J23/00 ,  B01J23/04 ,  C07C68/00 ,  B01J21/04 ,  C04B35/10

CPC分类号： B01J23/04 ,  B01J23/005 ,  C07C68/00 ,  Y10S502/524

摘要： A porous lithium aluminate carrier for catalyst has a spinel structure which has a mean pore diameter in the range of 40 to 1,000 angstroms and a total pore volume in the range of 0.2 to 1.5 mL/g. The porous lithium aluminate carrier can be used for supporting a catalyst compound containing a platinum group metal. The catalyst on the carrier can be favorably employed for promoting catalytic reaction of a nitrite ester and carbon monoxide to prepare a carbonate diester such as dimethyl carbonate.

摘要翻译： 用于催化剂的多孔铝酸锂载体具有尖晶石结构，其平均孔径在40至1,000埃的范围内，总孔体积在0.2至1.5mL / g的范围内。 多孔铝酸锂载体可用于负载含有铂族金属的催化剂化合物。 载体上的催化剂可以有利地用于促进亚硝酸酯和一氧化碳的催化反应以制备碳酸二酯如碳酸二甲酯。

公开(公告)号：US5688984A

公开(公告)日：1997-11-18

申请号：US652729

申请日：1996-05-22

申请人： Kyoji Ohdan ,  Tokuo Matsuzaki ,  Mikio Hidaka

发明人： Kyoji Ohdan ,  Tokuo Matsuzaki ,  Mikio Hidaka

IPC分类号： B01J23/00 ,  B01J23/04 ,  C07C68/00 ,  C07C69/96

CPC分类号： B01J23/04 ,  B01J23/005 ,  C07C68/00 ,  Y10S502/524

摘要： A porous lithium aluminate carrier for catalyst has a spinel structure which has a mean pore diameter in the range of 40 to 1,000 angstroms and a total pore volume in the range of 0.2 to 1.5 mL/g. The porous lithium aluminate carrier can be used for supporting a catalyst compound containing a platinum group metal. The catalyst on the carrier can be favorably employed for promoting catalytic reaction of a nitrite ester and carbon monoxide to prepare a carbonate diester such as dimethyl carbonate.

摘要翻译： 用于催化剂的多孔铝酸锂载体具有尖晶石结构，其平均孔径在40至1,000埃的范围内，总孔体积在0.2至1.5mL / g的范围内。 多孔铝酸锂载体可用于负载含有铂族金属的催化剂化合物。 载体上的催化剂可以有利地用于促进亚硝酸酯和一氧化碳的催化反应以制备碳酸二酯如碳酸二甲酯。

公开(公告)号：US4264476A

公开(公告)日：1981-04-28

申请号：US85708

申请日：1979-10-17

申请人： Sumio Umemura ,  Kyoji Ohdan ,  Mikio Hidaka ,  Toshio Kurafuji

发明人： Sumio Umemura ,  Kyoji Ohdan ,  Mikio Hidaka ,  Toshio Kurafuji

IPC分类号： B01J27/057 ,  B01J23/88 ,  B01J35/10 ,  C07B61/00 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J29/00 ,  B01J27/02 ,  B01J29/10 ,  B01J29/16

CPC分类号： B01J23/8872 ,  B01J23/8876 ,  B01J23/8877 ,  B01J23/8878 ,  C07C253/26 ,  Y02P20/52

摘要： An improved catalyst suitable for use in the production of acrylonitrile by the catalytic ammoxidation of propylene in a fluidized bed reactor is provided. This catalyst contains 40 to 60% by weight of silica, in terms of SiO.sub.2 , and 60 to 40% by weight of a composition having the formula:Mo.sub.10 Co.sub.2-8 Ni.sub.0-8 Fe.sub.0.1-7 Bi.sub.0.1-3 Zr.sub.0.1-4 A.sub.0.01-1 X.sub.0-5 O.sub.32.5-78.5wherein A is the alkali metals, X is Ti, Te, V, Mn, Cr, W and/or Sn, provided that the total number of Co and Ni atoms is 2 to 10, and has 150 to 500 A of the average pore radius, 0.2 to 0.5 cm.sup.3 /g of the total pore volume and 30 to 60 m.sup.2 /g of the specific surface area. This catalyst has an improved attrition resistance and acrylonitrile can be produced, in the presence of this catalyst, at a high yield by the ammoxidation reaction of propylene in a fluidized bed reactor.

摘要翻译： 提供了一种适用于在流化床反应器中通过丙烯催化氨氧化制备丙烯腈的改进的催化剂。 该催化剂含有40至60重量％的二氧化硅，以SiO 2计，和60至40重量％的具有下列通式的组合物：Mo10Co2-8Ni0-8Fe0.1-7Bi0.1-3Zr0.1-4A0.01 -1 X0-5O32.5-78。

公开(公告)号：US5514844A

公开(公告)日：1996-05-07

申请号：US94876

申请日：1993-07-22

申请人： Suenobu Hamano ,  Hiroyuki Sasao ,  Katsuhiko Horinouchi ,  Mikio Hidaka ,  Yoshiki Hirano ,  Haruhiko Kohyama

发明人： Suenobu Hamano ,  Hiroyuki Sasao ,  Katsuhiko Horinouchi ,  Mikio Hidaka ,  Yoshiki Hirano ,  Haruhiko Kohyama

IPC分类号： H01H33/70 ,  H01H33/90 ,  H01H33/91 ,  H01H33/915 ,  H01H33/98 ,  H01H33/18

CPC分类号： H01H33/901 ,  H01H33/982

摘要： A switch for use in electric power includes a fixed contact, a moving contact performing a switching operation with respect to the fixed contact, a cylinder working with the moving contact, a piston slidably provided in the cylinder, a buffer chamber which is surrounded by the cylinder and the piston, and is filled with an arc-extinguishing gas, and a second insulating nozzle mounted to an end of the cylinder on the side of the fixed contact, wherein the arc-extinguishing gas in the buffer chamber is sprayed through the nozzle on an arc generating between the fixed contact and the moving contact at an opening time of the moving contact.

摘要翻译： 用于电力的开关包括固定触点，执行相对于固定触点的切换操作的移动触点，与移动触点一起工作的气缸，可滑动地设置在气缸中的活塞，缓冲室，其被 气缸和活塞，并且填充有灭弧气体;以及第二绝缘喷嘴，其安装在固定触头一侧的气缸的端部，其中缓冲室中的灭弧气体通过喷嘴喷射 在活动触点的打开时间在固定触点和移动触点之间产生电弧。

公开(公告)号：US5354959A

公开(公告)日：1994-10-11

申请号：US034866

申请日：1993-03-19

申请人： Toshiaki Yoshizumi ,  Mikio Hidaka ,  Yoshiki Hirano

发明人： Toshiaki Yoshizumi ,  Mikio Hidaka ,  Yoshiki Hirano

IPC分类号： H01H33/14 ,  H01H33/16 ,  H01H33/34 ,  H01H33/42 ,  H01H33/50

CPC分类号： H01H33/168 ,  H01H33/34 ,  H01H2033/146 ,  H01H33/14

摘要： A double-break type circuit breaker includes two resistor contacts which are to be connected in parallel with respectively two main contacts when the main contacts are closed. An engagement mechanism is provided for linking the main contacts operated by a first hydraulic operation apparatus and the resistor contacts operated by a second hydraulic operation apparatus.

摘要翻译： 双断路型断路器包括两个电阻触点，当主触点闭合时，两个电阻触点与两个主触点并联连接。 提供一种接合机构，用于连接由第一液压操作装置操作的主触点和由第二液压操作装置操作的电阻触头。

公开(公告)号：US5367134A

公开(公告)日：1994-11-22

申请号：US46997

申请日：1993-04-16

申请人： Toshiaki Yoshizumi ,  Mikio Hidaka ,  Yoshiki Hirano

发明人： Toshiaki Yoshizumi ,  Mikio Hidaka ,  Yoshiki Hirano

IPC分类号： H01H33/12 ,  H01H33/16 ,  H01H33/34 ,  H01H33/42 ,  H01H33/70 ,  H01H33/52

CPC分类号： H01H33/34 ,  H01H33/16

摘要： In a closing operation of a circuit breaker with resistor contact, a resister contact is closed prior to closing of a main contact by the same first hydraulic operation system. In opening operation, the resistor contact is driven by a second hydraulic operation system used to close the main contact after operating the main contact by the first hydraulic operation system. Opening timing of the resistor contact is controlled by a mechanical interlock mechanism or hydraulic control circuit.

摘要翻译： 在具有电阻接触的断路器的闭合操作中，在通过相同的第一液压操作系统关闭主触头之前，电阻触点被闭合。 在打开操作中，电阻接触由第二液压操作系统驱动，用于在通过第一液压操作系统操作主触点之后关闭主触点。 电阻触点的开启时间由机械互锁机构或液压控制电路控制。