摘要:
Disclosed are a modified conjugated diene-based polymer capable of providing a polymer composition improved in tan δ balance, a polymer composition containing the modified conjugated diene-based polymer and silica, and a process for producing the modified conjugated diene-based polymer. The modified conjugated diene-based polymer is obtained by melt-kneading a conjugated diene-based polymer and 0.01 to 2 parts by weight of a Bunte salt per 100 parts by weight of the conjugated diene-based polymer, in the presence of water whose amount is from 0.1 to 1,000 parts by weight per one part by weight of the Bunte salt.
摘要:
A conjugated diene copolymer has a covalent bond reversibly dissociated and added by heat, and has at least two peaks in each of curves of molecular weight distributions measured at 40° C. and 60° C. by gel permeation chromatography, wherein a change rate of the proportion of the area of the peak having the lowest molecular weight in measurement at 60° C. to the proportion of the area of the peak having the lowest molecular weight in measurement at 40° C.
摘要:
Provided is an item made of a polypropylene resin composition that is suppressed from the emission of volatile organic compound components, examples of which item include a container, a cap of a container, an item for packaging, stationery, a toy, a miscellaneous daily item, an item for furniture, fiber, an agricultural film, an item for automobiles, an item for household electric appliances, an item for medical applications, or an item for building applications. The polypropylene resin composition includes a specific propylene polymer, a specific sugar compound, and a specific compound having a hydroxyphenyl group.
摘要:
A conjugated diene-based rubber including a polymer block (A) containing isoprene monomer unit as the main component and a polymer block (B) containing 1,3-butadiene monomer unit as the main component, wherein at least one of the polymer block (A) and the polymer block (B) contains a unit of a vinyl compound having a functional group interactive with silica, the polymer block (A) has a weight average molecular weight (Mw) in the range of 1,000 to 30,000, and the entire conjugated diene-based rubber has a weight average molecular weight (Mw) in the range of 50,000 to 5,000,000.
摘要:
An olefin polymerization catalyst is obtained by bringing the following components (A), (B) and (C) into contact with one another: (A) a solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom and a halogen atom; (B) an organoaluminum compound; and (C) a triether represented by formula (I). An olefin polymerization solid catalyst can be provided having a sufficiently high polymerization activity and an ability to produce an olefin polymer with a low content of low-molecular weight components and amorphous components.
摘要:
A modified conjugated diene rubber having a modifying structure derived from a siloxane compound at at least one terminal of a polymer chain containing conjugated diene monomer unit and a monomer unit of a vinyl compound having a functional group interactive with silica.
摘要:
A conjugated diene polymer contains at least conjugated diene monomer units, wherein the conjugated diene polymer has an ionic strength index of 25% or more and a molecular weight distribution curve where two or more peaks are present when measured by gel permeation chromatography, wherein when among the peaks in the molecular weight distribution curve, a peak having the largest peak area proportion is defined as a first peak, and a peak having the second largest peak area proportion is defined as a second peak, the conjugated diene polymer has an entire molecular weight distribution (Mw/Mn) of 1.50 or more, the first peak has a molecular weight distribution (Mw/Mn) of 1.30 or less, and the second peak has a molecular weight distribution (Mw/Mn) of 1.30 or less.
摘要:
A conjugated diene-based polymer including at least conjugated diene monomer units, and having a shrinkage factor of high molecular weight molecules of 0.4 to 0.8, a degree of adsorption of high molecular weight molecules onto silica of 75% or less, and a degree of adsorption of medium molecular weight molecules of 40 to 100%.
摘要:
A rubber composition contains a rubber component, an additive, and a filler, wherein the additive includes a compound including carbon atoms and at least one atomic species selected from the group made of silicon atoms, nitrogen atoms and oxygen atoms; the total number of silicon atoms, nitrogen atoms and oxygen atoms constituting the compound is 0.27 or more and 0.80 or less based on the number of the carbon atoms; the Hansen solubility parameter of the compound satisfies a relationship represented by the following formula (2); and the molecular weight of the compound is 200 or more and 15000 or less. 6≤{4(δD1−δD2)2+(δP1−δP2)2+(δH1−δH2)2}0.5 (2)
摘要:
A method for producing conjugated diene rubber is provided, including: a first step of obtaining a conjugated diene polymer chain having an active end by polymerizing a monomer comprising a conjugated diene compound and a vinyl compound having a functional group interactive with silica using a polymerization initiator in an inert solvent; a second step of reacting a siloxane compound with the active end of the conjugated diene polymer chain having the active end; and a third step of reacting a hydrocarbyloxysilane compound with the conjugated diene polymer chain with which the siloxane compound has been reacted that is obtained in the second step.