公开(公告)号：US20070244349A1

公开(公告)日：2007-10-18

申请号：US11718814

申请日：2005-11-11

申请人： Sven Crone ,  Catharina Klanner ,  Gotz-Peter Schindler ,  Mark Duda ,  Frieder Borgmeier

发明人： Sven Crone ,  Catharina Klanner ,  Gotz-Peter Schindler ,  Mark Duda ,  Frieder Borgmeier

IPC分类号： C07C5/333 ,  C07C11/167

CPC分类号： C07C7/09 ,  C07C5/333 ,  C07C11/167

摘要： Processes for producing butadiene from n-butane comprising: (a) providing a feed gas stream comprising n-butane; (b) non-oxidatively dehydrogenating the feed gas stream in the presence of a catalyst in a first dehydrogenation zone to form a first intermediate gas stream comprising n-butane, 1-butene, 2-butene, butadiene and hydrogen; (c) oxidatively dehydrogenating the first intermediate gas stream in the presence of an oxygenous gas having an oxygen content of at least 75% by volume in a second dehydrogenation zone to form a second intermediate gas stream comprising n-butane, butadiene, hydrogen, carbon dioxide and steam; (d) compressing and cooling the second intermediate gas to form a first condensate stream comprising water and a third intermediate gas stream comprising n-butane, butadiene, hydrogen, carbon dioxide and steam; (e) compressing and cooling the third intermediate gas to form a second condensate stream comprising n-butane, butadiene and water and a fourth intermediate gas stream comprising n-butane, butadiene, hydrogen and carbon dioxide; (f) cooling the fourth intermediate gas stream to form a third condensate stream comprising n-butane and butadiene, and an offgas stream comprising carbon dioxide and hydrogen; (g) removing water from the second condensate stream and combining the second condensate stream and third condensate stream to form a C4 hydrocarbon stream comprising n-butane and butadiene; and (h) separating the C4 hydrocarbon stream to form a recycle stream comprising n-butane and a product stream comprising butadiene; wherein at least a portion of the recycle stream is fed to the first dehydrogenation zone.

摘要翻译： 用于从正丁烷生产丁二烯的方法包括：（a）提供包含正丁烷的进料气流; （b）在催化剂存在下在第一脱氢区中使进料气流非氧化脱氢，以形成包含正丁烷，1-丁烯，2-丁烯，丁二烯和氢的第一中间气流; （c）在第二脱氢区中在氧含量至少为75体积％的氧气存在下，使第一中间气流氧化脱氢以形成包含正丁烷，丁二烯，氢，碳的第二中间气流 二氧化碳和蒸汽; （d）压缩和冷却第二中间气体以形成包含水的第一冷凝物流和包含正丁烷，丁二烯，氢气，二氧化碳和蒸汽的第三中间气流; （e）压缩和冷却第三中间气体以形成包含正丁烷，丁二烯和水的第二冷凝物流和包含正丁烷，丁二烯，氢气和二氧化碳的第四中间气流; （f）冷却第四中间气流以形成包含正丁烷和丁二烯的第三冷凝物流和包含二氧化碳和氢气的废气流; （g）从第二冷凝物流中除去水并将第二冷凝物流和第三冷凝物流合并以形成包含正丁烷和丁二烯的C 4烃流; 和（h）分离C 4 O 4烃流以形成包含正丁烷和包含丁二烯的产物流的再循环料流; 其中所述再循环流的至少一部分被供给到所述第一脱氢区。

公开(公告)号：US20080097133A1

公开(公告)日：2008-04-24

申请号：US11721240

申请日：2005-12-07

申请人： Sven Crone ,  Catharina Klanner ,  Gotz-Peter Schindler ,  Mark Duda ,  Frieder Borgmeier

发明人： Sven Crone ,  Catharina Klanner ,  Gotz-Peter Schindler ,  Mark Duda ,  Frieder Borgmeier

IPC分类号： C07C5/333

CPC分类号： C07C11/167 ,  C07C5/48

摘要： A process for preparing butadiene from n-butane, comprising the steps of A) providing a feed gas stream a comprising n-butane; B) feeding the feed gas stream a comprising n-butane into at least one first dehydrogenation zone and nonoxidatively, catalytically dehydrogenating n-butane to obtain a gas stream b comprising n-butane, 1-butene, 2-butene, butadiene and hydrogen, with or without carbon dioxide and with or without steam; C) feeding the gas stream b and an oxygenous gas into at least one second dehydrogenation zone and oxidatively dehydrogenating 1-butene and 2-butene to obtain a gas stream c comprising n-butane, butadiene, hydrogen, carbon dioxide and steam, D) compressing in at least one first compression stage and cooling the gas stream c to obtain at least one condensate stream d1 comprising water and a gas stream d2 comprising n-butane, butadiene, hydrogen, carbon dioxide and steam, E) separating the gas stream d2 by extractive distillation into a product stream e1 consisting substantially of butadiene and a stream e2 comprising n-butane, hydrogen, carbon dioxide and steam, F) compressing in at least one further compression stage and cooling the gas stream e2 to obtain at least one condensate stream f1 comprising n-butane and water, and a gas stream f2 comprising n-butane, hydrogen and carbon dioxide, G) cooling the gas stream f2 to obtain a condensate stream g1 comprising n-butane and an offgas stream g2 comprising carbon dioxide and hydrogen, H) removing water from the at least one condensate stream f1 and, if appropriate, from the condensate stream g1 by phase separation to obtain at least one recycle stream hi comprising n-butane and at least one wastewater stream h2, and recycling the at least one recycle stream h1 into the first dehydrogenation zone.

摘要翻译： 一种从正丁烷制备丁二烯的方法，包括以下步骤：A）提供包含正丁烷的进料气流a; B）将包含正丁烷的进料气流a进料到至少一个第一脱氢区和非氧化催化脱氢的正丁烷中，以获得包含正丁烷，1-丁烯，2-丁烯，丁二烯和氢的气流b， 有或没有二氧化碳，有或没有蒸汽; C）将气流b和氧气送入至少一个第二脱氢区并使1-丁烯和2-丁烯氧化脱氢得到包含正丁烷，丁二烯，氢气，二氧化碳和蒸汽的气流c，D） 在至少一个第一压缩级中压缩并冷却气流c以获得至少一个包含水的冷凝物流d 1和包含正丁烷，丁二烯，氢气，二氧化碳和蒸汽的气流d 2，E）将气体分离 流d 2通过萃取蒸馏成基本上由丁二烯组成的产物流e 1和包含正丁烷，氢气，二氧化碳和蒸汽的流e 2，F）在至少一个另外的压缩级中压缩并冷却气流e 2 以获得包含正丁烷和水的至少一个冷凝物流f 1和包含正丁烷，氢气和二氧化碳的气流f 2，G）冷却气流f 2以获得包含正丁烷和水的冷凝物流g 1， 丁烷和 废气流g 2包括二氧化碳和氢气，H）从至少一个冷凝物流f 1中除去水，如果合适的话，通过相分离从冷凝物流g 1中除去水，以获得至少一个包含正丁烷和 至少一个废水流h 2，并将所述至少一个循环流h 1再循环到第一脱氢区中。

公开(公告)号：US20080183024A1

公开(公告)日：2008-07-31

申请号：US11813935

申请日：2006-01-16

申请人： Catharina Klanner ,  Gotz-Peter Schindler ,  Sven Crone ,  Frieder Borgmeier ,  Mark Duda ,  Falk Simon

发明人： Catharina Klanner ,  Gotz-Peter Schindler ,  Sven Crone ,  Frieder Borgmeier ,  Mark Duda ,  Falk Simon

IPC分类号： C07C5/327

CPC分类号： C07C5/3337 ,  C07C7/08 ,  C07C11/167

摘要： A process for preparing butadiene from n-butane, comprising the steps of A) providing a feed gas stream a comprising n-butane; B) feeding the feed gas stream a comprising n-butane into at least one first dehydrogenation zone and nonoxidatively catalytically dehydrogenating n-butane to obtain a product gas stream b comprising n-butane, 1-butene, 2-butene, butadiene, hydrogen and low-boiling secondary constituents, with or without carbon oxides and with or without steam; C) feeding the product gas stream b of the nonoxidative catalytic dehydrogenation and an oxygenous gas into at least one second dehydrogenation zone and oxidatively dehydrogenating n-butane, 1-butene and 2-butene to obtain a product gas stream c comprising n-butane, 2-butene, butadiene, low-boiling secondary constituents, carbon oxides and steam, said product gas stream c having a higher content of butadiene than product gas stream b; D) removing the low-boiling secondary constituents and steam to obtain a C4 product gas stream d substantially consisting of n-butane, 2-butene and butadiene; E) separating the C4 product gas stream d into a stream e1 consisting substantially of n-butane and 2-butene and a product-of-value stream e2 consisting substantially of butadiene by extractive distillation; F) recycling stream e1 into the first dehydrogenation zone.

摘要翻译： 一种从正丁烷制备丁二烯的方法，包括以下步骤：A）提供包含正丁烷的进料气流a; B）将包含正丁烷的进料气流a进料到至少一个第一脱氢区和非氧化催化脱氢的正丁烷中，以获得包含正丁烷，1-丁烯，2-丁烯，丁二烯，氢和 低沸点二次成分，有或没有碳氧化物，有或没有蒸汽; C）将非氧化催化脱氢的产物气流b和氧气输送到至少一个第二脱氢区，并使正丁烷，1-丁烯和2-丁烯氧化脱氢得到包含正丁烷的产物气流c， 丁二烯，低沸点二次成分，碳氧化物和蒸汽，所述产物气流c具有比产物气流b更高的丁二烯含量; D）除去低沸点二次成分和蒸汽，得到基本上由正丁烷，2-丁烯和丁二烯组成的C 4 H 4产物气流d; E）通过萃取蒸馏将C 4 S 4产物气流d分离成基本上由正丁烷和2-丁烯组成的流e 1和基本上由丁二烯组成的价值产物流e 2; F）将流e 1再循环到第一脱氢区。

公开(公告)号：US20080119680A1

公开(公告)日：2008-05-22

申请号：US11722278

申请日：2005-12-19

申请人： Sven Crone ,  Catharina Klanner ,  Gotz-Peter Schindler ,  Mark Duda ,  Frieder Borgmeier

发明人： Sven Crone ,  Catharina Klanner ,  Gotz-Peter Schindler ,  Mark Duda ,  Frieder Borgmeier

IPC分类号： C07C5/333

CPC分类号： C07C5/333 ,  C07C11/167

摘要： A process for preparing butadiene from n-butane, comprising the steps of A) providing a feed gas stream a comprising n-butane; B) feeding the feed gas stream a comprising n-butane into at least one first dehydrogenation zone and nonoxidatively, catalytically dehydrogenating n-butane to obtain a gas stream b comprising n-butane, 1-butene, 2-butene, butadiene and hydrogen, with or without steam, with or without carbon oxides and with or without inert gases; C) feeding the gas stream b and an oxygenous gas into at least one second dehydrogenation zone and oxidatively dehydrogenating 1-butene and 2-butene to obtain a gas stream c comprising n-butane, butadiene, hydrogen, steam, with or without carbon oxides and with or without inert gases; D) compressing in at least one first compression stage and cooling the gas stream c to obtain at least one condensate stream d1 comprising water and a gas stream d2 comprising n-butane, butadiene, hydrogen and steam, with or without carbon oxides and with or without inert gases; E) separating the gas stream d2 by extractive distillation into a product stream e1 consisting substantially of butadiene and a stream e2 comprising n-butane, hydrogen and steam, with or without carbon oxides and with or without inert gases, F) if appropriate compressing in one or more further compression stages and cooling the gas stream e2 to obtain at least one condensate stream f1 comprising n-butane and water, and a gas stream f2 comprising n-butane and hydrogen, with or without carbon oxides and with or without inert gases, and if appropriate recycling the condensate stream f1 into the first dehydrogenation zone; G) separating the gas stream f2 into a recycle stream g1 comprising n-butane and an offgas stream g2 comprising hydrogen, with or without carbon oxides and with or without inert gases, by contacting the gas stream f2 with a high-boiling absorbent and subsequently desorbing the gas constituents dissolved in the absorbent.

公开(公告)号：US20080221374A1

公开(公告)日：2008-09-11

申请号：US11813360

申请日：2006-01-04

申请人： Sven Crone ,  Otto Machhammer ,  Gotz-Peter Schindler ,  Frieder Borgmeier

发明人： Sven Crone ,  Otto Machhammer ,  Gotz-Peter Schindler ,  Frieder Borgmeier

IPC分类号： C07C5/02

CPC分类号： C07C5/3337 ,  C07C7/11 ,  C07C11/06

摘要： A process for preparing propene from propane, comprising the steps: A) a feed gas stream a comprising propane is provided; B) the fed gas stream a comprising propane, if appropriate steam and, if appropriate, an oxygenous gas stream are fed into a dehydrogenation zone and propane is subjected to a dehydrogenation to propene to obtain a product gas stream b comprising propane, propene, methane, ethane, ethene, carbon monoxide, carbon dioxide, steam, if appropriate hydrogen and, if appropriate, oxygen; C) product gas stream b is cooled, if appropriate condensed and steam is removed by condensation to obtain a steam-depleted product gas stream c; D) product gas stream c is contacted in a first absorption zone with a selective, inert absorbent which selectively absorbs propene to obtain an absorbent stream d1 laden substantially with propene and a gas stream d2 comprising propane, methane, ethane, ethene, carbon monoxide, carbon dioxide and hydrogen; E) if appropriate, the absorbent stream d1 is decompressed to a lower pressure in a first desorption zone to obtain an absorbent stream e1 laden substantially with propene and a gas stream e2 comprising propene, and gas stream e2 is recycled into the first absorption zone, F) from the absorbent stream d1 or e1 laden substantially with propene, in at least one second desorption zone, by decompression, heating and/or stripping the absorbent stream d1 or e1, a gas stream f1 comprising propene is released and the selective absorbent is recovered.

摘要翻译： 一种从丙烷制备丙烯的方法，包括以下步骤：A）提供包含丙烷的进料气流a; B）包含丙烷的进料气流a（如果合适的话）蒸汽，如果合适的话，将含氧气流送入脱氢区，然后使丙烷脱氢至丙烯，得到包含丙烷，丙烯，甲烷的产物气流b 乙烷，乙烯，一氧化碳，二氧化碳，蒸汽，如果合适的话，以及适当的话，氧气; C）产物气流b被冷却，如果合适的话冷凝和蒸汽通过冷凝除去，得到蒸汽消耗产物气流c; D）产物气流c在第一吸收区域与选择性吸收丙烯的选择性惰性吸收剂接触，从而获得基本上与丙烯一起填充的吸收剂流d1和包含丙烷，甲烷，乙烷，乙烯，一氧化碳， 二氧化碳和氢气; E）如果合适，在第一解吸区中将吸收剂流d1减压至较低的压力，以获得基本上与丙烯和包含丙烯的气流e2并且气流e2再循环到第一吸收区中的吸收剂流e1， F）通过减压，加热和/或汽提吸收剂流d1或e1，从至少一个第二解吸区中基本上与丙烯充分接触的吸收剂流d1或e1，释放包含丙烯的气流f1，并且选择性吸附剂 恢复。

公开(公告)号：US20070167661A1

公开(公告)日：2007-07-19

申请号：US10584758

申请日：2004-12-30

申请人： Thorsten Johann ,  Gotz-Peter Schindler ,  Andreas Brodhagen ,  Sven Crone ,  Regina Benfer ,  Thomas Hill ,  Mark Duda

发明人： Thorsten Johann ,  Gotz-Peter Schindler ,  Andreas Brodhagen ,  Sven Crone ,  Regina Benfer ,  Thomas Hill ,  Mark Duda

IPC分类号： C07C5/327

CPC分类号： C07C5/333 ,  C07C5/48 ,  C07C11/167

摘要： The invention relates to a process for preparing butadiene from n-butane having the steps of A) providing a feed gas stream a comprising n-butane; B) feeding the feed gas stream a comprising n-butane into at least one first dehydrogenation zone and nonoxidatively catalytically dehydrogenating n-butane to obtain a product gas stream b comprising n-butane, 1-butene, 2-butene, butadiene, hydrogen, low-boiling secondary constituents and in some cases steam; C) feeding the product gas stream b of the nonoxidative catalytic dehydrogenation and an oxygenous gas into at least one second dehydrogenation zone and oxidatively dehydrogenating 1-butene and 2-butene to obtain a product gas stream c comprising n-butane, 2-butene, butadiene, hydrogen, low-boiling secondary constituents and steam, said product gas stream c having a higher content of butadiene than the product gas stream b; D) removing hydrogen, the low-boiling secondary constituents and steam to obtain a C4 product gas stream d substantially consisting of n-butane, 2-butene and butadiene; E) separating the C4 product gas stream d into a recycle stream e1 consisting substantially of n-butane and 2-butene and a stream e2 consisting substantially of butadiene by extractively distilling and recycling the stream e1 into the first dehydrogenation zone; F) if desired, feeding some or all of the stream e2 consisting substantially of butadiene into a selective hydrogenation zone and selectively hydrogenating butadiene to 1- and/or 2-butene to obtain a stream f comprising 1-butene and 2-butene; G) if desired, feeding the stream f comprising 1-butene and 2-butene into a distillation zone and removing a product of value stream g1 consisting substantially of 1-butene to leave a stream g2 comprising 2-butene; H) if desired, recycling the stream g2 comprising 2-butene into the first dehydrogenation zone.

摘要翻译： 本发明涉及一种从正丁烷制备丁二烯的方法，该方法具有以下步骤：A）提供包含正丁烷的进料气流a; B）将包含正丁烷的进料气流（a）进料到至少一个第一脱氢区和非氧化催化脱氢的正丁烷中，以获得包含正丁烷，1-丁烯，2-丁烯，丁二烯，氢， 低沸点次生成分，有时还有蒸汽; C）将非氧化催化脱氢的产物气流b和氧气输送到至少一个第二脱氢区，并使1-丁烯和2-丁烯氧化脱氢得到包含正丁烷，2-丁烯， 丁二烯，氢，低沸点二次成分和蒸汽，所述产物气流c具有比产物气流b更高含量的丁二烯; D）除去氢气，低沸点次级组分和蒸汽，得到基本上由正丁烷，2-丁烯和丁二烯组成的C 4 H 4产物气流d; E）将C 4 H 4产物气流d分离成基本上由正丁烷和2-丁烯组成的循环流e1和基本上由丁二烯组成的物流e2，通过萃取蒸馏并将流e1再循环到 第一个脱氢区; F）如果需要，将基本上由丁二烯组成的一些或全部流e2加入到选择性氢化区中，并将丁二烯选择性氢化为1-和/或2-丁烯，以获得包含1-丁烯和2-丁烯的料流f; 如果需要，将包含1-丁烯和2-丁烯的料流f加入到蒸馏区中并除去基本上由1-丁烯组成的物流g1的产物以留下包含2-丁烯的料流g2; H）如果需要，将包含2-丁烯的料流g2再循环到第一脱氢区中。

公开(公告)号：US20070161842A1

公开(公告)日：2007-07-12

申请号：US10584783

申请日：2004-12-30

申请人： Thorsten Johann ,  Gotz-Peter Schindler ,  Andreas Brodhagen ,  Sven Crone ,  Regina Benfer ,  Marcus Sigl ,  Mark Duda

发明人： Thorsten Johann ,  Gotz-Peter Schindler ,  Andreas Brodhagen ,  Sven Crone ,  Regina Benfer ,  Marcus Sigl ,  Mark Duda

IPC分类号： C07C5/327 ,  C07C1/00

CPC分类号： C07C5/327 ,  C07C5/333 ,  C07C5/48 ,  C07C11/167

摘要： The invention relates to a process for preparing butadiene from n-butane having the steps of A) providing a feed gas stream a comprising n-butane; B) feeding the feed gas stream a comprising n-butane into at least one first dehydrogenation zone and nonoxidatively catalytically dehydrogenating n-butane to obtain a product gas stream b comprising n-butane, 1-butene, 2-butene, butadiene, hydrogen, low-boiling secondary constituents and in some cases steam; C) feeding the product gas stream b of the nonoxidative catalytic dehydrogenation and an oxygenous gas into at least one second dehydrogenation zone and oxidatively dehydrogenating n-butane, 1-butene and 2-butene to obtain a product gas stream c comprising n-butane, 2-butene, butadiene, low-boiling secondary constituents and steam, said product gas stream c having a higher content of butadiene than the product gas stream b; D) removing the low-boiling secondary constituents and steam to obtain a C4 product gas stream d substantially consisting of n-butane, 2-butene and butadiene; E) separating the C4 product gas stream d into a stream e1 consisting substantially of n-butane and 2-butene and a product of value stream e2 consisting substantially of butadiene by extractive distillation; F) feeding the stream e1 consisting substantially of n-butane and 2-butene and a cycle stream g comprising 1-butene and 2-butene into a distillation zone and separating into a 1-butene-rich product of value stream f1, a recycle stream f2 comprising 2-butene and n-butane and a stream f3 comprising 2-butene, and recycling the recycle stream f2 into the first dehydrogenation zone; G) feeding the stream f3 comprising 2-butene into an isomerization zone and isomerizing 2-butene to 1-butene to obtain a cycle stream g comprising 1-butene and 2-butene, and recycling the cycle gas stream g into the distillation zone.

摘要翻译： 本发明涉及一种从正丁烷制备丁二烯的方法，该方法具有以下步骤：A）提供包含正丁烷的进料气流a; B）将包含正丁烷的进料气流（a）进料到至少一个第一脱氢区和非氧化催化脱氢的正丁烷中，以获得包含正丁烷，1-丁烯，2-丁烯，丁二烯，氢， 低沸点次生成分，有时还有蒸汽; C）将非氧化催化脱氢的产物气流b和氧气输送到至少一个第二脱氢区，并使正丁烷，1-丁烯和2-丁烯氧化脱氢得到包含正丁烷的产物气流c， 丁二烯，低沸点二次成分和蒸汽，所述产物气流c具有比产物气流b更高含量的丁二烯; D）除去低沸点二次成分和蒸汽，得到基本上由正丁烷，2-丁烯和丁二烯组成的C 4 H 4产物气流d; E）将C 4 H 4产物气流d分离成基本上由正丁烷和2-丁烯组成的物流e1和通过萃取蒸馏基本上由丁二烯组成的价值流e2的产物; F）将基本上由正丁烷和2-丁烯组成的流e1和包含1-丁烯和2-丁烯的循环流g加入到蒸馏区中并分离成价值流f1的富含1-丁烯的产物，再循环 包含2-丁烯和正丁烷的料流f2和包含2-丁烯的料流f3，并将再循环料流f2再循环到第一脱氢区中; G）将包含2-丁烯的料流f3进料到异构化区并将2-丁烯异构化成1-丁烯，得到包含1-丁烯和2-丁烯的循环流g，并将循环气流g再循环到蒸馏区中。

公开(公告)号：US20070179330A1

公开(公告)日：2007-08-02

申请号：US10584785

申请日：2004-12-30

申请人： Thorsten Johann ,  Gotz-Peter Schindler ,  Andreas Brodhagen ,  Sven Crone ,  Mark Duda

发明人： Thorsten Johann ,  Gotz-Peter Schindler ,  Andreas Brodhagen ,  Sven Crone ,  Mark Duda

IPC分类号： C07C5/333 ,  C07C2/00

CPC分类号： C07C5/333 ,  C07C5/48 ,  C07C11/167

摘要： The invention relates to a process for preparing butadiene from n-butane having the steps of A) providing a feed gas stream a comprising n-butane; B) feeding the feed gas stream a comprising n-butane into at least one first dehydrogenation zone and nonoxidatively catalytically dehydrogenating n-butane to obtain a product gas stream b comprising n-butane, 1-butene, 2-butene, butadiene, hydrogen, low-boiling secondary constituents and in some cases steam; C) feeding the product gas stream b of the nonoxidative catalytic dehydrogenation and an oxygenous gas into at least one second dehydrogenation zone and oxidatively dehydrogenating 1-butene and 2-butene to obtain a product gas stream c comprising n-butane, 2-butene, butadiene, hydrogen, low-boiling secondary constituents and steam, said product gas stream c having a higher content of butadiene than the product gas stream b; D) removing hydrogen, the low-boiling secondary constituents and steam to obtain a C4 product gas stream d substantially consisting of n-butane, 2-butene and butadiene; E) feeding the C4 product gas stream d into a distillation zone and removing a butadiene/butane mixture as the product of value stream e1, to leave a stream e2 consisting substantially of n-butane and 2-butene; F) recycling the stream e2 into the first dehydrogenation zone.

摘要翻译： 本发明涉及一种从正丁烷制备丁二烯的方法，该方法具有以下步骤：A）提供包含正丁烷的进料气流a; B）将包含正丁烷的进料气流（a）进料到至少一个第一脱氢区和非氧化催化脱氢的正丁烷中，以获得包含正丁烷，1-丁烯，2-丁烯，丁二烯，氢， 低沸点次生成分，有时还有蒸汽; C）将非氧化催化脱氢的产物气流b和氧气输送到至少一个第二脱氢区，并使1-丁烯和2-丁烯氧化脱氢得到包含正丁烷，2-丁烯， 丁二烯，氢，低沸点二次成分和蒸汽，所述产物气流c具有比产物气流b更高含量的丁二烯; D）除去氢气，低沸点次级组分和蒸汽，得到基本上由正丁烷，2-丁烯和丁二烯组成的C 4 H 4产物气流d; E）将C 4 H 4产物气流d进料到蒸馏区中并除去作为值流e1的产物的丁二烯/丁烷混合物，以留下基本上由正丁烷和2- 丁烯 F）将流e2再循环到第一脱氢区。

公开(公告)号：US20070142689A1

公开(公告)日：2007-06-21

申请号：US11614425

申请日：2006-12-21

申请人： Claus Hechler ,  Wilhelm Ruppel ,  Gotz-Peter Schindler ,  Catharina Klanner ,  Hans-Jurgen Bassler ,  Martin Dieterle ,  Karl-Heinrich Klappert ,  Klaus Muller-Engel

发明人： Claus Hechler ,  Wilhelm Ruppel ,  Gotz-Peter Schindler ,  Catharina Klanner ,  Hans-Jurgen Bassler ,  Martin Dieterle ,  Karl-Heinrich Klappert ,  Klaus Muller-Engel

IPC分类号： C07C5/327 ,  C07C5/333 ,  B01J8/00

CPC分类号： C07C5/3335 ,  B01J8/008 ,  B01J8/02 ,  B01J8/18 ,  B01J19/02 ,  B01J2219/00033 ,  B01J2219/0236 ,  B01J2219/0286 ,  C07C5/321 ,  C07C5/333 ,  C07C5/48 ,  C07C45/33 ,  C07C45/35 ,  C07C51/215 ,  C07C51/252 ,  C07C51/43 ,  C07C67/08 ,  C22C38/001 ,  C22C38/005 ,  C22C38/02 ,  C22C38/04 ,  C22C38/34 ,  C22C38/40 ,  C23C10/08 ,  C23C10/50 ,  Y02P20/52 ,  Y02T50/67 ,  C07C11/06 ,  C07C57/04 ,  C07C69/54 ,  C07C11/04 ,  C07C47/22

摘要： A process for continuous heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated in a reactor which is manufactured from a steel with specific elemental composition on its side in contact with the reaction gas, and also partial oxidations of the dehydrogenated hydrocarbon and the reactor itself.

摘要翻译： 在反应器中连续不均匀地催化部分脱氢至少一种待脱氢烃的方法，该反应器由与反应气体接触的一侧具有特定元素组成的钢制成，以及脱氢烃和反应器的部分氧化 本身。

公开(公告)号：US20080045685A1

公开(公告)日：2008-02-21

申请号：US11829424

申请日：2007-07-27

申请人： Martin DIETERLE ,  Catharina Klanner ,  Gotz-Peter Schindler ,  Klaus Muller-Engel ,  Jens Scheidel ,  Christoph Adami

发明人： Martin DIETERLE ,  Catharina Klanner ,  Gotz-Peter Schindler ,  Klaus Muller-Engel ,  Jens Scheidel ,  Christoph Adami

IPC分类号： C08F20/18

CPC分类号： B01J8/0453 ,  B01J8/0496 ,  B01J8/062 ,  B01J8/067 ,  B01J19/0033 ,  B01J2208/00221 ,  B01J2208/00407 ,  B01J2208/00415 ,  B01J2208/00522 ,  B01J2208/025 ,  C07C5/3337 ,  C07C45/33 ,  C07C45/35 ,  C07C67/08 ,  C07C2523/42 ,  Y02P20/52 ,  C07C11/02 ,  C07C11/06 ,  C07C47/22 ,  C07C69/54

摘要： A process for long-term operation of a continuous heterogeneously catalyzed partial dehydrogenation of a hydrocarbon to be dehydrogenated, in which a reaction gas mixture stream comprising the hydrocarbon to be dehydrogenated in a molar starting amount KW is conducted through an overall catalyst bed comprising the total amount M of dehydrogenation catalyst and the deactivation of the overall catalyst bed is counteracted in such a way that, with increasing operating time, the contribution to the conversion in the first third of the total amount M of dehydrogenation catalyst in flow direction decreases, the contribution to the conversion in the last third of the total amount M of dehydrogenation catalyst in flow direction increases, and the contribution to the conversion in the second third of the total amount M of dehydrogenation catalyst in flow direction passes through a maximum.

摘要翻译： 一种用于长期运行待脱氢烃的连续不均匀催化的部分脱氢的方法，其中包含待脱氢的烃以摩尔起始量KW的反应气体混合物流通过包含总共的催化剂床 脱氢催化剂的量M和整个催化剂床的失活以这样的方式被抵消：随着操作时间的增加，在流动方向上对脱氢催化剂总量M的前三分之一转化的贡献减小，贡献 到脱氢催化剂流向总量M的最后三分之一的转化率增加，并且对流化方向的脱氢催化剂总量M的第二分之三转化率的影响最大。