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1.发明申请公开(公告)号：US20080045685A1
公开(公告)日：2008-02-21
申请号：US11829424
申请日：2007-07-27
申请人： Martin DIETERLE , Catharina Klanner , Gotz-Peter Schindler , Klaus Muller-Engel , Jens Scheidel , Christoph Adami
发明人： Martin DIETERLE , Catharina Klanner , Gotz-Peter Schindler , Klaus Muller-Engel , Jens Scheidel , Christoph Adami
IPC分类号： C08F20/18
CPC分类号： B01J8/0453 , B01J8/0496 , B01J8/062 , B01J8/067 , B01J19/0033 , B01J2208/00221 , B01J2208/00407 , B01J2208/00415 , B01J2208/00522 , B01J2208/025 , C07C5/3337 , C07C45/33 , C07C45/35 , C07C67/08 , C07C2523/42 , Y02P20/52 , C07C11/02 , C07C11/06 , C07C47/22 , C07C69/54
摘要： A process for long-term operation of a continuous heterogeneously catalyzed partial dehydrogenation of a hydrocarbon to be dehydrogenated, in which a reaction gas mixture stream comprising the hydrocarbon to be dehydrogenated in a molar starting amount KW is conducted through an overall catalyst bed comprising the total amount M of dehydrogenation catalyst and the deactivation of the overall catalyst bed is counteracted in such a way that, with increasing operating time, the contribution to the conversion in the first third of the total amount M of dehydrogenation catalyst in flow direction decreases, the contribution to the conversion in the last third of the total amount M of dehydrogenation catalyst in flow direction increases, and the contribution to the conversion in the second third of the total amount M of dehydrogenation catalyst in flow direction passes through a maximum.
摘要翻译： 一种用于长期运行待脱氢烃的连续不均匀催化的部分脱氢的方法，其中包含待脱氢的烃以摩尔起始量KW的反应气体混合物流通过包含总共的催化剂床 脱氢催化剂的量M和整个催化剂床的失活以这样的方式被抵消：随着操作时间的增加，在流动方向上对脱氢催化剂总量M的前三分之一转化的贡献减小，贡献 到脱氢催化剂流向总量M的最后三分之一的转化率增加，并且对流化方向的脱氢催化剂总量M的第二分之三转化率的影响最大。
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2.发明申请公开(公告)号：US20070142689A1
公开(公告)日：2007-06-21
申请号：US11614425
申请日：2006-12-21
申请人： Claus Hechler , Wilhelm Ruppel , Gotz-Peter Schindler , Catharina Klanner , Hans-Jurgen Bassler , Martin Dieterle , Karl-Heinrich Klappert , Klaus Muller-Engel
发明人： Claus Hechler , Wilhelm Ruppel , Gotz-Peter Schindler , Catharina Klanner , Hans-Jurgen Bassler , Martin Dieterle , Karl-Heinrich Klappert , Klaus Muller-Engel
CPC分类号： C07C5/3335 , B01J8/008 , B01J8/02 , B01J8/18 , B01J19/02 , B01J2219/00033 , B01J2219/0236 , B01J2219/0286 , C07C5/321 , C07C5/333 , C07C5/48 , C07C45/33 , C07C45/35 , C07C51/215 , C07C51/252 , C07C51/43 , C07C67/08 , C22C38/001 , C22C38/005 , C22C38/02 , C22C38/04 , C22C38/34 , C22C38/40 , C23C10/08 , C23C10/50 , Y02P20/52 , Y02T50/67 , C07C11/06 , C07C57/04 , C07C69/54 , C07C11/04 , C07C47/22
摘要： A process for continuous heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated in a reactor which is manufactured from a steel with specific elemental composition on its side in contact with the reaction gas, and also partial oxidations of the dehydrogenated hydrocarbon and the reactor itself.
摘要翻译： 在反应器中连续不均匀地催化部分脱氢至少一种待脱氢烃的方法，该反应器由与反应气体接触的一侧具有特定元素组成的钢制成，以及脱氢烃和反应器的部分氧化 本身。
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3.发明申请PROCESS FOR PREPARING ACROLEIN OR ACRYLIC ACID OR A MIXTURE THEREOF FROM PROPANE 有权制备丙烯酸或丙烯酸或其混合物的方法公开(公告)号：US20070088092A1
公开(公告)日：2007-04-19
申请号：US11533177
申请日：2006-09-19
申请人： Catharina Klanner , Martin Dieterle , Gotz-Peter Schindler , Tsung-Chieh Cheng , Klaus Muller-Engel
发明人： Catharina Klanner , Martin Dieterle , Gotz-Peter Schindler , Tsung-Chieh Cheng , Klaus Muller-Engel
IPC分类号： C07B63/02
CPC分类号： B01J8/067 , B01J8/0415 , B01J2208/00814 , B01J2208/00849 , B01J2208/025 , C07C45/33 , C07C45/35 , C07C51/215 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for preparing acrolein or acrylic acid or a mixture thereof from propane, in which propane is dehydrogenated under heterogeneous catalysis in a reaction zone A and the propylene formed is partially oxidized heterogeneously in a reaction zone, reaction zone A being operated in loop mode and reaction gas mixture input stream A fed to the reaction zone A comprising added molecular hydrogen which is added to this input stream as late as possible.
摘要翻译： 由丙烷制备丙烯醛或丙烯酸或其混合物的方法，其中丙烷在反应区A中在非均相催化下脱氢，形成的丙烯在反应区中部分氧化，反应区A以循环模式操作， 反应气体混合物输入流A，其进料到反应区A，其包含加入的分子氢，其尽可能晚地加入到该输入流中。
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公开(公告)号：US20060199977A1
公开(公告)日：2006-09-07
申请号：US11357975
申请日：2006-02-22
IPC分类号： C07C51/42
摘要： A process for removing methacrolein from liquid phase P comprising acrylic acid as a main constituent and target product, and methacrolein as a secondary component in which the removal is effected by crystallization, the acrylic acid accumulating in the crystals formed and the methacrolein in the remaining mother liquor.
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5.发明申请Process for removing methacrylic acid from liquid phase comprising acrylic acid as a main constituent and target product, and methacrylic acid as a secondary component 有权从包含丙烯酸作为主要成分和目标产物的液相中除去甲基丙烯酸的方法和甲基丙烯酸作为次要组分公开(公告)号：US20060199976A1
公开(公告)日：2006-09-07
申请号：US11354101
申请日：2006-02-15
IPC分类号： C07C51/42
摘要： A process for removing methacrylic acid from liquid phase P comprising acrylic acid as a main constituent and target product, and methacrylic acid as a secondary component in which the removal is effected by crystallization, the acrylic acid accumulating in the crystals formed and the methacrylic acid in the remaining mother liquor.
摘要翻译： 从包含丙烯酸作为主要成分和目标产物的液相P中除去甲基丙烯酸的方法，以及甲基丙烯酸作为其中通过结晶进行除去的次要组分，在形成的晶体中积聚的丙烯酸和形成的晶体中的甲基丙烯酸 剩下的母酒。
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6.发明申请Process for preparing acrolein or acrylic acid or a mixture thereof from propane 有权从丙烷制备丙烯醛或丙烯酸或其混合物的方法公开(公告)号：US20070117998A1
公开(公告)日：2007-05-24
申请号：US11505800
申请日：2006-08-18
IPC分类号： C07C51/16
CPC分类号： C07C45/35 , C07C45/33 , C07C51/215 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for preparing acrolein, or acrylic acid or a mixture thereof as a target product from propane, in which propane is partially dehydrogenated under heterogeneous catalysis in a reaction zone A, molecular hydrogen thus formed is incinerated partly to water and the product gas A thus formed in reaction zone A is used without secondary component removal to charge a reaction zone B in which propylene present in product gas A is partially oxidized to the target product. From the product gas B formed in reaction zone B, the target product is removed and the residual gas I remaining after an aftertreatment comprising a CO2 scrubbing and a partial discharge thereof is recycled into reaction zone A.
摘要翻译： 制备丙烯醛或丙烯酸或其混合物作为丙烷的目标产物的方法，其中丙烷在反应区A中在非均相催化下部分脱氢，因此形成的分子氢部分地被焚烧成水，产物气A因此 在反应区A中形成的反应区A被使用，而不需要除去二次分量，从而向产物气体A中存在的丙烯部分氧化成目标产物的反应区B进行充电。 从在反应区B中形成的产物气体B中，除去目标产物，并且在包括CO 2洗涤和部分排放的后处理之后残留的残余气体I再循环到反应区A中。
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7.发明申请Preparation of acrylic acid by heterogeneously catalyzed gas phase partial oxidation of at least one C3 hydrocarbon precursor compound 审中-公开通过至少一种C3烃前体化合物的非均相催化气相部分氧化制备丙烯酸公开(公告)号：US20050272952A1
公开(公告)日：2005-12-08
申请号：US11107919
申请日：2005-04-18
CPC分类号： C07C51/252 , C07C57/04
摘要： A process for preparing acrylic acid by heterogeneously catalyzed partial oxidation of at least one C3 hydrocarbon precursor compound, in which the secondary component formation is ≦1.5 mol %.
摘要翻译： 通过至少一种C 3 O 3烃前体化合物的非均相催化部分氧化制备丙烯酸的方法，其中第二组分形成<= 1.5mol％。
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8.发明申请公开(公告)号：US20070149807A1
公开(公告)日：2007-06-28
申请号：US11564530
申请日：2006-11-29
申请人： Martin Dieterle , Jorg Heilek , Klaus Muller-Engel
发明人： Martin Dieterle , Jorg Heilek , Klaus Muller-Engel
IPC分类号： C07C51/16 , C07C51/235
CPC分类号： C07C51/252 , B01J23/002 , B01J2523/00 , C07C45/35 , C07C51/43 , C07C47/22 , C07C57/04 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/17 , B01J2523/55 , B01J2523/69 , B01J2523/13 , B01J2523/41 , B01J2523/845
摘要： A process for heterogeneously catalyzed partial gas phase oxidation of propylene to acrylic acid, in which the starting reaction gas mixture comprises cyclopropane as an impurity and the acrylic acid, after conversion from the product gas mixture into the condensed phase, is removed with the aid of a crystallative removal.
摘要翻译： 丙烯到丙烯酸的非均相催化的部分气相氧化丙烯酸的方法，其中起始反应气体混合物包含环丙烷作为杂质，丙烯酸在从产物气体混合物转化为冷凝相之后，借助于 结晶除去。
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9.发明申请Method of charging catalyst tubes of a bundle of catalyst tubes in a structured fashion 有权以结构化方式对催化剂管束的催化剂管进行充电的方法公开(公告)号：US20060045825A1
公开(公告)日：2006-03-02
申请号：US11118433
申请日：2005-05-02
IPC分类号： B01D53/34
CPC分类号： B01J8/0015 , B01J8/003 , B01J8/06 , B01J8/067 , B01J23/002 , B01J23/8885 , B01J35/0006 , B01J35/026 , B01J2208/00212 , B01J2208/00752 , B01J2208/00814 , B01J2208/025 , B01J2523/00 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845
摘要： A method of charging catalyst tubes of a bundle of catalyst tubes in a structured fashion, in which uniformly predispensed portions of formulations of shaped catalyst bodies are used for producing a section of charge.
摘要翻译： 以结构方式装载一束催化剂管的催化剂管的方法，其中使用成形催化剂体的制剂的均匀预分配部分来产生一部分电荷。
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10.发明申请公开(公告)号：US20060004229A1
公开(公告)日：2006-01-05
申请号：US11131256
申请日：2005-05-18
IPC分类号： C07C51/25
CPC分类号： C07C51/252 , C07C45/35 , C07C57/04 , C07C47/22
摘要： The present invention relates to a process for preparing acrylic acid by two-stage heterogeneously catalyzed partial gas phase oxidation of propylene, in which the propylene source used is a preceding propane dehydrogenation and in which the first oxidation stage is operated with restricted propylene conversion, and unconverted propane and propylene present in the product gas mixture of the second partial oxidation stage are recycled substantially into the preceding propane dehydrogenation.
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