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公开(公告)号:US10421889B2
公开(公告)日:2019-09-24
申请号:US15581514
申请日:2017-04-28
Applicant: tesa SE
Inventor: Benjamin Pütz , Nils Thebud , Lisa Wieghardt
IPC: C09J133/08 , B41C1/18 , C09J5/00 , C08L33/08
Abstract: A pressure-sensitive adhesive comprising at least 60 wt % of a polymer blend, where the polymer blend consists of a first polymer component A, a second polymer component B, and optionally one or more further polymer components (C, D, . . . ), where the first polymer component A is present at not less than x wt % in the polymer blend, where 90≤x≤99, and where the second polymer component B and any further polymer components C, D, . . . present are present in total at y wt % in the polymer blend, where y=100−x, where each polymer component (A, B, C, . . . ) derives to an extent of at least 60 wt % from (meth)acrylic monomers, wherein none of the polymer components (A, B, C, . . . ) is homogeneously miscible at room temperature with any of the other polymer components (A, B, C, . . . ), and so a multi-phase system is present.
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公开(公告)号:US12264271B2
公开(公告)日:2025-04-01
申请号:US16812950
申请日:2020-03-09
Applicant: tesa SE
Inventor: Benjamin Pütz , Sarah Zimmermann
IPC: C09J7/38 , C08F18/08 , C08F220/06 , C08F220/18 , C09J123/02 , C09J133/08 , C09J169/00 , C09J193/04
Abstract: Pressure-sensitive adhesives, adhesive tapes, and methods enable high bond strengths on non-polar or rough substrates. The pressure-sensitive adhesives and methods comprise (a) at least one poly(meth)acrylate, (b) at least one resin A selected from colophony resins and terpene-phenolic resins, (c) at least one hydrocarbon resin B1 having a softening point of greater than 50° C., and (d) at least one hydrocarbon resin B2 having a softening point of less than or equal to 25° C. The adhesive tapes comprise one or more layers of the pressure-sensitive adhesives, and the methods may produce adhesive bonds on substrates with low surface energy and/or on substrates with a mean roughness of at least 5 μm.
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公开(公告)号:US12054655B2
公开(公告)日:2024-08-06
申请号:US17126416
申请日:2020-12-18
Applicant: tesa SE
Inventor: Benjamin Pütz , Ralf Kretzmer
IPC: C09J7/38 , C08F220/06 , C08F220/20 , C08F220/28 , C08F226/02 , C09J7/21 , C09J7/35
CPC classification number: C09J7/385 , C08F220/06 , C08F220/20 , C08F220/285 , C08F226/02 , C09J7/21 , C09J7/35 , C09J2301/30 , C09J2433/00
Abstract: A repulpable pressure-sensitive adhesive useful on polar and apolar papers and storage-stable comprises a polymer whose parent monomer composition comprises:
a) 10 to 30 wt % of at least one compound of the formula (I)
CH2═CH—C(O)NR1R2 (I),
wherein R1 is an unsubstituted alkyl group, a hydroxyalkyl group or an acetonyl radical and R2 is a hydrogen atom, an unsubstituted alkyl group, a hydroxyalkyl group, an acetonyl radical or an aminoalkyl group;
b) 60 to 80 wt % of at least one compound of the formula (II)
CH2═CH—C(O)O—(CH2)2—O—R3 (II),
wherein R3 is an unsubstituted alkyl group, an alkoxyalkyl group or a (polyalkoxy)alkyl group; and
c) 0.5 to 10 wt % of at least one monomer selected from the group consisting of acrylic acid, methacrylic acid and (C2-C4 hydroxyalkyl) acrylates.
Also disclosed is an adhesive tape comprising the pressure-sensitive adhesive, and use of the pressure-sensitive adhesive and/or the adhesive tape for producing water-soluble bonds.-
4.
公开(公告)号:US10316117B2
公开(公告)日:2019-06-11
申请号:US15104288
申请日:2014-11-19
Applicant: TESA SE
Inventor: Stephan Zöllner , Alexander Prenzel , Bernd Lühmann , Benjamin Pütz , Helmut Ritter
Abstract: End-group-functionalized oligomers with controlled degrees of functionality based on styrene are produced by reacting the monomer with a regulator by means of free-radical polymerization. At least some of the quantity of regulator is added according to a prescribed program so that at every juncture t the value of the quantitative fraction added up to said juncture does not fall short of the value of the respective conversion U(t) in the polymerization reaction at said juncture t by more than 5 percentage points and does not exceed said value U(t) by more than 5 percentage points.
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公开(公告)号:US10150320B2
公开(公告)日:2018-12-11
申请号:US15652989
申请日:2017-07-18
Applicant: tesa SE
Inventor: Kai Ellringmann , Kristin Kerber , Benjamin Pütz
IPC: B41N6/00 , C09J5/00 , C09J133/08 , B41N6/02 , C08L31/04
Abstract: Pressure-sensitive adhesives and methods, for bonding flexible printing plates, comprising at least one adhesive component comprising at least one polymer component based on a monomer mixture comprising at least one of the following monomers: at least one acrylic ester; at least one methacrylic ester; acrylic acid; and methacrylic acid. The pressure-sensitive adhesives further comprise 1 to 30 wt %, based on the overall blend of the at least one adhesive component without solvent, of a polyvinyl acetate.
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公开(公告)号:US11384263B2
公开(公告)日:2022-07-12
申请号:US16076067
申请日:2017-01-23
Applicant: TESA SE
Inventor: Elisabetta Ardente , Benjamin Pütz , Markus Peters
IPC: C09J11/06 , C09J133/02 , C09J133/08 , C08K5/00
Abstract: Crosslinkable adhesive compound comprising at least a first base polymer component having functional groups suitable for covalent crosslinking and for coordinative crosslinking, and comprising at least one covalent crosslinker and at least one coordinative crosslinker, wherein the coordinative crosslinker is present in molar excess in relation to the covalent crosslinker.
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公开(公告)号:US10696872B2
公开(公告)日:2020-06-30
申请号:US15758945
申请日:2016-09-07
Applicant: TESA SE
Inventor: Stephan Bernt , Benjamin Pütz
IPC: C09J7/38 , C09J7/24 , C09J4/00 , C08F220/18 , B29C65/50 , B29C65/00 , B29C70/42 , C08J5/00 , C08J5/12
Abstract: The invention relates to an adhesive tape which can be used in particular in a method for connecting two fiber-reinforced plastic components, comprising a carrier material made of polyethylene, wherein a polyacrylate-based self-adhesive compound is applied to one side of the carrier material, said adhesive compound can be reduced to the following reactant mixture containing monomers having the following composition: A1) acrylic acid ester, and/or methacrylic acid ester of the following formula CH2═CH(R1)(COOR2), wherein R1=H or CH3 and R2 is an alkyl chain with 1 to 14 carbon atoms at a proportion of between 65 to 98 wt. %, A2) acrylates and/or methacrylates whose alcohol component contains at least one primary hydroxyl- or carboxyl-group, and/or with acrylate-copolymerizable vinyl compounds containing the at least one primary hydroxyl or carboxyl group at a proportion of between 1 to 20 wt. %, A3) multi-functional isocyanate cross-linker which blocks with thermally reversible protective groups at a proportion of between 1-10 wt. %, A4) and, if the proportions of A1), A2) and A3) do not add up to 100 wt. %, olefinically unsaturated monomers having functional groups, with a proportion of 0 to 15 wt. %.
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公开(公告)号:US09834636B2
公开(公告)日:2017-12-05
申请号:US15104323
申请日:2014-11-19
Applicant: TESA SE
Inventor: Bernd Lühmann , Alexander Prenzel , Benjamin Pütz , Helmut Ritter , Stephan Zöllner
IPC: B32B27/00 , B32B7/12 , C08F265/06 , C09J151/00 , C09J7/02 , B32B27/08 , B32B27/30
CPC classification number: C08F265/06 , B32B7/12 , B32B27/08 , B32B27/308 , B32B2307/718 , B32B2405/00 , C08F285/00 , C09J151/003 , C08F220/18 , C08F220/06 , C08F2220/1833 , C08F2220/1858
Abstract: Crosslinked pressure-sensitive adhesives (PSAs) based on polymers of branched macromolecules each comprising a main chain and one or more sidechains pendent to the main chain, the constitutional units thereof originating from a) X wt % of one or more acrylic and/or methacrylic esters, with 80 =1000 g/mol, and the respective amounts of constitutional units originating from a), b) and c) can be the same in each case or differ by not more than 1%, and where a), b) and c) may in each case be the same or different monomers, have detachment properties which can be set independently of one another.
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