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公开(公告)号:US20240425440A1
公开(公告)日:2024-12-26
申请号:US18697720
申请日:2022-10-20
Applicant: TOKYO OHKA KOGYO CO., LTD.
Inventor: Rin Odashima , Hiroki Kato
Abstract: A method for producing an acid generator including reacting a carboxylic acid represented by Formula (d0-1) having a pKa of 0.50 or more with at least one of a nitrogen-containing base compound and an onium compound to obtain an intermediate represented by Formula (d0-p), and subjecting the intermediate (d0-p) to an ion exchange reaction with a compound represented by Formula (c0) to obtain a compound represented by Formula (d0). In the formulae, X0 represents a bromine atom or an iodine atom, Rm represents a hydroxy group, nb1 represents an integer in a range of 1 to 5, 1≤nb1+nb2≤5 is satisfied, Yd represents a divalent linking group or a single bond, Mpm′+ represents an organic ammonium cation having a logPOW of 4.8 or less or an onium cation having a logPOW of 4.8 or less, X− represents a counter anion, and Mm+ represents an onium cation.
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公开(公告)号:US20240302741A1
公开(公告)日:2024-09-12
申请号:US18568071
申请日:2022-06-10
Applicant: TOKYO OHKA KOGYO CO., LTD.
Inventor: Shuichi Ishii , Hiroki Kato , KhanhTin Nguyen , Takuya Ikeda , Koshi Onishi , Rin Odashima , Tetsuo Fujinami , Seiji Todoroki , Ryo Kawatani
IPC: G03F7/004
CPC classification number: G03F7/0045
Abstract: A resist composition that contains a resin component having a constitutional unit containing an acid-dissociable group represented by General Formula (a01-r) below and contains an acid generator component containing a compound represented by General Formula (b0) below. In General Formula (a01-r), Ra01 and Ra02 represent a saturated aliphatic hydrocarbon group, Ra01 and Ra02 may be bonded to each other to form an alicyclic group. Ra03 to Ra05 represent an aliphatic hydrocarbon group and two or more of Ra03 to Ra05 may be bonded to each other to form an alicyclic group. In General Formula (b-0), X0 represents an iodine atom, Rm represents a hydroxy group, nb1 represents an integer in a range of 1 to 5, nb2 represents an integer in a range of 0 to 4, 1≤nb1+nb2≤5, Yb0 represents a divalent linking group, Vb0 represents an alkylene group, R0 represents a fluorinated alkyl group having 1 to 5 carbon atoms, and Mm+ represents an m-valent organic cation
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公开(公告)号:US20240411226A1
公开(公告)日:2024-12-12
申请号:US18694868
申请日:2022-10-06
Applicant: TOKYO OHKA KOGYO CO., LTD.
Inventor: Hiroki Kato , Shuichi Ishii , Tetsuo Fujinami
Abstract: A resist composition which generates an acid upon exposure to light and whose solubility in a developing solution is changed under action of an acid, the resist composition containing a resin component whose solubility in a developing solution is changed under action of an acid, in which the resin component has a constitutional unit derived from a compound represented by General Formula (a0) in which W represents a polymerizable group, Ar represents an aromatic hydrocarbon group, —OH represents a hydroxy group, La0 represents a divalent linking group, Ya0 represents a single bond or a divalent linking group, Ra01 and Ra02 each independently represents a hydrogen atom, a fluorine atom, or a fluorinated alkyl group, n0 represents an integer in a range of 1 to 4, m represents an integer of 1 or more, and Mm+ represents an m-valent organic cation.
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4.
公开(公告)号:US20240402604A1
公开(公告)日:2024-12-05
申请号:US18699225
申请日:2022-10-18
Applicant: TOKYO OHKA KOGYO CO., LTD.
Inventor: Rin Odashima , Hiroki Kato
Abstract: A resist composition containing a resin component (A1) and a photodecomposable base (D0) represented by General Formula (d0) that generates a carboxylic acid having a pKa of 0.50 or more as a generated acid. In the formula, Rm represents a hydrogen atom or a hydroxy group, X0 represents a bromine atom or an iodine atom, Yd0 represents a divalent linking group or a single bond, Rb1 represents a fluorine atom or a fluorinated alkyl group, p01 represents an integer in a range of 1 to 5, and Rb2 and Rb3 are hydrocarbon groups, provided that at least one Rb1 is bonded to an ortho-position or a meta-position of a benzene ring, and the number of all fluorine atoms contained in —F and/or —CFRx1Rx2 bonded to an aromatic ring bonded to the sulfur atom in the formula is 3 or more, and Rx1 and Rx2 represent a fluorine atom or a hydrogen atom
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公开(公告)号:US20240264527A1
公开(公告)日:2024-08-08
申请号:US18563359
申请日:2022-06-14
Applicant: TOKYO OHKA KOGYO CO., LTD.
Inventor: Takuya Uehara , Tetsuya Matsushita , Junichi Miyakawa , KhanhTin Nguyen , Hiroki Kato , Yuuki Fujimoto
IPC: G03F7/039 , C08F212/14 , C08F220/18 , G03F7/004 , G03F7/038
CPC classification number: G03F7/039 , C08F212/24 , C08F220/1806 , C08F220/1808 , C08F220/1809 , C08F220/1811 , G03F7/0045 , G03F7/038
Abstract: A resist composition including a resin component which has a constitutional unit (a01a) containing a polycyclic lactone-containing cyclic group and a constitutional unit (a02) represented by General Formula (a0-2), and a compound (B0) represented by General Formula (b0), Ra05 to Ra08 each independently represents a hydrogen atom, X0 represents a bromine atom or an iodine atom, Rm represents a hydroxy group, 1≤nb1+nb2≤5 is satisfied, Yb0 represents a divalent linking group or a single bond, Vb0 represents a single bond, R0 represents a hydrogen atom, Mm+ represents an m-valent organic cation, m represents an integer of 1 or greater
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6.
公开(公告)号:US20240295812A1
公开(公告)日:2024-09-05
申请号:US18566338
申请日:2022-06-15
Applicant: TOKYO OHKA KOGYO CO., LTD.
Inventor: Junichi Miyakawa , Hiroki Kato , KhanhTin Nguyen , Takuya Ikeda , Seiji Todoroki , Tetsuya Matsushita
IPC: G03F7/004 , C07C25/18 , C07C211/63 , C07C303/22 , C07C309/12 , C07C381/12 , C07D333/76
CPC classification number: G03F7/0045 , C07C25/18 , C07C211/63 , C07C303/22 , C07C309/12 , C07C381/12 , C07D333/76
Abstract: A resin component (A1) and a compound (B0) represented by General Formula (b0) in which X0 represents a bromine atom or an iodine atom, Rm represents a hydroxy group, nb1 represents an integer of 1 to 5, and nb2 represents an integer of 0 to 4, 1≤nb1+nb2≤5 is satisfied, Yb0 represents a divalent linking group or a single bond, Vb0 represents a single bond, an alkylene group, or a fluorinated alkylene group, R0 represents a hydrogen atom, a fluorinated alkyl group having 1 to 5 carbon atoms, or a fluorine atom, and Rb1 to Rb15 each independently represents a hydrogen atom or a substituent, and at least two of Rb1 to Rb5 represent a fluorine atom or at least one of Rb1 to Rb5 represents a perfluoroalkyl group
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