HEAT-SHRINKABLE MULTI-LAYER FILM FOR DEEP-DRAW FORMING, AND PROCESS FOR PRODUCTION THEREOF
    3.
    发明申请
    HEAT-SHRINKABLE MULTI-LAYER FILM FOR DEEP-DRAW FORMING, AND PROCESS FOR PRODUCTION THEREOF 有权
    用于深冲成型的热收缩多层薄膜及其生产方法

    公开(公告)号:US20130136906A1

    公开(公告)日:2013-05-30

    申请号:US13520888

    申请日:2010-12-17

    IPC分类号: B32B27/08 B32B27/34

    摘要: A polyamide resin-based heat-shrinkable multilayer film having excellent heat shrinkability and strength, as well as a high degree of deep A polyamide resin-based heat-shrinkable multilayer film having excellent heat shrinkability and strength, as well as a high degree of deep drawability as represented a shorter side-basis draw ratio (D/L) in excess of 0.6 between a maximum draw depth (D) and a shorter side length (L) of a mold opening is provided. The multilayer film is characterized by including a surface layer (a) comprising a thermoplastic resin, an intermediate layer (b) comprising a polyamide resin, and a surface layer (c) comprising a sealable resin, wherein (A) the intermediate layer (b) comprises a mixture of an aliphatic polyamide having a melting point of at least 180° C., and an amorphous aromatic polyamide comprising a polycondensation product of an aliphatic diamine with is ophthalmic acid and terephthalic acid as main acid components, including 25-45 wt. % of the amorphous aromatic polyamide, and has a thickness exceeding 25% and at most 50% of a total thickness of whole layers, and exhibiting: (B) tensile stresses at an elongation of 100% as measured in a tensile test at 100° C., including 3-22 N in at least one of a longitudinal direction (MD) and a transverse direction (TD) and an average of MD and TD values of 3-20N, and (C) a shrinkage in hot water at 90° C. of 3 to 20% in each of MD and TD. The film is produced through a process of strictly controlling biaxial stretching ratios and heat-relaxation ratios.

    摘要翻译: 具有优异的热收缩性和强度的聚酰胺树脂系的热收缩性多层膜以及具有优异的热收缩性和强度的高度的深A聚酰胺树脂系的热收缩性多层膜,以及高度的深度 提供了在模具开口的最大牵引深度(D)和较短的侧边长度(L)之间的较短的侧向拉伸比(D / L)超过0.6的拉伸性。 多层膜的特征在于包括包含热塑性树脂的表面层(a),包含聚酰胺树脂的中间层(b)和包含可密封树脂的表面层(c),其中(A)中间层(b) )包含熔点至少为180℃的脂族聚酰胺和包含脂类二胺与眼酸和对苯二甲酸作为主要酸成分的缩聚产物的无定形芳族聚酰胺的混合物,包括25-45wt 。 %的无定形芳族聚酰胺,并且具有超过全层总厚度的25%和至多50%的厚度,并且显示:(B)在100℃的拉伸试验中测量的伸长率为100%时的拉伸应力 C,在纵向(MD)和横向(TD)中的至少一个中包括3-22N,MD和TD值的平均值为3-20N,(C)90℃的热水收缩 在MD和TD各自为3〜20%。 该膜通过严格控制双轴拉伸比和热松弛率的方法制备。

    Laminated packaging material and process for producing the same
    4.
    发明授权
    Laminated packaging material and process for producing the same 失效
    层压包装材料及其制造方法

    公开(公告)号:US06592975B1

    公开(公告)日:2003-07-15

    申请号:US09582178

    申请日:2000-06-22

    IPC分类号: B32B702

    摘要: A laminated packaging material which comprises at least three layers of polymer materials comprising a surface layer, one or more intermediate layers adjacent thereto, and another surface layer, characterized in that the intermediate layer adjacent to each surface layer contains a lubricant, at least one of the intermediate layers has gas-barrier properties, and the total amount of a lubricant in the two surface layers is smaller than that in the intermediate layer(s) adjacent thereto. In production of the packaging material, adhesion of a lubricant to a die lip is reduced. The laminated packaging material has excellent transparency and gloss.

    摘要翻译: 一种层压包装材料,其包括至少三层聚合物材料,其包括表面层,与其相邻的一个或多个中间层和另一表面层,其特征在于,与每个表面层相邻的中间层含有润滑剂,至少一种 中间层具有气体阻隔性,并且两个表面层中的润滑剂的总量小于与其相邻的中间层中的润滑剂的总量。 在包装材料的生产中,润滑剂与模唇的粘合性降低。 层压包装材料具有优异的透明度和光泽度。

    Heat-shrinkable multi-layer film for deep-draw forming, and process for production thereof
    5.
    发明授权
    Heat-shrinkable multi-layer film for deep-draw forming, and process for production thereof 有权
    用于深拉伸成形的热收缩性多层膜及其制造方法

    公开(公告)号:US09352395B2

    公开(公告)日:2016-05-31

    申请号:US13520888

    申请日:2010-12-17

    摘要: A polyamide resin-based heat-shrinkable multilayer film having excellent heat shrinkability and strength, as well as a high degree of deep A polyamide resin-based heat-shrinkable multilayer film having excellent heat shrinkability and strength, as well as a high degree of deep drawability as represented a shorter side-basis draw ratio (D/L) in excess of 0.6 between a maximum draw depth (D) and a shorter side length (L) of a mold opening is provided. The multilayer film is characterized by including a surface layer (a) comprising a thermoplastic resin, an intermediate layer (b) comprising a polyamide resin, and a surface layer (c) comprising a sealable resin, wherein (A) the intermediate layer (b) comprises a mixture of an aliphatic polyamide having a melting point of at least 180° C., and an amorphous aromatic polyamide comprising a polycondensation product of an aliphatic diamine with is ophthalmic acid and terephthalic acid as main acid components, including 25-45 wt. % of the amorphous aromatic polyamide, and has a thickness exceeding 25% and at most 50% of a total thickness of whole layers, and exhibiting: (B) tensile stresses at an elongation of 100% as measured in a tensile test at 100° C., including 3-22 N in at least one of a longitudinal direction (MD) and a transverse direction (TD) and an average of MD and TD values of 3-20N, and (C) a shrinkage in hot water at 90° C. of 3 to 20% in each of MD and TD. The film is produced through a process of strictly controlling biaxial stretching ratios and heat-relaxation ratios.

    摘要翻译: 具有优异的热收缩性和强度的聚酰胺树脂系的热收缩性多层膜以及具有优异的热收缩性和强度的高度的深A聚酰胺树脂系的热收缩性多层膜,以及高度的深度 提供了在模具开口的最大牵引深度(D)和较短的侧边长度(L)之间的较短的侧向拉伸比(D / L)超过0.6的拉伸性。 多层膜的特征在于包括包含热塑性树脂的表面层(a),包含聚酰胺树脂的中间层(b)和包含可密封树脂的表面层(c),其中(A)中间层(b) )包含熔点至少为180℃的脂族聚酰胺和包含脂类二胺与眼酸和对苯二甲酸作为主要酸成分的缩聚产物的无定形芳族聚酰胺的混合物,包括25-45wt 。 %的无定形芳族聚酰胺,并且具有超过全层总厚度的25%和至多50%的厚度,并且显示:(B)在100℃的拉伸试验中测量的伸长率为100%时的拉伸应力 C,在纵向(MD)和横向(TD)中的至少一个中包括3-22N,MD和TD值的平均值为3-20N,(C)90℃的热水收缩 在MD和TD各自为3〜20%。 该膜通过严格控制双轴拉伸比和热松弛率的方法制备。

    Heat-shrinkable multilayer film
    6.
    发明授权

    公开(公告)号:US06565985B2

    公开(公告)日:2003-05-20

    申请号:US09962333

    申请日:2001-09-26

    IPC分类号: B32B2734

    摘要: A polyamide resin-based heat-shrinkable multilayer film is caused to satisfy various properties required of a packaging material, especially a food packaging material, at high levels, and particularly exhibit a highest level of heat-shrinkability. The multilayer film comprises at least three layers including an outer surface layer (a) which comprises a polyester resin or a polyolefin resin; an intermediate layer (b) which comprises a mixture of 85-60 wt. % of an aliphatic polyamide resin, and 15-40 wt. % of an aromatic copolyamide resin which is a copolymer of aliphatic diamine/isophthalic acid and aliphatic diamine/terephthalic acid, and an inner surface layer (c) which essentially comprises a copolymer of ethylene and &agr;-olefin having a density below 0.915. The heat-shrinkable multilayer film has been biaxially stretched and then heat-treated to have hot-water shrinkabilities at 80° C. of at least 30% in each of longitudinal/transverse directions and at least 35% in at least one of longitudinal/transverse directions.

    Laminate resin product
    8.
    发明授权
    Laminate resin product 失效
    层压树脂制品

    公开(公告)号:US5633065A

    公开(公告)日:1997-05-27

    申请号:US531065

    申请日:1995-09-20

    摘要: A laminate resin film having two major surfaces is constituted by plural resin species. In the laminate, layers of the plural resin species are laminated obliquely to the two major surfaces in at least one section perpendicular to the two major surfaces, and each layer of the plural species of resins is exposed to the two major surfaces. The laminate resin film has equivalent properties in the thickness direction (such as gas-barrier property) as in a conventional laminated film but has properties in the planar extension direction which are remarkably affected by properties (such as low Young's modulus and heat-shrinkability) of a certain component resin layer.

    摘要翻译: 具有两个主表面的层压树脂膜由多种树脂种类构成。 在层叠体中,在垂直于两个主表面的至少一个部分中,多个树脂种类的层与两个主表面倾斜地层叠,并且多层树脂的各层暴露于两个主表面。 层压树脂膜在常规层压膜中的厚度方向上具有等同的性质(例如阻气性),但是在平面延伸方向上具有受特性(如低杨氏模量和热收缩性)的显着影响的性能, 的某一组分树脂层。