-
公开(公告)号：US08534333B2
公开(公告)日：2013-09-17
申请号：US12810774
申请日：2009-02-13
IPC分类号： B60C11/00
CPC分类号： C08L7/00 , B60C1/0016 , B60C11/14 , B60C2011/0025 , C08J9/32 , C08J2203/22 , C08J2307/00 , C08J2309/00 , C08K3/04 , C08K3/36 , C08K5/548 , C08K7/22 , C08K9/10 , C08L9/00 , C08L21/00 , C08L2666/08
摘要： A tread rubber is made of a rubber composition containing 100 pbw of a diene rubber, 30 to 100 pbw of a reinforcing filler including at least 10 pbw of silica, and 1 to 20 pbw of microcapsules each encapsulating a heat-expandable substance. A sulfur-containing silane coupling agent is mixed in the rubber composition in an amount of 3 to 15 wt. % based on the weight of the silica. A shell material of each microcapsule is made of a thermoplastic resin which essentially contains a nitrile monomer. A vapor pressure of the heat-expandable substance is 1.4 to 3.0 MPa at 150° C. An average diameter of the microcapsules is 20 to 30 μm before vulcanization of the rubber composition. An average diameter of the microcapsules expanded due to the vulcanization is 40 to 80 μm. The tread rubber has a proportion of a cell-occupying area of 5 to 30%.
摘要翻译： 胎面橡胶由含有100pbw的二烯橡胶，30-100pbw的包含至少10pbw的二氧化硅的增强填料和1至20pbw的每个包封热膨胀性物质的微胶囊的橡胶组合物制成。 含硫硅烷偶联剂在橡胶组合物中以3〜15重量％的量混合。 基于二氧化硅的重量％。 每个微胶囊的壳材料由基本上含有腈单体的热塑性树脂制成。 在150℃下，热膨胀性物质的蒸气压为1.4〜3.0MPa。在橡胶组合物硫化之前，微胶囊的平均直径为20〜30μm。 由于硫化而膨胀的微胶囊的平均直径为40-80μm。 胎面橡胶占电池占用面积的比例为5〜30％。
-
公开(公告)号：US20100288406A1
公开(公告)日：2010-11-18
申请号：US12810774
申请日：2009-02-13
IPC分类号： B60C11/00
CPC分类号： C08L7/00 , B60C1/0016 , B60C11/14 , B60C2011/0025 , C08J9/32 , C08J2203/22 , C08J2307/00 , C08J2309/00 , C08K3/04 , C08K3/36 , C08K5/548 , C08K7/22 , C08K9/10 , C08L9/00 , C08L21/00 , C08L2666/08
摘要： Provided is a pneumatic tire whose frictional force on ice is improved by satisfactorily forming resin-encapsulated cells from heat-expandable microcapsules, even when a tread rubber contains silica. The tire is characterized in that: the tread rubber is made of a rubber composition containing 100 parts by weight of a diene rubber, 30 to 100 parts by weight of a reinforcing filler including at least 10 parts by weight of silica, and 1 to 20 parts by weight of microcapsules each encapsulating a heat-expandable substance; a sulfur-containing silane coupling agent is mixed in the rubber composition in an amount of 3 to 15 wt. % based on the weight of the silica; a shell material of each microcapsule is made of a thermoplastic resin which essentially contains a nitrile monomer (I); a vapor pressure of the heat-expandable substance is set at 1.4 to 3.0 MPa at 150° C.; an average particle diameter of the microcapsules is set at 20 to 30 μm before vulcanization of the rubber composition; an average particle diameter of the microcapsules expanded due to the vulcanization is set at 40 to 80 μm; and thus, a proportion of an area occupied by the cells in the tread rubber is set at 5 to 30%.
摘要翻译： 本发明提供一种充气轮胎，即使在胎面橡胶含有二氧化硅的情况下，也可以通过令人满意地形成来自热膨胀性微胶囊的树脂封装的细胞来提高冰上的摩擦力。 轮胎的特征在于：胎面橡胶由含有100重量份二烯橡胶的橡胶组合物制成，30至100重量份的包含至少10重量份二氧化硅的增强填料和1至20重量份 每个包封热膨胀物质的微胶囊重量份; 将含硫硅烷偶联剂在橡胶组合物中以3〜15重量％的量混合。 基于二氧化硅的重量％ 每个微胶囊的壳材料由基本上含有腈单体（I）的热塑性树脂制成; 在150℃下将热膨胀性物质的蒸气压设定为1.4〜3.0MPa。 在橡胶组合物硫化之前，将微胶囊的平均粒径设定为20〜30μm。 将由于硫化而膨胀的微胶囊的平均粒径设定为40〜80μm， 因此胎面胶中的细胞所占的面积的比例为5〜30％。
-
3.发明授权公开(公告)号：US08247465B2
公开(公告)日：2012-08-21
申请号：US12679661
申请日：2008-10-09
CPC分类号： B01J13/14 , B01J13/18 , B01J13/20 , C08J9/32 , C08J2203/22 , Y10T428/2982 , Y10T428/2998
摘要： Heat-expandable microspheres include a shell of thermoplastic resin and core material encapsulated in the shell. The core material include a blowing agent having a boiling point not higher than the softening point of the thermoplastic resin and a gas migration inhibitor having a boiling point higher than the softening point of the thermoplastic resin. The ratio of the gas migration inhibitor to the core material is at least 1 weight percent and below 30 weight percent. The average particle size of the heat-expandable microspheres ranges from 1 to 100 micrometers.
摘要翻译： 热膨胀性微球包括热塑性树脂的外壳和包封在壳中的芯材料。 核心材料包括沸点不高于热塑性树脂的软化点的发泡剂和沸点高于热塑性树脂的软化点的气体迁移抑制剂。 气体迁移抑制剂与核心材料的比例至少为1重量％且低于30重量％。 热膨胀性微球的平均粒径为1〜100微米。
-
4.发明授权公开(公告)号：US08324286B2
公开(公告)日：2012-12-04
申请号：US12089600
申请日：2006-11-16
申请人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takeyoshi Fukuda , Takayuki Aoki , Satoshi Kawanami
发明人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takeyoshi Fukuda , Takayuki Aoki , Satoshi Kawanami
CPC分类号： B01J13/14 , C08F220/14 , C08F220/44 , C08F220/48 , C08F222/1006 , Y10T428/2984
摘要： Heat-expandable microspheres include a shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin, have a maximum expanding ratio not lower than 50 times, and are thermally expanded into hollow particulates having a repeated-compression durability not lower than 75 percent. The method of producing the heat-expandable microspheres includes the steps of dispersing an oily mixture containing a polymerizable component and the blowing agent in an aqueous dispersing medium containing a specific water-soluble compound and polymerizing the polymerizable component contained in the oily mixture.
摘要翻译： 热膨胀性微球包括热塑性树脂的壳和其中包含沸点不高于热塑性树脂的软化点的发泡剂，其最大膨胀比不低于50倍，并且被热膨胀成具有 重复压缩耐久性不低于75％。 制造热膨胀性微球的方法包括以下步骤：将含有可聚合组分和发泡剂的油性混合物分散在含有特定水溶性化合物的水性分散介质中，并使包含在油性混合物中的可聚合组分聚合。
-
公开(公告)号：US20090176098A1
公开(公告)日：2009-07-09
申请号：US12067771
申请日：2006-10-04
CPC分类号： B01J13/14 , Y10T428/2982 , Y10T428/2984 , Y10T428/2985 , Y10T428/2987 , Y10T428/2998
摘要： A method that heat-expandable microspheres includes the use of a shell of thermoplastic resin and a non-fluorine blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin. The method includes a step of dispersing an oily mixture containing a polymerizable component, the blowing agent, and a polymerization initiator containing a peroxydicarbonate in an aqueous dispersing medium to polymerize the polymerizable component contained in the oily mixture. The resultant heat-expandable microspheres have a shell which is less apt to become thinner than its theoretical value, contain minimum amount of resin particle inside their shell, and have excellent heat-expanding performance.
摘要翻译： 热膨胀性微球的方法包括使用热塑性树脂的壳和封入其中的沸点不高于热塑性树脂的软化点的非氟发泡剂。 该方法包括将含有可聚合组分的油性混合物，发泡剂和含有过氧化二碳酸酯的聚合引发剂分散在水性分散介质中以使包含在油性混合物中的可聚合组分聚合的步骤。 所得到的热膨胀性微球体的外壳不易于其理论值变薄，在其壳内含有最少量的树脂颗粒，并且具有优异的热膨胀性能。
-
公开(公告)号：US08486531B2
公开(公告)日：2013-07-16
申请号：US13355647
申请日：2012-01-23
申请人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takayuki Aoki
发明人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takayuki Aoki
CPC分类号： B01J13/20 , B29C44/3461 , C08J9/143 , C08J9/32 , C08J2333/18 , Y10T428/2982 , Y10T428/2984 , Y10T428/2985 , Y10T428/2991 , Y10T428/2998
摘要： The present invention provides heat-expanded microspheres having high packing efficiency, and a production method thereof. The heat-expanded microspheres are produced by expanding heat-expandable microspheres, which comprise shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 micrometer, at a temperature not lower than their expansion initiating temperature, and the heat-expanded microspheres result in a void fraction not higher than 0.70.
摘要翻译： 本发明提供具有高填充效率的热膨胀微球及其制造方法。 热膨胀微球体是通过膨胀包含热塑性树脂壳和封装在其中的沸点不高于热塑性树脂的软化点的发泡剂的热膨胀性微球而制成的，平均粒径为1〜100 微米，其温度不低于其膨胀起始温度，热膨胀微球导致不高于0.70的空隙率。
-
公开(公告)号：US08329298B2
公开(公告)日：2012-12-11
申请号：US12067771
申请日：2006-10-04
CPC分类号： B01J13/14 , Y10T428/2982 , Y10T428/2984 , Y10T428/2985 , Y10T428/2987 , Y10T428/2998
摘要： A method that heat-expandable microspheres includes the use of a shell of thermoplastic resin and a non-fluorine blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin. The method includes, a step of dispersing an oily mixture containing a polymerizable component, the blowing agent, and a polymerization initiator containing a peroxydicarbonate in an aqueous dispersing medium to polymerize the polymerizable component contained in the oily mixture. The resultant heat-expandable microsphres have a shell which is less apt to become thinner than its theoretical value, contain minimum amount of resin particle inside their shell, and have excellent heat-expanding performance.
摘要翻译： 热膨胀性微球的方法包括使用热塑性树脂的壳和封入其中的沸点不高于热塑性树脂的软化点的非氟发泡剂。 该方法包括：将含有可聚合组分的油性混合物，发泡剂和含有过氧化二碳酸酯的聚合引发剂在含水分散介质中分散以使包含在油性混合物中的可聚合组分聚合的步骤。 所得到的热膨胀微孔具有较不易于其理论值变薄的外壳，其外壳中含有最少量的树脂颗粒，并且具有优异的热膨胀性能。
-
8.发明申请公开(公告)号：US20090149559A1
公开(公告)日：2009-06-11
申请号：US12089600
申请日：2006-11-16
申请人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takeyoshi Fukuda , Takayuki Aoki , Satoshi Kawanami
发明人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takeyoshi Fukuda , Takayuki Aoki , Satoshi Kawanami
CPC分类号： B01J13/14 , C08F220/14 , C08F220/44 , C08F220/48 , C08F222/1006 , Y10T428/2984
摘要： Heat-expandable microspheres include a shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin, have a maximum expanding ratio not lower than 50 times, and are thermally expanded into hollow particulates having a repeated-compression durability not lower than 75 percent. The method of producing the heat-expandable microspheres includes the steps of dispersing an oily mixture containing a polymerizable component and the blowing agent in an aqueous dispersing medium containing a specific water-soluble compound and polymerizing the polymerizable component contained in the oily mixture.
摘要翻译： 热膨胀性微球包括热塑性树脂的壳和其中包含沸点不高于热塑性树脂的软化点的发泡剂，其最大膨胀比不低于50倍，并且被热膨胀成具有 重复压缩耐久性不低于75％。 制造热膨胀性微球的方法包括以下步骤：将含有可聚合组分和发泡剂的油性混合物分散在含有特定水溶性化合物的水性分散介质中，并使包含在油性混合物中的可聚合组分聚合。
-
公开(公告)号：US08129020B2
公开(公告)日：2012-03-06
申请号：US12066057
申请日：2006-09-14
申请人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takayuki Aoki
发明人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takayuki Aoki
CPC分类号： B01J13/20 , B29C44/3461 , C08J9/143 , C08J9/32 , C08J2333/18 , Y10T428/2982 , Y10T428/2984 , Y10T428/2985 , Y10T428/2991 , Y10T428/2998
摘要： Heat-expanded microspheres having high packing efficiency are produced by expanding heat-expandable microspheres, which include a shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 micrometer, at a temperature not lower than their expansion initiating temperature, and the heat-expanded microspheres result in a void fraction not higher than 0.70.
摘要翻译： 具有高填充效率的热膨胀微球通过膨胀热膨胀性微球来制造，该微球包括热塑性树脂壳和封装在其中的发泡剂，其沸点不高于热塑性树脂的软化点，并且具有平均粒径 1至100微米，温度不低于其膨胀起始温度，热膨胀微球体的空隙率不高于0.70。
-
10.发明申请公开(公告)号：US20100204349A1
公开(公告)日：2010-08-12
申请号：US12679661
申请日：2008-10-09
CPC分类号： B01J13/14 , B01J13/18 , B01J13/20 , C08J9/32 , C08J2203/22 , Y10T428/2982 , Y10T428/2998
摘要： Heat-expandable microspheres include a shell of thermoplastic resin and core material encapsulated in the shell. The core material include a blowing agent having a boiling point not higher than the softening point of the thermoplastic resin and a gas migration inhibitor having a boiling point higher than the softening point of the thermoplastic resin. The ratio of the gas migration inhibitor to the core material is at least 1 weight percent and below 30 weight percent. The average particle size of the heat-expandable microspheres ranges from 1 to 100 micrometers.
摘要翻译： 热膨胀性微球包括热塑性树脂的外壳和包封在壳中的芯材料。 核心材料包括沸点不高于热塑性树脂的软化点的发泡剂和沸点高于热塑性树脂的软化点的气体迁移抑制剂。 气体迁移抑制剂与核心材料的比例至少为1重量％且低于30重量％。 热膨胀性微球的平均粒径为1〜100微米。
-
-
-
-
-
-
-
-
-
搜索结果
12 条记录 (耗时 0.029 秒)
