公开(公告)号：US5344874A

公开(公告)日：1994-09-06

申请号：US726763

申请日：1991-07-08

Applicant: Takao Doi ,  Noriko Itaya ,  Masami Yamashita ,  Nobuaki Kunii

Inventor： Takao Doi ,  Noriko Itaya ,  Masami Yamashita ,  Nobuaki Kunii

IPC: C08G18/08 ,  C08G18/40 ,  C08G18/54 ,  C08J3/07

CPC classification number: C08G18/40 ,  C08G18/0876 ,  C08G18/409 ,  C08G18/54 ,  C08G2101/00

Abstract: A process for producing a condensed resin dispersion, which comprises subjecting an aldehyde and a compound condensable with the aldehyde, or their precondensate, to a condensation reaction in a dispersion medium consisting essentially of water and/or an organic solvent, to precipitate fine condensed resin particles which hardly settle in said dispersion medium, and then replacing the water and/or the organic solvent by an active hydrogen-containing compound having at least two active hydrogen-containing groups reactive with isocyanate groups.

Abstract translation: 一种缩合树脂分散体的制造方法，其特征在于，使醛和可与醛缩合的化合物或其预缩合物在基本上由水和/或有机溶剂组成的分散介质中进行缩合反应，使细缩合树脂 几乎不沉淀在所述分散介质中的颗粒，然后用具有至少两个与异氰酸酯基团反应的活性氢基团的活性含氢化合物代替水和/或有机溶剂。

公开(公告)号：US5030685A

公开(公告)日：1991-07-09

申请号：US413584

申请日：1989-09-28

Applicant: Takao Doi ,  Noriko Itaya ,  Masami Yamashita ,  Nobuaki Kunii

Inventor： Takao Doi ,  Noriko Itaya ,  Masami Yamashita ,  Nobuaki Kunii

IPC: C08G18/08 ,  C08G18/40 ,  C08G18/54

CPC classification number: C08G18/40 ,  C08G18/0876 ,  C08G18/409 ,  C08G18/54 ,  C08G2101/00

Abstract: A process for producing a condensed resin dispersion, which comprises subjecting an aldehyde and a compound condensable with the aldehyde, or their precondensate, to a condensation reaction in a dispersion medium consisting essentially of water and/or an organic solvent, to precipitate fine condensed resin particles which hardly settle in said dispersion medium, and then replacing the water and/or the organic solvent by an active hydrogen-containing compound having at least two active hydrogen-containing groups reactive with isocyanate groups.

公开(公告)号：US5290898A

公开(公告)日：1994-03-01

申请号：US961059

申请日：1992-10-14

Applicant: Takao Doi ,  Noriko Itaya ,  Masami Yamashita

Inventor： Takao Doi ,  Noriko Itaya ,  Masami Yamashita

IPC: C08G18/40 ,  C08G18/50 ,  C08G18/54 ,  C08L75/08 ,  C08J9/30 ,  C08G12/32 ,  C08K5/06 ,  C08L61/28

CPC classification number: C08G18/4027 ,  C08G18/409 ,  C08G18/5045 ,  C08G18/544 ,  C08L75/08

Abstract: A condensed resin dispersion having fine particles of a condensed resin dispersed stably in a polyether polyol (c), the condensed resin being a reaction product of an aldehyde and a compound condensable with the aldehyde, or of their precondensate, wherein the fine particles of the condensed resin are fine condensed resin particles formed by the reaction and precipitation conducted in an isocyanate-modified polyether (b) obtained by reacting an organic polyisocyanate to a polyether (a) having at least one active hydrogen group reactive with an isocyanate group, or to such a polyether (a) and a low molecular weight active hydrogen-containing compound having at least one active hydrogen group, and having substantially no free isocyanate group.

Abstract translation: 一种冷凝树脂分散体，其具有在聚醚多元醇（c）中稳定分散的冷凝树脂微粒，所述缩合树脂是醛与可与醛缩合的化合物或其预缩合物的反应产物，其中， 缩合树脂是通过使有机多异氰酸酯与具有至少一个与异氰酸酯基反应的活性氢基团的聚醚（a）反应得到的异氰酸酯改性聚醚（b）中进行的反应和沉淀而形成的细缩合树脂颗粒， 这种聚醚（a）和具有至少一个活性氢基团且基本上不含游离异氰酸酯基团的低分子量含活性氢化合物。

公开(公告)号：US5438107A

公开(公告)日：1995-08-01

申请号：US121574

申请日：1993-09-16

Applicant: Takao Doi ,  Noriko Itaya ,  Masami Yamashita

Inventor： Takao Doi ,  Noriko Itaya ,  Masami Yamashita

IPC: C08G18/40 ,  C08G18/50 ,  C08G18/54 ,  C08L75/08 ,  C08J9/30 ,  C08G12/32 ,  C08K5/06 ,  C08L61/28

CPC classification number: C08G18/4027 ,  C08G18/409 ,  C08G18/5045 ,  C08G18/544 ,  C08L75/08

Abstract: A condensed resin dispersion having fine particles of a condensed resin dispersed stably in a polyether polyol (c), the condensed resin being a reaction product of an aldehyde and a compound condensable with the aldehyde, or of their precondensate, wherein the fine particles of the condensed resin are fine condensed resin particles formed by the reaction and precipitation conducted in an isocyanate-modified polyether (b) obtained by reacting an organic polyisocyanate to a polyether (a) having at least one active hydrogen group reactive with an isocyanate group, or to such a polyether (a) and a low molecular weight active hydrogen-containing compound having at least one active hydrogen group, and having substantially no free isocyanate group.

Abstract translation: 一种冷凝树脂分散体，其具有在聚醚多元醇（c）中稳定分散的冷凝树脂微粒，所述缩合树脂是醛与可与醛缩合的化合物或其预缩合物的反应产物，其中， 缩合树脂是通过使有机多异氰酸酯与具有至少一个与异氰酸酯基反应的活性氢基团的聚醚（a）反应得到的异氰酸酯改性聚醚（b）中进行的反应和沉淀而形成的细缩合树脂颗粒， 这种聚醚（a）和具有至少一个活性氢基团且基本上不含游离异氰酸酯基团的低分子量含活性氢化合物。

公开(公告)号：US4342840A

公开(公告)日：1982-08-03

申请号：US214283

申请日：1980-12-08

Applicant: Shigeyuki Kozawa ,  Takao Doi ,  Nobuaki Kunii

Inventor： Shigeyuki Kozawa ,  Takao Doi ,  Nobuaki Kunii

IPC: C08G18/63 ,  C08G18/67 ,  C08G18/14 ,  C07C125/06

CPC classification number: C08G18/675 ,  C08G18/635

Abstract: A polymer polyol is produced by polymerizing a monomer having a polymerizable unsaturated group in a nitrogen bond-containing unsaturated polyol or polyol mixture having at least two nitrogen-containing bonds formed by reacting isocyanate groups with active hydrogen groups, at least one polymerizable unsaturated group and at least 1.7 hydroxyl groups, as average.A polymer polyol is produced by polymerizing a monomer having a polymerizable unsaturated group in a nitrogen bond-containing unsaturated polyol or polyol mixture having at least 1.7 hydroxyl groups as average obtained by reacting a polyisocyanate with a mixture of a substantially saturated polyol having at least two hydroxyl groups and an unsaturated active hydrogen compound having at least one active hydrogen group and at least one polymerizable unsaturated group or by reacting said polyisocyanate with either of said substantially saturated polyol or said unsaturated active hydrogen compound and then reacting the remainder with the intermediate; or a polyol mixture obtained by diluting said nitrogen bond-containing unsaturated polyol or polyol mixture with a substantially saturated polyol.

Abstract translation: 聚合物多元醇通过在具有含氮键的不饱和多元醇或多元醇混合物中使具有聚合性不饱和基团的单体聚合而制备，所述多元醇混合物具有至少两个通过异氰酸酯基团与活性氢基团反应形成的含氮键，至少一个可聚合不饱和基团和 至少1.7个羟基，平均值。 聚合物多元醇是通过在具有至少1.7个羟基的含氮键的不饱和多元醇或多元醇混合物中聚合具有可聚合不饱和基团的单体而制备的，所述多元醇混合物的平均值通过使多异氰酸酯与具有至少两个 羟基和具有至少一个活性氢基团和至少一个可聚合不饱和基团的不饱和活性氢化合物，或通过使所述多异氰酸酯与所述基本上饱和的多元醇或所述不饱和活性氢化合物反应，然后使剩余物与中间体反应; 或通过用基本上饱和的多元醇稀释所述含氮键的不饱和多元醇或多元醇混合物而获得的多元醇混合物。

公开(公告)号：US4987271A

公开(公告)日：1991-01-22

申请号：US480126

申请日：1990-02-14

Applicant: Takashi Watabe ,  Hiromitsu Takeyasu ,  Takao Doi ,  Nobuaki Kunii

Inventor： Takashi Watabe ,  Hiromitsu Takeyasu ,  Takao Doi ,  Nobuaki Kunii

IPC: C08G65/26 ,  C08G65/30

CPC classification number: C08G65/2663 ,  C08G65/30

Abstract: A method for purifying a polyoxyalkylene alcohol, which comprises treating with a treating agent consisting essentially of a pH buffer, a polyoxyalkylene alcohol containing a double metal cyanide complex catalyst, synthesized by ring-opening polymerization of an alkylene oxide in the presence of said catalyst, and then removing the catalyst and the treating agent from the polyoxyalkylene alcohol.

公开(公告)号：US06875508B1

公开(公告)日：2005-04-05

申请号：US09914356

申请日：2000-02-24

Applicant: Nobuyoshi Nambu ,  Osamu Ito ,  Shiho Horiuchi ,  Takao Doi

Inventor： Nobuyoshi Nambu ,  Osamu Ito ,  Shiho Horiuchi ,  Takao Doi

IPC: B01J45/00 ,  B01J20/26 ,  B01J47/12 ,  C02F1/28 ,  C09K3/00 ,  D02G3/00 ,  D06M13/11 ,  D06M13/248 ,  D06M13/252 ,  D06M13/325 ,  D06M13/332 ,  D06M14/02 ,  D06M14/04 ,  D06M101/00 ,  D06M101/02 ,  D06M101/06 ,  D02M11/00

CPC classification number: C02F1/288 ,  B01J45/00 ,  C02F1/285 ,  C02F1/286 ,  C02F1/505 ,  C02F1/66 ,  C02F1/683 ,  C02F1/725 ,  C02F2101/20 ,  C02F2303/16 ,  C05D9/02 ,  D06M14/04 ,  D06M14/06 ,  Y10S428/917 ,  Y10T428/2913 ,  Y10T428/2933 ,  Y10T428/2967

Abstract: A fiber capable of forming a metal chelate and a process for producing the same are disclosed, wherein the fiber is characterized in that at least one metal chelate-forming compound selected from the group consisting of aminodicarboxylic acids, aminocarboxylic acids, thiocarboxylic acids and phosphoric acid, which are reactive with a glycidyl group, is bonded to a molecule of a natural fiber or regenerated fiber through a crosslinkable compound having a reactive double bond and a glycidyl group in its molecule. There are also disclosed a method of capturing metal ions using the fiber and a metal chelate fiber which can effectively make use of the characteristics of the metals and can be easily discarded or incinerated.

Abstract translation: 公开了能够形成金属螯合物的纤维及其制备方法，其中所述纤维的特征在于，至少一种金属螯合形成化合物选自氨基二羧酸，氨基羧酸，硫代羧酸和磷酸 通过其分子中具有反应性双键和缩水甘油基的交联性化合物与天然纤维或再生纤维的分子结合，其与缩水甘油基反应。 还公开了使用纤维和金属螯合纤维捕获金属离子的方法，其可以有效地利用金属的特性并且可以容易地丢弃或焚化。

公开(公告)号：US06869537B1

公开(公告)日：2005-03-22

申请号：US09979632

申请日：2000-05-22

Applicant: Nobuyoshi Nambu ,  Osamu Ito ,  Takao Doi

Inventor： Nobuyoshi Nambu ,  Osamu Ito ,  Takao Doi

IPC: B01D39/14 ,  B01D39/16 ,  B01J45/00 ,  C02F1/28 ,  C02F1/68 ,  C08F4/40 ,  C08F8/00 ,  C08F283/00 ,  D06M13/02 ,  D06M13/11 ,  D06M13/165 ,  D06M13/192 ,  D06M13/224 ,  D06M13/248 ,  D06M13/252 ,  D06M13/322 ,  D06M13/325 ,  D06M13/332 ,  D06M13/342 ,  D06M15/273 ,  D06M101/00 ,  D06M101/16 ,  D06M101/30 ,  D06M101/32 ,  D06M101/34 ,  C02F1/42

CPC classification number: D06M13/192 ,  B01D39/1623 ,  B01J45/00 ,  C02F1/285 ,  C02F1/683 ,  C02F2101/20 ,  D06M13/11 ,  D06M13/165 ,  D06M13/2246 ,  D06M13/252 ,  D06M13/342 ,  D06M15/273 ,  Y10S210/912 ,  Y10S210/913 ,  Y10S210/914

Abstract: A fiber capable of forming a metal chelate and a process for producing the same are disclosed, wherein the fiber is characterized in that at least one metal chelate-forming compound selected from the group consisting of aminocarboxylic acid, aminocarboxylic acid, thiocarboxylic acid and phosphoric acid, which are reactive with a glycidyl group, is bonded to a molecule of a synthetic fiber through a crosslinkable compound having a reactive double bond and a glycidyl group in its molecule. The chelate-forming fiber is excellent in capturing harmful heavy metal ions and can be easily produced in a simple and safe way at a low cost.

Abstract translation: 公开了能够形成金属螯合物的纤维及其制备方法，其中纤维的特征在于，选自氨基羧酸，氨基羧酸，硫代羧酸和磷酸中的至少一种形成金属螯合物的化合物 通过其分子中具有反应性双键和缩水甘油基的交联性化合物与缩水甘油基反应的化合物与合成纤维的分子结合。 螯合形成纤维在捕获有害的重金属离子方面优异，并且可以以简单和安全的方式以低成本容易地生产。

公开(公告)号：US06872317B1

公开(公告)日：2005-03-29

申请号：US09674167

申请日：1999-04-16

Applicant: Nobuyoshi Nambu ,  Osamu Ito ,  Nobutake Mihara ,  Takao Doi

Inventor： Nobuyoshi Nambu ,  Osamu Ito ,  Nobutake Mihara ,  Takao Doi

IPC: A61K31/22 ,  B01D15/00 ,  B01D39/14 ,  C02F1/28 ,  C02F1/68 ,  C02F9/00 ,  C07K14/705 ,  D06M13/10 ,  D06M13/192 ,  D06M13/332 ,  D06M13/342 ,  F16K15/04

CPC classification number: B01D39/1607

Abstract: A chelate-forming filter which comprises a filter medium made of natural, regenerated, or synthetic fibers wherein the fiber molecules have, incorporated therein, chelate-forming functional groups represented by general formula (1) [wherein G represents a residue of a chain sugar alcohol or of a polyhydric alcohol; and R represents hydrogen, (lower) alkyl, or -G (wherein G has the same meaning as the above G, and the two G's may be the same or different)] or (3) (wherein R1, R2, and R3 each represents lower alkylene; and n is an integer of 1 to 4).

Abstract translation: 一种螯合形成过滤器，其包含由天然，再生或合成纤维制成的过滤介质，其中所述纤维分子内含有由通式（1）表示的螯合形成官能团[其中G表示链糖的残基 醇或多元醇; 并且R表示氢，（低级）烷基或-G（其中G具有与上述G相同的含义，并且两个G可以相同或不同）]或（3）（其中R 1， 2>，R 3各自表示低级亚烷基，n为1〜4的整数。

公开(公告)号：US20050065363A1

公开(公告)日：2005-03-24

申请号：US10980238

申请日：2004-11-04

Applicant: Yoshihiko Mori ,  Takao Doi ,  Tetsuo Asakawa ,  Takanori Miyake

Inventor： Yoshihiko Mori ,  Takao Doi ,  Tetsuo Asakawa ,  Takanori Miyake

IPC: C07C67/055 ,  C07C67/39

CPC classification number: C07C67/055 ,  C07C69/017 ,  C07C69/157

Abstract: A phenyl ester is produced by allowing benzene, a carboxylic acid and molecular oxygen to react with each other in the presence of a catalyst comprising (A) palladium, (B) at least one element selected from elements of groups IIIb, IVb, Vb and VIb of the periodic table, and (C) at least one element selected from elements of groups IIIa and IVa of the periodic table. Preferably, element (B) is selected from elements of group VIb of the periodic table, and element (C) is contained in a metal oxide form in the catalyst. The catalytic activity can be maintained at a high level, and a phenyl ester is stably produced. The phenyl ester can be converted to phenol by a conventional procedure.

Abstract translation: 通过使苯，羧酸和分子氧在包含（A）钯，（B）选自IIIb，IVb，Vb族元素中的至少一种元素的催化剂存在下，使苯，羧酸和分子氧彼此反应来制备苯基酯， VIb，和（C）选自元素周期表IIIa和IVa族元素的至少一种元素。 优选地，元素（B）选自元素周期表VIb族的元素，元素（C）以催化剂中的金属氧化物形式包含。 可以将催化活性维持在高水平，并稳定地生产苯酯。 苯基酯可以通过常规方法转化成苯酚。