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1.发明授权公开(公告)号：US08232361B2
公开(公告)日：2012-07-31
申请号：US11908888
申请日：2006-02-27
IPC分类号： C08F120/18 , B32B7/12
CPC分类号： C09J133/066 , C09J7/385 , G02B5/3025 , G02B5/3083 , G02F2202/28 , Y10T156/11 , Y10T156/1158 , Y10T156/1917 , Y10T428/28
摘要： An optical pressure-sensitive adhesive of the invention comprises a base polymer having a functional group (F); and a coupling agent that has a benzyl ester group and is represented by Formula (1): wherein A1 and A2 are different functional groups, one of A1 and A2 shows reactivity or interaction with the functional group (F) of the base polymer, R1 is an optionally substituted alkylene group of 1 to 12 carbon atoms and/or an optionally substituted phenylene group, and R2 and R3 are each a hydrogen atom or an alkyl group of 1 to 12 carbon atoms and may be the same or different. The pressure-sensitive adhesive is use in pressure-sensitive adhesive optical films and so on that is excellent in terms of both durability and release property.
摘要翻译： 本发明的光学粘合剂包括具有官能团（F）的基础聚合物; 和具有苄基酯基并由式（1）表示的偶联剂：其中A1和A2是不同的官能团，A1和A2之一表示与基础聚合物的官能团（F）的反应性或相互作用，R1 是1〜12个碳原子的任选取代的亚烷基和/或任意取代的亚苯基，R 2和R 3各自为氢原子或碳原子数为1〜12的烷基，可以相同也可以不同。 压敏粘合剂用于耐久性和剥离性优异的压敏粘合剂光学膜等中。
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2.发明授权Method for separating an optical film bonded to an adherend with a pressure-sensitive adhesive optical film 有权用粘合型光学膜分离粘合到被粘物上的光学膜的方法公开(公告)号：US08388801B2
公开(公告)日：2013-03-05
申请号：US13538041
申请日：2012-06-29
IPC分类号： B32B38/10
CPC分类号： C09J133/066 , C09J7/385 , G02B5/3025 , G02B5/3083 , G02F2202/28 , Y10T156/11 , Y10T156/1158 , Y10T156/1917 , Y10T428/28
摘要： There is provided a method for separating an optical film bonded to an adherend with a pressure-sensitive adhesive layer interposed therebetween from the adherend. The pressure-sensitive adhesive layer is formed using an optical pressure-sensitive adhesive. The optical pressure-sensitive adhesive of the invention comprises a base polymer having a functional group (F); and a coupling agent that has a benzyl ester group and is represented by Formula (1): wherein A1 and A2 are different functional groups, one of A1 and A2 shows reactivity or interaction with the functional group (F) of the base polymer, R1 is an optionally substituted alkylene group of 1 to 12 carbon atoms and/or an optionally substituted phenylene group, and R2 and R3 are each a hydrogen atom or an alkyl group of 1 to 12 carbon atoms and may be the same or different.
摘要翻译： 提供了一种从被粘物分离粘合到被粘物上的光学膜与其中夹在其间的压敏粘合剂层的方法。 使用光学压敏粘合剂形成压敏粘合剂层。 本发明的光学粘合剂包括具有官能团（F）的基础聚合物; 和具有苄基酯基并由式（1）表示的偶联剂：其中A1和A2是不同的官能团，A1和A2之一表示与基础聚合物的官能团（F）的反应性或相互作用，R1 是1〜12个碳原子的任选取代的亚烷基和/或任意取代的亚苯基，R 2和R 3各自为氢原子或碳原子数为1〜12的烷基，可以相同也可以不同。
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3.发明申请公开(公告)号：US20120261077A1
公开(公告)日：2012-10-18
申请号：US13538041
申请日：2012-06-29
IPC分类号： B32B38/10
CPC分类号： C09J133/066 , C09J7/385 , G02B5/3025 , G02B5/3083 , G02F2202/28 , Y10T156/11 , Y10T156/1158 , Y10T156/1917 , Y10T428/28
摘要： There is provided a method for separating an optical film bonded to an adherend with a pressure-sensitive adhesive layer interposed therebetween from the adherend. The pressure-sensitive adhesive layer is formed using an optical pressure-sensitive adhesive. The optical pressure-sensitive adhesive of the invention comprises a base polymer having a functional group (F); and a coupling agent that has a benzyl ester group and is represented by Formula (1): wherein A1 and A2 are different functional groups, one of A1 and A2 shows reactivity or interaction with the functional group (F) of the base polymer, R1 is an optionally substituted alkylene group of 1 to 12 carbon atoms and/or an optionally substituted phenylene group, and R2 and R3 are each a hydrogen atom or an alkyl group of 1 to 12 carbon atoms and may be the same or different.
摘要翻译： 提供了一种从被粘物分离粘合到被粘物上的光学膜与其中夹在其间的压敏粘合剂层的方法。 使用光学压敏粘合剂形成压敏粘合剂层。 本发明的光学粘合剂包括具有官能团（F）的基础聚合物; 和具有苄基酯基并由式（1）表示的偶联剂：其中A1和A2是不同的官能团，A1和A2之一表示与基础聚合物的官能团（F）的反应性或相互作用，R1 是1〜12个碳原子的任选取代的亚烷基和/或任意取代的亚苯基，R 2和R 3各自为氢原子或碳原子数为1〜12的烷基，可以相同也可以不同。
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4.发明申请OPTICAL PRESSURE-SENSITIVE ADHESIVE, PRESSURE-SENSITIVE ADHESIVE OPTICAL FILM, IMAGE DISPLAY, AND METHOD FOR SEPARATING PRESSURE-SENSITIVE ADHESIVE OPTICAL FILM 有权光敏感粘合剂，压敏粘合剂光学膜，图像显示器和用于分离压敏粘合剂光学膜的方法公开(公告)号：US20090078371A1
公开(公告)日：2009-03-26
申请号：US11908888
申请日：2006-02-27
IPC分类号： C08F120/18 , B32B38/00
CPC分类号： C09J133/066 , C09J7/385 , G02B5/3025 , G02B5/3083 , G02F2202/28 , Y10T156/11 , Y10T156/1158 , Y10T156/1917 , Y10T428/28
摘要： An optical pressure-sensitive adhesive of the invention comprises a base polymer having a functional group (F); and a coupling agent that has a benzyl ester group and is represented by Formula (1): wherein A1 and A2 are different functional groups, one of A1 and A2 shows reactivity or interaction with the functional group (F) of the base polymer, R1 is an optionally substituted alkylene group of 1 to 12 carbon atoms and/or an optionally substituted phenylene group, and R2 and R3 are each a hydrogen atom or an alkyl group of 1 to 12 carbon atoms and may be the same or different. The pressure-sensitive adhesive is use in pressure-sensitive adhesive optical films and so on that is excellent in terms of both durability and release property.
摘要翻译： 本发明的光学粘合剂包括具有官能团（F）的基础聚合物; 和具有苄基酯基并由式（1）表示的偶联剂：其中A1和A2是不同的官能团，A1和A2之一表示与基础聚合物的官能团（F）的反应性或相互作用，R1 是1〜12个碳原子的任选取代的亚烷基和/或任意取代的亚苯基，R 2和R 3各自为氢原子或碳原子数为1〜12的烷基，可以相同也可以不同。 压敏粘合剂用于耐久性和剥离性优异的压敏粘合剂光学膜等中。
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5.发明授权Adhesive layer for optical film, optical film having adhesive layer, image display device, and detachment method for optical film 有权用于光学膜的粘合剂层，具有粘合剂层的光学膜，图像显示装置和用于光学膜的剥离方法公开(公告)号：US09029468B2
公开(公告)日：2015-05-12
申请号：US13988631
申请日：2011-11-18
申请人： Kunihiro Inui , Toshitsugu Hosokawa , Takaaki Ishii , Masayuki Satake , Kenichi Okada , Toshitaka Takahashi , Taiki Shimokuri , Yousuke Makihata
发明人： Kunihiro Inui , Toshitsugu Hosokawa , Takaaki Ishii , Masayuki Satake , Kenichi Okada , Toshitaka Takahashi , Taiki Shimokuri , Yousuke Makihata
IPC分类号： B32B38/10 , C09J133/08 , C09J7/02 , C08L33/02 , C09J133/04 , G02F1/1335 , C09D133/08 , C09J7/00 , C08K3/36
CPC分类号： C09J133/08 , B32B38/10 , C08K3/36 , C08L33/02 , C08L2201/54 , C09D133/08 , C09J7/00 , C09J7/10 , C09J7/385 , C09J133/04 , C09J2201/606 , C09J2201/622 , C09J2203/318 , C09J2205/102 , C09J2433/00 , G02F1/1335 , G02F1/133528 , G02F2202/28 , Y10T156/11 , Y10T428/2891
摘要： A pressure-sensitive adhesive layer for an optical film made from an aqueous dispersion-type pressure-sensitive adhesive composition, wherein the aqueous dispersion-type pressure-sensitive adhesive composition is an aqueous dispersion comprising a water-dispersible (meth)acryl-based copolymer (A) having a glass transition temperature from −55° C. to less than 0° C.; and a water-soluble or water-dispersible component (B) having a glass transition temperature of 0° C. or more, a mixture ratio (A)/(B) is in the range of 50-97/3-50, the component (B) forms domains with maximum lengths between 1 nm and 200 nm in a resin component made of the (meth)acryl-based copolymer (A), and the pressure-sensitive adhesive layer has a haze value (H20) of 1% or less when having a thickness of 20 μm. The pressure-sensitive adhesive layer for an optical film, which is made from an aqueous dispersion-type pressure-sensitive adhesive composition has good reworkability or recyclability, and has a sufficient level of durability.
摘要翻译： 一种由水分散型压敏粘合剂组合物制成的用于光学膜的压敏粘合剂层，其中所述水性分散型压敏粘合剂组合物是包含水分散性（甲基）丙烯酸类共聚物 （A）的玻璃化转变温度为-55℃至小于0℃; 和玻璃化转变温度为0℃以上的水溶性或水分散性成分（B），混合比（A）/（B）在50-97 / 3-50的范围内， 在（甲基）丙烯酸系共聚物（A）的树脂成分中，成分（B）形成最大长度在1nm〜200nm之间的区域，该粘合剂层的雾度值（H 2 O）为1％ 或更小。 由水分散型压敏粘合剂组合物制成的用于光学膜的压敏粘合剂层具有良好的再加工性或可再循环性，并且具有足够的耐久性。
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6.发明授权公开(公告)号：US08703297B2
公开(公告)日：2014-04-22
申请号：US11577690
申请日：2005-10-12
CPC分类号： G02B1/16 , B32B27/00 , G02B1/105 , G02B1/12 , G02B27/0006 , G02F2202/22 , G02F2202/28 , H01L51/0036 , H01L51/5281 , Y10T428/25 , Y10T428/254 , Y10T428/28 , Y10T428/31504 , Y10T428/31786
摘要： The present invention aims at providing an antistatic optical film having excellent antistatic effect and high light transmittance, wherein an antistatic layer laminated on at least one side of the optical film. An antistatic optical film having an antistatic layer laminated on at least one side of the optical film, wherein rubbing treatment is performed on a surface of the optical film on which the antistatic layer is laminated, and a conductive polymer in the antistatic layer is aligned.
摘要翻译： 本发明的目的在于提供一种具有优异的抗静电效果和高透光率的抗静电光学膜，其中层压在光学膜的至少一侧的抗静电层。 在光学膜的至少一面层叠有抗静电层的抗静电光学膜，其中对抗静电层的光学膜的表面进行摩擦处理，并且将抗静电层中的导电性聚合物排列。
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7.发明申请PRESSURE-SENSITIVE ADHESIVE LAYER FOR TRANSPARENT CONDUCTIVE FILM, TRANSPARENT CONDUCTIVE FILM WITH PRESSURE-SENSITIVE ADHESIVE LAYER, TRANSPARENT CONDUCTIVE LAMINATE, AND TOUCH PANEL 审中-公开用于透明导电膜的压敏粘合层，具有压敏粘合层的透明导电膜，透明导电层压板和触控面板公开(公告)号：US20130093438A1
公开(公告)日：2013-04-18
申请号：US13703770
申请日：2011-07-22
申请人： Toshitsugu Hosokawa , Kunihiro Inui , Takaaki Ishii , Masayuki Satake , Ai Murakami , Yuka Yamazaki
发明人： Toshitsugu Hosokawa , Kunihiro Inui , Takaaki Ishii , Masayuki Satake , Ai Murakami , Yuka Yamazaki
CPC分类号： C09J143/02 , B32B7/06 , B32B7/12 , B32B27/306 , B32B2307/412 , B32B2405/00 , B32B2457/202 , B32B2457/208 , C08K3/28 , C09J7/22 , C09J7/38 , C09J7/385 , C09J133/08 , C09J2203/318 , C09J2205/102 , C09J2433/00 , G06F3/044 , Y10T428/2848
摘要： A pressure-sensitive adhesive layer of the invention for transparent conductive film has a thickness of 10 μm to 100 μm, and is made from a water-dispersible acryl-based pressure-sensitive adhesive that is an aqueous dispersion containing a water-dispersible (meth)acryl-based polymer and a water-soluble basic component, wherein the water-dispersible (meth)acryl-based polymer comprises 100 parts by weight of an alkyl(meth)acrylate with an alkyl group of 4 to 14 carbon atoms, as a monomer unit, and 1 to 8 parts by weight of a carboxyl group-containing monomer as a copolymerized monomer unit, and the pressure-sensitive adhesive layer contains 200 ng to 500,000 ng of the water-soluble basic component per 1 cm2 as determined by measurement of the pressure-sensitive adhesive layer. The pressure-sensitive adhesive layer can have satisfactory durability in a high-temperature or high-temperature, high-humidity environment and can suppress corrosion in a high-temperature, high-humidity environment.
摘要翻译： 本发明的透明导电膜用粘合剂层的厚度为10μm〜100μm，由作为水分散体的水分散性丙烯酸类粘合剂构成，该水性分散体含有水分散性（甲基 ）丙烯酸类聚合物和水溶性碱性成分，其中所述水分散性（甲基）丙烯酸类聚合物包含100重量份具有4至14个碳原子的烷基的（甲基）丙烯酸烷基酯，作为 单体单元和1〜8重量份作为共聚单体单元的含羧基单体，并且粘合剂层含有200〜500,000ng水溶性碱性组分/ 1cm 2，通过测定测定 的压敏粘合剂层。 压敏粘合剂层在高温高温高湿环境下具有令人满意的耐久性，能够抑制高温高湿环境下的腐蚀。
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8.发明申请ADHESIVE LAYER FOR OPTICAL FILM, OPTICAL FILM HAVING ADHESIVE LAYER, IMAGE DISPLAY DEVICE, AND DETACHMENT METHOD FOR OPTICAL FILM 有权用于光学胶片的粘合层，具有粘合层的光学膜，图像显示装置和用于光学膜的分离方法公开(公告)号：US20130248118A1
公开(公告)日：2013-09-26
申请号：US13988631
申请日：2011-11-18
申请人： Kunihiro Inui , Toshitsugu Hosokawa , Takaaki Ishii , Masayuki Satake , Kenichi Okada , Toshitaka Takahashi , Taiki Shimokuri , Yousuke Makihata
发明人： Kunihiro Inui , Toshitsugu Hosokawa , Takaaki Ishii , Masayuki Satake , Kenichi Okada , Toshitaka Takahashi , Taiki Shimokuri , Yousuke Makihata
IPC分类号： C09J133/08 , B32B38/10 , C09J7/02
CPC分类号： C09J133/08 , B32B38/10 , C08K3/36 , C08L33/02 , C08L2201/54 , C09D133/08 , C09J7/00 , C09J7/10 , C09J7/385 , C09J133/04 , C09J2201/606 , C09J2201/622 , C09J2203/318 , C09J2205/102 , C09J2433/00 , G02F1/1335 , G02F1/133528 , G02F2202/28 , Y10T156/11 , Y10T428/2891
摘要： A pressure-sensitive adhesive layer for an optical film made from an aqueous dispersion-type pressure-sensitive adhesive composition, wherein the aqueous dispersion-type pressure-sensitive adhesive composition is an aqueous dispersion comprising a water-dispersible (meth)acryl-based copolymer (A) having a glass transition temperature from −55° C. to less than 0° C.; and a water-soluble or water-dispersible component (B) having a glass transition temperature of 0° C. or more, a mixture ratio (A)/(B) is in the range of 50-97/3-50, the component (B) forms domains with maximum lengths between 1 nm and 200 nm in a resin component made of the (meth)acryl-based copolymer (A), and the pressure-sensitive adhesive layer has a haze value (H20) of 1% or less when having a thickness of 20 μm. The pressure-sensitive adhesive layer for an optical film, which is made from an aqueous dispersion-type pressure-sensitive adhesive composition has good reworkability or recyclability, and has a sufficient level of durability.
摘要翻译： 一种由水分散型压敏粘合剂组合物制成的用于光学膜的压敏粘合剂层，其中所述水性分散型压敏粘合剂组合物是包含水分散性（甲基）丙烯酸类共聚物 （A）的玻璃化转变温度为-55℃至小于0℃; 和玻璃化转变温度为0℃以上的水溶性或水分散性成分（B），混合比（A）/（B）在50-97 / 3-50的范围内， 在（甲基）丙烯酸系共聚物（A）的树脂成分中，成分（B）形成最大长度在1nm〜200nm之间的区域，该粘合剂层的雾度值（H 2 O）为1％ 或更小。 由水分散型压敏粘合剂组合物制成的用于光学膜的压敏粘合剂层具有良好的再加工性或可再循环性，并且具有足够的耐久性。
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9.发明申请ADHESIVE LAYER FOR OPTICAL FILM, METHOD FOR PRODUCING SAME, OPTICAL FILM WITH ADHESIVE LAYER, AND IMAGE DISPLAY DEVICE 审中-公开用于光学膜的粘合层，其制造方法，具有胶粘层的光学膜和图像显示装置公开(公告)号：US20130182324A1
公开(公告)日：2013-07-18
申请号：US13822499
申请日：2011-09-13
IPC分类号： C09J133/12 , G02B5/30
CPC分类号： C09J133/12 , C08F2220/1825 , C09J7/22 , C09J7/38 , C09J2201/622 , C09J2203/318 , C09J2433/00 , G02B5/30 , G02B5/3025 , Y10T428/254 , C08F220/14 , C08F220/06
摘要： The pressure-sensitive adhesive layer for an optical film of the invention is formed by a process comprising applying a water-dispersible pressure-sensitive adhesive containing emulsion particles comprising polymer particles emulsified with a surfactant and then drying the applied water-dispersible pressure-sensitive adhesive, and is in such a state that the polymer particles have a number average particle size (a) of 10 nm to 100 nm and that the ratio (a/b) of the number average particle size (a) to the average distance (b) between adjacent polymer particles is from 80/20 to 99.9/0.1, when the pressure-sensitive adhesive layer being observed with a transmission electron microscope. The pressure-sensitive adhesive layer makes it possible to reduce depolarization even when it is used on a high-contrast polarizing plate or any other component having a high degree of polarization.
摘要翻译： 本发明的光学膜用粘合剂层通过以下方法形成，该方法包括：将含有乳液颗粒的乳液颗粒与含有表面活性剂乳化的水分散性压敏粘合剂，然后干燥所施加的水分散性压敏粘合剂 并且处于这样的状态，即聚合物颗粒的数均粒径（a）为10nm至100nm，并且数均粒径（a）与平均距离（b）的比（a / b） ）在80/20至99.9 / 0.1之间，当透射电子显微镜观察粘合剂层时。 即使将其用于高对比度偏光板或具有高度偏振度的任何其他部件，也可以减小去极化。
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公开(公告)号：US10266629B2
公开(公告)日：2019-04-23
申请号：US13641904
申请日：2011-05-16
申请人： Kunihiro Inui , Toshitsugu Hosokawa , Takaaki Ishii , Masayuki Satake , Kenichi Okada , Toshitaka Takahashi , Yousuke Makihata , Taiki Shimokuri , Shusaku Goto , Takeharu Kitagawa , Minoru Miyatake , Tomohiro Mori , Takashi Kamijo
发明人： Kunihiro Inui , Toshitsugu Hosokawa , Takaaki Ishii , Masayuki Satake , Kenichi Okada , Toshitaka Takahashi , Yousuke Makihata , Taiki Shimokuri , Shusaku Goto , Takeharu Kitagawa , Minoru Miyatake , Tomohiro Mori , Takashi Kamijo
IPC分类号： C08F265/06 , C08F220/06 , C09J151/06 , C08F220/18
摘要： An aqueous dispersion-type pressure-sensitive adhesive composition for an optical film includes a emulsion particles of a core-shell structure, wherein the emulsion particles include a (meth)acryl-based copolymer (A) having a glass transition temperature of −55° C. to 0° C. and a (meth)acryl-based copolymer (B) having a glass transition temperature of 0° C. to 180° C., in a single emulsion particle, one of the copolymers (A) and (B) forms a core layer, and another forms a shell layer, at least one of the copolymers (A) and (B) contains a carboxyl group-containing monomer, a difference of the glass transition temperatures between the copolymers (A) and (B) is 50° C. or more, and a ratio (A)/(B) (by weight) is in the range of 50/50 to 90/10.
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