公开(公告)号：US5106998A

公开(公告)日：1992-04-21

申请号：US491157

申请日：1990-03-09

申请人： Takashi Tanaka ,  Satoshi Imura ,  Kenji Tanaka ,  Yasuji Kida

发明人： Takashi Tanaka ,  Satoshi Imura ,  Kenji Tanaka ,  Yasuji Kida

IPC分类号： C07D311/96 ,  C07D407/04 ,  C07D409/04 ,  C07D417/04 ,  C07D491/04 ,  C07D491/107 ,  C07D495/04 ,  C08K5/1545 ,  C09K9/02

CPC分类号： C07D407/04 ,  C07D311/96 ,  C07D409/04 ,  C07D417/04 ,  C07D491/04 ,  C07D495/04 ,  C08K5/1545 ,  C09K9/02

摘要： Disclosed is a compound represented by the following general formula(I): ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, represent a hydrogen atom, an alkyl group, an aryl group, an aralkyl group or a substituted amino group, R.sub.3 and R.sub.4, which may be the same or different, represent an alkyl group, or R.sub.3 and R.sub.4 together form a nobornylidene group or bicyclo (3, 3, 1) 9-nonylidene group which may have a substituent, and ##STR2## represents a divalent aromatic hydrocarbon group or divalent unsaturated heterocyclic group which may have a substituent, with the proviso that when R.sub.3 and R.sub.4 represent an alkyl group, ##STR3## represents a bicyclic aromatic fused ring which is substituted with at least one substituent selected form the group consisting of a halgoen atom, an alkyl group, an alkoxy group, --R.sub.5 --S--R.sub.6 and ##STR4## (in which R.sub.5 represents an alkylene group or --O--R.sub.8).sub.n (in which R.sub.8 represents an alkylene group and n is a positive integer), R.sub.6 and R.sub.7, which may be the same or different, represent an alkyl group, and X represents --N

公开(公告)号：US4882438A

公开(公告)日：1989-11-21

申请号：US268497

申请日：1988-11-08

申请人： Takashi Tanaka ,  Satoshi Imura ,  Yasuji Kida

发明人： Takashi Tanaka ,  Satoshi Imura ,  Yasuji Kida

IPC分类号： C07D209/94 ,  C07D209/96 ,  C07D307/93 ,  C07D487/10 ,  C07D491/10 ,  C07D491/107 ,  C07D493/10 ,  C07D495/04 ,  C07D495/10 ,  C07D521/00 ,  C09K9/02 ,  G02C7/02 ,  G02F1/17 ,  G03C1/685 ,  G03C1/73

CPC分类号： C07D487/10 ,  C07D209/96 ,  C07D307/93 ,  C07D491/10 ,  C07D493/10 ,  C07D495/04 ,  C07D495/10 ,  C09K9/02 ,  G03C1/73 ,  Y10S430/163

摘要： A compound represented by the following general formula [I] ##STR1## wherein ##STR2## represents a norbornylidene group or an adamantylidene group each of which may have a substituent, andX represents an oxygen atom, the group >N-R.sub.2, the group >N-A.sub.1 -B.sub.1 --A.sub.2).sub.m (B.sub.2).sub.n R.sub.3, the group >N-A.sub.3 -A.sub.4, or the group >N-A.sub.3 -R.sub.4, provided that when ##STR3## is an adamantylidene group, X is selected from the above groups excepting the oxygen atom and the group >N-R.sub.2 ; and plastic lens containing the compound of the above formula [I].

公开(公告)号：US5349065A

公开(公告)日：1994-09-20

申请号：US977882

申请日：1992-11-17

申请人： Takashi Tanaka ,  Satoshi Imura ,  Kenji Tanaka ,  Yasuji Kida

发明人： Takashi Tanaka ,  Satoshi Imura ,  Kenji Tanaka ,  Yasuji Kida

IPC分类号： C07D311/96 ,  C07D407/04 ,  C07D409/04 ,  C07D417/04 ,  C07D491/04 ,  C07D491/107 ,  C07D495/04 ,  C08K5/1545 ,  C09K9/02 ,  C07D311/68

CPC分类号： C07D407/04 ,  C07D311/96 ,  C07D409/04 ,  C07D417/04 ,  C07D491/04 ,  C07D495/04 ,  C08K5/1545 ,  C09K9/02

摘要： A compound represented by the following general formula (II): ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, a phenyl group, a benzyl group, a phenethyl group, an alkylamine group having 1 to 4 carbon atoms, or a dialkylamino group having 2 to 8 carbon atoms, and ##STR2## represents a nobornylidene group or bicyclo [3,3,1]9-nonylidene group which may have a substituent, and ##STR3## represents a pyridine, quinoline, pyrrole or benzothiophene group which may have a substituent.

摘要翻译： 由下列通式（II）表示的化合物：其中R 1和R 2可以相同或不同，表示氢原子，具有1-20个碳原子的烷基，苯基， 苄基，苯乙基，碳原子数1〜4的烷基胺基或碳原子数2〜8的二烷基氨基，作为降冰片基或双环[3,3,1] 9-壬叉基 其可以具有取代基，并且表示可以具有取代基的吡啶，喹啉，吡咯或苯并噻吩基团。

公开(公告)号：US5130058A

公开(公告)日：1992-07-14

申请号：US373100

申请日：1989-06-29

申请人： Takashi Tanaka ,  Kenji Tanaka ,  Satoshi Imura ,  Yasuji Kida

发明人： Takashi Tanaka ,  Kenji Tanaka ,  Satoshi Imura ,  Yasuji Kida

IPC分类号： G03C1/685 ,  C07D209/96 ,  C07D307/77 ,  C07D307/92 ,  C07D307/93 ,  C07D487/10 ,  C07D491/10 ,  C07D491/107 ,  C07D493/10 ,  C07D495/10 ,  C07D521/00 ,  C09K9/02

CPC分类号： C07D307/92 ,  C07D307/93 ,  C07D487/10 ,  C07D491/10 ,  C07D493/10 ,  C07D495/10 ,  C09K9/02

摘要： A photochromic compound represented by the following general formula [I] ##STR1## wherein ##STR2## represents a divalent aromatic hydrocarbon group or a divalent heterocyclic group each of which may have a substituent,R.sub.1 represents a monovalent hydrocarbon group or a monovalent heterocyclic group each of which may have a substituent, ##STR3## represents a norbornylidene or adamantylidene group which may have a substituent,X represents an oxygen atom or a group of the formula >N--R.sub.3 in which R.sub.3 represents a hydrogen atom or a hydrocarbon group which may have a substituent, andR.sub.2 represents a monovalent hydrocarbon group which may have a substituent.Also provided are a process for production of the photochromic compound, a composition containing the photochromic compound, and the use of the photochromic compound. The colored form of this photochromic compound has excellent thermal stability.

公开(公告)号：US4960678A

公开(公告)日：1990-10-02

申请号：US403487

申请日：1989-09-06

申请人： Takashi Tanaka ,  Satoshi Imura ,  Yasuji Kida

发明人： Takashi Tanaka ,  Satoshi Imura ,  Yasuji Kida

IPC分类号： C07D209/94 ,  C07D209/96 ,  C07D307/93 ,  C07D487/10 ,  C07D491/10 ,  C07D491/107 ,  C07D493/10 ,  C07D495/04 ,  C07D495/10 ,  C07D521/00 ,  C09K9/02 ,  G02C7/02 ,  G02F1/17 ,  G03C1/685 ,  G03C1/73 ,  G03C1/733

CPC分类号： C07D487/10 ,  C07D209/96 ,  C07D307/93 ,  C07D491/10 ,  C07D493/10 ,  C07D495/04 ,  C07D495/10 ,  C09K9/02 ,  G03C1/73 ,  Y10S430/163

摘要： A compound represented by the following general formula [I] ##STR1## wherein ##STR2## represents a norbornylidene group or an adamantylidene group each of which may have a substituent, andX represents an oxygen atom, the group >N--R.sub.2, the group >N--A.sub.1 --B.sub.1 --A.sub.2).sub.m (B.sub.2).sub.n R.sub.3, the group >N--A.sub.3 --A.sub.4, or the group >N--A.sub.3 --A.sub.4, provided that when ##STR3## is an adamantylidene group, X is selected from the above groups excepting the oxygen atom and the group >N--R.sub.2 ; and plastic lens containing the compound of the above formula [I].

公开(公告)号：US5246989A

公开(公告)日：1993-09-21

申请号：US676285

申请日：1991-03-28

申请人： Kayo Iwamoto ,  Takashi Tanaka ,  Satoshi Imura ,  Seiji Okazaki ,  Shinsuke Tanaka

发明人： Kayo Iwamoto ,  Takashi Tanaka ,  Satoshi Imura ,  Seiji Okazaki ,  Shinsuke Tanaka

IPC分类号： C07D498/10 ,  C07D498/20 ,  C07D498/22 ,  G03C1/685

CPC分类号： C07D498/10 ,  C07D498/20 ,  C07D498/22 ,  G03C1/685

摘要： A photochromic compound of the present invention is a spiroxazine compound represented by the following formula: ##STR1## wherein R.sup.1 to R.sup.3 represent a monovalent organic group such as alkyl group, Y represents a fused heterocyclic aromatic hydrocarbon group or an unsaturated heterocyclic group if R.sup.1 and R.sup.2 are both methyl groups, and represents an aromatic hydrocarbon group or unsaturated heterocyclic group if R.sup.1 and R.sup.2 are other than the above mentioned. This compound shows an excellent photochromic characteristics even at high temperatures not less than ambient temperature.

公开(公告)号：US5879591A

公开(公告)日：1999-03-09

申请号：US776243

申请日：1997-01-24

申请人： Hironobu Nagoh ,  Kazumasa Itonaga ,  Satoshi Imura

发明人： Hironobu Nagoh ,  Kazumasa Itonaga ,  Satoshi Imura

IPC分类号： C08J5/00 ,  C08F2/44 ,  C08F22/10 ,  C08F290/00 ,  C08F299/02 ,  C08G59/40 ,  C08K5/35 ,  C09D4/00 ,  C09D4/02 ,  C09D133/04 ,  C09D133/06 ,  C09K9/02 ,  G03C1/685 ,  G03C1/73 ,  G02B5/23

CPC分类号： C09K9/02 ,  C08F2/44 ,  C08F22/105 ,  G03C1/733 ,  G03C1/685

摘要： A process for producing a photochromic cured product by allowing an unpurified, impurities-containing polyfunctional (meth)acrylate monomer such as unpurified polyalkylene glycol dimethacrylate and a photochromic spirooxazine compound to contain a compound having at least one epoxy group in the molecule such as glycidyl methacrylate and then polymerizing the resulting composition. The process can provide a spirooxazine-based photochromic cured product which hardy undergoes initial coloring and is superior in initial color-developing performance.

摘要翻译： PCT No.PCT / JP96 / 01386 Sec。 371日期1997年1月24日 102（e）日期1997年1月24日PCT提交1996年5月24日PCT公布。 公开号WO96 / 37575 日期：1996年11月28日一种通过使未纯化的含杂质的多官能（甲基）丙烯酸酯单体如未纯化的聚亚烷基二醇二甲基丙烯酸酯和光致变色螺恶嗪化合物含有含有至少一个环氧基的化合物的方法制备光致变色固化产物 分子如甲基丙烯酸缩水甘油酯，然后聚合所得组合物。 该方法可以提供耐受初始着色的螺恶嗪基光致变色固化产物，并且具有优异的初始显色性能。

公开(公告)号：US5556931A

公开(公告)日：1996-09-17

申请号：US499070

申请日：1995-07-06

申请人： Satoshi Imura ,  Hironobu Nagoh ,  Kazuhiko Kuramoto

发明人： Satoshi Imura ,  Hironobu Nagoh ,  Kazuhiko Kuramoto

IPC分类号： C08F20/10 ,  C08F220/30 ,  C08F290/00 ,  C08F290/06 ,  G02B1/04 ,  C08F220/20 ,  C08F220/10

CPC分类号： C08F220/30 ,  G02B1/041

摘要： A polymerizable composition comprising at least two di(meth)acrylate compounds of the specific general formula (I), e.g., dimethacrylate compounds of polyethylene glycol adduct of 2,2-bis(4-hydroxyphenyl)propane, wherein the content of di(meth)acrylate compound of the general formula (I) in which m+n is 2 to 3 is 30 to 80 mol % and the content of di(meth)acrylate compound of the general formula (I) in which m+n is 6 to 12 is 20 to 50 mol %, and organic glass formed of a polymer from the polymerizable composition, the polymerizable composition being suitable as a transparent resin, particularly as a raw material for an ophthalmic lens which is free of optical strain, has sufficient hardness and is excellent in impact resistance and light resistance.

摘要翻译： 一种包含至少两种特定通式（I）的二（甲基）丙烯酸酯化合物的可聚合组合物，例如2,2-双（4-羟基苯基）丙烷的聚乙二醇加合物的二甲基丙烯酸酯化合物，其中二（甲基） ）m + n为2〜3的通式（I）的丙烯酸酯化合物为30〜80摩尔％，通式（I）的二（甲基）丙烯酸酯化合物的含量m + n为6〜 12为20〜50摩尔％，可聚合组合物由聚合物形成的有机玻璃，可聚合组合物作为透明树脂，特别是作为无光学应变的眼镜用原料，具有足够的硬度和 耐冲击性和耐光性优异。

公开(公告)号：US07036980B2

公开(公告)日：2006-05-02

申请号：US10329514

申请日：2002-12-27

申请人： Ryoichi Hirano ,  Satoshi Imura ,  Noriaki Nakayamada

发明人： Ryoichi Hirano ,  Satoshi Imura ,  Noriaki Nakayamada

IPC分类号： G01K13/12 ,  G01K1/16

CPC分类号： B82Y10/00 ,  B82Y40/00 ,  G03F1/78 ,  H01J37/3174 ,  H01J2237/2001 ,  H01J2237/304 ,  Y10S430/143

摘要： A pattern forming apparatus includes a drawing chamber having a drawing substrate on which an original pattern is drawn, a first temperature control unit having a first temperature regulator to make the temperature of the drawing chamber constant, and a constant-temperature member arranged near the drawing substrate. The pattern forming apparatus further includes a second temperature control unit having a second temperature regulator. The second temperature control unit is configured to control the set temperature of the constant-temperature member independently such that the temperature of the drawing substrate becomes substantially constant when the original pattern is drawn.

摘要翻译： 图案形成装置包括具有绘制原始图案的绘图基板的拉伸室，具有使拉伸室的温度恒定的第一温度调节器的第一温度控制单元和布置在图中的恒温部件 基质。 图案形成装置还包括具有第二温度调节器的第二温度控制单元。 第二温度控制单元被配置为独立地控制恒温部件的设定温度，使得当拉制原始图案时拉伸基板的温度基本上恒定。

公开(公告)号：US5708063A

公开(公告)日：1998-01-13

申请号：US601832

申请日：1996-02-15

申请人： Satoshi Imura ,  Tsuneyoshi Tanizawa ,  Takashi Kobayakawa

发明人： Satoshi Imura ,  Tsuneyoshi Tanizawa ,  Takashi Kobayakawa

IPC分类号： C07D209/96 ,  C07D209/66 ,  C07D209/90 ,  C07D307/92 ,  C07D487/10 ,  C07D491/10 ,  C07D491/107 ,  C07D493/04 ,  C07D493/10 ,  C07D495/04 ,  C07D495/10 ,  C09K9/02 ,  G03C1/73 ,  G03F7/004 ,  C08K5/15 ,  C08K5/3417

CPC分类号： C07D307/92 ,  C07D209/66 ,  C07D487/10 ,  C07D491/10 ,  C07D493/10 ,  C07D495/10 ,  G03C1/73

摘要： A fulgide or fulgimide compound having a cyclopropyl group as a substituent. The compound has excellent durability which changes reversibly in color from a colorless form to a colored form by the action of light containing ultraviolet rays such as sunlight or the light from a mercury lamp. There are also provided processes for its production, a composition comprising it, and its use.

摘要翻译： 具有环丙基作为取代基的吡啶或菲咯啉化合物。 该化合物具有优异的耐久性，其通过含有紫外线如阳光或来自汞灯的光的光的作用从颜色可逆地从无色形式改变为着色形式。 还提供了用于其生产的方法，包含其的组合物及其用途。