摘要:
A process for preparing polycarbonate oligomers by reacting phosgene with an alkaline aqueous solution containing an alkali metal salt or alkaline earth metal salt of a dihydric phenol in the presence of an inert organic solvent, which comprises previously cooling said alkaline aqueous solution to not higher than 0.degree. C., reacting the cooled aqueous solution with phosgene to perform a phosgenation reaction and also to absorb the heat of the phosgenation reaction by the quantity of heat that said cooled aqueous solution has, thereby to adjust the phosgenation reaction system substantially to not higher than 10.degree. C., and then oligomerizing the phosgenation product at a temperature of 15.degree. C. or higher.
摘要:
A process for producing polycarbonate oligomers by the reaction of dihydroxy compounds with phosgene, which comprises contacting a mixture of a dihydroxy compound and an aqueous alkali solution with phosgene in the presence of an organic solvent in a tubular reactor to perform a first-stage reaction, introducing the first-stage reaction mixture into a tank-type reactor equipped with a stirrer and containing the aqueous alkali solution and a solution in the organic solvent of a polycarbonate oligomer formed by the reaction of the first-stage reaction product in a second stage, and performing the second-stage reaction while stirring the reaction mixture in the tank-type reactor and maintaining it at a predetermined temperature by sufficient removal of the heat of reaction.
摘要:
A multilayer stretched film with barrier property that is free from deterioration of barrier properties attributable to dimensional change caused by moisture absorption, and bending, etc. A multilayer stretched film with barrier property obtained by biaxially stretching a multilayer laminate including at least three layers, namely, a polyester-based resin layer (Layer A), a polyamide-based resin layer (Layer B), and a polyester-based resin layer (Layer A), in this order (wherein the two Layers A may be the same or different) to obtain a biaxially stretched multilayer film; and providing a deposition layer (Layer C) on at least one surface of the biaxially stretched multilayer film; both of the Layers A containing a crystalline polyester; Layer B containing 70 to 99 wt % of aliphatic polyamide and 1 to 30 wt % of aromatic polyamide; and Layer C containing an inorganic substance.
摘要:
A process is disclosed for producing powdery polycarbonate from a polycarbonate solution which comprises:(a) charging the solution into the feed opening of a disolvating apparatus, the apparatus being composed of a casing and having at least two screws incorporated therein, the screws meshing with each other; the apparatus comprising two parts; a evaporating zone and a powdering zone; a space being provided above the screws in the evaporating zone, the space extending in the axial direction of the screws and having at least one degassing opening, and side and bottom portions of screws generally fitting with the casing in the evaporating zone; top, side and bottom portions of screws generally fitting with the casing in the powdering zone, heating means being installed in the casing and/or screws;(b) in the evaporating zone, evaporating the solvent of the polycarbonate solution using the heating means while moving the solution by the screws;(c) powdering the dried polycarbonate in the powdering zone; and(d) discharging the powdery polycarbonate from the product exit in the powdering zone.
摘要:
An object of the invention is to provide a multilayer stretched film with barrier property that is free from deterioration of barrier properties attributable to dimensional change caused by moisture absorption, and bending, etc. [Method for Achieving the Object]A multilayer stretched film with barrier property obtained by biaxially stretching a multilayer laminate comprising at least three layers, namely, a polyester-based resin layer (Layer A), a polyamide-based resin layer (Layer B), and a polyester-based resin layer (Layer A), in this order (wherein the two Layers A may be the same or different) to obtain a biaxially stretched multilayer film; and providing a deposition layer (Layer C) on at least one surface of the biaxially stretched multilayer film;both of the Layers A containing a crystalline polyester;Layer B containing 70 to 99 wt % of aliphatic polyamide and 1 to 30 wt % of aromatic polyamide; andLayer C containing an inorganic substance.
摘要:
The present invention provides a film that has excellent anti-fogging properties, processability without causing curling, as a film for use in food packaging. Specifically, the present invention provides a multilayered film including a polyolefin layer (A), an adhesive layer (B), a polyamide layer (C), a barrier layer (D), an anti-fogging agent layer (E), and an anti-fogging agent volatilization-preventing layer (F), the polyamide layer (C) including 5 to 30 wt % of amorphous aromatic polyamide, the barrier layer (D) including a saponified ethylene vinyl acetate copolymer (EVOH) having an ethylene content of 35 mol % or less and a saponification degree of vinyl acetate of 90 mol % or more, the anti-fogging agent layer (E) including an anti-fogging agent and polyolefin, and the anti-fogging agent volatilization-preventing layer (F) including polyolefin; and the multilayered film having an (A)/(B)/(X)/(B)/(E)/(F) layer structure (wherein the layer (X) represents a (C)/(D)/(C), (D)/(C)/(D), (C)/(D), or (D)/(C) layer structure); and a method for producing the same.
摘要:
An object of the present invention is to provide a multilayer stretched polyamide-based film having excellent bending resistance, thermal dimensional stability and aroma retention, whose lamination strength is measureable when a sealing layer is laminated thereon.Specifically, the invention provides a multilayer stretched polyamide-based film obtained by biaxially stretching a multilayer laminate including three layers consisting of a polyester layer (Layer A), an adhesive layer (Layer B), and a polyamide layer (Layer C), wherein Layer A contains a crystalline polyester, Layer B contains a modified polyester-based elastomer, Layer C contains an aliphatic polyamide, and Layer C has a thickness of 5 μm or more, and wherein a sealing layer is to be laminated on Layer C by a lamination method, after biaxially stretching the multilayer laminate.
摘要:
[Object] An object of the invention is to provide a multilayer stretched film with barrier property that is free from deterioration of barrier properties attributable to dimensional change caused by moisture absorption, and bending, etc.[Method for Achieving the Object] A multilayer stretched film with barrier property obtained by biaxially stretching a multilayer laminate comprising at least two layers, namely, a polyester-based resin layer (Layer A) and a polyamide-based resin layer (Layer B) to obtain a biaxially stretched multilayer film; and providing a deposition layer (Layer C) on at least one surface of the biaxially stretched multilayer film; Layer A containing a crystalline polyester; Layer B containing 70 to 99 wt % of aliphatic polyamide and 1 to 30 wt % of aromatic polyamide; and Layer C containing an inorganic substance. [Selected Drawings] None
摘要:
A flame retardant resin composition having a high impact resistance is disclosed, containing (A) 20 to 85 weight percent of a high molecular weight aromatic polycarbonate copolymer comprising (1) 2 to 30 molar percent of a bisphenol the nucleus of which is substituted with a halogen and (2) 70 to 98 molar percent of a halogen-free bisphenol and (B) 80 to 15 weight percent of an ABS resin comprising a mixture of (1) a graft copolymer of a butadiene-based rubbery polymer to which is grafted a vinyl aromatic hydrocarbon and acrylonitrile and and (2) a copolymer of a vinyl aromatic hydrocarbon and acrylonitrile. The amount of said rubbery polymer is 5 to 40 weight percent of the ABS resin.
摘要:
A multilayer stretched film with barrier property that is free from deterioration of barrier properties attributable to dimensional change caused by moisture absorption, and bending, etc. A multilayer stretched film with barrier property obtained by biaxially stretching a multilayer laminate including at least three layers, namely, a polyester-based resin layer (Layer A), a polyamide-based resin layer (Layer B), and a polyester-based resin layer (Layer A), in this order (wherein the two Layers A may be the same or different) to obtain a biaxially stretched multilayer film; and providing a deposition layer (Layer C) on at least one surface of the biaxially stretched multilayer film; both of the Layers A containing a crystalline polyester; Layer B containing 70 to 99 wt % of aliphatic polyamide and 1 to 30 wt % of aromatic polyamide; and Layer C containing an inorganic substance.