Abstract:
The silicone rubber composition of the invention essentially comprises (a) a silanolic hydroxy-terminated diorganopolysiloxane, (b) a hydrolyzable vinyl silane compound such as a vinyl trialkoxysilane and (c) an organopolysiloxane having at least two mercapto groups in the form of, for example, 3-mercaptopropyl groups, in a molecule. The composition can be cured by two different mechanisms of crosslink formation one by the condensation reaction between the silanol groups in (a) and the hydrolyzable groups in (b) in the presence of atmospheric moisture and the other between the vinyl groups in (b) and mercapto groups in (c) under irradiation with ultraviolet light. The two-way cruability of the composition greatly expands the application fields of the silicone rubber composition.
Abstract:
A heat conductive BN filler having a cohesive factor of 3-50% is provided. An electrically insulating/heat dissipating sheet is obtained by mixing the BN filler with an organopolysiloxane and a crosslinking agent, shaping the resulting silicone rubber composition into a sheet form, followed by vulcanization. Without special orienting means, the BN particles are oriented in the sheeting step such that their a-axis is perpendicular to the sheet surface.
Abstract:
An adhesive sheet is obtained by sheeting a claylike silicone composition comprising an organopolysiloxane, a filler, and an adhesive aid to a gage of 0.1 to 5 mm. The adhesive sheet is easy to handle and bondable to such adherends as metals and plastics to exert a high bond strength.
Abstract:
Disclosed is a heat conductive silicone rubber composition comprising a cross-linkable organopolysiloxane composition and a filler, with the filler being magnesium oxide treated so as to have a hydrophobic surface and having a content of from 30 to 70% by volume in the composition.
Abstract:
A fuser roll having a metal core shaft has a resilient layer placed around the metal core shaft with at least the surface layer of the resilient layer comprising a fluorosilicone rubber layer containing 5 to 50 wt. % polytetrafluoroethylene. Since this fuser roll is excellent in releasability and silicone oil resistance, the durability is excellent, and the image obtained by a copying machine wherein the roll is used becomes sharp.
Abstract:
A gel-forming silicone composition comprising, compounded in a gel-forming base composition, a silane compound having the following general formula (1) or (2): ##STR1## wherein R.sup.1 is an alkyl or aryl group, R.sup.2 is an alkyl or alkoxyalkyl group, R.sup.3 and R.sup.4 are each a hydrogen atom, a methyl group or an ethyl group, R.sup.5 is an alkyl group or an ester linkage-containing group, and a, b and n are each an integer from 0 to 2. The composition is capable of forming, under mild conditions, a silicone gel which exhibits good adherence to a variety of substrates.
Abstract:
The composite silicone rubber sheet comprises a thermal conductive silicone rubber layer, both surfaces of which are tacky, containing a thermal conductive filler such as aluminum oxide and having a Asker C hardness of 5 to 50 and a thickness of 0.4 mm or less; at least one reinforcing sheet such as glass cloth arranged within said silicone rubber layer; and a releasable protective sheet such as a release paper covered on at least one tacky surface of said silicone rubber layer. Since the composite silicone rubber sheet is superior in thermal conductivity and has a good flexibility and tackiness, when used as a heat dissipating insulation sheet, the composite silicone rubber sheet has the advantages of being superior in adherence, free of oil-bleeding, suitable for mass-production, and capable of not lowering workability in assembling electronic parts and the like. The composite silicone rubber sheet is thin and lightweight and has a superior thermal conductivity, so that it can be used in the heat dissipation of a display panel for mounting on motor vehicles, railway vehicles or aircrafts.
Abstract:
An addition-curable type organopolysiloxane composition having a volume resistivity of 10.sup.7 .OMEGA.cm or below, comprising (A) an organopolysiloxane having at least two alkenyl group in its molecule and a viscosity at 25.degree. C. of from 100 to 200,000 cSt, (B) an organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms in its molecule, (C) a platinum group metal catalyst, (D) an organosilicon compound which has at least one silicon-bonded hydrogen atom in its molecule and in which at least one member selected from the group consisting of epoxy group-containing organic groups and alkoxy groups is attached to a silicon atom, and (E) an electrically conductive filler. This composition can be cured by an ultra high frequency heating system to form an adhesive cured product. It is therefore possible to obtain cured products with stable physical properties under constantly fixed conditions irrespective of the heat capacity of adherends.
Abstract:
The adhesive organopolysiloxane composition contains a compound having two or more allyl ester groups in combination with an adhesion imparting agent of a silicon compound having at least one group selected from the group consisting of an alkoxy group and an epoxy containing hydrocarbon group and also having at least one silicon-bonded hydrogen atom. This composition is markedly improved in adhesion to various substrates and durability of the adhesion.
Abstract:
The room temperature-curable organopolysiloxane composition of the invention is characteristic in the remarkably increased adhesive bonding strength of the rubber of the composition to the surface of a substrate of metals, plastics and others on which the composition has been cured. The composition is also advantageous in the improved thixotropy despite the admixture of an adhesion improver mentioned below. Thus, the composition comprises, in addition to conventional components in a deacidification type room temperature curable organopolysiloxane composition, a specific organic silicon compound represented by the general formula(R.sup.3 O).sub.b (MeCOO).sub.3-b Si--O--R.sup.4 --O--Si(OCOMe).sub.3-b (OR.sup.3).sub.b,in which R.sup.3 is a monovalent hydrocarbon group, R.sup.4 is a divalent hydrocarbon group or a polyoxyalkylene group of the formula --C.sub.x H.sub.2x --O).sub.n C.sub.x H.sub.2x --, x being 2 to 4 and n being a positive integer, and b is 1 or 2.