摘要:
The present invention provides a novel solvent which is capable of providing an excellent isobutylene polymer, little affects the environment, has a lower solubility in water than those of halogenated hydrocarbons having 1 or 2 carbon atoms and can be decomposed relatively easily. Namely, the present invention relates to: a process for producing an isobutylene polymer, which comprises performing a cationic polymerization reaction in a solvent containing primary and/or secondary monohalogenated hydrocarbon(s) having 3 to 8 carbon atoms, and an isobutylene polymer thus obtained; and a process for producing an isobutylene polymer having a vinyl group introduced into the terminal thereof, which comprises reacting the isobutylene polymer produced above with 1,9-decadiene or allyltrimethylsilane, and an isobutylene polymer thus obtained.
摘要:
The present invention provides a novel halogen-free solvent system which can produce a good isobutylene polymer and can be easily reused. A novel process for the production of an isobutylene polymer is provided which comprises using a hydrocarbon solvent having a boiling point of not lower than 105.degree. C. and a melting point of not higher than -90.degree. C. Heretofore, a solvent system containing a halogenated hydrocarbon such as methylene chloride has been used for the production of an isobutylene polymer. However, such a solvent system has a great adverse effect on the environment. Therefore, a non-halogenated solvent is desirable. The present invention is characterized by the use of a hydrocarbon solvent as a reaction solvent. The resulting polymer has good properties. Further, compounds which are produced as by-products during the reaction can be easily removed, enabling the recycling of the solvent used. Thus, the production cost can be reduced.
摘要:
Processes for the isolation of a telechelic isobutylene polymer in a non-aqueous system to prevent the generation of waste water having a solvent dissolved therein and processes for the preparation of a telechelic isobutylene polymer having more advantageous unsaturated groups. A process for the isolation of an isobutylene polymer includes a cationic polymerization reaction in a non-aqueous system in the presence of a catalyst MX.sub.n wherein M represents a metallic atom and X may be the same or different and represents a halogen atom or a monovalent hydrocarbon group. The process comprises conducting the cationic polymerization reaction, conducting a ligand exchange reaction of said catalyst, and then removing a component containing M. Another process for the isolation includes a cationic polymerization in a non-aqueous system in the presence of the catalyst, the process comprises producing a telechelic isobutylene polymer and at the same time removing the catalyst with an adsorption material capable of adsorbing an acid. Another process for the isolation comprises conducting a cationic polymerization reaction in a non-aqueous system in the presence of the catalyst; adding a compound represented by the general formula Q(OR).sub.m where Q is a metallic atom and R is hydrogen or a monovalent organic group to effect the dehydrochlorination reaction at the ends of the polymer and the ligand exchange reaction of the catalyst so as to produce a telechelic isobutylene polymer having an unsaturated group; and removing a component containing M.
摘要:
An isobutylene polymer having an unsaturated group and comprising more than one unit per molecule on the average of the formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are the same or different and each a hydrogen atom or a C.sub.1 -C.sub.8 alkyl group, R' and R" are the same or different and each a hydrogen atom, a methyl group or an ethyl group, and Q is a C.sub.1 -C.sub.30 divalent organic group, which provides a cured material having improved weather resistance.
摘要:
An isobutylene base polymer with a functional group having repeating units derived from isobutylene and at least one unit of the formula: ##STR1## wherein R.sup.1 is a hydrogen atom, a methyl group or an ethyl group and R.sup.2 is a divalent organic group, and a number average molecular weight of 500 to 500,000.
摘要:
A two-sided attraction structure including an electrostatic chuck portion (2) and a power supply portion (5), the electrostatic chuck portion (2) including a dielectric member (3) in a plate-like shape, which is made of an insulating material and has a front side and a back side, and an internal electrode (4) mounted into the dielectric member, the front side and the back side of the dielectric member each serving as an attraction surface when voltage is applied to the internal electrode (4), the power supply portion (5) applying the voltage to the internal electrode, of the electrostatic chuck portion (2), in which the power supply portion (5) includes a solar cell (6) and a voltage boost circuit (7) for boosting power generated by the solar cell (6).
摘要:
Provided is an electrostatic chuck (8) of self power supply type, which is capable of supplying power while generating power to be used by an attraction electrode (3) during processing of a substrate. The electrostatic chuck (8) attracts and holds a substrate in a substrate processing apparatus (11) that processes the substrate while generating optical energy. The electrostatic chuck (8) includes: an electrode sheet (5) including an attraction electrode (3); a metal base (1) having the electrode sheet (5) laminated on an upper surface side thereof; an internal power supply for obtaining power to be supplied to the attraction electrode (3); and a voltage boost circuit (7) for boosting voltage of the power obtained by the internal power supply. The internal power supply includes a solar cell (6), and converts the optical energy into the power during the processing of the substrate, to thereby cause the electrode sheet (5) to attract and hold the substrate.
摘要:
A bipolar electrostatic chuck which has excellent dielectric breakdown strength and provides excellent attracting performance. The bipolar electrostatic chuck eliminates difficulty in dismounting a sample from a sample attracting plane as much as possible after application of a voltage to electrodes is finished. The bipolar electrostatic chuck is provided with a first electrode and a second electrode in an insulator and permits a surface of the insulator to be the sample attracting plane. The insulator has the first electrode, an interelectrode insulating layer and the second electrode in this order from the sample attracting plane in the depth direction. The second electrode has a region not overlapping with the first electrode in a normal line direction of the sample attracting plane.
摘要:
Provided is a bipolar electrostatic chuck, which has excellent substrate attracting/holding performance when a voltage is applied, and excellent residual charges reducing performance when voltage application is stopped. The bipolar electrostatic chuck includes at least an electrode layer including a first electrode and a second electrode, and an upper insulating layer which forms a substrate attracting surface for attracting a substrate. In a case where a surface of the electrode layer is regarded to be divided into a plurality of virtual cells having a predetermined width (L) in an x direction and a y direction, first electrode sections forming the first electrode and second electrode sections forming the second electrode are alternately arranged in the plurality of virtual cells in the x direction, and are alternately arranged in the plurality of virtual cells in the y direction.
摘要:
A highlight of a representative track of each album stored in a recording medium and a highlight of each track of a designated album are pre-set. Highlights of representative tracks of albums are successively reproduced from album 1. As a result, albums are searched for a desired track. When the desired album has been found, highlights of tracks of the album are successively reproduced from track 1. As a result, the album is searched for the desired track.