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    Method of manufacturing dielectric ceramic composition and electronic device containing dielectric layer
    4.
    发明授权
    Method of manufacturing dielectric ceramic composition and electronic device containing dielectric layer 失效
    制造介电陶瓷组合物的方法和含有电介质层的电子器件

    公开(公告)号：US06485672B1

    公开(公告)日：2002-11-26

    申请号：US09673957

    申请日：2000-10-24

    申请人： Takeshi Nomura ,  Shigeki Sato

    发明人： Takeshi Nomura ,  Shigeki Sato

    IPC分类号： C04B35468

    CPC分类号： C04B35/4682 ,  H01G4/1227

    摘要： A method of manufacturing a dielectric ceramic composition comprising at least a main component of BaTiO3, a second subcomponent as represented by (Ba, Ca)xSiO2+x (where, x=0.8 to 1.2), and other subcomponents. The main component and at least part of the subcomponents except the second subcomponent are mixed to prepare a pre-calcination powder and the pre-calcination powder is calcined to prepare a calcined powder. The second subcomponent is at least mixed in the calcined powder to obtain a dielectric ceramic composition having a ratio of each subcomponent to the main component of BaTiO3 of a predetermined molar ratio. It is therefore possible to obtain an electronic device containing a dielectric layer such as a multi-layer ceramic capacitor able to satisfy both of the capacity-temperature characteristics of the X7R characteristic (EIA standard) and the B characteristic (EIAJ standard), even when the dielectric layer is a superthin one of not more than 4 &mgr;m and having a small change in the capacity under a DC electric field along with time and further having a long accelerated lifetime of the insulation resistance and a small drop in capacity under a DC bias.

    摘要翻译： 一种电介质陶瓷组合物的制造方法，其至少包含BaTiO 3的主要成分，由（Ba，Ca）xSiO 2 + x（其中x = 0.8〜1.2）表示的第二副成分，以及其他亚成分。 混合除了第二副成分以外的主成分和副成分的至少一部分，制备预煅烧粉末，并煅烧预煅烧粉末以制备煅烧粉末。 将第二副成分至少在煅烧粉末中混合，得到具有预定摩尔比的BaTiO 3的每个副成分与主要成分的比例的电介质陶瓷组合物。 因此，即使是能够满足X7R特性（EIA标准）和B特性（EIAJ标准）的容量 - 温度特性两者的多层陶瓷电容器的电介质层，也能够得到电子装置， 电介质层是不超过4μm的超导体，并且随着时间的推移在DC电场下的容量变化很小，并且还具有绝缘电阻的长加速寿命和在DC偏压下的容量的小的下降 。

    Dielectric ceramic composition and electronic device
    5.
    发明授权
    Dielectric ceramic composition and electronic device 有权
    介电陶瓷组合物和电子器件

    公开(公告)号：US06226172B1

    公开(公告)日：2001-05-01

    申请号：US09361311

    申请日：1999-07-27

    申请人： Shigeki Sato ,  Takeshi Nomura ,  Akira Sato

    发明人： Shigeki Sato ,  Takeshi Nomura ,  Akira Sato

    IPC分类号： H01G412

    CPC分类号： H01G4/1227

    摘要： A dielectric ceramic composition having at least a main component of BaTiO3, a first subcomponent including at least one compound selected from MgO, CaO, BaO, SrO and Cr2O3, a second subcomponent of (Ba, Ca)x,SiO2+x(where, x=0.8 to 1.2), a third subcomponent including at least one compound selected from V2O5, MoO3, and WO3, and a fourth subcomponent including an oxide of R1 (where R1 is at least one element selected from Sc, Er, Tm, Yb, and Lu), wherein the ratios of the subcomponents to 100 moles of the main component of BaTiO3 are as follows: first subcomponent: 0.1 to 3 moles, second subcomponent: 2 to 10 moles, third subcomponent: 0.01 to 0.5 mole, and fourth subcomponent: 0.5 to 7 moles (where the number of moles of the fourth subcomponent is the ratio of R1 alone). The dielectric ceramic composition has a high relative dielectric constant, has a capacity-temperature characteristic satisfying the X8R characteristic of the EIA standard (−55 to 150° C., &Dgr;C =±15% or less), enables sintering in a reducing atmosphere, has a small change in the capacity under a direct current electric field along with time, and further has a long lifetime of the insulation resistance.

    摘要翻译： 具有BaTiO 3的至少主要成分的电介质陶瓷组合物，包含选自MgO，CaO，BaO，SrO和Cr 2 O 3中的至少一种化合物的第一副成分，（Ba，Ca）x，SiO 2 + x的第二副成分（其中， x = 0.8〜1.2），包含至少一种选自V 2 O 5，MoO 3和WO 3的化合物的第三副成分和包含R1的氧化物的第四副成分（其中，R 1为选自Sc，Er，Tm，Yb中的至少一种元素 和Lu），其中副成分与100摩尔BaTiO 3的主要成分的比例如下：第一副成分：0.1〜3摩尔，第2副成分：2〜10摩尔，第3副成分：0.01〜0.5摩尔，第4次 副成分：0.5〜7摩尔（第四副成分的摩尔数为单独的R1的比例）。 电介质陶瓷组合物具有高相对介电常数，具有满足EIA标准（-55〜150℃，DELTAC =±15％以下）的X8R特性的容量 - 温度特性，能够在还原气氛中进行烧结， 随着时间的推移，直流电场下的容量变化很小，绝缘电阻的寿命也较长。

    Method of production of dielectric ceramic composition and method of production of electronic device containing dielectric layers
    6.
    发明授权
    Method of production of dielectric ceramic composition and method of production of electronic device containing dielectric layers 有权
    电介质陶瓷组合物的制造方法和含有电介质层的电子器件的制造方法

    公开(公告)号：US06800270B2

    公开(公告)日：2004-10-05

    申请号：US09932023

    申请日：2001-08-20

    申请人： Takeshi Nomura ,  Shigeki Sato

    发明人： Takeshi Nomura ,  Shigeki Sato

    IPC分类号： C01G2300

    CPC分类号： C04B35/468 ,  H01G4/1227 ,  Y10T29/417

    摘要： A method of production of a dielectric ceramic composition having at least a main component of Ba2TiO3, a second subcomponent including at least one compound selected from SiO2, MO (where M is at least one element selected from Ba, Ca, Sr, and Mg), Li2O, and B2O3, and other subcomponents, comprising the step of: mixing in said main component at least part of other subcomponents except for said second subcomponent to prepare a pre-calcination powder, calcining the pre-calcination powder to prepare a calcined powder, and mixing at least said second subcomponent in said calcined powder to obtain the dielectric ceramic composition having molar ratios of the subcomponents to the main component of predetermined ratios. As the other subcomponents, there is a third subcomponent including at least one compound selected from V2O5, MoO3, and WO3. A ratio of the third subcomponent to 100 moles of the main component is preferably 0.01 to 0.1 mole.

    摘要翻译： 一种制备具有至少主要成分为Ba2TiO3的电介质陶瓷组合物的方法，包括至少一种选自SiO 2，MO（其中M为选自Ba，Ca，Sr和Mg中的至少一种元素）的第二副成分的方法， ，Li 2 O和B 2 O 3以及其它副成分的方法，包括以下步骤：在所述主成分中除了所述第二副成分以外的至少一部分其他副成分混合以制备预煅烧粉末，煅烧所述预煅烧粉末以制备煅烧粉末 ，并将所述第二副成分混合在所述煅烧粉末中，得到具有预定比例的副成分与主成分的摩尔比的电介质陶瓷组合物。 作为其它副成分，存在包含至少一种选自V 2 O 5，MoO 3和WO 3的化合物的第三副成分。 第三副成分与主成分100摩尔的比优选为0.01〜0.1摩尔。

    Non-reducible dielectric ceramic material, making method, and multilayer ceramic capacitor
    8.
    发明授权
    Non-reducible dielectric ceramic material, making method, and multilayer ceramic capacitor 失效
    不可还原电介质陶瓷材料，制造方法和多层陶瓷电容器

    公开(公告)号：US06329311B1

    公开(公告)日：2001-12-11

    申请号：US09580585

    申请日：2000-05-30

    申请人： Mari Fujii ,  Akira Sato ,  Shigeki Sato ,  Takeshi Nomura

    发明人： Mari Fujii ,  Akira Sato ,  Shigeki Sato ,  Takeshi Nomura

    IPC分类号： C04B3547

    CPC分类号： C04B35/49 ,  C04B35/486 ,  H01B3/12 ,  H01G4/1227 ,  H01G4/1245

    摘要： In conjunction with the manufacture of a multilayer ceramic capacitor having nickel-containing internal electrodes involving a polishing step for exposing the end of the internal electrodes, a non-reducible dielectric ceramic material is prepared, for the purpose of preventing the polishing step from being prolonged, by furnishing a calcined material containing a compound oxide represented by the formula (I): [(CaxSr1−x)O]m[(TiyZr1−y)O2] wherein 0≦x≦1, 0≦y≦0.10, and 0.75≦m≦1.04, as a main component, adding 0.001-10 mol % based on the main component of MgO or rare earth oxide and firing the mixture. The ceramic material contains predetermined amounts of SiO2 and BaO and/or CaO, and MnO as auxiliary components.

    摘要翻译： 结合制造具有含镍内部电极的多层陶瓷电容器，其包括用于暴露内部电极的端部的抛光步骤，为了防止抛光步骤延长，制备了不可还原的介电陶瓷材料 通过提供含有由式（I）表示的复合氧化物的煅烧材料：其中0≤x≤1,0<= y <= 0.10和0.75 <= m <= 1.04作为主要成分，加入 基于MgO或稀土氧化物的主要成分为0.001-10摩尔％，并烧制该混合物。 陶瓷材料含有预定量的SiO 2和BaO和/或CaO，MnO作为辅助成分。

    Anode active material and metal ion battery prepared therewith
    9.
    发明授权
    Anode active material and metal ion battery prepared therewith 有权
    阳极活性材料和金属离子电池

    公开(公告)号：US09406935B2

    公开(公告)日：2016-08-02

    申请号：US14345776

    申请日：2012-10-09

    申请人： Shigeki Sato ,  Masafumi Nose ,  Hideki Nakayama

    发明人： Shigeki Sato ,  Masafumi Nose ,  Hideki Nakayama

    IPC分类号： H01M4/58 ,  H01M4/525 ,  H01M10/052 ,  H01M10/054 ,  C01G49/00 ,  C01F7/00 ,  C01F7/76

    CPC分类号： H01M4/525 ,  C01F7/002 ,  C01F7/762 ,  C01G49/009 ,  C01P2002/72 ,  H01M4/5825 ,  H01M10/052 ,  H01M10/054 ,  H01M2220/30 ,  Y02E60/122 ,  Y02T10/7011

    摘要： A main object of the present invention is to provide an anode active material capable of increasing energy density at the same time increasing battery safety, and a metal ion battery prepared with the anode active material. The present invention is an anode active material including an element that belongs to alunite group capable to insert and remove an ion(s) of at least one metal element selected from the group consisting of alkali metal elements and alkaline-earth metal elements, and a metal ion battery having a cathode, an anode, and an electrolyte filled between the cathode and the anode, the electrolyte conducting a metal ion(s), wherein the anode active material is contained in the anode.

    摘要翻译： 本发明的主要目的在于提供能够提高电池安全性的同时提高能量密度的负极活性物质，以及利用阳极活性物质制备的金属离子电池。 本发明是一种负极活性物质，其包含属于能够插入和除去选自碱金属元素和碱土金属元素中的至少一种金属元素的离子的铝酸盐基的元素，和 金属离子电池具有阴极，阳极和填充在阴极和阳极之间的电解质，导电金属离子的电解质，其中负极活性物质包含在阳极中。