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公开(公告)号：US4599469A
公开(公告)日：1986-07-08
申请号：US614891
申请日：1984-05-29
申请人： Ted H. Cymbaluk , Jim D. Byers , Marvin M. Johnson
发明人： Ted H. Cymbaluk , Jim D. Byers , Marvin M. Johnson
IPC分类号： C07C17/354 , C07C21/24
CPC分类号： C07C17/354
摘要： Process for the hydrogenation of functionally substituted acetylenic compounds employing catalyst comprising nickel boride on an inorganic oxide support is disclosed. Functionally-substituted acetylenic compounds are selectively reduced under mild reaction conditions to give functionally-substituted cis-olefinic compounds in high yield.
摘要翻译： 公开了在无机氧化物载体上使用包含镍硼化物的催化剂来氢化功能取代的炔属化合物的方法。 功能取代的炔属化合物在温和的反应条件下选择性还原，以高产率得到功能取代的顺式 - 烯烃化合物。
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公开(公告)号：US5516966A
公开(公告)日：1996-05-14
申请号：US465475
申请日：1995-06-05
CPC分类号： C07C51/412
摘要： A method for preparing cuprous carboxylates (Cu(I) carboxylates) is provided wherein Cu(II) carboxylates are reacted with copper powder in an aromatic solvent under a reducing atmosphere, optionally in the presence of at least one of a carboxylic acid or carboxylic acid anhydride. Also, a method for preparing desired Cu(II) carboxylates is provided wherein a Cu(II) carboxylate having fewer carbon atoms is reacted with a carboxylic acid corresponding to the desired Cu(II) carboxylate. The invention method reactions achieve good conversions with rapid rates of reaction. The Cu(I) carboxylates produced according to the invention method are useful as reagents or in the preparation of olefin complexing reagents.
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公开(公告)号：US5371258A
公开(公告)日：1994-12-06
申请号：US815692
申请日：1991-12-31
CPC分类号： C07C51/412
摘要： A method for preparing cuprous carboxylates (Cu(I) carboxylates) is provided wherein Cu(II) carboxylates are reacted with copper powder in an aromatic solvent under a reducing atmosphere, optionally in the presence of at least one of a carboxylic acid or carboxylic acid anhydride. Also, a method for prepared desired Cu(II) carboxylates is provided wherein a Cu(II) carboxylate having fewer carbon atoms is reacted with a carboxylic acid corresponding to the desired Cu(II) carboxylate. The invention method reactions achieve good conversions with rapid rates of reaction. The Cu(I) carboxylates produced according to the invention method are useful as reagents or in the preparation of olefin complexing reagents.
摘要翻译： 提供了制备羧酸亚铜（Cu（I）羧酸盐）的方法，其中在还原气氛下，任选地在至少一种羧酸或羧酸存在下，使羧酸铜（II）与铜粉末在芳族溶剂中反应 酐。 此外，提供了制备的所需的Cu（II）羧酸盐的方法，其中具有较少碳原子的Cu（II）羧酸酯与对应于所需的羧酸铜（II）的羧酸反应。 本发明方法反应以快速反应实现良好的转化。 根据本发明方法制备的Cu（I）羧酸盐可用作试剂或用于制备烯烃络合试剂。
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公开(公告)号：US5096682A
公开(公告)日：1992-03-17
申请号：US686066
申请日：1991-04-16
摘要： Trialkyl arsines (in particular trimethyl arsine) are removed from a fluid (e.g., a hydrocarbon-containing gas) by contacting the fluid with a sorbent material comprising at least one copper hydrocarbon sulfonate, preferably a copper salt of an aliphatic or aromatic sulfonic acid, or with a copper-exchanged, sulfonated styrene polymer.
摘要翻译： 通过使流体与包含至少一种铜烃磺酸盐，优选脂族或芳族磺酸铜盐的吸附剂材料接触，从流体（例如含烃气体）中除去三烷基胂（特别是三甲基胂） 或用铜交换的磺化苯乙烯聚合物。
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公开(公告)号：US5064626A
公开(公告)日：1991-11-12
申请号：US619355
申请日：1990-11-28
CPC分类号： B01D53/02 , B01D53/46 , B01J20/0229 , B01J20/0285 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/20 , B01J20/28004 , B01J20/3021 , B01J20/3204 , B01J20/3236
摘要： Trialkyl arsine (in particular trimethyl arsine) is removed from a fluid (e.g. a hydrocarbon-containing gas) by contacting the fluid with a sorbent material comprising (a) a transition metal polysulfide (preferably Fe.sub.2 (S.sub.3).sub.3, and (b) an inorganic support material (preferably alumina).
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公开(公告)号：US5259986A
公开(公告)日：1993-11-09
申请号：US816425
申请日：1991-12-31
CPC分类号： C07C7/156 , B01D53/1493
摘要： Complexing reagents are provided which comprise Cu(I) carboxylates or Cu(I) sulfonates and high molecular weight olefins. The invention complexing reagents are useful for separating olefins from mixtures of olefins and paraffins.
摘要翻译： 提供了包含Cu（I）羧酸盐或Cu（I）磺酸盐和高分子量烯烃的络合试剂。 本发明络合试剂可用于从烯烃和链烷烃的混合物中分离烯烃。
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公开(公告)号：US5024683A
公开(公告)日：1991-06-18
申请号：US537320
申请日：1990-06-12
申请人： Patricia A. Tooley , Tin-Tack P. Cheung , Ted H. Cymbaluk , Gerhard P. Nowack , Marvin M. Johnson
发明人： Patricia A. Tooley , Tin-Tack P. Cheung , Ted H. Cymbaluk , Gerhard P. Nowack , Marvin M. Johnson
CPC分类号： B01D53/02 , B01J20/0237 , B01J20/0248 , B01J20/0285 , B01J20/0292 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/16 , B01J20/20 , Y10S95/90
摘要： Trialky arsine(s) are removed from a fluid (e.g., a hydrocarbon-containing gas) by contacting the fluid with a sorbent material comprising (a) copper sulfide, preferably copper(I) sulfide, and (b) an inorganic support material, preferably zinc oxide and/or alumina.
摘要翻译： 通过使流体与包含（a）硫化铜，优选硫化铜（I））和（b）无机载体材料的吸附剂材料接触，将流体（例如含烃气体）从流体（例如含烃气体）中除去， 优选氧化锌和/或氧化铝。
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公开(公告)号：US4992620A
公开(公告)日：1991-02-12
申请号：US439745
申请日：1989-11-21
摘要： Trialkyl arsines are removed from fluids, in particular gases, by contacting with a solid sorbent material containing at least one manganese oxide (preferably MnO.sub.2) and at least one Group IB metal oxide (preferably CuO). In a preferred feature, the used solid sorbent material is regenerated by oxidizing treatment, washing with an aqueous liquid, and drying.
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公开(公告)号：US4849576A
公开(公告)日：1989-07-18
申请号：US198541
申请日：1988-05-17
CPC分类号： C07C11/08 , C07C11/02 , C07C5/2556 , C07C7/12
摘要： In a process for isomerizing monoolefins having a terminal double bond (in particular the isomerization of butene-1 to butene-2) in the presence of a Group VIII metal catalyst (in particular an alumina-supported Pd catalyst) which is contaminated by impurities in the monoolefin containing feed, the improvement comprises pretreating the feed with a solid material comprising tin oxide and a refractory support material (in particular alumina).
摘要翻译： 在将VIII族金属催化剂（特别是氧化铝负载型Pd催化剂）存在下，将具有末端双键的单烯烃（特别是丁烯-1异丁烯化成丁烯-2）异构化的方法中， 含有单烯烃的进料，改进包括用包含氧化锡和耐火载体材料（特别是氧化铝）的固体材料预处理进料。
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公开(公告)号：US5523512A
公开(公告)日：1996-06-04
申请号：US082223
申请日：1993-06-24
CPC分类号： C07C7/156 , B01D53/1493
摘要： Complexing reagents are provided which comprise Cu(I) carboxylates or Cu(I) sulfonates and high molecular weight olefins. The invention complexing reagents are useful for separating olefins from mixtures of olefins and paraffins.
摘要翻译： 提供了包含Cu（I）羧酸盐或Cu（I）磺酸盐和高分子量烯烃的络合试剂。 本发明络合试剂可用于从烯烃和链烷烃的混合物中分离烯烃。
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