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    ANIONIC POLYMERIZATION INITIATORS AND POLYMERS THEREFROM
    1.
    发明申请
    ANIONIC POLYMERIZATION INITIATORS AND POLYMERS THEREFROM 审中-公开
    阴离子聚合引发剂和聚合物

    公开(公告)号：US20110112263A1

    公开(公告)日：2011-05-12

    申请号：US13010290

    申请日：2011-01-20

    申请人： Terrence E. Hogan ,  William L. Hergenrother ,  Yuan-Yong Yan

    发明人： Terrence E. Hogan ,  William L. Hergenrother ,  Yuan-Yong Yan

    IPC分类号： C08F4/48 ,  C09K3/00

    CPC分类号： C08F4/484 ,  C08F36/04

    摘要： One or more embodiments of the present invention provides a method for preparing a chain-extended lithiated thioacetal solution, the method comprising (i) preparing a lithiated thioacetal by reacting an initiator precursor compound with an organolithium compound; and (ii) chain extending the lithiated thioacetal by polymerizing monomer including conjugated diene monomer, optionally together with vinyl aromatic monomer, to form a polymeric or oligomeric segment having at least 3 and less than 125 repeat units.

    摘要翻译： 本发明的一个或多个实施方案提供了制备链延长锂化硫代缩醛溶液的方法，该方法包括（i）通过使引发剂前体化合物与有机锂化合物反应制备锂化硫代缩醛; 和（ii）通过将包括共轭二烯单体的单体（任选地与乙烯基芳族单体）一起聚合以形成具有至少3个且小于125个重复单元的聚合或低聚链段，从而延伸锂化的硫代缩醛。

    Method for making alkoxy-modified silsesquioxanes and amino alkoxy-modified silsesquioxanes
    2.
    发明授权
    Method for making alkoxy-modified silsesquioxanes and amino alkoxy-modified silsesquioxanes 有权
    制备烷氧基改性倍半硅氧烷和氨基烷氧基改性倍半硅氧烷的方法

    公开(公告)号：US08501895B2

    公开(公告)日：2013-08-06

    申请号：US12347047

    申请日：2008-12-31

    申请人： William L. Hergenrother ,  James H. Pawlow ,  Terrence E. Hogan ,  Ashley S. Hilton

    发明人： William L. Hergenrother ,  James H. Pawlow ,  Terrence E. Hogan ,  Ashley S. Hilton

    IPC分类号： C08G77/26

    CPC分类号： C08G77/28 ,  C08G77/26 ,  Y02P20/584

    摘要： A method is presented for making an amino alkoxy-modified silsesquioxane (amino AMS) comprising one or more compounds selected from the group consisting of an amino-AMS, an amino/mercaptan co-AMS, an amino/blocked mercaptan co-AMS, and mixtures of these. The use of solid strong cationic catalysts in this reaction system is advantageous because the catalyst remains as a solid throughout the reaction, allowing simplified separation of the solid catalyst from the soluble amino AMS or amino co-AMS products, resulting in total or near total recovery of the amino AMS or amino co-AMS products, as well as virtual total recovery of the catalyst for recycling. The use of the solid strong cationic catalysts is advantageous because it results in amino AMS products that are free of, or substantially free of, residual acid catalyst.

    摘要翻译： 提出了一种制备氨基烷氧基改性倍半硅氧烷（氨基AMS）的方法，其包含一种或多种选自氨基AMS，氨基/硫醇共-AMS，氨基/封端的硫醇共-AMS的化合物和 这些的混合物。 在该反应体系中使用固体强阳离子催化剂是有利的，因为催化剂在整个反应中保持固体，使固体催化剂与可溶性氨基AMS或氨基共聚AMS产物的分离更简单，导致总的或接近总的回收 的氨基AMS或氨基共AMS产物，以及用于再循环的催化剂的虚拟总回收率。 使用固体强阳离子催化剂是有利的，因为其导致氨基AMS产物不含或基本上不含残留的酸催化剂。

    Amino Alkoxy-Modified Silsesquioxane Adhesives For Improved Metal Adhesion And Metal Adhesion Retention To Cured Rubber
    4.
    发明申请
    Amino Alkoxy-Modified Silsesquioxane Adhesives For Improved Metal Adhesion And Metal Adhesion Retention To Cured Rubber 有权
    用于改善金属粘附性和固化橡胶金属粘附保持性的氨基烷氧基改性倍半硅氧烷粘合剂

    公开(公告)号：US20120077922A1

    公开(公告)日：2012-03-29

    申请号：US13174129

    申请日：2011-06-30

    申请人： William L. Hergenrother ,  Walter Tomaszewski ,  Ashley Hilton ,  Michael Hayes ,  James H. Pawlow ,  Terrence E. Hogan ,  Zhong-Ren Chen

    发明人： William L. Hergenrother ,  Walter Tomaszewski ,  Ashley Hilton ,  Michael Hayes ,  James H. Pawlow ,  Terrence E. Hogan ,  Zhong-Ren Chen

    IPC分类号： C08K3/08

    CPC分类号： C08K3/08 ,  C08G77/26 ,  C08K5/544 ,  C09J183/08 ,  C08L21/00

    摘要： Amino alkoxy-modified silsesquioxanes (amino AMS), and/or amino co-AMS compounds that also comprise a mercaptosilane or a blocked mercaptosilane, are excellent adhesives for coating plated or unplated metal wire for adherence of the wire to a rubber stock. The amino AMS and/or the amino/mercaptan co-AMS adhesives can be used with all types of rubber and there is no requirement for the use of special adhesive additives to the rubber vulcanizates, such as, but not limited to, cobalt, resins and high sulfur levels. In particular, the use of amino AMS and/or amino/mercaptan co-AMS compounds as adhesives for bonding wire to rubber also improves the adherence performance of the reinforcements to obtain sufficient bonding that is resistant to degradation over the course of time, especially resistance to thermal aging and/or thermo-oxidizing aging, in particular corrosion in the presence of water. Vulcanized rubber compositions that contain an amino AMS and/or amino/mercaptan co-AMS compound also have improved adhesion to embedded uncoated steel after humidity aging compared with vulcanized rubber compositions not containing the amino alkoxy-modified silsesquioxane.

    摘要翻译： 还包含巯基硅烷或封端巯基硅烷的氨基烷氧基改性倍半硅氧烷（氨基AMS）和/或氨基共-MSMS化合物是用于涂覆电镀或未镀覆金属丝的优良粘合剂，用于将线粘附到橡胶原料上。 氨基AMS和/或氨基/硫醇共-AMS粘合剂可以与所有类型的橡胶一起使用，并且不需要对橡胶硫化橡胶使用特殊的粘合剂添加剂，例如但不限于钴，树脂 和高硫含量。 特别地，使用氨基AMS和/或氨基/硫醇共-AMS化合物作为用于将线接合到橡胶上的粘合剂也提高了增强材料的粘附性能，以获得足够的粘合，其耐受在时间上的劣化，特别是电阻 热老化和/或热氧化老化，特别是在水存在下的腐蚀。 与不含氨基烷氧基改性的倍半硅氧烷的硫化橡胶组合物相比，含有氨基AMS和/或氨基/硫醇共-AMS化合物的硫化橡胶组合物在湿度老化后也具有改善的对包埋未涂层钢的粘附性。

    Vulcanizable compositions and tire treads prepared therewith
    5.
    发明授权
    Vulcanizable compositions and tire treads prepared therewith 有权
    可硫化组合物和用其制备的轮胎胎面

    公开(公告)号：US08058357B2

    公开(公告)日：2011-11-15

    申请号：US12347762

    申请日：2008-12-31

    申请人： Amy Randall ,  Terrence E. Hogan ,  William L. Hergenrother

    发明人： Amy Randall ,  Terrence E. Hogan ,  William L. Hergenrother

    IPC分类号： C08C19/20 ,  C08F8/34

    CPC分类号： B60C1/0016 ,  C08C19/44 ,  C08K5/40 ,  C08L15/00 ,  C08L21/00

    摘要： A method for preparing a tire tread, the method comprising vulcanizing a vulcanizable composition comprising a rubber component including a functionalized polymer and a cure system, where the cure system includes sulfur and a disulfide compound represented by the formula I R1—S—S—R3—S—S—R2 where R3 represents a divalent organic group and R1 and R2 each independently include a monovalent organic group including a nitrogen atom.

    摘要翻译： 一种制备轮胎胎面的方法，所述方法包括硫化包含含官能化聚合物和固化体系的橡胶组分的可硫化组合物，其中所述固化体系包括硫和由式I R1-S-S-R3表示的二硫化物 -S-S-R 2，其中R 3表示二价有机基团，并且R 1和R 2各自独立地包括包含氮原子的一价有机基团。

    Silica-reinforced rubber compounded with an alkoxysilane and a strong organic base
    6.
    发明授权
    Silica-reinforced rubber compounded with an alkoxysilane and a strong organic base 有权
    二氧化硅增强橡胶与烷氧基硅烷和强有机碱配合

    公开(公告)号：US07271208B2

    公开(公告)日：2007-09-18

    申请号：US11416295

    申请日：2006-05-02

    申请人： Chenchy Jeffrey Lin ,  William L. Hergenrother ,  Terrence E. Hogan

    发明人： Chenchy Jeffrey Lin ,  William L. Hergenrother ,  Terrence E. Hogan

    IPC分类号： C08G18/62

    CPC分类号： C08K5/31 ,  C08K3/36 ,  C08K5/54 ,  C08L43/04 ,  C08L21/00

    摘要： Improved tensile mechanical and dynamic viscoelastic properties of silica-reinforced sulfur vulcanized rubbers can be achieved by compounding elastomers with silica in the presence of an alkoxysilane and a catalytic amount of a strong organic base. The strong organic base acts as a catalyst to accelerate the alkoxysilane-silica reaction, especially at high compounding temperatures, resulting in rubber compounds that exhibit reduced compound viscosity, improved dispersion of silica, and reduced filler flocculation after compounding, and reduced hysteresis and improved abrasion resistance in the vulcanized product, compared to similar compounds prepared at the temperature without the strong organic base catalyst.

    摘要翻译： 通过在烷氧基硅烷和催化量的强有机碱的存在下，将弹性体与二氧化硅混合可以实现二氧化硅增强的硫磺硫化橡胶的拉伸机械和动态粘弹性的改进。 强有机碱作为加速烷氧基硅烷 - 二氧化硅反应的催化剂，特别是在高复合温度下，导致化合物粘度降低，二氧化硅分散性提高，配混后填料絮凝减少的橡胶化合物，减少滞后和改善磨损 与在没有强有机碱催化剂的温度下制备的类似化合物相比，硫化产物中的电阻。