公开(公告)号：US20150360201A1

公开(公告)日：2015-12-17

申请号：US14766132

申请日：2014-02-05

Applicant: THE BOARD OF REGENTS OF THE UNIVERSITY OF TEXAS SYSTEM

Inventor： Banglin CHEN ,  Chuande WU

IPC: B01J20/22 ,  C01B3/56 ,  C07F1/08

CPC classification number: B01J20/226 ,  B01D53/04 ,  B01D2253/204 ,  C01B3/56 ,  C01B2203/042 ,  C01B2210/0051 ,  C01B2210/007 ,  C07F1/08

Abstract: Disclosed herein are metal-organic frameworks (MOF) and uses thereof, including those comprising a repeat unit of the formula [Cu3(L1)2(H20)3] or [Cu3(L2)2(H20)3], wherein L1 is a ligand of the formula: (structurally represented), and where L2 is a ligand of the formula: (structurally represented). These are useful for many applications, including in the purification of hydrogen gas from production byproducts CH4 and C02, sensing, heterogeneous catalysis, drug delivery, lithium sulfide battery, membrane and analytical devices.

Abstract translation: 本文公开了金属 - 有机骨架（MOF）及其用途，包括包含式[Cu 3（L1）2（H 2 O 3）]或[Cu 3（L 2）2（H 2 O 3）]的重复单元的那些，其中L 1为 （结构上表示）的配体，其中L 2是下式的配体：（结构上被表示）。 这些可用于许多应用，包括从生产副产物CH4和CO2，感测，多相催化，药物递送，硫化锂电池，膜和分析装置中纯化氢气。

公开(公告)号：US20170341055A1

公开(公告)日：2017-11-30

申请号：US15494449

申请日：2017-04-22

Applicant: The Board of Regents of the University of Texas System ,  East China Institute of Technology

Inventor： Banglin CHEN ,  Feng LUO

IPC: B01J20/22 ,  C07C65/05 ,  B01J20/30 ,  C01B32/50 ,  B01D53/02 ,  C07C7/12

CPC classification number: B01J20/226 ,  B01D53/02 ,  B01D2253/204 ,  B01D2256/22 ,  B01D2257/504 ,  B01D2257/7022 ,  B01J20/3085 ,  C01B32/50 ,  C01B39/00 ,  C07C7/12 ,  C07C65/05 ,  Y02C10/08 ,  Y02P20/152

Abstract: A metal-organic framework (MOF) and uses thereof are provided herein, including an MOF comprising a repeat unit of the formula [Zn2(H2O)L.0.5H2O]n, wherein L is a ligand of the formula: The MOFs provided herein may be used in the separation of two or more gaseous molecules from each other. In some embodiments, the gaseous molecules are carbon dioxide and acetylene.

公开(公告)号：US20220081397A1

公开(公告)日：2022-03-17

申请号：US17478425

申请日：2021-09-17

Applicant: THE BOARD OF REGENTS OF THE UNIVERSITY OF TEXAS SYSTEM

Inventor： Banglin CHEN ,  Zhangjing ZHANG ,  Shengchang XIANG

IPC: C07D209/82 ,  C07D219/04 ,  B01J20/22 ,  B01J20/28 ,  B01J20/282 ,  C07C7/12

Abstract: In some aspects, the present disclosure provides one or more compounds of the formula: The compounds maybe used to form one or more organic frameworks that may be used in the separation of two or more molecules from each other. In some embodiments, the molecules are ethylene and ethane. In some embodiments, the organic frameworks may be used to separate one or more of these molecules with high selectivity.

公开(公告)号：US20210284661A1

公开(公告)日：2021-09-16

申请号：US17200108

申请日：2021-03-12

Applicant: The Board of Regents of The University of Texas System

Inventor： Banglin CHEN ,  Rui-Biao LIN ,  Yanshu SHI

IPC: C07F3/00 ,  B01D53/04

Abstract: Methods of preparing and using a metal-organic framework (MOF) are provided herein, including methods of using an MOF comprising a repeat unit of the formula [ML]n, wherein M is a divalent metal ion and L is a ligand of the formula: The MOFs provided herein may be used in the separation of two or more molecules from each other. In some embodiments, the molecules are ethylene and ethane. In some embodiments, UTSA-280 may be synthesized from calcium oxide (CaO) or calcium hydroxide (Ca(OH)2) and squaric acid (SA) through mechanochemical synthesis.

公开(公告)号：US20180085733A1

公开(公告)日：2018-03-29

申请号：US15560570

申请日：2016-03-23

Applicant: THE BOARD OF REGENTS OF THE UNIVERSITY OF TEXAS SYSTEM

Inventor： Banglin CHEN ,  Tong-Liang HU

IPC: B01J20/22 ,  C07C7/12 ,  C07F15/02 ,  C07F1/08 ,  C07F3/02 ,  C07F15/06

CPC classification number: B01J20/226 ,  B01D53/02 ,  B01D2253/204 ,  B01D2256/24 ,  B01D2257/7022 ,  B01J20/28011 ,  B01J20/28057 ,  B01J20/28069 ,  C07C7/12 ,  C07F1/08 ,  C07F3/02 ,  C07F15/025 ,  C07F15/065

Abstract: A metal-organic framework (MOF) and uses thereof are provided herein, including MOF comprising a repeat unit of the formula [ML], wherein L is a ligand of the following formula: and M is a divalent metal such as copper. The MOFs provided herein may be used in the separation of two or more gaseous molecules from each other. In some embodiments, the gaseous molecules are ethylene and acetylene.

公开(公告)号：US20130210157A1

公开(公告)日：2013-08-15

申请号：US13744237

申请日：2013-01-17

Applicant: The Board of Regents of the University of Texas System

Inventor： Banglin CHEN ,  Shengchang XIANG

IPC: C07F19/00 ,  B01J20/22

CPC classification number: C07F19/005 ,  B01D53/02 ,  B01D2253/204 ,  B01D2257/504 ,  B01J20/226 ,  C07F3/003 ,  F17C11/005 ,  G01N31/22 ,  Y02C10/08 ,  Y02P20/152

Abstract: Disclosed herein are mixed metal-organic frameworks, Zn3(BDC)3[Cu(SalPycy)] and Zn3(CDC)3[Cu(SalPycy)], wherein BDC is 1,4-benzenedicarboxylate, CDC is 1,4-cyclohexanedicarboxylate, and SalPyCy is a ligand of the formula: These are useful for applications such as selective gas storage, selective molecular separations, and selective detection of molecules, including enantioselective applications thereof.

Abstract translation: 本文公开了混合的金属 - 有机骨架，Zn3（BDC）3 [Cu（SalPycy）]和Zn3（CDC）3 [Cu（SalPycy）]，其中BDC是1,4-苯二甲酸酯，CDC是1,4-环己烷二羧酸酯， SalPyCy是下式的配体：它们可用于诸如选择性气体储存，选择性分子分离和选择性检测分子（包括其对映选择性应用）的应用。

公开(公告)号：US20240309023A1

公开(公告)日：2024-09-19

申请号：US18577066

申请日：2022-07-06

Applicant: THE BOARD OF REGENTS OF THE UNIVERSITY OF TEXAS SYSTEM

Inventor： Rasika DIAS ,  Anurag Noonikara POYIL ,  Banglin CHEN ,  Hui CUI

IPC: C07F5/05 ,  B01J20/22 ,  C07C7/11 ,  C07C7/12

CPC classification number: C07F5/05 ,  B01J20/223 ,  C07C7/11 ,  C07C7/12 ,  B01J2220/58

Abstract: Provided herein is a molecular sorbent based on copper that provides high-purity separation, such as separation of ethylene from ethylene-ethane mixtures and propylene from propylene-propane mixtures. Further provided herein are compositions thereof, methods of manufacturing these, and methods of use thereof.

公开(公告)号：US20170173559A1

公开(公告)日：2017-06-22

申请号：US15127514

申请日：2015-03-20

Applicant: The Board of Regents of the University of Texas System

Inventor： Banglin CHEN ,  Bin LI ,  Hui-Min WEN

IPC: B01J20/22 ,  C07D239/26 ,  B01D53/02 ,  C07C7/12

CPC classification number: B01J20/226 ,  B01D53/02 ,  B01D2253/202 ,  B01D2253/204 ,  B01D2256/14 ,  B01D2256/16 ,  B01D2257/504 ,  B01D2257/7022 ,  B01J20/28066 ,  B01J20/28076 ,  B01J31/1691 ,  B01J31/1815 ,  B01J2531/0216 ,  B01J2531/0219 ,  B01J2531/16 ,  C07C7/12 ,  C07D239/26 ,  C07F1/08 ,  Y02C10/08 ,  Y02P20/152

Abstract: Disclosed herein are metal-organic frameworks (MOF) and uses thereof, including those comprising a repeat unit of the formula [Cu2L(H2O)2]-5DMF-3H2O, wherein L is a ligand of the formula: These are useful for many applications, including in the purification of hydrogen gas from production byproducts CH4 and CO2, sensing, heterogeneous catalysis, drug delivery, lithium sulfide battery, membrane and analytical devices.