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公开(公告)号：US09938214B1
公开(公告)日：2018-04-10
申请号：US14847245
申请日：2015-09-08
IPC分类号： C07C29/149 , C07C2/34 , C07C31/02
CPC分类号： C07C2/34 , C07C29/095 , C07C29/141 , C07C29/48 , C07C45/52 , C07C67/05 , C07C2521/06 , C07C2531/14 , C07C2531/22 , C07C31/125 , C07C11/02 , C07C69/16 , C07C31/20 , C07C47/02
摘要： An efficient, low-temperature process to convert well-defined olefin oligomers, particularly butene oligomers to branched chain alcohols suitable for use as precursors to plasticizers commonly used in industry, and more specifically, the olefin feedstocks can be conveniently and renewably produced from short chain alcohols.
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公开(公告)号：US09517987B1
公开(公告)日：2016-12-13
申请号：US14692362
申请日：2015-04-21
IPC分类号： C08G64/20 , C08G64/24 , C08G64/28 , C07C37/20 , C07C37/00 , C08G64/30 , C08G73/00 , C08L69/00 , C08K7/14 , C08K7/06 , C07C39/16 , C08L79/00 , C08G64/06
CPC分类号： C07C37/20 , C07C37/002 , C07C37/50 , C07C51/353 , C08G8/10 , C08G8/12 , C08G64/06 , C08G64/24 , C08G64/28 , C08G64/307 , C08L69/00 , C07C65/105 , C07C39/16 , C07C39/04
摘要： A method for the selective synthesis of bisphenols, thermosetting resins, and thermoplastics from salicylic acid, the major component of wintergreen oil, and a viable target for engineered biosynthesis. Condensation of salicylic acid, structural analogs of salicylic acid, and derivatives of salicylic acid with short chain aldehydes or ketones and subsequent decarboxylation has the potential to produce bisphenols that are direct replacements for conventional resins, while the steric and electronic effects of salicylic acid improve the efficiency and selectivity of the conversion process. The utilization of renewable polyphenols as precursors to epoxies, poly carbonates, and high temperature thermosets including cyanate esters, provides an opportunity to develop full-performance resins while reducing the use of petroleum based feedstocks. This approach will then diminish the overall environmental impact of resin production while allowing for a sustainable source of phenols.
摘要翻译： 一种从水杨酸，冬青油的主要组分选择性合成双酚，热固性树脂和热塑性塑料的方法，以及工程生物合成的可行目标。 水杨酸的缩合，水杨酸的结构类似物和水杨酸的衍生物与短链醛或酮和随后的脱羧有可能生产直接替代常规树脂的双酚，而水杨酸的空间和电子效应改善了 转换过程的效率和选择性。 可再生多酚作为环氧树脂，聚碳酸酯和高温热固性物质（包括氰酸酯）的前体的利用提供了开发全性能树脂同时减少使用石油基原料的机会。 然后，这种方法将减少树脂生产的总体环境影响，同时允许可持续的酚类来源。
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公开(公告)号：US10119953B1
公开(公告)日：2018-11-06
申请号：US15705731
申请日：2017-09-15
IPC分类号： G01N33/22 , G01N21/64 , G01N31/22 , C01G15/00 , C06B25/04 , B82Y20/00 , G01N21/47 , C06B25/34
摘要： The synthesis of AgInS2 based quantum dots and their use as fluorometric probes for the selective detection of nitroaromatic explosive chemicals, without the use of ligands specific to nitroaromatic explosive chemicals. These quantum dots allow the detection of nitroaromatic explosive molecules by eye. The present invention also represents a simple patterning method for quantum dots on substrates, including low cost filter paper. The ease of fabrication, use of less toxic materials, and the selectivity to nitroaromatic explosive chemicals results in a practical solution to the development of a portable fluorescent probe based on quantum dots for the detection of nitroaromatic explosive chemicals.
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公开(公告)号：US10107787B1
公开(公告)日：2018-10-23
申请号：US15247344
申请日：2016-08-25
摘要： A testing element, and methods of use therefor, for the detection of target analytes, for example metal ions and other environmental hazards, utilizing ligand functionalized fluorescent nanoparticles on a substrate. The non-toxic, air, and water stable fluorescent nanoparticles of the present invention are made from varying ratios of metals including zinc, silver, copper, and indium and sulfur. By varying the ratios of these metals nanoparticles can be synthesized that emit over a large range of the visible spectrum. Charge transfer between a target analyte and the nanoparticle is readily identified by a fluorescence change allowing for a fast, simple, visual detection system without the need for expensive analytical instrumentation. The test element can have more than one type of functionalized fluorescent nanoparticle which allows for the detection of multiple target analytes using a single test element.
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公开(公告)号：US09994498B2
公开(公告)日：2018-06-12
申请号：US13676541
申请日：2012-11-14
CPC分类号： C07C5/13 , C07C5/2506 , C07C7/00 , C10G1/00 , C10G3/42 , C10G3/44 , C10G3/45 , C10G3/50 , C10G2300/1014 , C10G2400/04 , C10G2400/08 , C10L1/04 , C10L1/08 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： A fuel and method for conversion of sesquiterpenes to high density fuels. The sesquiterpenes can be either extracted from plants or specifically produced by bioengineered organisms from waste biomass. This approach allows for the synthesis of high performance renewable fuels.
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公开(公告)号：US09127115B1
公开(公告)日：2015-09-08
申请号：US14618836
申请日：2015-02-10
IPC分类号： C07C37/055 , C07C37/20 , C08G61/10 , C08G63/19 , C08G63/193 , C08G64/24 , C08G64/06 , C08G73/12 , C08G59/04
CPC分类号： C08G59/04 , C07C37/50 , C07C41/18 , C07C41/20 , C07C41/30 , C07C45/65 , C07C261/02 , C07C263/00 , C08G18/00 , C08G63/19 , C08L79/00 , C07C47/575 , C07C43/215 , C07C43/23 , C07C43/2055 , C07C39/16
摘要： A method to generate renewable high performance composites and thermoplastics. These materials can be generated from a renewable phenol (syringaldehyde) that can be derived from lignocellulosic biomass. The use of syringaldehyde as a precursor to composites has the potential to reduce the cost and environmental impact of structural materials, while meeting or exceeding the performance of current petroleum derived resins.
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公开(公告)号：US09051414B1
公开(公告)日：2015-06-09
申请号：US14618424
申请日：2015-02-10
IPC分类号： C07C37/055 , C07C37/20 , C08G59/04 , C08G61/10 , C08G63/193 , C08G64/24 , C08G64/06 , C08G73/12 , C08G63/19
CPC分类号： C08G59/04 , C07C37/50 , C07C41/18 , C07C41/20 , C07C41/30 , C07C45/65 , C07C261/02 , C07C263/00 , C08G18/00 , C08G63/19 , C08L79/00 , C07C47/575 , C07C43/215 , C07C43/23 , C07C43/2055 , C07C39/16
摘要： A method to generate renewable high performance composites and thermoplastics. These materials can be generated from a renewable phenol (syringaldehyde) that can be derived from lignocellulosic biomass. The use of syringaldehyde as a precursor to composites has the potential to reduce the cost and environmental impact of structural materials, while meeting or exceeding the performance of current petroleum derived resins.
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公开(公告)号：US10711215B1
公开(公告)日：2020-07-14
申请号：US14834071
申请日：2015-08-24
IPC分类号： C10L10/10 , C10L1/18 , C10L1/02 , C07D317/12 , C10L1/185
摘要： A method to generate dioxolanes from renewable feedstocks, and more specifically, these oxygenated hydrocarbons can be used as gasoline-range fuels and diesel additives.
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公开(公告)号：US10252966B1
公开(公告)日：2019-04-09
申请号：US13860975
申请日：2013-04-11
IPC分类号： C04B26/12 , C07C41/30 , C07C261/02 , C07C41/18 , C07C43/205 , C07C43/23 , C08G64/16 , C08G73/06
摘要： A series of renewable bisphenols has been synthesized from creosol (2-methoxy-4-methylphenol) through stoichiometric condensation with short chain aldehydes. Creosol can be readily produced from lignin, potentially allowing for the large scale synthesis of bisphenol A replacements from abundant waste biomass. The renewable bisphenols were isolated in good yield and purity without resorting to solvent intense purification methods. Zinc acetate was shown to be selective catalyst for ortho-coupling of formaldehyde but was unreactive with more sterically demanding aldehydes. Dilute HCl and HBr solutions were shown to be effective catalysts for the selective coupling of aldehydes in the position meta to the phenol. Acid solutions could be recycled and used multiple times without decreases in activity or yield.
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公开(公告)号：US09187591B1
公开(公告)日：2015-11-17
申请号：US14618554
申请日：2015-02-10
IPC分类号： C07C37/055 , C07C37/20 , C08G59/04 , C08G61/10 , C08G63/19 , C08G63/193 , C08G64/24 , C08G64/06 , C08G73/12
CPC分类号： C08G59/04 , C07C37/50 , C07C41/18 , C07C41/20 , C07C41/30 , C07C45/65 , C07C261/02 , C07C263/00 , C08G18/00 , C08G63/19 , C08L79/00 , C07C47/575 , C07C43/215 , C07C43/23 , C07C43/2055 , C07C39/16
摘要： A method to generate renewable high performance composites and thermoplastics. These materials can be generated from a renewable phenol (syringaldehyde) that can be derived from lignocellulosic biomass. The use of syringaldehyde as a precursor to composites has the potential to reduce the cost and environmental impact of structural materials, while meeting or exceeding the performance of current petroleum derived resins.
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