Aromatization process
    4.
    发明授权
    Aromatization process 失效
    芳香化过程

    公开(公告)号:US4861932A

    公开(公告)日:1989-08-29

    申请号:US140274

    申请日:1987-12-31

    IPC分类号: C07C5/41 C10G35/095 C10G59/02

    摘要: A process for converting a C.sub.2 -C.sub.12 paraffinic hydrocarbon feed to aromatics comprising passing the feed through a first conversion zone wherein the feed contacts a noble metal/low acidity medium pore size zeolite catalyst, and then passing the resulting hydrocarbon mixture through a second conversion zone wherein the resulting hydrocarbon mixture contacts a medium pore size acidic zeolite catalyst.

    摘要翻译: 将C2-C12链烷烃进料转化为芳族化合物的方法,包括使进料通过第一转化区,其中进料接触贵金属/低酸度介质孔径沸石催化剂,然后使所得烃混合物通过第二转化区 其中所得烃类混合物与中等孔径的酸性沸石催化剂接触。

    Hydrocarbon coversion using improved zeolite Beta catalyst
    5.
    发明授权
    Hydrocarbon coversion using improved zeolite Beta catalyst 失效
    使用改进的沸石β催化剂进行烃转化

    公开(公告)号:US5658454A

    公开(公告)日:1997-08-19

    申请号:US461484

    申请日:1995-06-05

    摘要: A catalyst composition which comprises a crystalline metallosilicate having the structure of zeolite Beta, phosphor and a matrix that is substantially free of crystalline aluminum phosphate which has improved resistance to steam deactivation which has higher cracking activity than analogous catalysts prepared without phosphorus. The crystalline metallosilicate be used in the as-synthesized form or in the calcined form. included is the method to produce the catalyst composition and methods for the use of catalysts prepared by the present method in organic conversion processes. Specific embodiments of the invention involve various techniques for preparation of catalyst containing phosphorus and crystalline metallosilicates having the structure of zeolite Beta. Catalysts prepared according to the method of this invention are useful for organic compound, e.g., hydrocarbon compound, conversion processes. Organic compound conversion processes include cracking, hydrocracking, and transalkylation, among others.

    摘要翻译: 一种催化剂组合物,其包含具有沸石β,磷光体和基本上不含结晶磷酸铝的结构的结晶金属硅酸盐,其具有改善的对蒸汽失活的抗性,其具有比不用磷制备的类似催化剂更高的裂化活性。 结晶金属硅酸盐以合成形式或煅烧形式使用。 包括制备催化剂组合物的方法和通过本发明方法在有机转化方法中制备的催化剂的使用方法。 本发明的具体实施方案涉及用于制备含有β沸石结构的磷的磷和结晶金属硅酸盐的各种技术。 根据本发明方法制备的催化剂可用于有机化合物,例如烃化合物,转化方法。 有机化合物转化方法包括裂化,加氢裂化和烷基转移等。

    Hydrogenation process
    6.
    发明授权
    Hydrogenation process 失效
    氢化过程

    公开(公告)号:US5573657A

    公开(公告)日:1996-11-12

    申请号:US309288

    申请日:1994-09-20

    IPC分类号: B01J29/04 C10G45/00 C10G45/54

    摘要: A hydrogenation process for reducing the unsaturation of lubricants uses a catalyst which is based on an ultra-large pore crystalline material. The crystalline material has pores of at least 13 .ANG. diameter arranged in a uniform manner and exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams (50 torr and 25.degree. C.). A preferred form of the catalyst has a hexagonal structure which exhibits a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 .ANG.. The hydrogenation catalysts based on these materials are capable of reducing the unsaturation in poly alpha olefin lubricants to a low level.

    摘要翻译: 用于降低润滑剂的不饱和度的氢化方法使用基于超大孔结晶材料的催化剂。 结晶材料具有均匀排列的至少13安培直径的孔,并且通过苯吸附能力大于约15克苯/ 100克(50托和25℃)表现出非常大的吸附能力。 催化剂的优选形式具有六角形结构,其显示六方电子衍射图,其可以以大于约18安培的d100值进行索引。 基于这些材料的氢化催化剂能够将聚α-烯烃润滑剂的不饱和度降低至低水平。

    Manufacture of improved zeolite Beta catalyst
    7.
    发明授权
    Manufacture of improved zeolite Beta catalyst 失效
    改良沸石β催化剂的制造

    公开(公告)号:US5457078A

    公开(公告)日:1995-10-10

    申请号:US158325

    申请日:1993-11-29

    摘要: A catalyst composition which comprises a crystalline metallosilicate having the structure of zeolite Beta, phosphorus, and a matrix that is substantially free of crystalline aluminum phosphate which has improved resistance to steam deactivation and which has higher cracking activity than analogous catalysts prepared without phosphorus. The crystalline metallosilicate may be used in the as-synthesized form or in the calcined form. Also included is the method to produce the catalyst composition and methods for the use of catalysts prepared by the present method in organic conversion processes. Specific embodiments of the invention involve various techniques for preparation of catalysts containing phosphorus and crystalline metallosilicates having the structure of zeolite Beta. Catalysts prepared according to the method of this invention are useful for organic compound, e.g., hydrocarbon compound, conversion processes. Organic compound conversion processes include cracking, hydrocracking, and transalkylation, among others.

    摘要翻译: 一种催化剂组合物,其包含具有沸石β,磷的结构的结晶金属硅酸盐和基本上不含结晶磷酸铝的基质,其具有改善的对蒸汽失活的抗性,并且具有比不含磷制备的类似催化剂更高的裂化活性。 结晶金属硅酸盐可以以合成形式或以煅烧形式使用。 还包括制备催化剂组合物的方法和使用通过本发明方法制备的催化剂在有机转化方法中的方法。 本发明的具体实施方案涉及用于制备含有β沸石结构的含有磷的结晶金属硅酸盐的催化剂的各种技术。 根据本发明方法制备的催化剂可用于有机化合物,例如烃化合物,转化方法。 有机化合物转化方法包括裂化,加氢裂化和烷基转移等。

    Catalyst and method of manufacture
    8.
    发明授权
    Catalyst and method of manufacture 失效
    催化剂及其制造方法

    公开(公告)号:US5470810A

    公开(公告)日:1995-11-28

    申请号:US190438

    申请日:1994-02-02

    摘要: This invention relates to the catalyst composition resulting from the addition of phosphorus, and optionally, a matrix material, to a porous crystalline material having the structure of MCM-22, along with the method for making the catalyst composition, and the method for using the catalyst composition in catalytic cracking. It is desirable to improve the hydrothermal stability of the catalysts which are based upon porous crystalline materials having the X-ray structure of MCM-22 to increase the activity that the catalyst maintains after repeated cycles of steaming such as is experienced in the FCC process. It has been found that phosphorus addition to a porous crystalline material having the structure of MCM-22 improves the hydrothermal stability of the resulting catalyst. This improved catalyst is useful in organic conversion processes, e.g., catalytic cracking processes.

    摘要翻译: 本发明涉及通过向具有MCM-22结构的多孔结晶材料以及制备催化剂组合物的方法中添加磷和任选的基质材料而得到的催化剂组合物,以及使用该方法 催化剂组成催化裂化。 希望提高基于具有MCM-22的X射线结构的多孔结晶材料的催化剂的水热稳定性,以增加如在FCC方法中经历的重复蒸汽循环之后催化剂维持的活性。 已经发现,具有MCM-22结构的多孔结晶材料中的磷添加改善了所得催化剂的水热稳定性。 这种改进的催化剂可用于有机转化方法,例如催化裂化方法。

    Process for isomerization dewaxing of hydrocarbon streams
    9.
    发明授权
    Process for isomerization dewaxing of hydrocarbon streams 有权
    烃流异构化脱蜡方法

    公开(公告)号:US06652735B2

    公开(公告)日:2003-11-25

    申请号:US09843125

    申请日:2001-04-26

    IPC分类号: C10G7338

    摘要: A process for isomerization dewaxing of a hydrocarbon feed which includes contacting the hydrocarbon feed with a large pore size, small crystal size, crystalline molecular sieve and an intermediate pore size, small crystal size, crystalline molecular sieve to produce a dewaxed product with a reduced pour point and a reduced cloud point. In a preferred embodiment, the feed is contacted with the molecular sieves sequentially, first with the large pore sieve followed by the intermediate pore sieve.

    摘要翻译: 烃原料异构化脱蜡的方法,其包括使烃进料与大孔径,小结晶尺寸,结晶分子筛和中等孔径,小晶体尺寸,结晶分子筛接触以产生具有降低的倾倒的脱蜡产物 点和减少的浊点。 在一个优选的实施方案中,进料与分子筛依次接触,首先用大孔筛,然后是中间孔筛。

    Aromatic alkylation process
    10.
    发明授权
    Aromatic alkylation process 有权
    芳香烷基化工艺

    公开(公告)号:US06313362B1

    公开(公告)日:2001-11-06

    申请号:US09213798

    申请日:1998-12-17

    IPC分类号: C07C264

    CPC分类号: C07C15/085 C07C15/073

    摘要: Akylation product is contacted with a purification medium in a liquid phase pre-reaction step to remove impurities and form a purified stream. The purified stream may then be further processed by liquid phase transalkylation to convert the polyalkylated aromatic compound to a monoalkylated aromatic compound. The process may use a large pore molecular sieve catalyst such as MCM-22 as the purification medium in the pre-reaction step because of its high reactivity for alkylation, strong retention of catalyst poisons and low reactivity for oligomerization under the pre-reactor conditions. Olefins, diolefins, styrene, oxygenated organic compounds, sulfur containing compounds, nitrogen containing compounds and oligomeric compounds are removed.

    摘要翻译: 将Akylation产物在液相预反应步骤中与净化介质接触以除去杂质并形成纯化的物流。 然后可以通过液相烷基转移进一步处理纯化的物流,以将多烷基化芳族化合物转化为单烷基化芳族化合物。 在预反应步骤中,该方法可以使用大孔分子筛催化剂例如MCM-22作为纯化介质,因为其在烷基化反应活性高,催化剂毒物强烈的保留和在反应器前条件下的低聚反应低。 除去烯烃,二烯烃,苯乙烯,含氧有机化合物,含硫化合物,含氮化合物和低聚物。