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公开(公告)号：US5185310A
公开(公告)日：1993-02-09
申请号：US829149
申请日：1992-01-31
IPC分类号： B01J29/85
CPC分类号： B01J29/85 , B01J2229/42
摘要： A method of activating silicoaluminophosphate (SAPO) compositions by contacting as-synthesized SAPO with hydrated alumina and water, followed by heating to at least 425.degree. C., preferably in nitrogen and then air.
摘要翻译： 通过将合成的SAPO与水合氧化铝和水接触，然后加热至至少425℃，优选在氮气中然后空气来活化硅铝磷酸盐（SAPO）组合物的方法。
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2.发明授权
公开(公告)号：US5220101A
公开(公告)日：1993-06-15
申请号：US918322
申请日：1992-07-22
申请人： Jeffrey S. Beck , David C. Calabro , Sharon B. McCullen , Bruce P. Pelrine , Kirk D. Schmitt , James C. Vartuli
发明人： Jeffrey S. Beck , David C. Calabro , Sharon B. McCullen , Bruce P. Pelrine , Kirk D. Schmitt , James C. Vartuli
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16
CPC分类号： C10G47/16 , B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/18 , B01J20/3078 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , B01J2229/12 , B01J2229/14 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42
摘要： A process is provided for separating at least one component from a mixture of components which comprises contacting the mixture with a composition comprising a functionalized inorganic, porous, non-layered crystalline phase having uniformly sized pores of at least about 13, e.g., at least about 15, Angstrom Units in diameter.
摘要翻译： 提供了用于从组分混合物中分离至少一种组分的方法，其包括使混合物与包含官能化无机，多孔，非层状结晶相的组合物接触，该组合物具有至少约13，例如至少约 15，直径单位。
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公开(公告)号：US4861932A
公开(公告)日：1989-08-29
申请号：US140274
申请日：1987-12-31
IPC分类号： C07C5/41 , C10G35/095 , C10G59/02
CPC分类号： C10G59/02 , C07C5/417 , C10G35/095
摘要： A process for converting a C.sub.2 -C.sub.12 paraffinic hydrocarbon feed to aromatics comprising passing the feed through a first conversion zone wherein the feed contacts a noble metal/low acidity medium pore size zeolite catalyst, and then passing the resulting hydrocarbon mixture through a second conversion zone wherein the resulting hydrocarbon mixture contacts a medium pore size acidic zeolite catalyst.
摘要翻译： 将C2-C12链烷烃进料转化为芳族化合物的方法，包括使进料通过第一转化区，其中进料接触贵金属/低酸度介质孔径沸石催化剂，然后使所得烃混合物通过第二转化区 其中所得烃类混合物与中等孔径的酸性沸石催化剂接触。
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公开(公告)号：US5145816A
公开(公告)日：1992-09-08
申请号：US718056
申请日：1991-06-20
申请人： Jeffrey S. Beck , David C. Calabro , Sharon B. McCullen , Bruce P. Pelrine , Kirk D. Schmitt , James C. Vartuli
发明人： Jeffrey S. Beck , David C. Calabro , Sharon B. McCullen , Bruce P. Pelrine , Kirk D. Schmitt , James C. Vartuli
IPC分类号： B01J20/10 , B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/06 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C01B39/04 , C01B39/06 , C01B39/48 , C10G11/05 , C10G47/16
CPC分类号： B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/18 , B01J20/3078 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/045 , B01J29/40 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , B01J2229/12 , B01J2229/14 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/40 , B01J2229/42
摘要： A method is described for modifying an ultra-large pore crystalline material by contacting with a treatment composition M'X'Y'.sub.n wherein M' is an element of Groups IIA, IVA, VA, VIA, VIIA, IB, IIB, IVB, VB or VIB; X' is halide, hydride, alkoxide of C.sub.1-6', or acetate; Y' is X or phosphine, sulfide, carbonyl or cyano; and N=1-5. The contacted crystalline material becomes functionalized. The functionalized material is also described and can be used as a sorbent or catalyst component.
摘要翻译： 描述了通过与处理组合物M'X'Y'n接触来改性超大孔结晶材料的方法，其中M'是IIA，IVA，VA，VIA，VIIA，IB，IIB，IVB，IVB族的元素， VB或VIB; X'是卤化物，氢化物，C1-6'的醇盐或乙酸盐; Y'是X或膦，硫化物，羰基或氰基; N = 1-5。 接触的结晶材料变得官能化。 还描述了官能化材料并且可以用作吸附剂或催化剂组分。
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5.发明授权Aromatization process and catalyst utilizing a mixture of shape-selective porous crystalline silicate zeolite and pillared layered metal oxide 失效使用形状选择性多孔结晶硅酸盐沸石和柱状层状金属氧化物的混合物的芳构化方法和催化剂
公开(公告)号：US4935573A
公开(公告)日：1990-06-19
申请号：US314612
申请日：1989-02-23
IPC分类号： B01J29/04 , B01J29/40 , B01J29/44 , B01J29/65 , B01J29/70 , B01J29/80 , C07C15/00 , C10G35/095
CPC分类号： C10G35/095 , B01J29/049 , B01J29/40 , B01J29/405 , B01J29/44 , B01J29/80 , B01J2229/26 , B01J2229/42 , B01J29/65 , B01J29/70
摘要： A catalyst composition suitable for use in aromatization of non-aromatic hydrocarbons comprises a shape-selective crystalline slicate such as ZSM-5 and a titanometallate-type layered metal oxide comprising a layered metal oxide and pillars of an oxide of at least one element selected from Groups IB, IIB, IIIA, IIIB, IVA, IVB, VA, VB, VIA, VIIA and VIIIA of the Periodic Table of the Elements separating the layers of the metal oxide where each layer of the metal oxide has the general formula[M.sub.x .sub.y Z.sub.2-(x+y) O.sub.4 ].sup.q-wherein M is at least one metal of valence n wherein is an integer between 0 and 7, represents a vacancy site, Z is a tetravalent metal, and whereinq=4y-x(n-4)0
摘要翻译： 适合用于非芳族烃芳构化的催化剂组合物包括形状选择性晶体切片如ZSM-5和金属金属盐型层状金属氧化物，其包含层状金属氧化物和选自以下的至少一种元素的氧化物柱 分离金属氧化物层的元素周期表的IB，IIB，IIIA，IIIB，IVA，IVB，VA，VB，VIA，VIIA和VIIIA，其中每层金属氧化物具有通式[M x y Z2-（x + y）O4] q-其中M是价数n的至少一种金属，其中0和7之间的整数表示空位，Z是四价金属，并且其中q = 4y-x（n -4）0
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公开(公告)号：US5061466A
公开(公告)日：1991-10-29
申请号：US120891
申请日：1987-11-16
CPC分类号： B01J29/87 , C10G11/05 , C10G35/065
摘要： The invention is directed to increasing the cracking activity and providing aromatization activity to a large pore zeolite by incorporating gallium into the framework of a large pore zeolite.
摘要翻译： 本发明旨在通过将镓掺入大孔沸石的骨架中来提高裂化活性并为大孔沸石提供芳构化活性。
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7.发明授权Aromatization process and catalyst utilizing a mixture of shape-selective porous crystalline silicate zeolite and pillared layered metal oxide 失效使用形状选择性多孔结晶硅酸盐沸石和柱状层状金属氧化物的混合物的芳构化方法和催化剂
公开(公告)号：US4933310A
公开(公告)日：1990-06-12
申请号：US314606
申请日：1989-02-23
CPC分类号： C10G35/095 , B01J29/049 , B01J29/40 , B01J29/405 , B01J29/44 , B01J29/80 , B01J2229/26 , B01J2229/42 , B01J29/65 , B01J29/70
摘要： A catalyst composition suitable for use in aromatization of non-aromatic hydrocarbons comprises a shape-selective crystalline silicate such as ZSM-5 and a titanometallate-type layered metal oxide comprising a layered metal oxide and pillars of an oxide of at least one element selected from Groups IB, IIB, IIIA, IIIB, IVA, IVB, VA, VB, VIA, VIIA and VIIIA of the Periodic Table of the Elements separating the layers of the metal oxide where each layer of the metal oxide has the general formula[M.sub.x .quadrature..sub.y Z.sub.2-(x+y) O.sub.4 ].sup.q-wherein M is at least one metal of valence n wherein n is an integer between 0 and 7, .quadrature.represents a vacancy site, Z is a tetravalent metal, and whereinq=4y-x(n-4)O
摘要翻译： 适用于非芳族烃芳构化的催化剂组合物包括形状选择性结晶硅酸盐，例如ZSM-5和金属金属盐型层状金属氧化物，其包含层状金属氧化物和选自以下的至少一种元素的氧化物柱 分离金属氧化物层的元素周期表的IB，IIB，IIIA，IIIB，IVA，IVB，VA，VB，VIA，VIIA和VIIIA，其中每层金属氧化物具有通式[Mx＆ y Z2-（x + y）O4] q-其中M是价数n的至少一种金属，其中n是0和7之间的整数，并且表示空位，Z是四价金属，并且其中q = 4y- x（n-4）O
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8.发明授权
公开(公告)号：US5200058A
公开(公告)日：1993-04-06
申请号：US895283
申请日：1992-06-08
申请人： Jeffrey S. Beck , David C. Calabro , Sharon B. McCullen , Bruce P. Pelrine , Kirk D. Schmitt , James C. Vartuli
发明人： Jeffrey S. Beck , David C. Calabro , Sharon B. McCullen , Bruce P. Pelrine , Kirk D. Schmitt , James C. Vartuli
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16
CPC分类号： B01J29/045 , B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/3078 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , B01J2229/12 , B01J2229/14 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42
摘要： A process is provided for effecting catalytic conversion of an organic compound-containing feedstock to conversion product which comprises contacting said feedstock under catalytic conversion conditions with a catalyst comprising an active form of a functionalized inorganic, porous, non-layered crystalline phase having uniformly sized pores of at least about 13, e.g., at least about 15, Angstrom Units in diameter.
摘要翻译： 提供了一种用于将含有机化合物的原料催化转化成转化产物的方法，其包括在催化转化条件下使所述原料与包含具有均匀尺寸的孔的官能化无机，多孔，非层状结晶相的活性形式的催化剂接触 至少约13，例如至少约15埃，直径单位。
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公开(公告)号：US6054052A
公开(公告)日：2000-04-25
申请号：US572823
申请日：1995-12-14
CPC分类号： B01J20/186 , B01D15/00 , B01D15/34 , Y02W10/37
摘要： Incorporation of zirconium, nickel and/or copper into M41S results in selective sorption of bulky organic molecules. Zirconium, nickel and/or copper may be incorporated into M41S by exchange or impregnation.
摘要翻译： 将锆，镍和/或铜掺入M41S导致大量有机分子的选择性吸附。 锆，镍和/或铜可以通过交换或浸渍加入到M41S中。
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10.发明授权
公开(公告)号：US5689025A
公开(公告)日：1997-11-18
申请号：US382103
申请日：1995-02-01
CPC分类号： C07C6/123 , B01J29/40 , B01J37/086 , C07C2/66 , C07C2/864 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2529/06 , C07C2529/40 , C07C2529/65 , C07C2529/70
摘要： A process for ethylbenzene production that involves contacting a hydrocarbon feedstream including benzene and ethylene, under alkylation conditions, with a catalytic molecular sieve which has been modified by being ex situ selectivated with a silicon compound. The ex situ selectivation involves exposing the molecular sieve to at least two selectivation sequences, each selectivation sequence comprising contacting the catalyst with a silicon compound followed by calcination. The modified catalyst used in the process may also be steamed. Optionally, the modified catalyst may be trim-selectivated.
摘要翻译： 一种乙苯生产方法，其涉及在烷基化条件下使含有苯和乙烯的烃进料流与通过用硅化合物进行原位选择性修饰的催化分子筛接触。 异位选择包括将分子筛暴露于至少两个选择性序列，每个选择活性序列包括使催化剂与硅化合物接触，随后煅烧。 在该方法中使用的改性催化剂也可以蒸。 任选地，修饰的催化剂可以是修剪选择的。
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