摘要:
Coating compositions that are stable to thermal yellowing that include coating materials containing I) one or more dispersions of hydroxyl-free polyurethanes and/or polyurethane-ureas, II) one or more aqueous solutions or dispersions of ionically modified, hydroxyl-containing polyurethanes and/or polyurethane-ureas, other than the constituents of component I), and III) at least one crosslinker. The dispersions are obtained by A) preparing an NCO-containing polyurethane prepolymer by reacting polyisocyanates with polymeric polyols and/or polyamines having number-average molecular weights of 400 to 8000 g/mol, isocyanate-reactive, ionically or potentially ionically hydrophilicizing compounds and/or isocyanate-reactive nonionically hydrophilicizing compounds; B) either dissolving the prepolymer obtained from step A) in aliphatic ketones or, diluting the prepolymer solution if the preparation has already been carried out in the presence of A6) by further addition of aliphatic ketones, and C) reacting the remaining free NCO groups of the prepolymer with a chain extender component.
摘要:
Aqueous polyurethane-polyurea dispersions, stabilized with respect to thermal yellowing, which have excellent mechanical properties and also to their preparation and use.
摘要:
Coating compositions that are stable to thermal yellowing that include coating materials containing I) one or more dispersions of hydroxyl-free polyurethanes and/or polyurethane-ureas, II) one or more aqueous solutions or dispersions of ionically modified, hydroxyl-containing polyurethanes and/or polyurethane-ureas, other than the constituents of component I), and III) at least one crosslinker. The dispersions are obtained by A) preparing an NCO-containing polyurethane prepolymer by reacting polyisocyanates with polymeric polyols and/or polyamines having number-average molecular weights of 400 to 8000 g/mol, isocyanate-reactive, ionically or potentially ionically hydrophilicizing compounds and/or isocyanate-reactive nonionically hydrophilicizing compounds; B) either dissolving the prepolymer obtained from step A) in aliphatic ketones or, diluting the prepolymer solution if the preparation has already been carried out in the presence of A6) by further addition of aliphatic ketones, and C) reacting the remaining free NCO groups of the prepolymer with a chain extender component.
摘要:
The invention relates to aqueous coating material compositions stable to hydrolysis, to a process for preparing them and to their use as soft feel paint. The compositions comprise hydroxyl-free polyurethanes and/or polyurethane-ureas based on polycarbonate polyols and polytetramethylene glycol polyols, ionically modified, hydroxyl- and/or amino-containing polyurethanes and/or polyurethane-ureas and at least one crosslinker, and optionally further film-forming resins.
摘要:
Aqueous coating materials are provided. The materials comprise I) hydroxyl-free polyurethanes and/or polyurethane-ureas, II) ionically modified, hydroxyl-containing polyurethanes and/or polyurethane-ureas, and III) at least one crosslinker, characterized in that the components (I) and (II) comprise polycarbonate polyols which have at least 25% by weight of 1,4-butanediol as synthesis component. A process for preparing the coating materials, and their use as soft feel paint, is also provided.
摘要:
The invention relates to water-dilutable, hydroxy-functional polyurethanes containing amide structural units, to a process for preparing them, to aqueous coating compositions prepared from them, and to their use for coating substrates.
摘要:
The invention relates to water-dilutable, hydroxy-functional polyurethanes containing amide structural units, to a process for preparing them, to aqueous coating compositions prepared from them, and to their use for coating substrates.
摘要:
The present invention relates to composite plastic moldings containing A) a thermoplastically formable, heat-resistant composite film having A1) a carrier film of a thermoplastic resin and A2) a layer of a heat-resistant soft touch coating on one side of the carrier film (A1) and B) a thermoplastic layer on the side of the carrier film (A1) facing away from the soft touch coating, wherein the soft touch coating (A2) is obtained from a composition containing i) polyurethanes and/or polyurethane-ureas which are free from hydroxyl and/or amine groups, ii) ionically modified polyurethanes and/or polyurethane-ureas which contain hydroxyl and/or amine groups, iii) at least one crosslinking agent, iv) optionally film-forming resins other than A1) or A2), and v) optionally additives. The present invention also relates to a process for the production of these composite moldings and their use in telecommunications equipment and in vehicle, ship and aircraft construction.
摘要:
The invention provides aqueous preparations having soft-feel properties, foams obtainable by mechanically foaming these preparations, and soft-feel coatings based on the foams. The preparations comprise aqueous polyurethane-polyurea dispersions, hydroxy-functional, aqueous or water-dilutable binders, polyisocyanates which may have been hydrophilically modified, and foam stabilizers.
摘要:
A process for preparing polyester-polyurethane resin dispersions comprising: A) reacting i) one or more polyol components having a number average molecular weight of at least 300 daltons, at least 60% by weight of component i) being a polyester polyol with the fraction of aromatic carboxylic acid groups relative to all of the carboxylic acid groups used to prepared said polyester polyol being at least 60 mol %, ii) optionally one or more polyol components having a number average molecular weight of 62 to 299 daltons, and iii) optionally a compound which is monofunctional for the purposes of the isocyanate polyaddition reaction and has an ethylene oxide content of at least 50% by weight and a number average molecular weight of at least 400 daltons, with iv) a polyisocyanate to form a prepolymer, B) dissolving the prepolymer in an organic solvent, C) reacting the prepolymer with v) one or more aliphatic and/or alicyclic primary and/or secondary polyamines having a number average molecular weight of 60 to 300 daltons, said polyamine optionally being in combination with hydrazine or hydrazine hydrate, and vi) a hydrophilicized aliphatic diamine, D) precipitating the product from C) by adding water to form a dispersion, and E) removing the organic solvent.