公开(公告)号：US06559270B1

公开(公告)日：2003-05-06

申请号：US09416529

申请日：1999-10-12

申请人： Tiberiu Mircea Siclovan ,  Jimmy Lynn Webb ,  Sterling Bruce Brown ,  Donald Joseph Buckley, Jr. ,  James Edward Pickett ,  Joseph Anthony Suriano ,  Paul Dean Sybert ,  Daniel Joseph Brunelle ,  Margaret Louise Blohm ,  Hongyi Zhou ,  Georgia Dris Fishburn

发明人： Tiberiu Mircea Siclovan ,  Jimmy Lynn Webb ,  Sterling Bruce Brown ,  Donald Joseph Buckley, Jr. ,  James Edward Pickett ,  Joseph Anthony Suriano ,  Paul Dean Sybert ,  Daniel Joseph Brunelle ,  Margaret Louise Blohm ,  Hongyi Zhou ,  Georgia Dris Fishburn

IPC分类号： C08G6401

CPC分类号： C08L67/00 ,  C08G63/64 ,  C08G63/78 ,  C08G64/18 ,  C08G2261/126 ,  C08K3/013 ,  C08L67/02 ,  C08L67/03 ,  C08L69/00 ,  C08L69/005 ,  C08L79/08 ,  F02B61/045

摘要： Block copolyestercarbonates may be prepared by first conducting a reaction between at least one of resorcinol or an alkyl- or haloresorcinol and at least one aromatic dicarboxylic acid dichloride, preferably isophthaloyl dichloride, terephthaloyl dichloride or a mixture thereof, to produce a hydroxy-terminated polyester intermediate, and then conducting a reaction of the intermediate with a carbonate precursor, preferably in the presence of a dihydroxy compound such as bisphenol A. The products have excellent physical properties, including a high degree of weatherability. They may be blended with other polymers such as polycarbonates, poly(alkylene carboxylates), polyarylates, polyetherimides, and addition polymers to improve the weatherability thereof.

摘要翻译： 嵌段共聚酯碳酸酯可以通过首先在间苯二酚或烷基 - 或卤代间苯二酚和至少一种芳族二羧酸二氯化物，优选间苯二酰氯，对苯二甲酰氯或其混合物中的至少一种之间进行反应来制备，以产生羟基封端的聚酯中间体 ，然后进行中间体与碳酸酯前体的反应，优选在二羟基化合物如双酚A的存在下进行。产物具有优异的物理性能，包括高度的耐候性。 它们可以与其他聚合物如聚碳酸酯，聚（亚烷基羧酸酯），聚芳酯，聚醚酰亚胺和加成聚合物共混以改善其耐候性。

公开(公告)号：US06462168B1

公开(公告)日：2002-10-08

申请号：US09842616

申请日：2001-04-25

申请人： Tiberiu Mircea Siclovan ,  Daniel Joseph Brunelle ,  James Edward Pickett ,  Joseph Anthony Suriano

发明人： Tiberiu Mircea Siclovan ,  Daniel Joseph Brunelle ,  James Edward Pickett ,  Joseph Anthony Suriano

IPC分类号： C08G6400

CPC分类号： C08G64/12

摘要： In one embodiment the present invention is a polycarbonate comprising structural units derived from at least one dihydric phenol, a carbonate precursor, and at least one member selected from the group consisting of an oxanilide-comprising compound, an oxamate-comprising compound, and mixtures thereof. In another embodiment the present invention is a method for making a polycarbonate comprising structural units derived from at least one dihydric phenol and at least one member selected from the group consisting of an oxanilide-comprising compound, an oxamate-comprising compound, and mixtures thereof, which comprises the step of contacting under reactive conditions at least one dihydric phenol, a carbonate precursor, and at least one member selected from the group consisting of an oxanilide-comprising compound, an oxamate-comprising compound, and mixtures thereof. In still another embodiment the present invention is an article comprising a polycarbonate comprising oxanilide structural units. In still another embodiment the present invention is a method for making a symmetrical or unsymmetrical oxanilide-comprising dihydric phenol which comprises the step of contacting at least one aromatic amine bearing a hydroxy group with a diaryl oxalate or a dialkyl oxalate bearing alkyl groups each substituted with at least one electron-withdrawing group. In still another embodiment the present invention is a method for making an oxamate-comprising monohydric phenol which comprises the step of contacting an aromatic amine bearing a hydroxy group with a diaryl oxalate or a dialkyl oxalate bearing alkyl groups each substituted with at least one electron-withdrawing group.

摘要翻译： 在一个实施方案中，本发明是包含衍生自至少一种二元酚，碳酸酯前体和至少一种选自由含草酰替苯的化合物，含草酸酯化合物及其混合物组成的组中的至少一种的结构单元的聚碳酸酯 。 在另一个实施方案中，本发明是一种制备聚碳酸酯的方法，该聚碳酸酯包含衍生自至少一种二元酚的结构单元和至少一种选自由含草酰替苯的化合物，含草酸酯化合物及其混合物组成的组， 其包括在反应条件下使至少一种二元酚，碳酸酯前体和选自由含草酰替苯的化合物，含草酸酯化合物及其混合物中的至少一种接触的步骤。 在另一个实施方案中，本发明是包含含有草酰替苯胺结构单元的聚碳酸酯的制品。 在另一个实施方案中，本发明是一种制备包含对称或不对称的草酰替苯胺的二元酚的方法，其包括使至少一种带有羟基的芳族胺与草酸二芳基酯或带有烷基的二烷基酯的烷基基团接触的步骤， 至少一个吸电子基团。 在另一个实施方案中，本发明是一种制备含草酸羟基的一元酚的方法，其包括使带有羟基的芳族胺与草酸二芳基酯或带有烷基的草酸二烷基酯接触的步骤，每个烷基取代有至少一个电子 - 退出组。

公开(公告)号：US06294647B1

公开(公告)日：2001-09-25

申请号：US09656207

申请日：2000-09-06

申请人： Daniel Joseph Brunelle ,  Joseph Anthony Suriano ,  Taeseok Jang ,  Tiberiu Mircea Siclovan ,  James Edward Pickett ,  Gregory Allen O'Neil

发明人： Daniel Joseph Brunelle ,  Joseph Anthony Suriano ,  Taeseok Jang ,  Tiberiu Mircea Siclovan ,  James Edward Pickett ,  Gregory Allen O'Neil

IPC分类号： C08F612

CPC分类号： B32B27/08 ,  B32B27/06 ,  B32B27/18 ,  B32B27/20 ,  B32B27/36 ,  B32B27/365 ,  B32B2307/4026 ,  B32B2367/00 ,  B32B2369/00 ,  B32B2605/00 ,  C08G63/19 ,  C08G63/64 ,  C08G63/676 ,  C08G63/6956 ,  C08G63/79 ,  C08G63/85 ,  C08J7/047 ,  C08J2467/00 ,  C09D167/03 ,  F02B61/045 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/25 ,  Y10T428/254 ,  Y10T428/2942 ,  Y10T428/31507 ,  Y10T428/31565 ,  Y10T428/31786

摘要： Thermally stable polymers comprising resorcinol arylate chain members are prepared using an interfacial method comprising the steps of: (a) combining at least one resorcinol moiety and at least one catalyst in a mixture of water and at least one organic solvent substantially immiscible with water; and (b) adding to the mixture from (a) at least one dicarboxylic acid dichloride while maintaining the pH between 3 and 8.5 through the presence of an acid acceptor, wherein the total molar amount of acid chloride groups is stoichiometrically deficient relative to the total molar amount of phenolic groups.

公开(公告)号：US06265522B1

公开(公告)日：2001-07-24

申请号：US09656206

申请日：2000-09-06

申请人： Daniel Joseph Brunelle ,  Joseph Anthony Suriano ,  Taeseok Jang ,  Tiberiu Mircea Siclovan ,  James Edward Pickett ,  Gregory Allen O'Neil

发明人： Daniel Joseph Brunelle ,  Joseph Anthony Suriano ,  Taeseok Jang ,  Tiberiu Mircea Siclovan ,  James Edward Pickett ,  Gregory Allen O'Neil

IPC分类号： C08G6312

CPC分类号： B32B27/08 ,  B32B27/06 ,  B32B27/18 ,  B32B27/20 ,  B32B27/36 ,  B32B27/365 ,  B32B2307/4026 ,  B32B2367/00 ,  B32B2369/00 ,  B32B2605/00 ,  C08G63/19 ,  C08G63/64 ,  C08G63/676 ,  C08G63/6956 ,  C08G63/79 ,  C08G63/85 ,  C08J7/047 ,  C08J2467/00 ,  C09D167/03 ,  F02B61/045 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/25 ,  Y10T428/254 ,  Y10T428/2942 ,  Y10T428/31507 ,  Y10T428/31565 ,  Y10T428/31786

摘要： Thermally stable polymers comprising resorcinol arylate chain members are prepared using an interfacial method comprising the steps of: (a) combining at least one resorcinol moiety and at least one catalyst in a mixture of water and at least one organic solvent substantially immiscible with water; and (b) adding to the mixture from (a) at least one dicarboxylic acid dichloride while maintaining the pH between 3 and 8.5 through the presence of an acid acceptor, wherein the total molar amount of acid chloride groups is stoichiometrically deficient relative to the total molar amount of phenolic groups.

公开(公告)号：US06291589B1

公开(公告)日：2001-09-18

申请号：US09656208

申请日：2000-09-06

申请人： Daniel Joseph Brunelle ,  Joseph Anthony Suriano ,  Taeseok Jang ,  Tiberiu Mircea Siclovan ,  James Edward Pickett ,  Gregory Allen O'Neil

发明人： Daniel Joseph Brunelle ,  Joseph Anthony Suriano ,  Taeseok Jang ,  Tiberiu Mircea Siclovan ,  James Edward Pickett ,  Gregory Allen O'Neil

IPC分类号： C08L6702

CPC分类号： B32B27/08 ,  B32B27/06 ,  B32B27/18 ,  B32B27/20 ,  B32B27/36 ,  B32B27/365 ,  B32B2307/4026 ,  B32B2367/00 ,  B32B2369/00 ,  B32B2605/00 ,  C08G63/19 ,  C08G63/64 ,  C08G63/676 ,  C08G63/6956 ,  C08G63/79 ,  C08G63/85 ,  C08J7/047 ,  C08J2467/00 ,  C09D167/03 ,  F02B61/045 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/25 ,  Y10T428/254 ,  Y10T428/2942 ,  Y10T428/31507 ,  Y10T428/31565 ,  Y10T428/31786

摘要： Thermally stable polymers comprising resorcinol arylate chain members are prepared using an interfacial method comprising the steps of: (a) combining at least one resorcinol moiety and at least one catalyst in a mixture of water and at least one organic solvent substantially immiscible with water; and (b) adding to the mixture from (a) at least one dicarboxylic acid dichloride while maintaining the pH between 3 and 8.5 through the presence of an acid acceptor, wherein the total molar amount of acid chloride groups is stoichiometrically deficient relative to the total molar amount of phenolic groups.

公开(公告)号：US06306507B1

公开(公告)日：2001-10-23

申请号：US09368706

申请日：1999-08-05

申请人： Daniel Joseph Brunelle ,  Joseph Anthony Suriano ,  Tiberiu Mircea Siclovan ,  James Edward Pickett

发明人： Daniel Joseph Brunelle ,  Joseph Anthony Suriano ,  Tiberiu Mircea Siclovan ,  James Edward Pickett

IPC分类号： B32B2708

CPC分类号： B32B27/08 ,  B32B27/06 ,  B32B27/18 ,  B32B27/20 ,  B32B27/36 ,  B32B27/365 ,  B32B2307/4026 ,  B32B2367/00 ,  B32B2369/00 ,  B32B2605/00 ,  C08G63/19 ,  C08G63/64 ,  C08G63/676 ,  C08G63/6956 ,  C08G63/79 ,  C08G63/85 ,  C08J7/047 ,  C08J2467/00 ,  C09D167/03 ,  F02B61/045 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/25 ,  Y10T428/254 ,  Y10T428/2942 ,  Y10T428/31507 ,  Y10T428/31565 ,  Y10T428/31786

摘要： Thermally stable polymers comprising resorcinol arylate chain members are prepared using an interfacial method comprising the steps of: (a) combining at least one resorcinol moiety and at least one catalyst in a mixture of water and at least one organic solvent substantially immiscible with water; and (b) adding to the mixture from (a) at least one dicarboxylic acid dichloride while maintaining the pH between 3 and 8.5 through the presence of an acid acceptor, wherein the total molar amount of acid chloride groups is stoichiometrically deficient relative to the total molar amount of phenolic groups.

摘要翻译： 包含间苯二酚芳基化物链成员的热稳定聚合物使用界面方法制备，包括以下步骤：（a）将至少一种间苯二酚部分和至少一种与水和至少一种与水不混溶的有机溶剂的混合物的催化剂混合; 和（b）通过酸受体的存在，将（a）至少一种二羧酸二氯化物同时保持pH在3至8.5之间来加入到混合物中，其中酰氯基团的总摩尔量相对于总计的化学计量缺乏 酚基摩尔量。

公开(公告)号：US6143839A

公开(公告)日：2000-11-07

申请号：US152877

申请日：1998-09-14

申请人： Jimmy Lynn Webb ,  Randall Lee Carter ,  Tiberiu Mircea Siclovan ,  James Edward Pickett

发明人： Jimmy Lynn Webb ,  Randall Lee Carter ,  Tiberiu Mircea Siclovan ,  James Edward Pickett

IPC分类号： C08K3/00 ,  C08K5/00 ,  C08L67/03 ,  C08L69/00

CPC分类号： C08L69/00

摘要： Weatherability of polycarbonates, or of blends of polycarbonates with other polymers such as polyesters, is improved by incorporating therein a thermoplastic arylate polymer comprising units derived from a resorcinol or alkylresorcinol isophthalate-terephthalate. These units may be combined with units derived from a resorcinol or alkylresorcinol ester of a C.sub.4-12 aliphatic, alicyclic or mixed aliphatic-alicyclic dicarboxylic acid, such as sebacic acid.

摘要翻译： 通过在其中加入包含衍生自间苯二酚或间苯二酚间苯二甲酸酯 - 对苯二甲酸酯的单元的热塑性芳基化合物聚合物来改善聚碳酸酯或聚碳酸酯与其它聚合物如聚酯的共混物的耐候性。 这些单元可以与衍生自C4-12脂族，脂环族或混合脂族 - 脂环族二羧酸如癸二酸的间苯二酚或烷基间苯二酚酯的单元组合。

公开(公告)号：US06689474B2

公开(公告)日：2004-02-10

申请号：US10310295

申请日：2002-12-05

申请人： James Edward Pickett ,  Joseph Anthony Suriano ,  Steven Thomas Rice ,  Xiangyang Li ,  Paul Dean Sybert

发明人： James Edward Pickett ,  Joseph Anthony Suriano ,  Steven Thomas Rice ,  Xiangyang Li ,  Paul Dean Sybert

IPC分类号： B32B2708

CPC分类号： C08J7/047 ,  B32B27/06 ,  B32B27/18 ,  C08G63/19 ,  C08G63/64 ,  C08G63/676 ,  C08G63/6956 ,  C08G63/79 ,  C08G63/85 ,  C08J2467/00 ,  C09D167/03 ,  F02B61/045 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/25 ,  Y10T428/254 ,  Y10T428/2942 ,  Y10T428/31507 ,  Y10T428/31565 ,  Y10T428/31786

摘要： The present invention provides compositions comprising (a) a thermally stable polymer comprising resorcinol arylate polyester chain members substantially free of anhydride linkages linking at least two mers of the polymer chain, and (b) at least one auxiliary stabilizer additive selected from the group consisting of 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) and 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane. Both multilayer and unitary articles comprising the composition are also provided.

摘要翻译： 本发明提供了包含（a）热稳定聚合物的组合物，其包含基本上不含连接至少两个聚合物链的酸酐键的间苯二酚芳基化聚酯链构件，和（b）至少一种选自以下的辅助稳定剂添加剂： 2,2' - （1,4-亚苯基）双（4H-3,1-苯并恶嗪-4-酮）和1,3-双[（2-氰基-3,3-二苯基丙烯酰基）氧基] -2,2 双[[（2-氰基-3,3-二苯基丙烯酰基）氧基]甲基]丙烷。 还提供了包含组合物的多层和单体制品。

公开(公告)号：US5916997A

公开(公告)日：1999-06-29

申请号：US30076

申请日：1998-02-25

申请人： Jimmy Lynn Webb ,  Randall Lee Carter ,  Tiberiu Mircca Siclovan ,  Matthew Hal Littlejohn ,  James Edward Pickett

发明人： Jimmy Lynn Webb ,  Randall Lee Carter ,  Tiberiu Mircca Siclovan ,  Matthew Hal Littlejohn ,  James Edward Pickett

IPC分类号： C08L67/02 ,  C08G63/16 ,  C08G63/19 ,  C08G63/60 ,  C08G63/18

CPC分类号： C08G63/60 ,  C08G63/19

摘要： Disclosed are weatherable polyester soft block copolymer compositions comprising copolymers of resorcinol or alternatively phenol, aromatic dicarboxylic acid, and a aliphatic dicarboxylic acid based structural units. These polyester soft block copolymers comprise a substantial proportion of direct linkages between the resorcinol or alternatively the phenol, and the aromatic dicarboxylic acid based structural units, the balance of the linkages being between resorcinol and the aliphatic dicarboxylic acid based structural units.

摘要翻译： 公开了耐候性聚酯软嵌段共聚物组合物，其包含间苯二酚或可选的苯酚，芳族二羧酸和基于脂族二羧酸的结构单元的共聚物。 这些聚酯软嵌段共聚物包括在间苯二酚或可选择的苯酚和基于芳族二羧酸的结构单元之间的相当大比例的直接连接，其间的连接是在间苯二酚和基于脂族二羧酸的结构单元之间。

公开(公告)号：US06572956B1

公开(公告)日：2003-06-03

申请号：US09368705

申请日：1999-08-05

申请人： James Edward Pickett ,  Randall Lee Carter ,  Jimmy Lynn Webb ,  Daniel Robert Olson ,  Frank Axel Hoefflin ,  Hua Wang

发明人： James Edward Pickett ,  Randall Lee Carter ,  Jimmy Lynn Webb ,  Daniel Robert Olson ,  Frank Axel Hoefflin ,  Hua Wang

IPC分类号： C08L6900

CPC分类号： B32B27/08 ,  B32B27/20 ,  B32B27/36 ,  B32B2305/30 ,  B32B2307/712 ,  B32B2367/00 ,  B32B2605/00 ,  C08J7/047 ,  C08J2467/00 ,  F02B61/045 ,  Y02P20/582 ,  Y10T428/1429 ,  Y10T428/24355 ,  Y10T428/24802 ,  Y10T428/24942 ,  Y10T428/31504 ,  Y10T428/31507 ,  Y10T428/31565

摘要： Substantially solvent-free multilayer articles characterized by excellent color retention and gloss retention, solvent resistance and recyclability comprise a substrate layer comprising a first material selected from the group consisting of a metal, ceramic, glass, a cellulosic material, a thermoset resin, and a thermoplastic resin, and a resinous coating layer which comprises resorcinol or alkylresorcinol isophthalate/terephthalate ester units. An intermediate layer may also be present.

摘要翻译： 特征在于优异的保色性和光泽保持性，耐溶剂性和可再循环性的基本无溶剂的多层制品包括基材层，其包含选自金属，陶瓷，玻璃，纤维素材料，热固性树脂和 热塑性树脂和包含间苯二酚或间苯二酚间苯二甲酸酯/对苯二酸酯酯单元的树脂涂层。 中间层也可以存在。