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1.发明授权
公开(公告)号：US6123910A
公开(公告)日：2000-09-26
申请号：US777477
申请日：1996-12-30
申请人： Yasuo Yoshii , Tomohiko Miyamoto , Jinichi Tomuro , Tooru Inada , Nobuyuki Hokari , Katsuya Oki
发明人： Yasuo Yoshii , Tomohiko Miyamoto , Jinichi Tomuro , Tooru Inada , Nobuyuki Hokari , Katsuya Oki
CPC分类号： B01D53/56 , B01D53/346
摘要： The present invention provides a method and an apparatus for predicting and calculating an amount of harmful oxide such as NOx contained in an exhaust gas from a reference concentration of harmful oxide, which is previously determined by a type of fuel supplied to a fluidized bed combustor, an amount of change of an air ratio and an amount of change of a gas residence time to the conditions of a specific air ratio and gas residence time in the combustor, and injecting a treatment agent such as NH.sub.3 in an amount optimum to the predicted amount into an exhaust gas. With this arrangement, an amount of harmful oxide in the exhaust gas can be securely lowered to a target value.
摘要翻译： 本发明提供了一种方法和装置，用于根据事先由供应给流化床燃烧器的燃料类型确定的有害氧化物的参考浓度来预测和计算废气中所含的诸如NOx的有害氧化物的量， 将空气比的变化量和气体停留时间的变化量与特定空气比的条件和在燃烧器中的气体停留时间的变化量进行比较，并且以最佳的预测量注入NH 3等处理剂 进入废气。 通过这种布置，可以将废气中的有害氧化物的量可靠地降低到目标值。
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2.发明授权
公开(公告)号：US5664505A
公开(公告)日：1997-09-09
申请号：US404425
申请日：1995-03-15
申请人： Tomohiko Miyamoto , Yasuo Yoshii , Tooru Inada , Jinichi Tomuro , Nobuyuki Hokari , Katsuya Oki
发明人： Tomohiko Miyamoto , Yasuo Yoshii , Tooru Inada , Jinichi Tomuro , Nobuyuki Hokari , Katsuya Oki
摘要： A method of and apparatus for detecting an abnormality of a fluidized bed boiler is characterized in that an abnormality of the fluidized bed boiler is detected on the basis of a physical quantity related to a condition change of a gas existing in a space defined by a pressure vessel and the fluidized bed boiler accommodated within the pressure vessel.
摘要翻译： 一种用于检测流化床锅炉异常的方法和装置，其特征在于，基于与存在于由压力限定的空间中存在的气体的状态变化相关的物理量来检测流化床锅炉的异常 容器和容纳在压力容器内的流化床锅炉。
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3.发明授权Apparatus for preventing coking in fluidized bed reactor for cracking heavy hydrocarbon oil 失效用于在流化床反应器中防止焦化用于裂解重质烃油的装置
公开(公告)号：US4294803A
公开(公告)日：1981-10-13
申请号：US068452
申请日：1979-08-21
申请人： Seiichi Uchida , Yoshihito Satomi , Norihiro Kiuchi , Takeo Yamagata , Susumu Yoshioka , Tomohiko Miyamoto , Jinichi Tomuro
发明人： Seiichi Uchida , Yoshihito Satomi , Norihiro Kiuchi , Takeo Yamagata , Susumu Yoshioka , Tomohiko Miyamoto , Jinichi Tomuro
CPC分类号： C10B43/14 , C10G11/18 , C10G9/32 , Y10S208/01 , Y10S423/16
摘要： In a reactor for cracking heavy hydrocarbon oil through a fluidized bed of the particles of natural ores, coke-like materials are deposited on a top of the reactor or pipe inside surfaces of a transfer line from the reactor to a scrubber. To effectively scour out the deposited coke-like materials, particles of natural ores having a mean diameter of a few hundred .mu.m is made to be contained in an effluent gas from the top of reactor, passing through the transfer line at a concentration of 1 to 40 g/m.sup.3. The particles of natural ores have a good effect of scouring out the deposited coke-like materials and can keep the transfer line efficiently clean even with a small amount of the particles of natural ores, decreasing a pressure drop in the transfer line.
摘要翻译： 在通过天然矿石颗粒的流化床裂解重质烃油的反应器中，焦炭状材料沉积在反应器的顶部或从反应器到洗涤器的输送管线的内表面中。 为了有效地冲出沉积的焦炭状材料，使平均直径为几百微米的天然矿石颗粒被包含在来自反应器顶部的流出气体中，其浓度为1 至40g / m 3。 天然矿石颗粒具有很好的清除沉积的焦炭状物质的效果，并且即使用少量的天然矿石颗粒也能有效地清洁输送管线，从而降低输送管线中的压降。
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4.发明授权
公开(公告)号：US4884396A
公开(公告)日：1989-12-05
申请号：US155814
申请日：1988-02-16
申请人： Tomohiko Miyamoto , Shuntaro Koyama , Jinichi Tomuro , Atsushi Morihara , Hisao Yamashita , Sadao Takahashi , Eiji Kida , Akio Ueda , Shigehito Takamoto
发明人： Tomohiko Miyamoto , Shuntaro Koyama , Jinichi Tomuro , Atsushi Morihara , Hisao Yamashita , Sadao Takahashi , Eiji Kida , Akio Ueda , Shigehito Takamoto
CPC分类号： F01N3/023 , B01D53/52 , B01J20/06 , C01B17/508 , C10J3/466 , C10K1/32 , F01N3/022 , C10J2300/093 , C10J2300/0996
摘要： The present invention provides a desulfurizing agent comprising a porous oxide carrier, at least one of molybdenum oxide and tungsten oxide as a first component, supported on the carrier, and at least one of manganese oxide, cobalt oxide and nickel oxide as a second component, supported mainly on the surface of the first component. In a coal gasification system using the present desulfurizing agent and a power generation system using the purified gas therefrom, a reduction column for converting a portion of sulfur dioxide in the regenerated gas to hydrogen sulfide as a pretreatment means to a Claus reaction column can be eliminated when the desulfurizing agent is regenerated. Furthermore, in the present invention a desulfurizing agent capable of reacting with hydrogen sulfide to form a solid sulfur compound at a high temperature is supplied to a gasification furnace and the resulting sulfur compound is withdrawn from the gasification furnace as molten slag together with ashes of fine coal powder, where desulfurization can be attained without a Claus reaction column and without a reduction column. Such desulfurization is likewise applicable to a coal gasification system and a power generation system based on the coal gasification.
摘要翻译： 本发明提供一种脱硫剂，其包含多孔氧化物载体，负载在载体上的作为第一成分的氧化钼和氧化钨中的至少一种，作为第二成分的氧化锰，氧化钴和氧化镍中的至少一种， 主要支撑在第一部件的表面上。 在使用本发明的脱硫剂的煤气化系统和使用净化气体的发电系统中，可以消除用于将再生气体中的二氧化硫的一部分转化为硫化氢作为预处理装置的还原塔至克劳斯反应塔 当脱硫剂再生时。 此外，在本发明中，将能够与硫化氢反应以在高温下形成固体硫化合物的脱硫剂被供给至气化炉，所得到的硫化合物与气化炉一起作为熔渣与精细灰分一起排出 煤粉，其中可以在没有Claus反应塔并且没有还原塔的情况下实现脱硫。 这种脱硫同样适用于煤气化系统和基于煤气化的发电系统。
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公开(公告)号：US4531949A
公开(公告)日：1985-07-30
申请号：US517034
申请日：1983-07-25
IPC分类号： C10J3/46
CPC分类号： C10J3/466 , C10J3/506 , C10J3/526 , C10J3/723 , C10J3/78 , C10J3/845 , C10J2300/0906 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10J2300/0976 , C10J2300/1807 , C10J2300/1846 , Y10S48/04
摘要： A process for gasifying coal comprising supplying to an upper portion of an entrained flow gasifier a coal powder having a particle size of 100 .mu.m or less whereby gasification is conducted at 900.degree. C. or higher in the absence of oxygen, supplying a coal powder including coarser particles and oxygen in an amount from that necessary for complete combustion of coal to a half of said amount to a lower portion of the gasifier whereby gasification is conducted at a melting point of coal ash or higher, and leading the gases produced at the lower portion of the gasifier directly to the upper portion of the gasifier, does not require recycle of char to the gasifier and gives a high gasification efficiency by passing coal powder through the gasifier only one time.
摘要翻译： 一种气化煤的方法，其特征在于，向粒状流动气化炉的上部供给粒径为100μm以下的煤粉，在不存在氧气的情况下，在900℃以上进行气化，供给煤粉 包括较粗的颗粒和氧气，其量从煤完全燃烧所需的量到所述量的一半量至气化器的下部，由此在煤灰或更高的熔点进行气化，并导致在 气化器的下部直接连接到气化器的上部，不需要将炭再循环到气化器，并且仅通过煤粉通过气化炉一次而使其具有高的气化效率。
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6.发明授权Method for preventing coking in fluidized bed reactor for cracking heavy hydrocarbon oil 失效流化床反应器中焦化反应器中重质烃油裂化的方法
公开(公告)号：US4220518A
公开(公告)日：1980-09-02
申请号：US946426
申请日：1978-09-27
申请人： Seiichi Uchida , Yoshihito Satomi , Norihiro Kiuchi , Takeo Yamagata , Susumu Yoshioka , Tomohiko Miyamoto , Jinichi Tomuro
发明人： Seiichi Uchida , Yoshihito Satomi , Norihiro Kiuchi , Takeo Yamagata , Susumu Yoshioka , Tomohiko Miyamoto , Jinichi Tomuro
CPC分类号： C10B43/14 , C10G11/18 , C10G9/32 , Y10S208/01 , Y10S423/16
摘要： In a reactor for cracking heavy hydrocarbon oil through a fluidized bed of particles of natural ores, coke-like materials are deposited on a top of the reactor or pipe inside surfaces of a transfer line from the reactor to a scrubber. To effectively scour out the deposited coke-like materials, particles of natural ores having a mean diameter of a few hundred .mu.m is made to be contained in an effluent gas from the top of reactor, passing through the transfer line at a concentration of 1 to 40 g/m.sup.3. The particles of natural ores have a good effect of scouring out the deposited coke-like materials and can keep the transfer line efficiently clean even with a small amount of the particles of natural ores, decreasing a pressure drop in the transfer line.
摘要翻译： 在通过天然矿石颗粒的流化床裂解重质烃油的反应器中，焦炭状材料沉积在反应器的顶部或从反应器到洗涤器的输送管线的内表面中。 为了有效地冲出沉积的焦炭状材料，使平均直径为几百微米的天然矿石颗粒被包含在来自反应器顶部的流出气体中，其浓度为1 至40g / m 3。 天然矿石颗粒具有很好的清除沉积的焦炭状物质的效果，并且即使用少量的天然矿石颗粒也能有效地清洁输送管线，从而降低输送管线中的压降。
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7.发明授权公开(公告)号：US07264710B2
公开(公告)日：2007-09-04
申请号：US10245398
申请日：2002-09-18
IPC分类号： C10G27/04
摘要： The reforming of heavy oil with supercritical water or subcritical water is accomplished by mixing together supercriticai water, heavy oil, and oxidizing agent, thereby oxidizing vanadium in heavy oil with the oxidizing agent at the time of treatment with supercritical water and separate vanadium oxide. The separated vanadium oxide is removed by the scavenger after treatment with supercritical water. In this way it is possible to solve the long-standing problem with corrosion of turbine blades by vanadium which arises when heavy oil is used as gas turbine fuel.
摘要翻译： 重油与超临界水或亚临界水的重整是通过将超临界水，重油和氧化剂混合在一起实现的，从而在用超临界水和单独的氧化钒处理时，用氧化剂氧化重油中的钒。 在用超临界水处理后，通过清除剂除去分离的氧化钒。 以这种方式，可以解决当使用重油作为燃气轮机燃料时产生的钒的涡轮叶片的腐蚀的长期存在的问题。
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8.发明申请公开(公告)号：US20070144941A1
公开(公告)日：2007-06-28
申请号：US11700921
申请日：2007-02-01
摘要： The reforming of heavy oil with supercritical water or subcritical water is accomplished by mixing together supercritical water, heavy oil, and oxidizing agent, thereby oxidizing vanadium in heavy oil with the oxidizing agent at the time of treatment with supercritical water and separate vanadium oxide. The separated vanadium oxide is removed by the scavenger after treatment with supercritical water. In this way it is possible to solve the long-standing problem with corrosion of turbine blades by vanadium which arises when heavy oil is used as gas turbine fuel.
摘要翻译： 重油与超临界水或亚临界水的重整是通过将超临界水，重油和氧化剂混合在一起完成的，从而在用超临界水和分离的氧化钒处理时用氧化剂氧化重油中的钒。 在用超临界水处理后，通过清除剂除去分离的氧化钒。 以这种方式，可以解决当使用重油作为燃气轮机燃料时产生的钒的涡轮叶片的腐蚀的长期存在的问题。
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9.发明授权公开(公告)号：US07767076B2
公开(公告)日：2010-08-03
申请号：US11700921
申请日：2007-02-01
IPC分类号： C10G27/04
摘要： The reforming of heavy oil with supercritical water or subcritical water is accomplished by mixing together supercritical water, heavy oil, and oxidizing agent, thereby oxidizing vanadium in heavy oil with the oxidizing agent at the time of treatment with supercritical water and separate vanadium oxide. The separated vanadium oxide is removed by the scavenger after treatment with supercritical water. In this way it is possible to solve the long-standing problem with corrosion of turbine blades by vanadium which arises when heavy oil is used as gas turbine fuel.
摘要翻译： 重油与超临界水或亚临界水的重整是通过将超临界水，重油和氧化剂混合在一起完成的，从而在用超临界水和分离的氧化钒处理时用氧化剂氧化重油中的钒。 在用超临界水处理后，通过清除剂除去分离的氧化钒。 以这种方式，可以解决当使用重油作为燃气轮机燃料时产生的钒的涡轮叶片的腐蚀的长期存在的问题。
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10.发明申请Heavy oil reforming method, an apparatus therefor, and gas turbine power generation system 审中-公开重油改性方法，其设备和燃气轮机发电系统公开(公告)号：US20060011511A1
公开(公告)日：2006-01-19
申请号：US11224059
申请日：2005-09-13
CPC分类号： F02C3/20 , B01J3/008 , B01J8/0055 , B01J8/025 , B01J8/065 , B01J2219/00006 , C01B3/34 , C01B3/36 , C01B2203/0216 , C01B2203/0255 , C01B2203/1247 , C01G31/02 , Y02P20/129 , Y02P20/544
摘要： The purpose of the invention is to provide a heavy oil reforming method which reforms a heavy oil to give a fuel suitable for a gas turbine, eliminates sulfur and vanadium, i.e., harmful components, from a heavy oil, and enables almost all the hydrocarbons in the heavy oil to be used in gas turbine combustion; an apparatus therefor; and a gas turbine power generation system using the reformed heavy oil as fuel. This method comprises reacting a heavy oil with supercritical water and then with a scavenger for sulfur and vanadium to eliminate sulfur and vanadium from the heavy oil. The apparatus for reforming a heavy oil is equipped with a reactor for reacting a heavy oil with supercritical water, a scavenging apparatus filled with a scavenger for scavenging sulfur and vanadium in the heavy oil, and a connecting pipe for connecting the reactor and the scavenging apparatus. The gas turbine power generation system has a burner for burning a heavy oil reformed with the reforming apparatus and a gas turbine driven by a combustion gas generated by the burner.
摘要翻译： 本发明的目的是提供一种重油改性方法，该方法改造重油以得到适用于燃气轮机的燃料，从重油中除去硫和钒，即有害成分，并使几乎所有的烃都能 用于燃气轮机燃烧的重油; 一种装置; 以及使用重整的重油作为燃料的燃气轮机发电系统。 该方法包括使重油与超临界水反应，然后与硫和钒的清除剂反应，以从重油中除去硫和钒。 重油改造装置配备有使重油与超临界水反应的反应器，在重油中填充有清除硫和钒的清除剂的扫气装置，以及连接反应器和清扫装置的连接管 。 燃气轮机发电系统具有用于燃烧由重整装置重整的重油的燃烧器和由燃烧器产生的燃烧气体驱动的燃气轮机。
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