摘要:
The present invention provides a nonaqueous electrolyte secondary battery, comprising a positive electrode, a negative electrode containing a carbon material having an immersion heat ratio (&Dgr;Hin/&Dgr;Hih) defined by formula (1), and a nonaqueous electrolyte: 1.2≦&Dgr;Hin/&Dgr;Hih≦2 (1) where &Dgr;Hih denotes the immersion heat for n-heptane of the carbon material, and &Dgr;Hin denotes the immersion heat for 1-nitropropane of the carbon material.
摘要:
The present invention provides a nonaqueous electrolyte secondary battery, comprising an electrode group including a positive electrode, a negative electrode including a material for absorbing-desorbing lithium ions, and a separator arranged between the positive electrode and the negative electrode, a nonaqueous electrolyte impregnated in the electrode group and including a nonaqueous solvent and a lithium salt dissolved in the nonaqueous solvent, and a jacket for housing the electrode group and having a thickness of 0.3 mm or less, wherein the nonaqueous solvent γ-butyrolactone in an amount larger than 50% by volume and not larger than 95% by volume based on the total amount of the nonaqueous solvent.
摘要:
There is provided a secondary battery comprising an electrode group comprising a positive electrode, a negative electrode having a negative electrode collector and a negative electrode layer held to the collector, and a separator interposed between the positive electrode and the negative electrode layer, a nonaqueous electrolyte held by the electrode group, and a jacket housing the electrode group and having a thickness of not more than 0.3 mm, wherein the positive electrode, the negative electrode and the separator are formed integral, and the peeling strength between the negative electrode layer and the separator is lower than the peeling strength between the negative electrode layer and the negative electrode collector.
摘要:
A negative electrode for use in a secondary battery which comprises milled graphite fibers derived from mesophase pitch each having circumferential, upper end and lower end faces, the milled graphite fibers each being composed of graphite layers having therebetween voids as inlets and outlets for lithium ions, all of the circumferential, upper end and lower end faces having openings of the voids between the graphite layers, which serve as inlets or outlets for lithium ions. This negative electrode for use in a secondary battery can be utilized to provide a lithium secondary battery of nonaqueous electrolyte which has large charge and discharge capacities and which permits setting the current density at charge or discharge high.
摘要:
This invention provides a lithium secondary battery comprising a positive electrode, a negative electrode comprising a carbonaceous material which is capable of absorbing and desorbing lithium ions, and a nonaqueous electrolyte, wherein the carbonaceous material has a region of amorphous carbon structure and a region of graphite structure, and the carbonaceous material has a true density of 1.8 g/cm.sup.3 or more and a peak in powder X-ray diffraction which corresponds to not more than 0.340 nm in an interplanar spacing d.sub.002 derived from (002) reflection.
摘要:
A lithium ion secondary battery improved in large-current discharge characteristics, discharge capacity, and cycle life is disclosed. This lithium ion secondary battery includes a positive electrode, a negative electrode comprising a collector and carbon fibers held to the collector for absorbing and desorbing lithium ions, a separator arranged between the positive electrode and the negative electrode, and a nonaqueous electrolyte. The carbon fibers have a radial orientation from an axis of the fibers, and 50 vol % or more of all carbon fibers are arranged such that an angle between an axis of each carbon fiber and a surface of the collector is 45.degree. or less.
摘要:
A negative electrode for use in a secondary battery is disclosed, comprising milled carbon fibers derived from mesophase pitch wherein the milled carbon fibers each has a fiber cut surface and a fiber axis intersecting with each other at cross angles, the smaller one thereof being at least 65.degree. on the average. This negative electrode does not suffer from property deterioration, irrespective of multiple repetitions of charge and discharge, from which a nonaqueous-electrolyte-loaded lithic secondary battery having excellent cycle characteristics can be fabricated.
摘要:
A nonaqueous electrolyte secondary battery having an enhanced capacity and a long charge/discharge cycle life is disclosed. The nonaqueous electrolyte secondary battery comprises a positive electrode housed in a case and containing a chalcogen compound as an active material, a negative electrode arranged in the case such that a separator is sandwiched between the positive and negative electrodes and containing a carbonaceous material as an active material that absorbs and discharges lithium ions and a nonaqueous electrolyte contained in the case and prepared by dissolving 0.5 mol/l to 1.5 mol/l of electrolytic salt selected from the group consisting of LiPF.sub.6, LiBF.sub.4, LiAsF.sub.6 and LiCF.sub.3 SO.sub.3 in a solvent mixture comprising at least one first nonaqueous solvent selected from the group consisting of noncyclic carbonate, cyclic carbonate, .gamma.-butyrolactone and acetonitrile and at least one second nonaqueous solvent containing selected from the group consisting of 1,2-diethoxyethane, 1,2-dimethoxyethane, 1,2-ethoxymethoxyethane, 1,3-dimethoxypropane, diethylether and tetrahydrofurane, the amount of said second nonaqueous solvent in the solvent mixture being so determined that the mol ratio ([S]/[Li]) of the second nonaqueous solvent [S]to lithium ions [Li]is 0.5 to 3.
摘要:
A nonaqueous electrolyte secondary battery comprising a positive electrode housed in a case a negative electrode arranged in the case so that a separator is sandwiched between the positive and negative electrodes consisting of lithium or lithium-containing material, and a nonaqueous electrolyte contained in the case and prepared by dissolving an electrolytic salt consisting of lithium phosphate hexafluoride (LiPF.sub.6) or lithium borofluoride (LiBF.sub.4) in a solvent mixture consisting of ethylene carbonate, 2-methyltetrahydrofuran, and at least one ester-based nonaqueous solvent selected from the group consisting of butylene carbonate, dimethyl carbonate, .gamma.-butyrolactone, and sulfolane.
摘要:
The present invention provides a nonaqueous electrolyte secondary battery, comprising an electrode group including a positive electrode, a negative electrode including a material for absorbing-desorbing lithium ions, and a separator arranged between the positive electrode and the negative electrode, a nonaqueous electrolyte impregnated in the electrode group and including a nonaqueous solvent and a lithium salt dissolved in the nonaqueous solvent, and a jacket for housing the electrode group and having a thickness of 0.3 mm or less, wherein the nonaqueous solvent γ-butyrolactone in an amount larger than 50% by volume and not larger than 95% by volume based on the total amount of the nonaqueous solvent.