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公开(公告)号：US07678448B2
公开(公告)日：2010-03-16
申请号：US10597425
申请日：2005-01-26
申请人： Tooru Hachisuka , Shigenobu Yoshida , Chiharu Okawara , Yoshinori Kobayashi , Kenji Ito , Hisashi Togashi , Kouichi Hirata
发明人： Tooru Hachisuka , Shigenobu Yoshida , Chiharu Okawara , Yoshinori Kobayashi , Kenji Ito , Hisashi Togashi , Kouichi Hirata
IPC分类号： B32B9/00
CPC分类号： B32B15/08 , B32B27/08 , B32B27/10 , B32B27/18 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2255/10 , B32B2255/20 , B32B2255/26 , B32B2255/28 , B32B2307/31 , B32B2307/4023 , B32B2307/412 , B32B2307/54 , B32B2307/552 , B32B2307/7163 , B32B2307/7242 , B32B2439/46 , B32B2439/62 , B32B2439/70 , C23C14/10 , Y10T428/24843 , Y10T428/256 , Y10T428/259 , Y10T428/26 , Y10T428/265 , Y10T428/31667
摘要： The gas barrier film of the present invention is a gas barrier film comprising a base material, and an inorganic thin film composed of a silicon oxide film formed on one or both surfaces of the base material, wherein radical density of the Pb center of the silicon oxide film observed by an electron spin resonance method (ESR method) is from 1×1016 to 1×1019 spins/cm3, or a gas barrier film comprising a base material, an inorganic thin film containing silicon oxide and the other metal component formed on one or both surfaces of the base material, wherein radical density of the Pb center of the silicon oxide in the inorganic thin film observed by an ESR method is from 13×1014 to 3×1017 spins/mol, and a laminate wherein at least one paper and/or plastic film is laminated on the gas barrier film.
摘要翻译： 本发明的阻气膜是由基材构成的阻气膜和由在基材的一面或两面形成的氧化硅膜构成的无机薄膜，其中硅的Pb中心的自由基密度 通过电子自旋共振法（ESR法）观察到的氧化膜的摩尔比为1×1016〜1×1019自旋/ cm3，或者是含有基材的阻气膜，含有氧化硅的无机薄膜和形成于 基体材料的一个或两个表面，其中通过ESR方法观察到的无机薄膜中的氧化硅的Pb中心的自由基密度为13×1014至3×1017自旋/摩尔，并且其中至少一个 纸和/或塑料膜层压在阻气膜上。
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公开(公告)号：US20080254266A1
公开(公告)日：2008-10-16
申请号：US10597425
申请日：2005-01-26
申请人： Tooru Hachisuka , Shigenobu Yoshida , Chiharu Okawara , Yoshinori Kobayashi , Kenji Ito , Hisashi Togashi , Kouichi Hirata
发明人： Tooru Hachisuka , Shigenobu Yoshida , Chiharu Okawara , Yoshinori Kobayashi , Kenji Ito , Hisashi Togashi , Kouichi Hirata
CPC分类号： B32B15/08 , B32B27/08 , B32B27/10 , B32B27/18 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2255/10 , B32B2255/20 , B32B2255/26 , B32B2255/28 , B32B2307/31 , B32B2307/4023 , B32B2307/412 , B32B2307/54 , B32B2307/552 , B32B2307/7163 , B32B2307/7242 , B32B2439/46 , B32B2439/62 , B32B2439/70 , C23C14/10 , Y10T428/24843 , Y10T428/256 , Y10T428/259 , Y10T428/26 , Y10T428/265 , Y10T428/31667
摘要： The gas barrier film of the present invention is a gas barrier film comprising a base material, and an inorganic thin film composed of a silicon oxide film formed on one or both surfaces of the base material, wherein radical density of the Pb center of the silicon oxide film observed by an electron spin resonance method (ESR method) is from 1×1016 to 1×1019 spins/cm3, or a gas barrier film comprising a base material, an inorganic thin film containing silicon oxide and the other metal component formed on one or both surfaces of the base material, wherein radical density of the Pb center of the silicon oxide in the inorganic thin film observed by an ESR method is from 13×1014 to 3×1017 spins/mol, and a laminate wherein at least one paper and/or plastic film is laminated on the gas barrier film.
摘要翻译： 本发明的阻气膜是由基材构成的阻气膜和由在基材的一面或两面形成的氧化硅膜构成的无机薄膜，其中硅的Pb中心的自由基密度 通过电子自旋共振法观察的氧化膜（ESR法）为1×10 16〜1×10 9个自由度/ cm 3以上，或气体阻隔层 包含基材的薄膜，含有氧化硅的无机薄膜和形成在基材的一面或两面上的其它金属成分，其中通过ESR方法观察到的无机薄膜中的氧化硅的Pb中心的自由基密度 为13×10 14〜3×10 17个自旋/摩尔，以及层压体，其中至少一个纸和/或塑料膜层压在阻气膜上。
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公开(公告)号：US07910213B2
公开(公告)日：2011-03-22
申请号：US10599065
申请日：2005-03-23
IPC分类号： B32B27/40
CPC分类号： C08J7/045 , B32B27/08 , C08J2323/10 , C08J2475/04 , Y10T428/24851 , Y10T428/263 , Y10T428/31551 , Y10T428/31663 , Y10T428/31681 , Y10T428/31786
摘要： A gas-barrier laminate with a plastic substrate, an inorganic thin film formed on at least one surface of the plastic substrate, and a coating layer formed by applying a coating material on a surface of the inorganic thin film, wherein said coating layer contains a polyester-based resin having a molecular weight of 3000 to 15000 and a polyurethane-based resin having a molecular weight of 8000 to 30000 at a weight ratio of 5/95 to 95/5, and said gas-barrier laminate has an oxygen permeability of not more than 25 fmol/m2/s/Pa; and a gas-barrier laminate comprising a plastic substrate, an inorganic thin film formed on at least one surface of the plastic substrate, and a coating layer formed by applying a coating material on a surface of the inorganic thin film, wherein the gas-barrier laminate exhibits an oxygen permeability of not more than 50 fmol/m2/s/Pa as measured with respect to a gas-barrier film obtained by laminating an unstretched polypropylene film having a thickness of 60 μm on the coating layer of the gas-barrier laminate after subjecting the gas-barrier film to hydrothermal treatment at 120° C. for 30 min, and the coating layer has either a hardness of 0.1 to 0.5 GPa as measured at 23° C. in atmospheric air by a nano-indentation hardness testing method, a hardness of 0.03 to 0.5 GPa as measured at 23° C. in water by a nano-indentation hardness testing method, or a ratio of number of carbon atoms derived from carboxyl groups to number of carbon atoms constituting the surface of the coating layer of 0.005 to 0.1.
摘要翻译： 一种具有塑料基板的阻气层压材料，在塑料基板的至少一个表面上形成的无机薄膜，以及通过在无机薄膜的表面上涂覆涂层而形成的涂层，其中所述涂层含有 分子量为3000〜15000的聚酯类树脂和重量比为5/95〜95/5的分子量为8000〜30000的聚氨酯类树脂，所述阻气性层压体的氧透过率为 不超过25 fmol / m2 / s / Pa; 以及包含塑料基板，形成在所述塑料基板的至少一个表面上的无机薄膜和通过在所述无机薄膜的表面上涂覆涂料而形成的涂层的阻气性层压体，其中所述气体阻隔层 相对于通过在阻气性层压体的涂层上层压厚度为60μm的未拉伸聚丙烯膜得到的阻气膜测定，层压体的透氧度为50fmol / m 2 / s / Pa以下， 在120℃下对该阻气膜进行水热处理30分钟后，通过纳米压痕硬度试验法在大气中在23℃下测定的涂层的硬度为0.1〜0.5GPa ，通过纳米压痕硬度测试方法在23℃下在水中测量的硬度为0.03至0.5GPa，或由羧基衍生的碳原子数与构成涂层1a表面的碳原子数的比例 0.005至0.1。
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公开(公告)号：US07615287B2
公开(公告)日：2009-11-10
申请号：US10595789
申请日：2004-11-29
CPC分类号： C08J7/04 , B05D3/101 , B05D7/04 , B05D2350/60 , C08J7/045 , C08J7/06 , C08J7/065 , C08J2367/02 , C23C14/10 , Y10T428/31504 , Y10T428/31667
摘要： The gas barrier film having a thermoplastic polymer film, and an inorganic thin film provided on at least one surface of the thermoplastic polymer film, which gas barrier film is formed by applying, to the inorganic thin film, a solution which contains at least one ion species selected from the group consisting of alkali metal ions, alkaline earth metal ions, and ammonium ions and originating from a low-molecular-weight electrolyte having a molecular weight of 1,000 or less and which has a total ion concentration of the ion species of 1×10−5 mol/L or more and less than 10 mol/L and a solution concentration less than a saturation concentration.
摘要翻译： 具有热塑性聚合物膜的阻气膜和设置在热塑性聚合物膜的至少一个表面上的无机薄膜，该阻气膜通过向无机薄膜施加含有至少一种离子的溶液而形成 从碱金属离子，碱土金属离子和铵离子组成的组中选出的并且分子量为1000以下的低分子量电解质的离子种类的总离子浓度为1×10 3 -5mol / L以上且小于10mol / L，溶液浓度小于饱和浓度。
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公开(公告)号：US20090274894A1
公开(公告)日：2009-11-05
申请号：US12297008
申请日：2007-04-13
CPC分类号： B32B27/30 , B32B27/34 , C08J7/045 , C08J2329/04 , H01L51/5253 , H05B33/04 , Y10T428/24999 , Y10T428/26 , Y10T428/266 , Y10T428/31573 , Y10T428/31797 , Y10T428/31855
摘要： There is provided a gas-barrier laminate composed of a base film and an inorganic thin film layer formed on the base film which considerably enhanced in gas-barrier property and gelbo flex resistance. The present invention relates to a gas-barrier laminate comprising a base film containing at least one compound selected from the group consisting of polyvinyl alcohol and an ethylene-vinyl alcohol copolymer, and an anchor coat layer and an inorganic thin film layer successively formed on one surface of the base film in this order, wherein the base film is in the form of a biaxially stretched film having a variation in thickness of 3.5 μm or less and a crystallinity of 30% or more.
摘要翻译： 提供了由基膜和形成在基膜上的无机薄膜层组成的阻气层压板，其显着提高了气体阻隔性和耐胶粘性。 本发明涉及一种阻气性层压体，其包含含有至少一种选自聚乙烯醇和乙烯 - 乙烯醇共聚物的化合物的基膜，以及在一个相继形成的锚固涂层和无机薄膜层 该基膜的厚度为3.5μm以下，结晶度为30％以上的双轴拉伸膜的形式。
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公开(公告)号：US20070092717A1
公开(公告)日：2007-04-26
申请号：US11604835
申请日：2006-11-28
CPC分类号： B32B27/36 , B32B7/12 , B32B27/08 , B32B27/34 , B32B2307/7242 , B32B2367/00 , B32B2377/00 , C08J7/045 , C08J2367/02 , C08J2377/00 , C23C14/024 , C23C14/5806 , Y10T428/265 , Y10T428/31551 , Y10T428/31667 , Y10T428/31678 , Y10T428/31681 , Y10T428/31725 , Y10T428/31786 , Y10T428/31935
摘要： A gas-barrier laminate comprising a base film, a thin film formed on the base film and comprising a metal compound selected from the group consisting of oxides, carbides and nitrides of metals, and mixtures thereof, and a plastic film formed on the metal compound thin film in which a film obtained by forming the metal compound thin film on the base film is subjected to a heat treatment, and having an oxygen permeability of not more than 2 cc/m2/day/atm, wherein when the laminate is subjected to hydrothermal treatment at 120° C. for 30 min, a change in oxygen permeability of the laminate between before and after the hydrothermal treatment is not more than 5.
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公开(公告)号：US20120125437A1
公开(公告)日：2012-05-24
申请号：US13361594
申请日：2012-01-30
IPC分类号： H01L31/0203
CPC分类号： H01L31/0749 , H01L31/048 , H01L31/0481 , H01L51/0078 , H01L51/42 , H01L51/448 , Y02E10/541 , Y02E10/549
摘要： A solar cell module including a thin-film solar cell element protected with a novel gas barrier film is provided. The solar cell module includes a laminate obtained by laminating a gas barrier film on a layer including at least a solar cell element. The gas barrier film is obtained by laminating at least a substrate film, weather-resistant coating layer, and inorganic thin film layer. The weather-resistant coating layer is made of at least one of (a) a material obtained by crosslinking modified polyvinyl alcohol, (b) a material obtained by crosslinking polycaprolactone polyol and/or a material obtained by crosslinking polycarbonate polyol, and (c) an acrylic polymer having at least one group selected from the group consisting of an UV-stabilizing group, UV-absorbing group, and cycloalkyl group. The solar cell element is a thin-film solar cell element.
摘要翻译： 提供一种太阳能电池模块，其包括用新型阻气膜保护的薄膜太阳能电池元件。 太阳能电池模块包括通过在至少包括太阳能电池元件的层上层压阻气膜而获得的层压体。 阻气膜通过至少层叠基材膜，耐候性涂层和无机薄膜层而获得。 耐候性涂层由（a）通过交联改性聚乙烯醇获得的材料，（b）通过交联聚己内酯多元醇获得的材料和/或通过交联聚碳酸酯多元醇获得的材料中的至少一种制成，以及（c） 具有选自由UV稳定基团，UV吸收基团和环烷基组成的组中的至少一种的丙烯酸类聚合物。 太阳能电池元件是薄膜太阳能电池元件。
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公开(公告)号：US20070224402A1
公开(公告)日：2007-09-27
申请号：US10599065
申请日：2005-03-23
IPC分类号： B32B27/06
CPC分类号： C08J7/045 , B32B27/08 , C08J2323/10 , C08J2475/04 , Y10T428/24851 , Y10T428/263 , Y10T428/31551 , Y10T428/31663 , Y10T428/31681 , Y10T428/31786
摘要： A gas-barrier laminate with a plastic substrate, an inorganic thin film formed on at least one surface of the plastic substrate, and a coating layer formed by applying a coating material on a surface of the inorganic thin film, wherein said coating layer contains a polyester-based resin having a molecular weight of 3000 to 15000 and a polyurethane-based resin having a molecular weight of 8000 to 30000 at a weight ratio of 5/95 to 95/5, and said gas-barrier laminate has an oxygen permeability of not more than 25 fmol/m2/s/Pa; and a gas-barrier laminate comprising a plastic substrate, an inorganic thin film formed on at least one surface of the plastic substrate, and a coating layer formed by applying a coating material on a surface of the inorganic thin film, wherein the gas-barrier laminate exhibits an oxygen permeability of not more than 50 fmol/m2/s/Pa as measured with respect to a gas-barrier film obtained by laminating an unstretched polypropylene film having a thickness of 60 μm on the coating layer of the gas-barrier laminate after subjecting the gas-barrier film to hydrothermal treatment at 120° C. for 30 min, and the coating layer has either a hardness of 0.1 to 0.5 GPa as measured at 23° C. in atmospheric air by a nano-indentation hardness testing method, a hardness of 0.03 to 0.5 GPa as measured at 23° C. in water by a nano-indentation hardness testing method, or a ratio of number of carbon atoms derived from carboxyl groups to number of carbon atoms constituting the surface of the coating layer of 0.005 to 0.1.
摘要翻译： 一种具有塑料基板的阻气层压材料，在塑料基板的至少一个表面上形成的无机薄膜，以及通过在无机薄膜的表面上涂覆涂层而形成的涂层，其中所述涂层含有 分子量为3000〜15000的聚酯类树脂和重量比为5/95〜95/5的分子量为8000〜30000的聚氨酯类树脂，所述阻气性层压体的氧透过率为 不大于25fmol / m 2 / s / Pa; 以及包含塑料基板，形成在所述塑料基板的至少一个表面上的无机薄膜和通过在所述无机薄膜的表面上涂覆涂料而形成的涂层的阻气性层压体，其中所述气体阻隔层 相对于通过将厚度为60μm的未拉伸聚丙烯膜层压在所述阻气膜上而测量的阻气膜，所述层压体的透氧度不大于50fmol / m 2 / s / Pa 在将阻气膜在120℃进行水热处理30分钟后，将阻气性层压体的涂层进行水热处理，涂层在大气中在23℃下测定的硬度为0.1〜0.5GPa 通过纳米压痕硬度测试方法，通过纳米压痕硬度测试方法在23℃下在水中测量的硬度为0.03至0.5GPa，或由羧基衍生的碳原子数与碳数之比 构成表面的原子 涂层0.005〜0.1。
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公开(公告)号：US20110129654A1
公开(公告)日：2011-06-02
申请号：US13022283
申请日：2011-02-07
CPC分类号： C08J7/045 , B32B7/12 , B32B27/08 , B32B27/10 , B32B27/281 , B32B27/285 , B32B27/286 , B32B27/288 , B32B27/306 , B32B27/308 , B32B27/32 , B32B27/325 , B32B27/34 , B32B27/36 , B32B27/365 , B32B27/42 , B32B2250/02 , B32B2250/03 , B32B2250/24 , B32B2255/10 , B32B2255/20 , B32B2255/26 , B32B2255/28 , B32B2307/31 , B32B2307/4023 , B32B2307/7163 , B32B2307/7244 , B32B2307/748 , B32B2307/75 , B32B2439/00 , B32B2439/40 , C08J2323/10 , C08J2475/04 , Y10T428/24851 , Y10T428/263 , Y10T428/31551 , Y10T428/31663 , Y10T428/31681 , Y10T428/31786
摘要： A gas-barrier laminate, containing a plastic substrate, an inorganic thin film on at least one surface of the plastic substrate, and a coating layer on a surface of the inorganic thin film is provided. The coating layer comprises at least one resin selected from the group consisting of a polyester resin, an urethane resin, an acrylic resin, an alkoxysilyl group-containing resin, an oxazoline group-containing resin and copolymer resins thereof and a hardness of the coating layer is from 0.1 to 0.5 GPa as measured at 23° C. in atmospheric air by a nano-indentation hardness testing method. When the gas-barrier laminate is further laminated on the coating layer with an unstretched polypropylene film having a thickness of 60 μm and the further obtained laminate subjected to a hydrothermal treatment at 120° C. for 30 min, an oxygen permeability of the further laminate is not more than 50 fmol/m2/s/Pa.
摘要翻译： 提供了在塑料基板的至少一个表面上包含塑料基板，无机薄膜和无机薄膜表面上的涂层的阻气层压板。 涂层包含选自聚酯树脂，聚氨酯树脂，丙烯酸树脂，含烷氧基甲硅烷基的树脂，含恶唑啉基的树脂及其共聚物树脂中的至少一种树脂和涂层的硬度 通过纳米压痕硬度测试方法在23℃下在大气中测量为0.1至0.5GPa。 当使用厚度为60μm的未拉伸聚丙烯膜将阻气性层压体进一步层压在该涂层上时，进一步得到的层压体在120℃进行水热处理30分钟后，进一步层压 不大于50fmol / m 2 / s / Pa。
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公开(公告)号：US20090214854A1
公开(公告)日：2009-08-27
申请号：US12065131
申请日：2006-08-30
IPC分类号： B32B5/16 , B32B27/28 , B32B27/36 , B32B27/40 , B32B27/38 , B32B27/06 , B32B27/34 , B05D7/04 , B32B27/10 , B32B27/08
CPC分类号： B65D65/42 , C08J5/18 , C08J7/045 , C08J2323/08 , C08J2329/04 , C08L23/0869 , C08L23/0876 , C09D5/028 , G02F1/133345 , Y10T428/24967 , Y10T428/25 , Y10T428/259 , Y10T428/263 , Y10T428/265 , Y10T428/269 , Y10T428/31511 , Y10T428/31515 , Y10T428/31551 , Y10T428/31725 , Y10T428/31765 , Y10T428/31786 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , C08L29/00
摘要： Provided is a film which can be industrially coated easily and exhibits excellent gas barrier performance without being subjected to a high-temperature heat treatment. The film exhibits good gas barrier performance immediately after the production, and maintains the excellent gas barrier performance while exhibiting excellent hot water resistance and printing resistance. More specifically, provided are: a gas barrier laminated film including a resin layer on an inorganic thin film formed on at least one surface of a support film, the resin layer being formed by applying: (1) an aqueous dispersion containing polyvinyl alcohol (a), an ethylene-unsaturated carboxylic acid copolymer (b), and inorganic particles (c); (2) an aqueous dispersion containing an ethylene-unsaturated carboxylic acid copolymer (b), inorganic particles (c), and/or a cross-linking agent (d); or (3) an aqueous dispersion containing polyvinyl alcohol (a), an ethylene-unsaturated carboxylic acid copolymer (b), inorganic particles (c), and a cross-linking agent (d), to the inorganic thin film surface; and a method of producing the gas barrier laminated film.
摘要翻译： 本发明提供一种易于工业涂布的膜，并且在不进行高温热处理的情况下，具有优异的阻气性。 该薄膜在生产后立即显示良好的阻气性能，并保持优异的阻气性能，同时具有优异的耐热水性和耐印刷性。 更具体地说，提供了一种阻气性叠层膜，其在形成在支撑膜的至少一个表面上的无机薄膜上具有树脂层，所述树脂层通过以下方式形成：（1）含有聚乙烯醇（a ），乙烯 - 不饱和羧酸共聚物（b）和无机颗粒（c）; （2）含有乙烯 - 不饱和羧酸共聚物（b），无机颗粒（c）和/或交联剂（d）的水分散体; 或（3）含有聚乙烯醇（a），乙烯 - 不饱和羧酸共聚物（b），无机粒子（c）和交联剂（d））的水性分散体的无机薄膜表面; 以及制造阻气层叠膜的方法。
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