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公开(公告)号：US20110156355A1
公开(公告)日：2011-06-30
申请号：US12647898
申请日：2009-12-28
申请人： Toru NOGUCHI , Hiroyuki UEKI , Shigeki INUKAI , Masaei ITO , Raghu MADHAVAN , Morinobu ENDO , Satoshi IINOU
发明人： Toru NOGUCHI , Hiroyuki UEKI , Shigeki INUKAI , Masaei ITO , Raghu MADHAVAN , Morinobu ENDO , Satoshi IINOU
CPC分类号： C08K7/06 , C08K2201/011 , C08L15/005
摘要： A seal member includes a hydrogenated acrylonitrile-butadiene rubber (HNBR) and carbon nanofibers. The seal member has a number of cycles to fracture of 7000 or more when subjected to a tensile fatigue test at a temperature of 70° C., a maximum tensile stress of 4 N/mm, and a frequency of 1 Hz. The seal member exhibits excellent abrasion resistance.
摘要翻译： 密封件包括氢化丙烯腈 - 丁二烯橡胶（HNBR）和碳纳米纤维。 当在70℃的温度，4N / mm的最大拉伸应力和1Hz的频率下进行拉伸疲劳试验时，密封构件具有7000以上的断裂的循环次数。 密封件表现出优异的耐磨性。
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公开(公告)号：US20110156356A1
公开(公告)日：2011-06-30
申请号：US12647943
申请日：2009-12-28
申请人： Toru NOGUCHI , Hiroyuki UEKI , Shigeki INUKAI , Masaei ITO , Raghu MADHAVAN , Morinobu ENDO , Satoshi IINOU
发明人： Toru NOGUCHI , Hiroyuki UEKI , Shigeki INUKAI , Masaei ITO , Raghu MADHAVAN , Morinobu ENDO , Satoshi IINOU
CPC分类号： E21B33/10 , B82Y30/00 , C08J5/005 , C08J2327/18 , C09K3/1009 , F01C1/107 , F01C13/00 , F01C19/005 , F01C19/125 , F04C2/1075 , F04C13/008
摘要： The seal member includes a tetrafluoroethylene-propylene copolymer (FEPM) and carbon nanofibers. The seal member has a number of cycles to fracture of 10 or more when subjected to a tension fatigue test at a temperature of 150° C., a maximum tensile stress of 2 N/mm, and a frequency of 1 Hz. The seal member exhibits excellent heat resistance and abrasion resistance.
摘要翻译： 密封件包括四氟乙烯 - 丙烯共聚物（FEPM）和碳纳米纤维。 当在150℃的温度，2N / mm的最大拉伸应力和1Hz的频率下进行拉伸疲劳试验时，密封构件具有10个以上的断裂的循环次数。 密封件表现出优异的耐热性和耐磨性。
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公开(公告)号：US20110156357A1
公开(公告)日：2011-06-30
申请号：US12647948
申请日：2009-12-28
申请人： Toru NOGUCHI , Hiroyuki UEKI , Shigeki INUKAI , Masaei ITO , Raghu MADHAVAN , Morinobu ENDO , Satoshi IINOU
发明人： Toru NOGUCHI , Hiroyuki UEKI , Shigeki INUKAI , Masaei ITO , Raghu MADHAVAN , Morinobu ENDO , Satoshi IINOU
CPC分类号： F16J15/3284 , C09K3/1009 , C09K2200/0208 , C09K2200/0282 , F04C2/1075 , F04C13/008 , F05C2225/00 , F05C2253/04 , Y10T428/249921 , Y10T428/25 , Y10T428/256 , Y10T428/259
摘要： A dynamic seal member includes a ternary fluoroelastomer (FKM) and carbon nanofibers. The carbon nanofibers are carbon nanofibers having an average diameter of 10 to 20 nm, or carbon nanofibers having an average diameter of 60 to 110 nm and subjected to a low-temperature heat treatment. The carbon nanofibers having an average diameter of 60 to 110 nm and subjected to the low-temperature heat treatment have a ratio (D/G) of a peak intensity D at around 1300 cm−1 to a peak intensity G at around 1600 cm−1 measured by Raman scattering spectroscopy of more than 0.9 and less than 1.6. The dynamic seal member has a number of cycles to fracture of 10 or more when subjected to a tension fatigue test at a temperature of 200° C., a maximum tensile stress of 2.5 N/mm, and a frequency of 1 Hz. The dynamic seal member exhibits excellent heat resistance and abrasion resistance.
摘要翻译： 动态密封件包括三元含氟弹性体（FKM）和碳纳米纤维。 碳纳米纤维是平均直径为10〜20nm的碳纳米纤维，平均直径为60〜110nm的碳纳米纤维，进行低温热处理。 平均直径为60〜110nm并进行低温热处理的碳纳米纤维具有1300cm -1左右的峰强度D与1600cm -1附近的峰值强度G的比（D / G） 1通过拉曼散射光谱测量，大于0.9且小于1.6。 当在200℃的温度，2.5N / mm的最大拉伸应力和1Hz的频率下进行拉伸疲劳试验时，动态密封构件具有10个以上的断裂的循环次数。 动态密封件表现出优异的耐热性和耐磨性。
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4.发明申请CARBON FIBER COMPOSITE MATERIAL, METHOD OF PRODUCING THE SAME, INSULATING ARTICLE, ELECTRONIC PART, AND LOGGING TOOL 有权碳纤维复合材料，其制造方法，绝缘品，电子部件和记录工具公开(公告)号：US20110160375A1
公开(公告)日：2011-06-30
申请号：US12648040
申请日：2009-12-28
申请人： Toru NOGUCHI , Hiroyuki UEKI , Shigeki INUKAI , Satoshi IINOU , Masaei ITO
发明人： Toru NOGUCHI , Hiroyuki UEKI , Shigeki INUKAI , Satoshi IINOU , Masaei ITO
IPC分类号： C08K3/04
CPC分类号： H01B3/47 , C08K3/04 , C08K2201/011
摘要： A carbon fiber composite material comprising 100 parts by mass of an elastomer, and 20 to 100 parts by mass of carbon nanofibers that have been oxidized and reduced in number of branch points. The carbon fiber composite material has a dynamic modulus of elasticity (E′) at 200° C. and 10 Hz of 10 to 1000 MPa, and a volume resistivity of 106 to 1018 ohms·cm.
摘要翻译： 一种碳纤维复合材料，其包含100质量份的弹性体，和20〜100质量份已经被氧化并且分支点数减少的碳纳米纤维。 碳纤维复合材料在200℃下的动态弹性模量（E'）和10〜1000MPa的10Hz，体积电阻率为106〜1018欧姆·厘米。
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5.发明申请CARBON NANOFIBER, METHOD FOR PRODUCTION THEREOF, METHOD FOR PRODUCTION OF CARBON FIBER COMPOSITE MATERIAL USING CARBON NANOFIBER, AND CARBON FIBER COMPOSITE MATERIAL 有权碳纳米纤维，其制造方法，使用碳纳米纤维生产碳纤维复合材料的方法和碳纤维复合材料公开(公告)号：US20120309887A1
公开(公告)日：2012-12-06
申请号：US13566577
申请日：2012-08-03
申请人： Toru NOGUCHI , Hiroyuki UEKI , Shigeki INUKAI , Kenji TAKEUCHI , Satoshi IINOU
发明人： Toru NOGUCHI , Hiroyuki UEKI , Shigeki INUKAI , Kenji TAKEUCHI , Satoshi IINOU
CPC分类号： C08J3/203 , B82Y30/00 , B82Y40/00 , C01B32/16 , C01B32/168 , C01P2004/03 , C08J5/005 , C08J2321/00 , D01F11/122 , Y10T428/298
摘要： A method of producing a carbon fiber composite material includes a first step and a second step. The first step includes oxidizing first carbon nanofibers produced by a vapor growth method to obtain second carbon nanofibers having an oxidized surface. The second step includes mixing the second carbon nanofibers into an elastomer, and uniformly dispersing the carbon nanofibers in the elastomer by applying a shear force to obtain the carbon fiber composite material. The second carbon nanofibers obtained by the first step have a surface oxygen concentration measured by X-ray photoelectron spectroscopy (XPS) of 2.6 to 4.6 atm %.
摘要翻译： 碳纤维复合材料的制造方法包括第一工序和第二工序。 第一步包括氧化通过气相生长法产生的第一碳纳米纤维，得到具有氧化表面的第二碳纳米纤维。 第二步包括将第二碳纳米纤维混合成弹性体，并通过施加剪切力将碳纳米纤维均匀分散在弹性体中以获得碳纤维复合材料。 通过第一步获得的第二碳纳米纤维具有通过X射线光电子能谱（XPS）测量的2.6至4.6atm％的表面氧浓度。
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6.发明申请HEAT-RESISTANT SEAL MATERIAL, ENDLESS SEAL MEMBER USING HEAT-RESISTANT SEAL MATERIAL, AND DOWNHOLE APPARATUS INCLUDING ENDLESS SEAL MEMBER 有权耐热密封材料，使用耐热密封材料的无缝密封件，以及包括无密封密封件的卧式设备公开(公告)号：US20090253852A1
公开(公告)日：2009-10-08
申请号：US12327396
申请日：2008-12-03
申请人： Toru NOGUCHI , Hiroyuki UEKI , Akira MAGARIO , Shigeki INUKAI , Masaei ITO , Takashi WANIBUCHI , Takushi MATSUSHITA , Tsuyoshi WATANABE
发明人： Toru NOGUCHI , Hiroyuki UEKI , Akira MAGARIO , Shigeki INUKAI , Masaei ITO , Takashi WANIBUCHI , Takushi MATSUSHITA , Tsuyoshi WATANABE
IPC分类号： C08K3/04
CPC分类号： C09K3/1009 , B82Y30/00 , E21B33/1208
摘要： A heat-resistant seal material includes 100 parts by weight of a ternary fluoroelastomer, 1 to 30 parts by weight of vapor-grown carbon fibers having an average diameter of more than 30 nm and 200 nm or less, and carbon black having an average particle diameter of 25 to 500 nm. The heat-resistant seal material contains the vapor-grown carbon fibers and the carbon black in an amount of 20 to 40 parts by weight in total. The heat-resistant seal material has a compression set when subjected to a compression set test at a compression rate of 25% and a temperature of 200° C. for 70 hours of 0 to 15% and a dynamic modulus of elasticity at 200° C. (E′/200° C.) of 30 to 100 MPa.
摘要翻译： 耐热密封材料包括100重量份的三元含氟弹性体，1至30重量份的平均直径大于30nm和200nm或更小的气相生长碳纤维，以及具有平均颗粒的炭黑 直径为25〜500nm。 耐热密封材料总共包含20至40重量份的气相生长碳纤维和炭黑。 当以25％的压缩率和200℃的温度进行压缩变形试验时，耐热密封材料具有0至15％的70小时和200℃的动态弹性模量的压缩永久变形 （E'/ 200℃）为30〜100MPa。
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7.发明申请CARBON NANOFIBERS, METHOD OF PRODUCING THE SAME, AND CARBON FIBER COMPOSITE MATERIAL 审中-公开碳纳米纤维，其制造方法和碳纤维复合材料公开(公告)号：US20100009204A1
公开(公告)日：2010-01-14
申请号：US12326490
申请日：2008-12-02
申请人： Toru NOGUCHI , Hiroyuki UEKI , Satoshi IINOU , Kenji TAKEUCHI
发明人： Toru NOGUCHI , Hiroyuki UEKI , Satoshi IINOU , Kenji TAKEUCHI
IPC分类号： B32B5/28
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/162 , C01B32/174 , C01B2202/26 , C01B2202/34 , C01B2202/36 , C08J5/005 , C08J2307/00 , C08J2323/16 , D01F9/127 , D01F9/1276 , D01F9/133
摘要： A carbon fiber composite material includes an elastomer and carbon nanofibers uniformly dispersed in the elastomer. The carbon nanofibers are produced by a vapor growth method and then heated at a temperature that is in a range from 1100 to 1600° C. and is higher than the reaction temperature employed in the vapor growth method.
摘要翻译： 碳纤维复合材料包括均匀分散在弹性体中的弹性体和碳纳米纤维。 碳纳米纤维通过气相生长法生产，然后在1100〜1600℃的温度范围内加热，高于气相生长法中使用的反应温度。
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8.发明申请CARBON NANOFIBERS, METHOD OF PRODUCING CARBON NANOFIBERS, CARBON FIBER COMPOSITE MATERIAL USING CARBON NANOFIBERS, AND METHOD OF PRODUCING THE CARBON FIBER COMPOSITE MATERIAL 有权碳纳米纤维，碳纳米纤维的制造方法，碳纳米纤维的碳纤维复合材料及碳纤维复合材料的制造方法公开(公告)号：US20100009160A1
公开(公告)日：2010-01-14
申请号：US12326509
申请日：2008-12-02
申请人： Toru NOGUCHI , Hiroyuki UEKI , Satoshi IINOU , Kenji TAKEUCHI
发明人： Toru NOGUCHI , Hiroyuki UEKI , Satoshi IINOU , Kenji TAKEUCHI
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/168 , C01B2202/32 , C01B2202/36 , C01P2006/11 , C08J5/005 , C08J2309/02 , C08J2323/16 , D01F9/127 , Y10T428/24994 , Y10T428/2918
摘要： A method of producing carbon nanofibers includes grinding untreated carbon nanofibers produced by a vapor growth method. The untreated carbon nanofibers are ground so that the ground carbon nanofibers have a tap density 1.5 to 10 times higher than that of the untreated carbon nanofibers. A method of producing a carbon fiber composite material includes mixing carbon nanofibers into an elastomer, and uniformly dispersing the carbon nanofibers in the elastomer by applying a shear force to obtain a carbon fiber composite material.
摘要翻译： 制造碳纳米纤维的方法包括研磨通过气相生长法生产的未处理的碳纳米纤维。 将未处理的碳纳米纤维研磨，使得研磨的碳纳米纤维的振实密度比未处理的碳纳米纤维的振实密度高1.5至10倍。 碳纤维复合材料的制造方法包括将碳纳米纤维混合成弹性体，通过施加剪切力将碳纳米纤维均匀分散在弹性体中，得到碳纤维复合材料。
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9.发明申请CARBON FIBER COMPOSITE MATERIAL AND METHOD OF PRODUCING THE SAME, FORMED PRODUCT OF CARBON FIBER COMPOSITE AND METHOD OF PRODUCING THE SAME, CARBON FIBER-METAL COMPOSITE MATERIAL AND METHOD OF PRODUCING THE SAME, AND FORMED PRODUCT OF CARBON FIBER-METAL COMPOSITE AND METHOD OF PRODUCING THE SAME 审中-公开碳纤维复合材料及其制造方法，碳纤维复合材料的成型品及其制造方法，碳纤维 - 金属复合材料及其制造方法以及碳纤维 - 金属复合材料的成型产品及其制造方法 一样公开(公告)号：US20120040176A1
公开(公告)日：2012-02-16
申请号：US13243675
申请日：2011-09-23
申请人： Toru NOGUCHI , Akira Magario
发明人： Toru NOGUCHI , Akira Magario
IPC分类号： B32B5/16
CPC分类号： B29C43/24 , B22F1/0059 , B22F2999/00 , B29K2105/162 , B82Y30/00 , C08J5/005 , C08J5/042 , C08J2321/00 , C08K7/06 , C08K7/18 , C08L21/00 , C22C26/00 , C22C47/06 , C22C47/08 , C22C49/14 , C22C2026/002 , Y10T428/25 , B22F1/0018
摘要： A method of producing a carbon fiber composite material including: mixing an elastomer which includes an unsaturated bond or a group having affinity to carbon nanofibers with metal particles; and dispersing the carbon nanofibers into the elastomer including the metal particles by a shear force.
摘要翻译： 一种碳纤维复合材料的制造方法，其特征在于，将包含不饱和键的弹性体或与碳纳米纤维具有亲和性的基团与金属粒子混合; 并通过剪切力将碳纳米纤维分散到包含金属颗粒的弹性体中。
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公开(公告)号：US20100279099A1
公开(公告)日：2010-11-04
申请号：US12836305
申请日：2010-07-14
申请人： Toru NOGUCHI , Shigeru FUKAZAWA , Shuichi SHIMIZU
发明人： Toru NOGUCHI , Shigeru FUKAZAWA , Shuichi SHIMIZU
IPC分类号： B32B27/04
CPC分类号： B82Y30/00 , C08J5/005 , C08J5/042 , C08J2321/00 , C08K7/06 , C08K7/24 , C08K2201/011 , Y10S428/903 , Y10S977/778 , Y10S977/783 , Y10T428/249924 , Y10T428/24994 , Y10T428/249945 , Y10T428/2913 , C08L21/00
摘要： The present invention provides a carbon fiber composite material comprising an elastomer and a carbon nanofiber dispersed in the elastomer, wherein the elastomer has an unsaturated bond or a group, having affinity to the carbon nanofiber. Also disclosed is a process for producing the carbon fiber composite material.
摘要翻译： 本发明提供一种碳纤维复合材料，其包含分散在弹性体中的弹性体和碳纳米纤维，其中弹性体具有对碳纳米纤维具有亲和性的不饱和键或基团。 还公开了一种碳纤维复合材料的制造方法。
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