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公开(公告)号：US07038217B2
公开(公告)日：2006-05-02
申请号：US11104443
申请日：2005-04-13
IPC分类号： B01D59/44
CPC分类号： H01J49/162 , H01J49/0422 , H01J49/0445
摘要： Here is disclosed a method for generation of a molecular beam from a sample solution, comprising steps of operating a spray-in device to introduce the sample solution in atomized state into a spray chamber, impinging a suitable gas on the sample solution in atomized state or heating the sample solution in atomized state to generate solute molecules deprived of solvent molecules, and then ejecting these solute molecules through an orifice into a low air pressure chamber. The apparatus as well as the method according to the present invention enable to generate a molecular beam for a variety of molecules, particularly for the neutral molecules which can be decomposed by heating at a high temperature or those which can not be sublimated or vaporized even by heating at a high temperature, as long as the sample solutions are prepared. Due to the method as well as the apparatus according to the invention, it is possible to conduct the mass spectroscopy studies and also other spectroscopic analyses about the molecules and the molecular clusters containing in the molecular beam generated in this manner, for example, by irradiating laser beams. It is possible to also possible to deposit the molecules on a substrate.
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公开(公告)号：US06906323B2
公开(公告)日：2005-06-14
申请号：US10299658
申请日：2002-11-20
IPC分类号： G01N27/62 , B01D59/44 , G01N1/00 , G01N1/28 , G01N21/27 , G01N27/64 , G01N35/08 , G01N37/00 , H01J27/00 , H01J49/00 , H01J49/02 , H01J49/04 , H01J49/10 , H05H3/02
CPC分类号： H01J49/162 , H01J49/0422 , H01J49/0445
摘要： Here is disclosed a method for generation of a molecular beam from a sample solution, comprising steps of operating a spray-in device to introduce the sample solution in atomized state into a spray chamber, impinging a suitable gas on the sample solution in atomized state or heating the sample solution in atomized state to generate solute molecules deprived of solvent molecules, and then ejecting these solute molecules through an orifice into a low air pressure chamber. The apparatus as well as the method according to the present invention enable to generate a molecular beam for a variety of molecules, particularly for the neutral molecules which can be decomposed by heating at a high temperature or those which can not be sublimated or vaporized even by heating at a high temperature, as long as the sample solutions are prepared. Due to the method as well as the apparatus according to the invention, it is possible to conduct the mass spectroscopy studies and also other spectroscopic analyses about the molecules and the molecular clusters containing in the molecular beam generated in this manner, for example, by irradiating laser beams. It is possible to also possible to deposit the molecules on a substrate.
摘要翻译： 这里公开了一种从样品溶液中产生分子束的方法，包括以下步骤：操作喷射装置以将雾化状态的样品溶液引入喷雾室，以雾化状态将合适的气体以样品溶液照射; 以雾化状态加热样品溶液以产生溶解分子的溶质分子，然后通过孔口将这些溶质分子喷射到低气压室中。 根据本发明的装置以及方法能够产生各种分子的分子束，特别是对于可以通过在高温下加热而分解的中性分子，或者甚至不能被升华或蒸发的分子束 只要制备样品溶液即可在高温下加热。 由于根据本发明的方法和装置，可以进行质谱分析研究以及关于分子生成的分子和分子簇的其他光谱分析，例如通过照射 激光束。 也可能将分子沉积在基底上。
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公开(公告)号：US20050199824A1
公开(公告)日：2005-09-15
申请号：US11104443
申请日：2005-04-13
IPC分类号： G01N27/62 , B01D59/44 , G01N1/00 , G01N1/28 , G01N21/27 , G01N27/64 , G01N35/08 , G01N37/00 , H01J27/00 , H01J49/00 , H01J49/02 , H01J49/04 , H01J49/10 , H05H3/02
CPC分类号： H01J49/162 , H01J49/0422 , H01J49/0445
摘要： Here is disclosed a method for generation of a molecular beam from a ample solution, comprising steps of operating a spray-in device to introduce the sample solution in atomized state into a spray chamber, impinging a suitable gas on the sample solution in atomized state or heating the sample solution in atomized state to generate solute molecules deprived of solvent molecules, and then ejecting these solute molecules through an orifice into a low air pressure chamber. The apparatus as well as the method according to the present invention enable to generate a molecular beam for a variety of molecules, particularly for the neutral molecules which can be decomposed by heating at a high temperature or those which can not be sublimated or vaporized even by heating at a high temperature, as long as the sample solutions are prepared. Due to the method as well as the apparatus according to the invention, it is possible to conduct the mass spectroscopy studies and also other spectroscopic analyses about the molecules and the molecular clusters containing in the molecular beam generated in this manner, for example, by irradiating laser beams. It is possible to also possible to deposit the molecules on a substrate.
摘要翻译： 这里公开了一种用于从充足的溶液产生分子束的方法，包括以下步骤：操作喷射装置以将雾化状态的样品溶液引入喷雾室中，以雾化状态将合适的气体冲入样品溶液;或 以雾化状态加热样品溶液以产生溶解分子的溶质分子，然后通过孔口将这些溶质分子喷射到低气压室中。 根据本发明的装置以及方法能够产生各种分子的分子束，特别是对于可以通过在高温下加热而分解的中性分子，或者甚至不能被升华或蒸发的分子束 只要制备样品溶液即可在高温下加热。 由于根据本发明的方法和装置，可以进行质谱分析研究以及关于分子生成的分子和分子簇的其他光谱分析，例如通过照射 激光束。 也可能将分子沉积在基底上。
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公开(公告)号：US20080076869A1
公开(公告)日：2008-03-27
申请号：US11898411
申请日：2007-09-12
申请人： Seiichi Furumi , Akira Otomo , Shinro Mashiko
发明人： Seiichi Furumi , Akira Otomo , Shinro Mashiko
IPC分类号： C08G73/02
CPC分类号： C08G83/003 , B82Y30/00 , C07C233/40 , C08F291/00 , C08G73/02 , C08G73/0206 , C08G73/0672
摘要： An object of the present invention is to provide a method of effectively producing a nano-particle and a nano-wire, and others. Specifically, the present invention provides a method of producing a molecular device including: the use of a molecular structure having a higher atomic density in the periphery than in the interior and bonding residues in the periphery; and a step of crosslinking the bonding residues, and the method of producing a molecular device according to claim 1, characterized in that the molecular structure is constituted by a skeleton portion having a skeleton structure, and a terminal portion which is arranged in the outer shell of the skeleton portion, has a higher atomic density than that of the skeleton portion and has bonding residues; and that in the step of crosslinking the bonding residues, the bonding residues in the terminal portion of the molecular structure are crosslinked to form the molecular structure into a shell structure, and others.
摘要翻译： 本发明的目的是提供一种有效地制造纳米颗粒和纳米线等的方法。 具体地说，本发明提供了一种分子装置的制造方法，其特征在于，在周边比在内部使用具有较高的原子密度的分子结构，并且在周边中键合残基; 权利要求1所述的分子装置的制造方法，其特征在于，所述分子结构由具有骨架结构的骨架部和所述外壳中配置的末端部构成 的骨架部分具有比骨架部分更高的原子密度并具有结合残基; 并且在交联键合残基的步骤中，分子结构的末端部分中的键合残基被交联以形成壳结构等分子结构。
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公开(公告)号：US07285604B2
公开(公告)日：2007-10-23
申请号：US10509380
申请日：2003-03-26
申请人： Seiichi Furumi , Akira Otomo , Shinro Mashiko
发明人： Seiichi Furumi , Akira Otomo , Shinro Mashiko
CPC分类号： C08G83/003 , B82Y30/00 , C07C233/40 , C08F291/00 , C08G73/02 , C08G73/0206 , C08G73/0672
摘要： An object of the present invention is to provide a method of effectively producing a nano-particle and a nano-wire, and others.Specifically, the present invention provides a method of producing a molecular device including: the use of a molecular structure having a higher atomic density in the periphery than in the interior and bonding residues in the periphery; and a step of crosslinking the bonding residues, and the method of producing a molecular device according to claim 1, characterized in that the molecular structure is constituted by a skeleton portion having a skeleton structure, and a terminal portion which is arranged in the outer shell of the skeleton portion, has a higher atomic density than that of the skeleton portion and has bonding residues; and that in the step of crosslinking the bonding residues, the bonding residues in the terminal portion of the molecular structure are crosslinked to form the molecular structure into a shell structure, and others.
摘要翻译： 本发明的目的是提供一种有效地制造纳米颗粒和纳米线等的方法。 具体地说，本发明提供了一种分子装置的制造方法，其特征在于，在周边比在内部使用具有较高的原子密度的分子结构，并且在周边中键合残基; 权利要求1所述的分子装置的制造方法，其特征在于，所述分子结构由具有骨架结构的骨架部和所述外壳中配置的末端部构成 的骨架部分具有比骨架部分更高的原子密度并具有结合残基; 并且在交联键合残基的步骤中，分子结构的末端部分中的键合残基被交联以形成壳结构等分子结构。
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6.发明申请Process for producing nano-device using potential singular points on substrate 失效在衬底上使用潜在的奇异点生产纳米器件的方法公开(公告)号：US20050023140A1
公开(公告)日：2005-02-03
申请号：US10886056
申请日：2004-07-08
CPC分类号： C25D1/18 , Y10S977/888 , Y10S977/896
摘要： The present invention provides a process for producing a bottom-up type nano-device in which a reaction is initiated from potential singular points on a substrate, and wherein compound molecules are arranged with regularity and a chain reaction is accelerated utilizing the sequence pattern of the potential singular points, specifically, the process comprises a step of producing potential singular points that involves placing potential singular points on a substrate and a contact step of contacting a compound having a functional group which interacts with the fore-mentioned potential singular points.
摘要翻译： 本发明提供了一种自底向上型纳米器件的制造方法，其中从衬底上的潜在奇点开始反应，并且其中化合物分子被规则地排列，并且使用序列模式来加速连锁反应 特别地，该方法包括产生潜在的奇异点的步骤，该步骤涉及将潜在的奇异点放置在基底上，以及使具有与上述潜在奇异点相互作用的官能团的化合物接触的接触步骤。
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公开(公告)号：US07205428B2
公开(公告)日：2007-04-17
申请号：US10346078
申请日：2003-01-17
IPC分类号： C07C323/00
CPC分类号： C08G83/003 , C08G75/0204 , C08L81/02
摘要： The present invention is directed to novel thioether dendritic molecules which respond immediately by emission of light when stimulated with light or electric energy.
摘要翻译： 本发明涉及当用光或电能刺激时立即响应光发射的新型硫醚树枝状分子。
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公开(公告)号：US07056446B2
公开(公告)日：2006-06-06
申请号：US10662886
申请日：2003-09-16
申请人： Takashi Nagase , Tohru Kubota , Shinro Mashiko
发明人： Takashi Nagase , Tohru Kubota , Shinro Mashiko
IPC分类号： B44C1/22
CPC分类号： H01L21/0332 , G01N27/07 , H01L21/32139 , H01L21/76838 , Y10S977/722
摘要： A method of easily manufacturing a nano-gap electrode by using a focused ion beam lithography includes a layer depositing step of depositing an electrode layer and a metal mask layer in this order on an insulating substrate, a mask pattern forming step of etching the metal mask layer by using the focused ion beam and thereby forming a mask pattern, a dry etching step of transferring a pattern to the electrode layer by dry etching, and a wet etching step of removing the metal mask layer by using a solution that selectively dissolves the metal mask layer compared to the electrode layer.
摘要翻译： 通过使用聚焦离子束光刻法容易地制造纳米间隙电极的方法包括在绝缘基板上依次沉积电极层和金属掩模层的层沉积步骤，蚀刻金属掩模的掩模图案形成步骤 通过使用聚焦离子束形成掩模图案的干蚀刻步骤，通过干蚀刻将图案转印到电极层的干蚀刻步骤以及通过使用选择性溶解金属的溶液去除金属掩模层的湿蚀刻步骤 掩模层与电极层相比。
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公开(公告)号：US06630578B2
公开(公告)日：2003-10-07
申请号：US09988774
申请日：2001-11-20
IPC分类号： C07C24500
CPC分类号： C08G83/003 , C08G75/0204 , C08L81/02
摘要： Novel dendritic molecules are provided which respond immediately by emission of light when stimulated with light or electric energy, and are useful, for example, as switching material of memory. The dendritic molecules have a core, a branch structure composed of Unit 1 represented by the following formula: wherein, ring A stands for a homo or heterocyclic six membered ring, optionally other branched structures, and surface functional groups as essential constituents.
摘要翻译： 提供了当用光或电能刺激时，通过发出光而立即响应的新型树枝状分子，并且例如用作存储器的切换材料是有用的。 树枝状分子具有核心，由下式表示的单元1构成的支链结构：其中环A代表同价或杂环六元环，任选其它支链结构和表面官能团作为必要成分。
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10.发明授权Process for producing nano-device using potential singular points on substrate 失效在衬底上使用潜在的奇异点生产纳米器件的方法公开(公告)号：US08084093B2
公开(公告)日：2011-12-27
申请号：US10886056
申请日：2004-07-08
IPC分类号： B05D3/04
CPC分类号： C25D1/18 , Y10S977/888 , Y10S977/896
摘要： The present invention provides a process for producing a bottom-up type nano-device in which a reaction is initiated from potential singular points on a substrate, and wherein compound molecules are arranged with regularity and a chain reaction is accelerated utilizing the sequence pattern of the potential singular points, specifically, the process comprises a step of producing potential singular points that involves placing potential singular points on a substrate and a contact step of contacting a compound having a functional group which interacts with the fore-mentioned potential singular points.
摘要翻译： 本发明提供了一种自底向上型纳米器件的制造方法，其中从衬底上的潜在奇点开始反应，并且其中化合物分子被规则地排列，并且使用序列模式来加速连锁反应 特别地，该方法包括产生潜在的奇异点的步骤，该步骤涉及将潜在的奇异点放置在基底上，以及使具有与上述潜在奇异点相互作用的官能团的化合物接触的接触步骤。
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