公开(公告)号：US5290835A

公开(公告)日：1994-03-01

申请号：US964251

申请日：1992-10-21

申请人： Toshio Hatayama ,  Mie Sasaki ,  Takeshi Kojima ,  Yoshinari Ogawa ,  Sakae Shimotsuma ,  Kouichi Sakai

发明人： Toshio Hatayama ,  Mie Sasaki ,  Takeshi Kojima ,  Yoshinari Ogawa ,  Sakae Shimotsuma ,  Kouichi Sakai

IPC分类号： C08L27/12 ,  C08L63/00 ,  C08L67/02 ,  H01G4/224 ,  H01H9/00 ,  H01H85/17 ,  H01L23/14 ,  H02G15/00 ,  C08K5/15 ,  C08K3/10 ,  C08K3/40

CPC分类号： H01G4/224 ,  C08L67/02 ,  H01H85/17 ,  H01H9/00 ,  H01L23/145 ,  H02G15/003 ,  C08L27/12 ,  C08L63/00 ,  H01L2924/0002

摘要： An electrical or electronic part having excellent resistance to moist heat, such as a coil bobbin, a condenser case, an IC carrier, a plug, a socket or a fuse case, formed from a polybutylene naphthalenedicarboxylate resin as a raw material; and a flame-retardant resin composition and an electrical part therefrom are also provided. The flame-retardant resin composition exhibits high fluidity and forms little burr, and the electrical part has excellent flame retardancy and well-balanced properties.

摘要翻译： 由作为原料的聚萘二甲酸丁二醇酯树脂形成的具有优异耐湿热性的电气或电子部件，例如线圈架，冷凝器壳，IC载体，插头，插座或熔断器壳体; 还提供阻燃性树脂组合物及其电气部件。 阻燃树脂组合物表现出高的流动性并且几乎没有毛刺，并且电气部件具有优异的阻燃性和良好的平衡性能。

公开(公告)号：US5221704A

公开(公告)日：1993-06-22

申请号：US591641

申请日：1990-10-02

申请人： Sakae Shimotsuma ,  Akihiro Suzuoka ,  Toshio Hatayama

发明人： Sakae Shimotsuma ,  Akihiro Suzuoka ,  Toshio Hatayama

IPC分类号： C08K3/00 ,  C08K3/22 ,  C08K3/26 ,  C08K5/03 ,  C08K13/02 ,  C08L63/02 ,  C08L67/00 ,  C08L67/02 ,  H01B3/42

CPC分类号： H01B3/422 ,  C08K3/2279 ,  C08K3/26 ,  C08L67/02

摘要： A flame-retardant resin composition comprising (A) polybutylene terephthalate, a copolymer comprising at least 60.0% by weight of butylene terephthalate units and/or a thermoplastic polyester blend comprising at least 60.0% by weight of polybutylene terephthalate, (B) a brominated epoxy resin type flame retardant and/or a brominated polycarbonate type flame retardant, (C) a flame retardant assistant composed mainly of antimony trioxide and/or antimony pentoxide, (D) a hydrous basic carbonate compound of magnesium and aluminum, and (E) optionally an inorganic filler.This resin composition has an excellent flame retardancy, balanced performances, and an improved molding processability (flowability, molding cycle, mold-staining resistance and the like), and a staining of metals or a formation of decomposition products and volatile substances is controlled when the composition is used for molding electrical parts.

公开(公告)号：US5262470A

公开(公告)日：1993-11-16

申请号：US789083

申请日：1991-11-07

申请人： Sakae Shimotsuma ,  Tetsuya Shiozaki ,  Akihiro Suzuoka ,  Mie Sasaki

发明人： Sakae Shimotsuma ,  Tetsuya Shiozaki ,  Akihiro Suzuoka ,  Mie Sasaki

IPC分类号： B41M5/26 ,  C08K3/04 ,  C08K5/03 ,  H01B1/06

CPC分类号： B41M5/267 ,  C08K3/04

摘要： A polyester resin composition;(A) which contains(a) a thermoplastic polyester resin, and(b) a carbon black and/or a graphite, and(B) in which the content of the above component (b) is 0.001 to 2% by weight based on the total weight of the components (a) and (b). The polyester resin composition may further contain (c) a bromine-containing flame retardant, (d) an antimony-containing flame retardant aid and (e) an inorganic filler in addition to the components (a) and (b). This polyester resin composition permits marking of fine lines and precise print with a high contrast with a laser light.

公开(公告)号：US5631060A

公开(公告)日：1997-05-20

申请号：US597933

申请日：1996-02-07

申请人： Noritsugu Saiki ,  Yoshihiro Akiba ,  Sakae Shimotsuma

发明人： Noritsugu Saiki ,  Yoshihiro Akiba ,  Sakae Shimotsuma

IPC分类号： C08J5/00 ,  B29C45/00 ,  C08K5/09 ,  C08L67/00 ,  C08L67/02 ,  G06F3/02 ,  H01H13/14 ,  H01H13/70 ,  G06C7/02

CPC分类号： H01H13/70 ,  B29C45/0001 ,  B29C45/0081 ,  B29L2031/466 ,  H01H2209/002 ,  H01H2229/044 ,  Y10T428/24025 ,  Y10T428/24479

摘要： A resin molded article having a moveable projecting portion suitable for use in forming a keyboard or keyboard switch and which is substantially free from flex fatigue. At least the moveable projecting portion of the molded article is formed from a resin composition containing a polyether ester block copolymer and a small amount of an alkali metal salt of an aliphatic carboxylic acid having 10 to 36 carbon atoms. The polyether ester block copolymer contains units from terephthalic acid, tetramethylene glycol and polyoxytetramethylene glycol. The resin molded article includes a thick projecting (moveable) portion, a base portion and a flexible thin side portion connecting the thick projecting portion to the base portion. The side portion has a thickness of 0.05 to 0.5 mm and a flexibility retention of at least 85%.

摘要翻译： 一种具有适于用于形成键盘或键盘开关并且基本上没有挠曲疲劳的可移动突出部分的树脂模制品。 至少模塑制品的可移动突出部分由含有聚醚酯嵌段共聚物和少量具有10至36个碳原子的脂族羧酸的碱金属盐的树脂组合物形成。 聚醚酯嵌段共聚物含有来自对苯二甲酸，四亚甲基二醇和聚氧四亚甲基二醇的单元。 树脂成形品具有厚的突起（可移动）部分，基部和将厚的突出部分连接到基部的柔性薄侧部分。 侧部的厚度为0.05〜0.5mm，弹性保持率为85％以上。

公开(公告)号：US3952125A

公开(公告)日：1976-04-20

申请号：US500502

申请日：1974-08-26

申请人： Takatoshi Kuratsuji ,  Hiroo Shima ,  Takeo Shima ,  Shoji Kawase ,  Sakae Shimotsuma ,  Masahiro Hosoi

发明人： Takatoshi Kuratsuji ,  Hiroo Shima ,  Takeo Shima ,  Shoji Kawase ,  Sakae Shimotsuma ,  Masahiro Hosoi

IPC分类号： H01B3/42 ,  C08G63/12

CPC分类号： H01B3/423 ,  Y10T428/266

摘要： An electrically insulating material composed of an unstretched film of a substantially linear polyester at least 85 mol% of the recurring units of which consist of a hexamethylene naphthalene-2,6-dicarboxylate unit and which has an intrinsic viscosity, as measured on its ortho-chlorophenol solution at 35.degree.C., of at least 0.3.

摘要翻译： 由绝缘材料构成的电绝缘材料，其基本线性聚酯的至少85摩尔％的重复单元的未拉伸膜由六亚甲基萘-2,6-二甲酸酯单元组成，并且其特性粘度为其邻位 - 氯酚溶液在35℃，至少0.3。

公开(公告)号：US3937754A

公开(公告)日：1976-02-10

申请号：US381580

申请日：1973-07-23

申请人： Sakae Shimotsuma ,  Takeo Asai ,  Masahiro Hosoi ,  Hiroshi Aoki ,  Masanori Masuda

发明人： Sakae Shimotsuma ,  Takeo Asai ,  Masahiro Hosoi ,  Hiroshi Aoki ,  Masanori Masuda

IPC分类号： C08L67/00 ,  B29C49/00 ,  B29C55/00 ,  B29C55/12 ,  C08L67/02 ,  G03C1/795 ,  G11B5/73 ,  G11B5/733 ,  H01B3/42 ,  C08G39/02

CPC分类号： H01B3/423 ,  C08L67/02 ,  G03C1/7954 ,  Y10T428/31786

摘要： A biaxially oriented polyethylene-2,6-naphthalate film, which comprises a blended mixture of1. a polyethylene-2,6-naphthalate resin which may contain a unit derived from not more than 10mol% of a polyester-forming component other than a polyethylene-2,6-naphthalate-forming component, and2. 0.5 to 10% by weight, based on the polyethylene-2,6-naphthalate resin (1), of a polyester resin other than the polyethylene-2,6-naphthalate resin (1) in which the amount of the homopolyester unit is at least 90 mol%,Said film having a softing point at least 1.degree.C. higher than the its equilibrium softening point, and a process for its production.

公开(公告)号：US06262184B1

公开(公告)日：2001-07-17

申请号：US09409443

申请日：1999-09-30

申请人： Takeshi Kanamori ,  Hiroshi Urayama ,  Kyohei Takakuwa ,  Makoto Nakamura ,  Yasuo Teraya ,  Sakae Shimotsuma

发明人： Takeshi Kanamori ,  Hiroshi Urayama ,  Kyohei Takakuwa ,  Makoto Nakamura ,  Yasuo Teraya ,  Sakae Shimotsuma

IPC分类号： C08L6702

CPC分类号： C08L67/04 ,  A42B3/06 ,  C08L69/005 ,  C08L2666/18

摘要： The present invention provides a resin composition comprising polylactic acid and aliphatic polyester carbonate, which has practically adequate heat-resistance temperature, moldability, thermostability, solvent resistance and high mechanical strength, as well as a molded article thereof. In the resin composition, the Vicat softening point is 60° C. or more, the tensile modulus of elasticity is 0.9 GPa or more, the modulus in flexure is 0.6 GPa or more, and the mixing ratio of polylactic acid (A) and aliphatic polyester carbonate (B), in terms of the ratio of (A)/(B) by weight, is 95/5 to 5/95. Further, the present invention provides a biodegradable injection-molded article having improvements in mechanical characteristics and impact resistance and superior disposal properties, particularly having strength enough to make it usable as a headgear material for use in helmets. The biodegradable injection-molded article is excellent in impact resistance, comprising mainly polylactic acid (A) and aliphatic polyester (E) and/or aliphatic polyester carbonate (B). This injection-molded article has a flexural strength of 30 MPa or more and an Izod impact strength of 3 kJ/m2 or more, and it is used as helmet headgear.

摘要翻译： 本发明提供了具有实际上足够的耐热温度，成型性，耐热性，耐溶剂性和高机械强度的聚乳酸和脂肪族聚酯碳酸酯的树脂组合物及其成型品。 在树脂组合物中，维卡软化点为60℃以上，拉伸弹性模量为0.9GPa以上，挠曲模量为0.6GPa以上，聚乳酸（A）和脂肪族 聚酯碳酸酯（B）按重量比（A）/（B）计为95/5〜5/95。 此外，本发明提供了具有机械特性和耐冲击性改善以及优异的处置性能的生物降解性注射成型制品，特别是具有足以使其可用作头盔用头盔材料的强度。 生物降解性注射成型品的耐冲击性优异，主要包括聚乳酸（A）和脂肪族聚酯（E）和/或脂肪族聚酯碳酸酯（B）。 该注射成型品的弯曲强度为30MPa以上，Izod冲击强度为3kJ / m 2以上，用作头盔头饰。

公开(公告)号：US3963844A

公开(公告)日：1976-06-15

申请号：US478101

申请日：1974-06-10

申请人： Sakae Shimotsuma ,  Masahiro Hosoi ,  Takatoshi Kuratsuji ,  Shoji Kawase ,  Takeo Shima

发明人： Sakae Shimotsuma ,  Masahiro Hosoi ,  Takatoshi Kuratsuji ,  Shoji Kawase ,  Takeo Shima

IPC分类号： B29C47/00 ,  B29C47/78 ,  B29C47/88 ,  B29D7/01 ,  C08L67/02 ,  F16L9/12

CPC分类号： C08J7/08 ,  B29C47/00 ,  B29C47/0021 ,  B29C47/0026 ,  B29C47/786 ,  B29C47/862 ,  B29C47/88 ,  B29C47/8815 ,  B29C47/8845 ,  B29C47/8875 ,  B29C47/8895 ,  C08J2367/00 ,  C08J2367/02 ,  Y10T428/139 ,  Y10T428/261 ,  Y10T428/268 ,  Y10T428/269 ,  Y10T428/31786

摘要： A thermally stable extrusion-molded article characterized by (1) consisting of a substantially linear polyester in which at least 90 mol% of the total recurring units consist of tetramethylene 2,6-naphthalate units, (2) having a density not in excess of 1.318, and (3) being in the unstretched state.This article is prepared by extruding a melt of a substantially linear polyester in which at least 90 mol% of the total recurring units consist of tetramethylene 2,6-naphthalate units into the form of a molded structure, and cooling the extruded molded structure to room temperature, wherein during the period in which the extruded molded structure is cooled from at least 75%C. to room temperature, the cooling of the molded structure is performed rapidly so that the density of the molded structure does not exceed 1.318.

摘要翻译： 一种热稳定的挤出模塑制品，其特征在于（1）由基本上线性的聚酯组成，其中至少90摩尔％的总重复单元由2,6-萘二甲酸丁二烯酯单元组成，（2）密度不超过 1.318，（3）处于未拉伸状态。

公开(公告)号：US3961008A

公开(公告)日：1976-06-01

申请号：US500503

申请日：1974-08-26

申请人： Takatoshi Kuratsuji ,  Shoji Kawase ,  Takeo Shima ,  Sakae Shimotsuma ,  Masahiro Hosoi

发明人： Takatoshi Kuratsuji ,  Shoji Kawase ,  Takeo Shima ,  Sakae Shimotsuma ,  Masahiro Hosoi

IPC分类号： B29C61/00 ,  B29C47/00 ,  B29C47/78 ,  B29C47/88 ,  B29D7/01 ,  B29C25/00 ,  B29D23/04

CPC分类号： C08J7/08 ,  B29C47/00 ,  B29C47/0021 ,  B29C47/0023 ,  B29C47/0026 ,  B29C47/862 ,  B29C47/88 ,  B29C47/8805 ,  B29C47/8815 ,  B29C47/8845 ,  B29C47/8895 ,  B29C47/0019 ,  C08J2367/00 ,  C08J2367/02

摘要： A process for preparing a shaped article by melt-extruding a polyester containing tetramethylene naphthalene-2,6-dicarboxylate or hexamethylene naphthalene-2,6-dicarboxylate as a main recurring unit, wherein the extrudate is exposed to a temperature of 75.degree. to 450.degree.C. for 1 to 180 seconds immediately after extrusion.

摘要翻译： 通过熔融挤出含有2,6-萘二甲酸2,6-二甲酯或六亚甲基萘-2,6-二羧酸六亚甲酯的聚酯作为主要重复单元制备成型制品的方法，其中将挤出物暴露于75℃至450℃的温度 在挤出后立即进行1至180秒。