摘要:
A bead-like glycidyl (meth)acrylate polymer is produced by aqueous suspension polymerization of glycidyl (meth)acrylate alone or a monomer mixture composed of more than 50 weight % of said monomer and at least one other monomer which forms the remainder, in the presence of a specific aqueous polymer, at a pH of from 2 to 9 and at a stirring speed of from 50 to 500 r.p.m. By heat treating said bead-like polymer at a pH below 3 and at a temperature above 70.degree. C., hydroxyl groups resulting from the ring opening of the epoxy groups are introduced, whereby a solvent-insoluble bead-like polymer having a gel water content not less than 30% is produced.
摘要:
Hard polyvinyl alcohol gel is produced by copolymerizing a carboxylic acid vinyl ester monomer with a particular cross-linking agent and then saponifying the copolymer. This hard polyvinyl alcohol gel has excellent mechanical strength and separation ability and has no problem in copolymerizability and polymerization speed. Moreover, it shows no change in cross-linked structure before and after saponification.
摘要:
The present invention provides chemically stable colloidal antimony oxide which has been treated with a particular organosilicon compound in the ratio of from 0.5 to 25 weight % based on the antimony and whose pH has been regulated to within the range of from 2 to 12.
摘要:
The present invention relates to a process for producing a packing material for use in liquid chromatography which comprises aqueous suspension polymerizing vinyl acetate, a (meth)acrylic acid ester or a glycidyl monovinyl ester or ether with a monomer mixture composed mainly of a cross-linking monomer in the presence of a diluent selected from among epichlorohydrin and glycidyl ethers and thereafter removing it from the resulting polymer particles by ring-opening the epoxy groups in said diluent. This process provides a packing material for use in liquid chromatography which is uniform and porous and moreover is excellent in mechanical strength.
摘要:
A process for copolymerizing acrylonitrile (AN) with an amount of a monomer of a specific structure in an organic solvent which can dissolve AN but cannot dissolve polyacrylonitrile (PAN). The polymer dispersion in the solvent is stable upon storage. The dispersed particles of the polymer are uniform and fine, and are sufficiently prevented from agglomeration and agglutination.
摘要:
Colloidal antimony oxide is produced by reacting hydrogen peroxide with antimony trioxide to form a colloidal salt of antimony oxide. In the reaction there is added to the reaction system 1.5 to 30 mol percent of an inorganic alkaline substance per mol of antimony trioxide.
摘要:
A stannic acid anhydride represented by the structural formula shown below. When said compound as it is, or the same coated on a substrate or impregnated into it, is baked, it is possible to finally form tin oxide which has excellent transparency and conductivity, ##STR1## wherein X represents ##STR2##
摘要:
The present invention provides a gel having excellent separation ability, operability and a long life, for separating useful components from a rhodanate-containing detoxication treated liquid. The gel consists of a cross-linked polymer with more than 50 weight % of repeating units which are composed of 2,3-dioxypropyl (meth)acrylate or 2,3-dioxypropyl (meth)allyl ether, and whose average particle diameter is more than 10.mu. and gel water content is from 30 to 150%. The present invention also provides a method of separation using said gel.
摘要:
By reacting a tin carboxylate with hydrogen peroxide at a particular ratio in an aqueous medium, this invention provides a transparent aqueous tin compound solution which can finally form, in an industrially advantageous manner, tin oxide having excellent transparency, uniformity, compactness, conductivity, etc.
摘要:
This invention provides an aqueous antimony oxide sol composed of Sb.sub.6 O.sub.13, 1 to 100 m.mu. in particle diameter, dispersed in an aqueous medium or composed of said Sb.sub.6 O.sub.13 treated with a particular quantity of a particular organic silicon compound and regulated to within a prescribed pH range, which has a high concentration and a small quantity of impurities, and moreover has excellent thermal stability and chemical stability.
摘要翻译:本发明提供一种由Sb6O13构成的水溶性氧化锑溶胶,其粒径为1〜100μm,分散在水性介质中,或者由用特定有机硅化合物处理的Sb 6 O 13构成,并调节至规定的pH范围 ,具有高浓度和少量杂质,而且具有优异的热稳定性和化学稳定性。