公开(公告)号：US08053588B2

公开(公告)日：2011-11-08

申请号：US12073339

申请日：2008-03-04

Applicant: Norihiro Mizoshita ,  Yasutomo Goto ,  Shinji Inagaki ,  Toyoshi Shimada

Inventor： Norihiro Mizoshita ,  Yasutomo Goto ,  Shinji Inagaki ,  Toyoshi Shimada

IPC: C07F7/04

CPC classification number: C08F30/08 ,  C07F7/1804 ,  C07F9/5325

Abstract: Provided is an organosilane compound expressed by any one of the following general formulae (1) to (7): (wherein: Ar represents a phenylene group or the like; R1 represents a hydrogen atom or the like; R2 to R8 each represent a methyl group or the like; n represents an integer in a range from 0 to 2; m represents an integer of 1 or 2; L represents a single bond or the like; X represents a hydrogen atom or the like; and Y represents a hydrogen atom or the like).

Abstract translation: 提供由以下通式（1）至（7）中的任一个表示的有机硅烷化合物：其中：Ar表示亚苯基等; R 1表示氢原子等; R 2〜R 8表示甲基 基团等; n表示0〜2的整数，m表示1或2的整数，L表示单键等; X表示氢原子等，Y表示氢原子 或类似物）。

公开(公告)号：US09409929B2

公开(公告)日：2016-08-09

申请号：US14129416

申请日：2012-06-28

Applicant: Toyoshi Shimada

Inventor： Toyoshi Shimada

IPC: C07H23/00 ,  C07F7/08 ,  C08B15/05 ,  C08B37/16 ,  C09K3/18 ,  C08K9/06 ,  C08J3/12 ,  C08K9/08 ,  C03C17/30 ,  C09C3/12

CPC classification number: C07F7/0818 ,  C03C17/30 ,  C03C2217/75 ,  C07F7/081 ,  C07F7/0812 ,  C07H23/00 ,  C08B15/05 ,  C08B37/0012 ,  C08J3/126 ,  C08J3/128 ,  C08K9/06 ,  C08K9/08 ,  C09C3/12 ,  C09K3/18

Abstract: A (meth)allylsilane compound chemically bonded to various alcohol derivatives including polyol derivatives such as saccharides, is raw material used to cause a substrate to express functionalities such as a defogging property and separation characteristics for column chromatography, can be easily prepared, is easily purified, and is stable and easy to handle, and a functional material in which those functionalities are expressed, while silyl group-containing groups are conveniently carried at a high density on the surface of the substrate, by using the (meth)allylsilane compound as a silane coupling agent for silane-coupling to the substrate. The (meth)allylsilane compound includes a (meth)allylsilyl group-containing alkyl group or a (meth)allylsilylalkyl group-containing aralkyl group that is bonded to an alcohol derivative. In the functional material, the silane coupling agent is ether-bonded to surface hydroxyl groups exposed on a substrate through the surface hydroxyl groups by silane coupling to have an ether bond on the functional material.

Abstract translation: 化学键合到各种醇衍生物（包括多元醇衍生物如糖类）上的（甲基）烯丙基硅烷化合物可以容易地制备，用于引起底物表达诸如除雾性能和柱色谱分离特性等功能的原料 并且稳定且易于处理，并且通过使用（甲基）烯丙基硅烷化合物作为基质，通过在基材的表面上方便地以高密度方式携带含有甲硅烷基的基团，其中表达这些官能团的官能材料 用于硅烷耦合到基底的硅烷偶联剂。 （甲基）烯丙基硅烷化合物包含（甲基）烯丙基含烷基或与醇衍生物结合的（甲基）丙烯酰基烷基烷基。 在功能材料中，硅烷偶联剂通过硅烷偶联通过表面羟基与基体上露出的表面羟基醚键合，在功能材料上具有醚键。

公开(公告)号：US09228107B2

公开(公告)日：2016-01-05

申请号：US14129824

申请日：2012-06-28

Applicant: Toyoshi Shimada ,  Yoshinori Takamatsu

Inventor： Toyoshi Shimada ,  Yoshinori Takamatsu

IPC: C09D143/04 ,  C07F7/08 ,  C07F7/18 ,  C08F230/08

CPC classification number: C09D143/04 ,  B01J20/286 ,  B01J20/3219 ,  B01J20/3246 ,  B01J20/3257 ,  C03C12/00 ,  C03C15/00 ,  C03C17/30 ,  C03C2217/75 ,  C03C2217/76 ,  C07F7/0803 ,  C07F7/0805 ,  C07F7/081 ,  C07F7/0836 ,  C07F7/0838 ,  C07F7/0874 ,  C07F7/1804 ,  C08F230/08

Abstract: A (meth)allylsilane compound that a functional group of a (meth)allylsilyl group or a halogenosilyl group bonded to the (meth)allylsilyl group via a spacer group is bonded directly or through a divergent spacer group to a dehydrogenated residue of an amino group of an amino group-containing compound; a carbaminic acid ester group or an amide group derived from a dehydrogenated residue of the amino group; an aromatic compound; a polymerizable unsaturated groups; perfluoro group; a dehydrogenated residue of saccharide or a carbohydrate polyol (excluding when the divergent spacer group is an alkylene group, or an alkylene group and an arylene group); a dehydrogenated residue of an amino acid; a halogenosilyl group; or a substituted silyl group in which a halogen of the halogenosilyl group is substituted.

Abstract translation: （甲基）烯丙基甲硅烷基或与间隔基团的（甲基）烯丙基甲硅烷基键合的卤代甲硅烷基的官能团直接或通过发散间隔基团键合到氨基的脱氢残基的（甲基） 的含氨基的化合物; 衍生自氨基脱氢残基的氨基甲酸酯基或酰胺基; 芳香族化合物 可聚合不饱和基团; 全氟基团 糖或碳水化合物多元醇的脱氢残基（不同于发泡间隔基为亚烷基，或亚烷基和亚芳基时）。 氨基酸的脱氢残基; 卤代甲硅烷基; 或卤代甲硅烷基的卤素被取代的取代甲硅烷基。

公开(公告)号：US20140142292A1

公开(公告)日：2014-05-22

申请号：US14129416

申请日：2012-06-28

Applicant: Toyoshi Shimada

Inventor： Toyoshi Shimada

IPC: C07F7/08 ,  C07H23/00

CPC classification number: C07F7/0818 ,  C03C17/30 ,  C03C2217/75 ,  C07F7/081 ,  C07F7/0812 ,  C07H23/00 ,  C08B15/05 ,  C08B37/0012 ,  C08J3/126 ,  C08J3/128 ,  C08K9/06 ,  C08K9/08 ,  C09C3/12 ,  C09K3/18

Abstract: A (meth)allylsilane compound chemically bonded to various alcohol derivatives including polyol derivatives such as saccharides, is raw material used to cause a substrate to express functionalities such as a defogging property and separation characteristics for column chromatography, can be easily prepared, is easily purified, and is stable and easy to handle, and a functional material in which those functionalities are expressed, while silyl group-containing groups are conveniently carried at a high density on the surface of the substrate, by using the (meth)allylsilane compound as a silane coupling agent for silane-coupling to the substrate. The (meth)allylsilane compound includes a (meth)allylsilyl group-containing alkyl group or a (meth)allylsilylalkyl group-containing aralkyl group that is bonded to an alcohol derivative. In the functional material, the silane coupling agent is ether-bonded to surface hydroxyl groups exposed on a substrate through the surface hydroxyl groups by silane coupling to have an ether bond on the functional material.

Abstract translation: 化学键合到各种醇衍生物（包括多元醇衍生物如糖类）上的（甲基）烯丙基硅烷化合物可以容易地制备，用于引起底物表达诸如除雾性能和柱色谱分离特性等功能的原料 并且稳定且易于处理，并且通过使用（甲基）烯丙基硅烷化合物作为基质，通过在基材的表面上方便地以高密度方式携带含有甲硅烷基的基团，其中表达这些官能团的官能材料 用于硅烷耦合到基底的硅烷偶联剂。 （甲基）烯丙基硅烷化合物包含（甲基）烯丙基含烷基或与醇衍生物结合的（甲基）丙烯酰基烷基烷基。 在功能材料中，硅烷偶联剂通过硅烷偶联通过表面羟基与基体上露出的表面羟基醚键合，在功能材料上具有醚键。

公开(公告)号：US20140200311A1

公开(公告)日：2014-07-17

申请号：US14129824

申请日：2012-06-28

Applicant: Toyoshi Shimada ,  Yoshinori Takamatsu

Inventor： Toyoshi Shimada ,  Yoshinori Takamatsu

IPC: C09D143/04 ,  C07F7/08

CPC classification number: C09D143/04 ,  B01J20/286 ,  B01J20/3219 ,  B01J20/3246 ,  B01J20/3257 ,  C03C12/00 ,  C03C15/00 ,  C03C17/30 ,  C03C2217/75 ,  C03C2217/76 ,  C07F7/0803 ,  C07F7/0805 ,  C07F7/081 ,  C07F7/0836 ,  C07F7/0838 ,  C07F7/0874 ,  C07F7/1804 ,  C08F230/08

Abstract: A (meth)allylsilane compound that a functional group of a (meth)allylsilyl group or a halogenosilyl group bonded to the (meth)allylsilyl group via a spacer group is bonded directly or through a divergent spacer group to a dehydrogenated residue of an amino group of an amino group-containing compound; a carbaminic acid ester group or an amide group derived from a dehydrogenated residue of the amino group; an aromatic compound; a polymerizable unsaturated groups; perfluoro group; a dehydrogenated residue of saccharide or a carbohydrate polyol (excluding when the divergent spacer group is an alkylene group, or an alkylene group and an arylene group); a dehydrogenated residue of an amino acid; a halogenosilyl group; or a substituted silyl group in which a halogen of the halogenosilyl group is substituted.

Abstract translation: （甲基）烯丙基甲硅烷基或与间隔基团的（甲基）烯丙基甲硅烷基键合的卤代甲硅烷基的官能团直接或通过发散间隔基团键合到氨基的脱氢残基的（甲基） 的含氨基的化合物; 衍生自氨基脱氢残基的氨基甲酸酯基或酰胺基; 芳香族化合物 可聚合不饱和基团; 全氟基团 糖或碳水化合物多元醇的脱氢残基（不同于发泡间隔基为亚烷基，或亚烷基和亚芳基时）。 氨基酸的脱氢残基; 卤代甲硅烷基; 或卤代甲硅烷基的卤素被取代的取代甲硅烷基。

公开(公告)号：US20090054649A1

公开(公告)日：2009-02-26

申请号：US11992139

申请日：2006-09-21

Applicant: Toyoshi Shimada ,  Yasutomo Goto ,  Shinji Inagaki ,  Norihiro Mizoshita ,  Masamichi Ikai

Inventor： Toyoshi Shimada ,  Yasutomo Goto ,  Shinji Inagaki ,  Norihiro Mizoshita ,  Masamichi Ikai

IPC: C07D221/08 ,  C07F7/08 ,  C07D209/58 ,  C07F7/10

CPC classification number: C07F7/1804

Abstract: Provided is a bridged organosilane, which has a large complex organic group, and which is useful in the synthesis of a mesoporous silica and a light-emitting material, and a production method of the bridged organosilane. The bridged organosilane is expressed by the following general formula (1): [in the formula (1), q represents an integer in a range from 2 to 4, X1— represents a substituent selected from the group consisting of substituents expressed by the following general formulae (2) to (5): (in the formulae (2) to (5), R1 represents alkyl group having 1 to 5 carbon atoms, R2 represents an allyl group, and n represents an integer in a range from 0 to 3, and m represents an integer in a range from 0 to 6), and A1 represents an organic group expressed by, for example, the following general formula (6): (in the formula (6), Y1

Abstract translation: 提供了具有大的络合有机基团的桥连有机硅烷，其可用于合成介孔二氧化硅和发光材料，以及桥连有机硅烷的制备方法。 桥接的有机硅烷由以下通式（1）表示：[式（1）中，q表示2〜4的整数，X 1表示选自下述的取代基 通式（2）〜（5）:(式（2）〜（5）中，R 1表示碳原子数1〜5的烷基，R 2表示烯丙基，n表示0〜 3，m表示0〜6的整数），A1表示由下述通式（6）表示的有机基团：（式（6）中，Y1 <表示的取代基 例如，OC <）]。

公开(公告)号：US20080227939A1

公开(公告)日：2008-09-18

申请号：US12073339

申请日：2008-03-04

Applicant: Norihiro Mizoshita ,  Yasutomo Goto ,  Shinji Inagaki ,  Toyoshi Shimada

Inventor： Norihiro Mizoshita ,  Yasutomo Goto ,  Shinji Inagaki ,  Toyoshi Shimada

IPC: C07F7/10 ,  C07F9/28 ,  C07F15/00 ,  C08F30/02 ,  C08F30/08 ,  C08F30/04

CPC classification number: C08F30/08 ,  C07F7/1804 ,  C07F9/5325

Abstract: Provided is an organosilane compound expressed by any one of the following general formulae (1) to (7): (wherein: Ar represents a phenylene group or the like; R1 represents a hydrogen atom or the like; R2 to R8 each represent a methyl group or the like; n represents an integer in a range from 0 to 2; m represents an integer of 1 or 2; L represents a single bond or the like; X represents a hydrogen atom or the like; and Y represents a hydrogen atom or the like).

Abstract translation: 提供由以下通式（1）至（7）中的任一个表示的有机硅烷化合物：其中：Ar表示亚苯基等; R 1表示氢原子等 R 2至R 8各自表示甲基等; n表示0至2的整数; m表示1或2的整数; L表示单键等; X表示氢原子等，Y表示氢原子等）。

公开(公告)号：US09006484B2

公开(公告)日：2015-04-14

申请号：US12376729

申请日：2007-03-12

Applicant: Toyoshi Shimada ,  Naomi Takenaka ,  Gakuto Goshima ,  Hiroyuki Hosoi

Inventor： Toyoshi Shimada ,  Naomi Takenaka ,  Gakuto Goshima ,  Hiroyuki Hosoi

IPC: C07C55/00 ,  C08G63/00 ,  B01J31/24 ,  C07C45/69 ,  C07F9/50 ,  B01J31/16 ,  C07B53/00 ,  C08F222/10 ,  C08G61/12 ,  C08G63/692

CPC classification number: C07F9/5027 ,  B01J31/1658 ,  B01J31/2452 ,  B01J2231/641 ,  B01J2231/643 ,  B01J2531/0266 ,  B01J2531/822 ,  C07B53/00 ,  C07C45/69 ,  C08F222/1006 ,  C08G61/12 ,  C08G63/00 ,  C08G63/6924 ,  C08G2261/344 ,  C08G2261/413 ,  C07C49/657

Abstract: A polymer having bis(diphenylphosphino)binaphthyl groups that can be used as a catalyst for an addition reaction, especially an asymmetric 1,4-addition reaction, or a reduction reaction, especially an asymmetric reduction reaction, and that can be easily recovered and recycled. The polymer having the bis(diphenylphosphino)binaphthyl groups is one resulting from repetition of a racemic or optically active 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl compound substituted at 5-position thereof with an unsaturated terminal of one (meth)acryloyl group of a compound having multiple (meth)acryloyl groups, that another 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl compound of a next unit is substituted at 5′-position thereof with an unsaturated terminal of another (meth)acryloyl group of the compound having multiple (meth)acryloyl groups so as to have a molecular weight of 1500 to 10000. The reduction catalyst comprises this polymer and a transition metal.

Abstract translation: 具有双（二苯基膦基）联萘基的聚合物，其可用作加成反应的催化剂，特别是不对称的1,4-加成反应或还原反应，特别是不对称还原反应，并且可以容易地回收和回收 。 具有双（二苯基膦基）联萘基的聚合物是由在5-位取代的外消旋或光学活性的2,2'-双（二苯基膦基）-1,1'-联萘化合物与不饱和末端一个 具有多个（甲基）丙烯酰基的化合物的（甲基）丙烯酰基，下一个单元的另一个2,2'-双（二苯基膦基）-1,1'-联萘化合物在其5'-位被不饱和 具有多个（甲基）丙烯酰基的化合物的另一（甲基）丙烯酰基的末端，以具有1500至10000的分子量。还原催化剂包含该聚合物和过渡金属。

公开(公告)号：US20100022800A1

公开(公告)日：2010-01-28

申请号：US12376729

申请日：2007-03-12

Applicant: Toyoshi Shimada ,  Naomi Takenaka ,  Gakuto Goshima ,  Hiroyuki Hosoi

Inventor： Toyoshi Shimada ,  Naomi Takenaka ,  Gakuto Goshima ,  Hiroyuki Hosoi

IPC: C07C55/10 ,  C08G63/692 ,  B01J31/06 ,  C07C45/00

CPC classification number: C07F9/5027 ,  B01J31/1658 ,  B01J31/2452 ,  B01J2231/641 ,  B01J2231/643 ,  B01J2531/0266 ,  B01J2531/822 ,  C07B53/00 ,  C07C45/69 ,  C08F222/1006 ,  C08G61/12 ,  C08G63/00 ,  C08G63/6924 ,  C08G2261/344 ,  C08G2261/413 ,  C07C49/657

Abstract: A polymer having bis(diphenylphosphino)binaphthyl groups that can be used as a catalyst for an addition reaction, especially an asymmetric 1,4-addition reaction, or a reduction reaction, especially an asymmetric reduction reaction, and that can be easily recovered and recycled. The polymer having the bis(diphenylphosphino)binaphthyl groups is one resulting from repetition of a racemic or optically active 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl compound substituted at 5-position thereof with an unsaturated terminal of one (meth)acryloyl group of a compound having multiple (meth)acryloyl groups, that another 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl compound of a next unit is substituted at 5′-position thereof with an unsaturated terminal of another (meth)acryloyl group of the compound having multiple (meth)acryloyl groups so as to have a molecular weight of 1500 to 10000. The reduction catalyst comprises this polymer and a transition metal.

Abstract translation: 具有双（二苯基膦基）联萘基的聚合物，其可用作加成反应的催化剂，特别是不对称的1,4-加成反应或还原反应，特别是不对称还原反应，并且可以容易地回收和回收 。 具有双（二苯基膦基）联萘基的聚合物是由在5-位取代的外消旋或光学活性的2,2'-双（二苯基膦基）-1,1'-联萘化合物与不饱和末端一个 具有多个（甲基）丙烯酰基的化合物的（甲基）丙烯酰基，下一个单元的另一个2,2'-双（二苯基膦基）-1,1'-联萘化合物在其5'-位被不饱和 具有多个（甲基）丙烯酰基的化合物的另一（甲基）丙烯酰基的末端，以具有1500至10000的分子量。还原催化剂包含该聚合物和过渡金属。

公开(公告)号：US07608673B2

公开(公告)日：2009-10-27

申请号：US12073347

申请日：2008-03-04

Applicant: Norihiro Mizoshita ,  Yasutomo Goto ,  Shinji Inagaki ,  Toyoshi Shimada

Inventor： Norihiro Mizoshita ,  Yasutomo Goto ,  Shinji Inagaki ,  Toyoshi Shimada

IPC: C08F130/08

CPC classification number: C07F7/0836 ,  C07F7/1804

Abstract: Provided is an organosilane compound expressed by the following general formula (1): where: Ar represents a divalent aromatic organic group, such as a phenylene group; R1 represents a hydrogen atom or the like; R2 to R6, which may be the same or different from each other, each represent a hydrogen atom or the like; and X represents a reactive substituent, such as a halogen atom.

Abstract translation: 提供由以下通式（1）表示的有机硅烷化合物：其中：Ar表示二价芳族有机基团，例如亚苯基; R1表示氢原子等; 可以相同或不同的R 2〜R 6各自表示氢原子等; X表示反应性取代基，例如卤素原子。