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1.发明授权Increased reactivity of isocyanate terminated polyether prepolymers with metal halide salt complexes of methylenedianiline 失效异氰酸酯封端的聚醚预聚物与亚甲基二苯胺的金属卤化物盐络合物的反应性增加
公开(公告)号：US4814411A
公开(公告)日：1989-03-21
申请号：US153233
申请日：1988-02-08
申请人： Tristram W. Bethea , James Oziomek , Joseph H. Tazewell , Douglas K. Hillshafer , Louis W. Meyer
发明人： Tristram W. Bethea , James Oziomek , Joseph H. Tazewell , Douglas K. Hillshafer , Louis W. Meyer
CPC分类号： C08G18/4841 , C08G18/10 , C08G18/4837
摘要： Increased reactivity of isocyanate terminated polyether prepolymers with metal halide salt complexes of methylenedianiline is obtained when the polyether intermediates are modified to contain an effective amount of ethylene oxide. A desired intermediate is poly(oxypropylene) diol or triol which are modified to contain ethylene oxide units therein and subsequently reacted with a polyisocyanate such as MDI, that is 4,4'-diphenylmethane diisocyanate, or TDI, that is, toluene diisocyanate. A desired metal halide salt complex of methylenedianiline is the sodium chloride salt complex (MDA.sub.3 -NaCl), dispersed in dioctylphthalate (50/50 wt/wt).
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2.发明授权
公开(公告)号：US5955553A
公开(公告)日：1999-09-21
申请号：US136583
申请日：1998-08-19
IPC分类号： C08F2/06 , C08F2/38 , C08F4/70 , C08F136/06
CPC分类号： C08F136/06
摘要： There is disclosed a process for the regulation of the molecular weight of high cis polybutadiene prepared by polymerizing butadiene under solution polymerization conditions employing as the catalyst system a mixture of (a) organoaluminum compounds; (b) organonickel compounds; and (c) fluorine containing compounds; said polymerization being conducted in the presence of alkali or alkaline earth metal salts of organic carboxylic acids.
摘要翻译： 公开了一种通过在溶液聚合条件下聚合丁二烯制备的高顺式聚丁二烯的分子量的方法，该方法使用（a）有机铝化合物作为催化剂体系， （b）有机锡化合物; 和（c）含氟化合物; 所述聚合在有机羧酸的碱金属或碱土金属盐的存在下进行。
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公开(公告)号：US20110171078A1
公开(公告)日：2011-07-14
申请号：US12982278
申请日：2010-12-30
CPC分类号： C07C11/167 , B01F3/04078 , B01F5/0696
摘要： A humidification system (A) for humidifying a dry hydrocarbon stream includes a column (10) which defines an interior cavity (20). The cavity is partially filled with a bed (12) of a packing material (40) and a layer of water (20), leaving a headspace above the water. An inlet (52) adjacent a lower end of the cavity receives a dry hydrocarbon stream which is broken up by the packing material and dissolves water as it passes therethrough. Entrained water droplets fall out of the wet blend in a disengagement zone (70) above the water layer leaving the hydrocarbon stream humidified yet substantially free of liquid water in an upper region (72) of the column.
摘要翻译： 用于加湿干烃流的加湿系统（A）包括限定内部空腔（20）的塔（10）。 空腔部分地填充有包装材料（40）的床（12）和一层水（20），在水面上留下顶部空间。 与空腔下端相邻的入口（52）接收由包装材料分解的干烃流，并在其通过时溶解水。 夹带的水滴在水层上方的分离区（70）中从湿共混物中脱落，使烃流在塔的上部区域（72）中被加湿而基本上没有液态水。
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4.发明授权公开(公告)号：US07465768B2
公开(公告)日：2008-12-16
申请号：US11137602
申请日：2005-05-25
申请人： James E. Hall , James Oziomek
发明人： James E. Hall , James Oziomek
IPC分类号： C08F297/04 , C08L47/00
摘要： A novel method of preparing carboxyl-terminated polymers. A monomer is mixed with an organolithium initiator in a hydrocarbon solvent so as to anionically polymerize linear living polymer lithium chains. A trialkyl aluminum compound is also mixed so as to form polymer lithium: aluminate complexes in equilibrium with the linear living polymer lithium chains. When a cyclic anhydride terminator is mixed, the cyclic anhydride terminator preferentially reacts with the C—Li center on a living polymer lithium chain rather than with the C—Al—Li center on a polymer lithium: aluminate complex.
摘要翻译： 一种制备羧基封端聚合物的新方法。 将单体与烃溶剂中的有机锂引发剂混合以使线性活性聚合物锂链阴离子聚合。 还将三烷基铝化合物混合以形成与线性活性聚合物锂链平衡的聚合物锂：铝酸盐络合物。 当环酸酐终止剂混合时，环酐终止剂优先与活性聚合物锂链上的C-Li中心反应，而不是与聚合物锂：铝酸盐络合物上的C-Al-Li中心反应。
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5.发明授权Method of converting anionic living end to protected free radical living end and applications thereof 有权将阴离子活性终端转化为受保护的自由基生物体的方法及其应用公开(公告)号：US07279527B2
公开(公告)日：2007-10-09
申请号：US11112997
申请日：2005-04-22
申请人： James Harwood , James Oziomek , David F. Lawson , James E. Hall
发明人： James Harwood , James Oziomek , David F. Lawson , James E. Hall
IPC分类号： C08F281/00 , C08F36/00
CPC分类号： C08F2/38 , C08C19/44 , C08F36/04 , C08F279/02 , C08F279/04 , C08F293/005 , C08F295/00 , C08F297/02 , C08L51/04 , C08L53/00 , C08L55/02 , C08F4/48
摘要： Provided is a method of converting an anionic living end to a protected free radical “living” end in a well-controlled manner, which enables copolymerization by plural mechanisms. The method is particularly useful for copolymerization of anionically polymerizable monomers and free radical polymerizable monomers, and therefore useful for production of PB-g-PS, HIPS, ABS, and MBS etc. Also provided is a reversibly coupled polymer, which, when decoupled, generates “living” free radical for further copolymer chain reaction.
摘要翻译： 提供了以良好控制的方式将阴离子活性末端转化为受保护的自由基“活性”末端的方法，其能够通过多种机理进行共聚。 该方法特别可用于阴离子聚合单体和可自由基聚合单体的共聚，因此可用于生产PB-g-PS，HIPS，ABS和MBS等。还提供了可逆耦合的聚合物，当分离时， 产生“活”自由基进一步进行共聚物链反应。
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公开(公告)号：US06444734B1
公开(公告)日：2002-09-03
申请号：US09723968
申请日：2000-11-28
IPC分类号： C08K515
CPC分类号： C08K3/36 , B60C1/0016 , C08K5/151 , C08L21/00
摘要： A silica-filled, vulcanized elastomeric compound comprises 100 parts by weight of an elastomer; from about 5 to about 100 parts by weight of a reinforcing filler per 100 parts of elastomer, wherein the reinforcing fillers are selected from the group consisting of carbon black and silica filler; from 0 to about 20 percent by weight of a silane, based upon the weight of the silica filler; a cure agent; from about 0 to about 20 parts by weight of a processing aid selected from the group consisting of fatty acid esters of hydrogenated and non-hydrogenated C5 and C6 sugars; from about 0 to about 20 parts by weight of a processing aid selected from the group consisting of polyoxyethylene derivatives of fatty acid esters of hydrogenated and non-hydrogenated C5 and C6 sugars; from about 0 to about 40 parts by weight of an additional filler other than silica or carbon black, with the provisos that at least one of the processing aids or additional fillers are present; that if the processing aid is sorbitan monooleate, then at least one of the polyoxyethylene derivatives or additional fillers is also present and, that the minimal amount for each processing aid and additional filler, if present, is about one part by weight. A process for the preparation of silica filled vulcanizable elastomers is provided as well as pneumatic tires employing tread stock comprising the novel vulcanizable elastomers.
摘要翻译： 二氧化硅填充的硫化弹性体混合物包含100重量份的弹性体; 每100份弹性体约5至约100重量份的增强填料，其中所述增强填料选自炭黑和二氧化硅填料; 0至约20重量％的硅烷，基于二氧化硅填料的重量; 治愈剂; 约0至约20重量份的选自氢化和非氢化C5和C6糖的脂肪酸酯的加工助剂; 约0至约20重量份的选自氢化和非氢化C5和C6糖的脂肪酸酯的聚氧乙烯衍生物的加工助剂; 约0至约40重量份的除二氧化硅或炭黑之外的另外的填料，条件是存在至少一种加工助剂或另外的填料; 如果加工助剂是脱水山梨糖醇单油酸酯，那么还存在至少一种聚氧乙烯衍生物或另外的填料，并且每种加工助剂和另外的填料（如果存在的话）的最小量为约1重量份。 提供了制备二氧化硅填充的可硫化弹性体的方法，以及使用包含新型可硫化弹性体的胎面胶料的充气轮胎。
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7.发明授权Diene polymers and copolymers incorporating partial coupling and terminals formed from hydrocarboxysilane compounds 有权二烯聚合物和共聚物结合部分偶联和由烃基甲硅烷化合物形成的末端公开(公告)号：US06228908B1
公开(公告)日：2001-05-08
申请号：US09229025
申请日：1999-01-12
申请人： Hideo Takeichi , Daniel F. Graves , Sunil B. Sarkar , David F. Lawson , William L. Hergenrother , William M. Cole , James Oziomek
发明人： Hideo Takeichi , Daniel F. Graves , Sunil B. Sarkar , David F. Lawson , William L. Hergenrother , William M. Cole , James Oziomek
IPC分类号： C08K515
CPC分类号： C08L7/00 , B60C1/0016 , C08C19/44 , C08K3/36 , C08K5/151 , C08K5/1535 , C08L9/00 , C08L9/06 , C08L15/00 , C08L19/006 , Y02T10/862 , C08L21/00 , C08L2666/08
摘要： Diene polymers or copolymers having improved balance between raw polymer viscosity and mixed compound viscosity, useful in tire tread compositions having highly balanced wet traction, rolling resistance, and traction in ice and snow, and fracture properties in the cured and white carbon reinforced states are provided. These diene polymers or copolymers comprise a mixture of diene polymer or copolymer chains containing carbon-tin bonds in the main polymer or copolymer chains and diene polymer or copolymer chains containing terminals derived from hydrocarboxysilane compounds. The diene polymer or copolymers are prepared by first coupling a portion of the living diene polymer or copolymer chains obtained by anionic polymerization using a tin polyhalide coupling agent and then terminating the remaining living diene polymer or copolymer chains using hydrocarboxysilane compounds. The resultant diene polymers or copolymers have improved balance between raw polymer viscosity and mixed compound viscosity when compounded with silica and/or carbon black and cured compositions are useful in tire tread having highly balanced wet traction, rolling resistance, and traction in ice and snow. The polymers can be utilized to form elastomer compositions for tire treads having balanced properties of reduced rolling resistance and wet traction and handling or balanced properties of wet traction and handling and traction in snow and ice.
摘要翻译： 本发明提供了在具有高均衡湿牵引力，滚动阻力和冰雪牵引力的轮胎胎面组合物中有用的原始聚合物粘度和混合化合物粘度之间的改进平衡的二烯聚合物或共聚物，以及固化和白色碳增强状态下的断裂性能 。 这些二烯聚合物或共聚物包含在主聚合物或共聚物链中含有碳 - 锡键的二烯聚合物或共聚物链的混合物，以及含有衍生自烃基甲硅烷化合物的末端的二烯聚合物或共聚物链。二烯聚合物或共聚物通过首先将 通过使用多卤化锡偶合剂的阴离子聚合得到的活性二烯聚合物或共聚物链的一部分，然后使用烃基甲硅烷化合物终止剩余的活性二烯聚合物或共聚物链。 所得到的二烯聚合物或共聚物在与二氧化硅和/或炭黑混合时与原料聚合物粘度和混合化合物粘度之间具有改善的平衡，并且固化的组合物可用于具有高均衡的湿牵引力，滚动阻力和在冰雪中的牵引力的轮胎胎面。 聚合物可用于形成用于轮胎胎面的弹性体组合物，其具有降低的滚动阻力和湿牵引力和处理性能的平衡性能或湿牵引和处理以及雪和冰中牵引的平衡性能。
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公开(公告)号：US06180710B2
公开(公告)日：2001-01-30
申请号：US09247375
申请日：1999-02-10
IPC分类号： C08K300
CPC分类号： B60C1/0016 , B60C1/00 , C08K3/36 , Y02T10/862 , C08L21/00
摘要： Incorporation of neutral water soluble inorganic salts into a precipitated silica improves the filler dispersion in a compounded rubber, reduces rolling resistance (hysteresis), and improves processability. These properties are achieved without loss of the expected reinforcement effect due to the substitution of inorganic salt for SiO2 in the silica. The properties are seen when a variety of silanes and processing aids are added to the silica.
摘要翻译： 将中性水溶性无机盐掺入沉淀二氧化硅改善了复合橡胶中的填料分散，降低了滚动阻力（滞后），并提高了加工性能。 由于在二氧化硅中用无机盐代替SiO 2，这些性能实现而不会损失预期的增强效果。 当将多种硅烷和加工助剂添加到二氧化硅中时，可以看到性能。
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公开(公告)号：US5872176A
公开(公告)日：1999-02-16
申请号：US893867
申请日：1997-07-11
CPC分类号： B60C1/0016 , B60C1/00 , C08K3/36
摘要： Incorporation of neutral water soluble inorganic salts into a precipitated silica improves the filler dispersion in a compounded rubber, reduces rolling resistance (hysteresis), and improves processability. These properties are achieved without loss of the expected reinforcement effect due to the substitution of inorganic salt for SiO.sub.2 in the silica. The properties are seen when a variety of silanes and processing aids are added to the silica.
摘要翻译： 将中性水溶性无机盐掺入沉淀二氧化硅改善了复合橡胶中的填料分散，降低了滚动阻力（滞后），并提高了加工性能。 由于在二氧化硅中用无机盐代替SiO 2，这些性能实现而不会损失预期的增强效果。 当将多种硅烷和加工助剂添加到二氧化硅中时，可以看到性能。
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10.发明授权Adhering cured polymers or prepolymers to high natural rubber content elastomer 失效将固化的聚合物或预聚物粘附到高天然橡胶含量的弹性体上
公开(公告)号：US4465535A
公开(公告)日：1984-08-14
申请号：US531317
申请日：1983-09-12
IPC分类号： B29C73/02 , B29C35/00 , B29C73/00 , B29C73/10 , B29K21/00 , B29L30/00 , C08J5/12 , C08J7/12 , B29H5/16 , B60C21/02 , B60C21/06
CPC分类号： C08J7/126 , B29C73/10 , C08J5/12 , C08J2321/00 , Y10T152/10495 , Y10T152/10909 , Y10T428/31569 , Y10T428/31826
摘要： In repairing articles of natural rubber or elastomer predominantly of natural rubber with cured polymer or prepolymer (polyurethane/polyurea), adhering advantages are obtained especially at elevated temperatures when the damaged area is treated with halogen-containing oxidant dissolved in 1,2-dichloroethane instead of other solvents.
摘要翻译： 在用固化的聚合物或预聚物（聚氨酯/聚脲）主要由天然橡胶制成的天然橡胶或弹性体的制品中，特别是在用溶解在1,2-二氯乙烷中的含卤素氧化剂处理损伤区域的情况下，特别是在升高的温度下， 的其他溶剂。
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