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1.发明授权
公开(公告)号：US5861108A
公开(公告)日：1999-01-19
申请号：US673093
申请日：1996-07-01
申请人： Tsutomu Ishida , Atsuo Otsuji , Yoshiyuki Totani , Motokazu Hirao , Hiroe Kayashima , Masakatsu Nakatsuka
发明人： Tsutomu Ishida , Atsuo Otsuji , Yoshiyuki Totani , Motokazu Hirao , Hiroe Kayashima , Masakatsu Nakatsuka
CPC分类号： C09K19/0225 , C07C69/94 , C09K19/02 , C09K19/322 , C09K19/3444
摘要： Provided is a naphthalene compound represented by the following Formula (1): ##STR1## wherein R.sub.1 and R.sub.2 each represent a linear or branched alkyl group having 1 to 20 carbon atoms, an alkoxyalkyl group having 2 to 20 carbon atoms or an alkenyl group having 2 to 20 carbon atoms which may be substituted with halogen atoms and have no asymmetric carbon atoms; A represents any of the groups represented by the following formulas: ##STR2## (wherein X.sub.1, X.sub.2, X.sub.3 and X.sub.4 each represent a hydrogen atom or a halogen atom); and z represents 0 or 1. The addition of this naphthalene compound to a liquid crystal composition makes it possible to improve various characteristics such as the high speed response property of the liquid crystal composition and the temperature dependency of the response time. The above naphthalene compound is useful as a liquid crystal material for liquid crystal compositions, particularly ferroelectric liquid crystal compositions.
摘要翻译： 提供由下式（1）表示的萘化合物：其中R 1和R 2各自表示具有1至20个碳原子的直链或支链烷基，具有2至20个碳原子的烷氧基烷基或 可以被卤素原子取代并且不具有不对称碳原子的具有2-20个碳原子的烯基; A表示由下式表示的任何基团：其中X 1，X 2，X 3和X 4各自表示氢原子或卤原子; z表示0或1.通过将该萘化合物加入到液晶组合物中，可以提高液晶组合物的高速响应特性和响应时间的温度依赖性等各种特性。 上述萘化合物可用作液晶组合物的液晶材料，特别是铁电液晶组合物。
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2.发明授权Pyrimidine compound and liquid crystal composition and liquid crystal element using the same 失效嘧啶化合物和液晶组合物及使用其的液晶元件
公开(公告)号：US5770108A
公开(公告)日：1998-06-23
申请号：US668157
申请日：1996-06-21
申请人： Yoshiyuki Totani , Motokazu Hirao , Atsuo Otsuji , Tsutomu Ishida , Hiroe Kayashima , Masakatsu Nakatsuka
发明人： Yoshiyuki Totani , Motokazu Hirao , Atsuo Otsuji , Tsutomu Ishida , Hiroe Kayashima , Masakatsu Nakatsuka
IPC分类号： C07D239/26 , C07D239/28 , C07D239/34 , C07D401/10 , C07D401/12 , C09K19/34 , C07D239/02 , C09K19/32 , C07D69/76
CPC分类号： C07D239/26 , C07D239/28 , C07D239/34 , C07D401/10 , C07D401/12 , C09K19/3458 , C09K19/3463 , C09K19/3466 , C09K19/3469
摘要： A novel pyrimidine compound represented by the following Formulas (1) and (2), a liquid crystal composition containing said compound and a liquid crystal element having excellent characteristics such as high speed response, orientation and high contrast ratio. ##STR1## wherein R.sub.1 and R.sub.2 each represent a linear or branched alkyl or alkenyl group, an alkoxyl or alkenyloxy group; R.sub.3 and R.sub.4 each represent a linear or branched alkyl group or alkenyl group; A.sub.1 and A.sub.2 each represent a substituted or unsubstituted 1,4-phenylene group, a pyridine-2,5-diyl or trans-1,4-cyclohexylene group; X.sub.1 and X.sub.2 each represent a single bond, --COO--, --OCO--, --OCH.sub.2 or --CH.sub.2 O-- group; Y.sub.1 and Y.sub.2 each represent --COO-- or --OCO-- group; and a, b, p, q, m and n each represent 0 or 1, provided that a+b+p+q is not 0.
摘要翻译： 一种由下式（1）和（2）表示的新型嘧啶化合物，含有所述化合物的液晶组合物和具有优异特性如高速响应，取向和高对比度的液晶元件。 （1）其中R1和R2各自表示直链或支链烷基或链烯基，烷氧基或烯氧基; R3和R4各自表示直链或支链烷基或烯基; A1和A2各自表示取代或未取代的1,4-亚苯基，吡啶-2,5-二基或反式-1,4-亚环己基; X1和X2各自表示单键，-COO-，-OCO-，-OCH2或-CH2O-基团; Y1和Y2各自表示-COO-或-OCO-基团; 并且a，b，p，q，m和n各自表示0或1，条件是a + b + p + q不为0。
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3.发明授权Fluoran compounds, crystalline toluene adducts thereof, recording material comprising same and process for their preparation 失效氟化合物，其结晶甲苯加合物，包含其的记录材料及其制备方法
公开(公告)号：US5324704A
公开(公告)日：1994-06-28
申请号：US037847
申请日：1993-03-29
IPC分类号： B41M5/145 , B41M5/327 , C07D493/10 , B41M5/20 , C07D311/78
CPC分类号： B41M5/1455 , B41M5/3275 , C07D493/10
摘要： Disclosed are novel fluoran compounds represented by the formula (I): ##STR1## wherein R.sub.1 and R.sub.2 are different groups selected from cyclohexyl, n-butyl and isobutyl, e.g., in the form of crystals characterized by a specific X-ray diffraction diagram; crystalline toluene adducts thereof; and recording materials containing these fluoran compounds.
摘要翻译： 公开了由式（I）表示的新型荧烷化合物：其中R 1和R 2是选自环己基，正丁基和异丁基的不同基团，例如以特征X射线 衍射图; 其结晶甲苯加合物; 和含有这些荧烷化合物的记录材料。
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4.发明授权Process for preparation of a recording material comprising a novel crystal of a fluoran compound 失效制备包含荧烷化合物的新晶体的记录材料的方法
公开(公告)号：US5300661A
公开(公告)日：1994-04-05
申请号：US094727
申请日：1993-07-21
IPC分类号： B41M5/145 , B41M5/327 , C07D493/10 , C07D311/88
CPC分类号： B41M5/3275 , B41M5/1455 , C07D493/10
摘要： Disclosed are novel crystal of the fluoran compound represented by the formula (I) ##STR1## ,characterized by a specific X-ray diffraction diagram; preparation process thereof; and recording materials comprising the crystal.
摘要翻译： 公开了由式（I）＆lt; IMAGE＆gt;表示的荧烷化合物的新晶体，其特征在于特定的X射线衍射图; 其制备方法; 和包含晶体的记录材料。
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5.发明授权Fluoran compound, heat sensitive recording materials comprising fluoran compound 失效氟族化合物，包含荧烷化合物的热敏记录材料
公开(公告)号：US5231069A
公开(公告)日：1993-07-27
申请号：US985723
申请日：1992-12-04
IPC分类号： B41M5/327 , C07D493/10
CPC分类号： B41M5/3275 , C07D493/10
摘要： Heat-sensitive recording paper which employs as a chromogenic compound a novel fluoran compound represented by the formula: ##STR1## and prepared reacting a benzoic acid derivative of the formula: ##STR2## with a diphenylamine derivative of the formula: ##STR3## wherein R is a lower alkyl group have excellent stability.
摘要翻译： 使用作为显色化合物的新型荧光化合物的热敏记录纸，其由下式表示：制备下式的苯甲酸衍生物与下式的二苯胺衍生物反应：其中R 是低级烷基具有优异的稳定性。
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公开(公告)号：US5391806A
公开(公告)日：1995-02-21
申请号：US131549
申请日：1993-10-05
申请人： Atsuo Otsuji , Toshihiro Motoshima , Yoshimitsu Tanabe , Kiyoharu Hasegawa , Kazuyoshi Kikkawa , Masakatsu Nakatsuka , Akihiro Yamaguchi
发明人： Atsuo Otsuji , Toshihiro Motoshima , Yoshimitsu Tanabe , Kiyoharu Hasegawa , Kazuyoshi Kikkawa , Masakatsu Nakatsuka , Akihiro Yamaguchi
IPC分类号： B41M5/337 , B41M5/30 , B41M5/333 , C07C39/00 , C07C271/28 , C07C271/58 , C07C317/22 , C07C317/42 , C07C323/20 , C07C323/43 , C07C333/08 , C09B11/28 , C09K9/00
CPC分类号： C07C333/08 , B41M5/3335 , C07C271/28 , C07C271/58 , C07C317/22 , C07C323/20 , C07C323/43 , B41M5/3333 , B41M5/3336 , C07C2101/14
摘要： Heat-sensitive recording materials contain an electron-donating chromogenic compound and an electron-attracting compound. The recording materials also contain at least one compound represented by the following formula: ##STR1## wherein R.sub.1 and R.sub.3 mean a hydrogen atom or an alkyl, aralkyl or aryl group, R.sub.2 and R.sub.4 denote an alkyl, alkenyl, aralkyl or aryl group, X.sub.1, X.sub.2, Y.sub.1 and Y.sub.2 stand for an oxygen or a sulfur atom, and --Z.sub.1 -- and --Z.sub.2 -- are a specific aromatic group. Also provided are phenol compounds represented by the following formula: ##STR2## wherein R.sub.1, R.sub.2, X.sub.1 and Y.sub.1 have the same meanings as defined above; R.sub.5 and R.sub.6 are a hydrogen or halogen atom or an alkyl, alkoxy, aralkyl, aryl or hydroxyl group; p and q stand for an integer of 1-4; R.sub.5 and R.sub.6 may be either the same or different when p and q represent an integer of 2 or greater; and --Z.sub.3 -- means a specific divalent group.
摘要翻译： 热敏记录材料含有给电子显色化合物和吸电子化合物。 记录材料还含有至少一种由下式表示的化合物：其中R 1和R 3表示氢原子或烷基，芳烷基或芳基，R 2和R 4表示烷基，烯基，芳烷基或芳基，X 1 ，X2，Y1和Y2表示氧或硫原子，-Z1和-Z2-是特定的芳族基团。 还提供了由下式表示的酚化合物：其中R1，R2，X1和Y1具有与上述相同的含义; R5和R6是氢或卤素原子或烷基，烷氧基，芳烷基，芳基或羟基; p和q代表1-4的整数; 当p和q表示2或更大的整数时，R 5和R 6可以相同或不同; 和-Z 3 - 表示特定的二价基团。
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7.发明授权
公开(公告)号：US5306688A
公开(公告)日：1994-04-26
申请号：US946694
申请日：1992-09-18
申请人： Yoshimitsu Tanabe , Yuki Kobayashi , Atsuo Otsuji , Masakatsu Nakatsuka , Kiyoharu Hasegawa , Kazuyoshi Kikkawa , Akihiro Yamaguchi , Naomasa Koike , Fumio Okumura
发明人： Yoshimitsu Tanabe , Yuki Kobayashi , Atsuo Otsuji , Masakatsu Nakatsuka , Kiyoharu Hasegawa , Kazuyoshi Kikkawa , Akihiro Yamaguchi , Naomasa Koike , Fumio Okumura
IPC分类号： B41M5/30 , B41M5/333 , C07C271/28 , C07C271/58 , C07C333/08 , C07C333/24 , B41M5/32
CPC分类号： C07C333/24 , B41M5/3335 , C07C271/28 , C07C271/58 , C07C333/08 , B41M5/3336
摘要： A heat-sensitive recording material comprising a color forming, electron donating compound and a salicylic acid derivative represented by the formula (1): ##STR1## wherein X.sub.1 and X.sub.2 are a hydrogen atom, an alkyl group, an alkoxy group, an aralkyl group, an aryl group or a halogen atom, Y.sub.1 and Y.sub.2 are an oxygen atom or a sulfur atom, R.sub.1 is a hydrogen atom, an alkyl group, an aralkyl group or an aryl group , and R.sub.2 is an alkyl group, an alkenyl group, an aralkyl group or an aryl group, and/or a metal salt of the salicylic acid derivative as an electron accepting compound, is disclosed.
摘要翻译： 一种热敏记录材料，其包含成色剂，给电子化合物和由式（1）表示的水杨酸衍生物：（*化学结构*）（I）其中X 1和X 2是氢原子，烷基， 烷氧基，芳烷基，芳基或卤素原子，Y1和Y2为氧原子或硫原子，R1为氢原子，烷基，芳烷基或芳基，R2为烷基 基团，烯基，芳烷基或芳基，和/或作为电子接受性化合物的水杨酸衍生物的金属盐。
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8.发明授权Recording material comprising novel crystalline fluoran and process for prepartion of the said crystalline fluoran 失效包含新型结晶荧烷的记录材料和用于制备所述结晶荧烷的方法
公开(公告)号：US5283222A
公开(公告)日：1994-02-01
申请号：US949932
申请日：1992-09-24
IPC分类号： B41M5/145 , B41M5/327 , C07D493/10 , B41M5/15 , B41M5/165
CPC分类号： B41M5/3275 , B41M5/1455 , C07D493/10
摘要： Disclosed are novel crystal of the fluoran compound represented by the formula (I) ##STR1## , characterized by a specific X-ray diffraction diagram; preparation process thereof; and recording materials comprising the crystal.
摘要翻译： 公开了由式（I）＆lt; IMAGE＆gt;表示的荧烷化合物的新晶体，其特征在于特定的X射线衍射图; 其制备方法; 和包含晶体的记录材料。
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9.发明授权Crystals of fluoran compound, crystalline solvates thereof and process for their preparation 失效氟化合物的晶体，其结晶溶剂及其制备方法
公开(公告)号：US5245049A
公开(公告)日：1993-09-14
申请号：US729299
申请日：1991-07-12
CPC分类号： C09B11/24 , B41M5/1455 , B41M5/3275
摘要： Disclosed are a crystal and crystalline solvate of a fluoran compound represented by the formula ##STR1## wherein R.sub.1 is ##STR2## and which are useful as chromogenic compounds in recording materials such as pressure-sensitive and heat-sensitive recording materials, a process for preparation of said crystal and said crystalline solvate, and recording materials comprising said crystal or said crystalline solvate.
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10.发明授权
公开(公告)号：US5220038A
公开(公告)日：1993-06-15
申请号：US553834
申请日：1990-07-18
IPC分类号： B41M5/145 , B41M5/327 , C07D493/10
CPC分类号： B41M5/1455 , B41M5/3275 , C07D493/10
摘要： Disclosed are novel fluoran compounds represented by the formula (I): ##STR1## wherein R.sub.1 and R.sub.2 are different groups selected from cyclohexyl, n-butyl and isobutyl, e.g., in the form of crystals characterized by a specific X-ray diffraction diagram; crystalline toluene adducts thereof; and recording materials containing these fluoran compounds.
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