公开(公告)号：US10336944B2

公开(公告)日：2019-07-02

申请号：US15711634

申请日：2017-09-21

Applicant: University of South Carolina

Inventor： Fanglin Chen ,  Libin Lei ,  Tong Liu ,  Shumin Fang

IPC: C25B1/04 ,  C25B9/00 ,  C25B9/08 ,  C25B9/06 ,  C10G2/00 ,  C25B3/04 ,  B01J23/10 ,  B01J23/78 ,  C25B15/02 ,  C25B15/08 ,  C25B9/10 ,  C07C1/12 ,  C07C1/10

Abstract: A hydrocarbon generation system that combines a solid oxide electrolysis cell (SOEC) and a Fischer-Tropsch unit in a single microtubular reactor is described. This system can directly synthesize hydrocarbons from carbon dioxide and water. High temperature co-electrolysis of H2O and CO2 and low temperature Fischer-Tropsch (F-T) process are integrated in a single microtubular reactor by designation of a temperature gradient along the axial length of the microtubular reactor. The microtubular reactor can provide direct conversion of CO2 to hydrocarbons for use as feedstock or energy storage.

公开(公告)号：US09687775B2

公开(公告)日：2017-06-27

申请号：US14678372

申请日：2015-04-03

Applicant: University of South Carolina

Inventor： Fanglin Chen ,  Shumin Fang ,  Kyle S. Brinkman

IPC: B01D53/22 ,  B01D67/00 ,  B01D71/02 ,  B01D69/12 ,  C01B3/50 ,  B22F3/12 ,  B22F5/00 ,  B01D69/14 ,  C22C1/05 ,  C22C29/12 ,  H01M8/124

CPC classification number: B01D53/22 ,  B01D53/228 ,  B01D67/0041 ,  B01D67/0083 ,  B01D69/12 ,  B01D69/141 ,  B01D71/022 ,  B01D71/024 ,  B01D2256/16 ,  B01D2323/08 ,  B01D2323/12 ,  B01D2325/20 ,  B22F3/12 ,  B22F5/006 ,  B22F2998/10 ,  C01B3/503 ,  C01B2203/0233 ,  C01B2203/0405 ,  C01B2203/0475 ,  C01B2203/0495 ,  C22C1/05 ,  C22C29/12 ,  H01M8/124 ,  H01M2300/0091 ,  Y02P70/56 ,  B22F3/1017 ,  B22F3/101 ,  B22F2201/02 ,  B22F2201/11 ,  B22F2201/013

Abstract: A hydrogen permeation membrane is provided that can include a metal and a ceramic material mixed together. The metal can be Ni, Zr, Nb, Ta, Y, Pd, Fe, Cr, Co, V, or combinations thereof, and the ceramic material can have the formula: BaZr1-x-yYxTyO3-δ where 0≦x≦0.5, 0≦y≦0.5, (x+y)>0; 0≦δ≦0.5, and T is Sc, Ti, Nb, Ta, Mo, Mn, Fe, Co, Ni, Cu, Zn, Ga, In, Sn, or combinations thereof. A method of forming such a membrane is also provided. A method is also provided for extracting hydrogen from a feed stream.

公开(公告)号：US20150314232A1

公开(公告)日：2015-11-05

申请号：US14678372

申请日：2015-04-03

Applicant: University of South Carolina

Inventor： Fanglin Chen ,  Shumin Fang ,  Kyle S. Brinkman

IPC: B01D53/22 ,  B01D67/00 ,  B22F5/00 ,  B01D71/02 ,  B22F3/12 ,  C01B3/50 ,  B01D69/12

CPC classification number: B01D53/22 ,  B01D53/228 ,  B01D67/0041 ,  B01D67/0083 ,  B01D69/12 ,  B01D69/141 ,  B01D71/022 ,  B01D71/024 ,  B01D2256/16 ,  B01D2323/08 ,  B01D2323/12 ,  B01D2325/20 ,  B22F3/12 ,  B22F5/006 ,  B22F2998/10 ,  C01B3/503 ,  C01B2203/0233 ,  C01B2203/0405 ,  C01B2203/0475 ,  C01B2203/0495 ,  C22C1/05 ,  C22C29/12 ,  H01M8/124 ,  H01M2300/0091 ,  Y02P70/56 ,  B22F3/1017 ,  B22F3/101 ,  B22F2201/02 ,  B22F2201/11 ,  B22F2201/013

Abstract: A hydrogen permeation membrane is provided that can include a metal and a ceramic material mixed together. The metal can be Ni, Zr, Nb, Ta, Y, Pd, Fe, Cr, Co, V, or combinations thereof, and the ceramic material can have the formula: BaZr1-x-yYxTyO3-δ where 0≦x≦0.5, 0≦y≦0.5, (x+y)>0; 0≦δ≦0.5, and T is Sc, Ti, Nb, Ta, Mo, Mn, Fe, Co, Ni, Cu, Zn, Ga, In, Sn, or combinations thereof. A method of forming such a membrane is also provided. A method is also provided for extracting hydrogen from a feed stream.

Abstract translation: 提供了可以包括混合在一起的金属和陶瓷材料的氢渗透膜。 金属可以是Ni，Zr，Nb，Ta，Y，Pd，Fe，Cr，Co，V或它们的组合，陶瓷材料可以具有下式：BaZr1-x-yYxTyO3-δ其​​中0＆nlE; x＆nlE; 0.5 ，0＆nlE; y＆nlE; 0.5，（x + y）> 0; 0＆nlE;δ＆nlE; 0.5，T是Sc，Ti，Nb，Ta，Mo，Mn，Fe，Co，Ni，Cu，Zn，Ga，In，Sn或其组合。 还提供了形成这种膜的方法。 还提供了用于从进料流中提取氢的方法。

公开(公告)号：US10899613B2

公开(公告)日：2021-01-26

申请号：US16158366

申请日：2018-10-12

Applicant: University of South Carolina ,  CLEMSON UNIVERSITY

Inventor： Fanglin Chen ,  Shumin Fang ,  Kyle Brinkman ,  Siwei Wang ,  Jian He ,  Yufei Liu

IPC: C01B3/50 ,  C04B35/50 ,  B01D53/32 ,  B01D67/00 ,  B01D53/22 ,  C04B35/80 ,  B01D69/14 ,  C04B35/52 ,  C01F17/206 ,  B01D71/02

Abstract: A hydrogen permeation membrane is provided that can include a carbon-based material (C) and a ceramic material (BZCYT) mixed together. The carbon-based material can include graphene, graphite, carbon nanotubes, or a combination thereof. The ceramic material can have the formula BaZr1-x-y-zCexYyTzO3-δ, where 0≤x≤0.5, 0≤y≤0.5, 0≤z≤0.5, (x+y+z)>0; 0≤δ≤0.5, and T is Yb, Sc, Ti, Nb, Ta, Mo, Mn, Fe, Co, Ni, Cu, Zn, Ga, In, or a combination thereof. In addition, the BZYCT can be present in the C-BZCYT mixture in an amount ranging from about 40% by volume to about 80% by volume. Further, a method of forming such a membrane is also provided. A method is also provided for extracting hydrogen from a feed stream.

公开(公告)号：US20180086984A1

公开(公告)日：2018-03-29

申请号：US15711634

申请日：2017-09-21

Applicant: University of South Carolina

Inventor： Fanglin Chen ,  Libin Lei ,  Tong Liu ,  Shumin Fang

IPC: C10G2/00 ,  C25B3/04 ,  B01J23/10 ,  B01J23/78

CPC classification number: C10G2/35 ,  B01J23/10 ,  B01J23/78 ,  B01J23/83 ,  C07C1/10 ,  C07C1/12 ,  C10G2/332 ,  C10G2/34 ,  C10G2/40 ,  C10G2/50 ,  C25B3/04 ,  C25B9/10 ,  C25B15/02 ,  C25B15/08

Abstract: A hydrocarbon generation system that combines a solid oxide electrolysis cell (SOEC) and a Fischer-Tropsch unit in a single microtubular reactor is described. This system can directly synthesize hydrocarbons from carbon dioxide and water. High temperature co-electrolysis of H2O and CO2 and low temperature Fischer-Tropsch (F-T) process are integrated in a single microtubular reactor by designation of a temperature gradient along the axial length of the microtubular reactor. The microtubular reactor can provide direct conversion of CO2 to hydrocarbons for use as feedstock or energy storage.

公开(公告)号：US10662383B2

公开(公告)日：2020-05-26

申请号：US16415513

申请日：2019-05-17

Applicant: UNIVERSITY OF SOUTH CAROLINA

Inventor： Fanglin Chen ,  Libin Lei ,  Tong Liu ,  Shumin Fang

IPC: C25C7/02 ,  C10G2/00 ,  C10G45/24 ,  C25B3/04 ,  B01J23/10 ,  B01J23/78 ,  C25B15/02 ,  C25B15/08 ,  C25B9/10 ,  B01J23/83 ,  C07C1/12 ,  C07C1/10

Abstract: A method for generating hydrocarbons using a solid oxide electrolysis cell (SOEC) and a Fischer-Tropsch unit in a single microtubular reactor is described. This method can directly synthesize hydrocarbons from carbon dioxide and water. The method integrates high temperature co-electrolysis of H2O and CO2 and low temperature Fischer-Tropsch (F-T) process in a single microtubular reactor by designation of a temperature gradient along the axial length of the microtubular reactor. In practice, methods disclosed herein can provide direct conversion of CO2 to hydrocarbons for use as feedstock or energy storage.

公开(公告)号：US20190119110A1

公开(公告)日：2019-04-25

申请号：US16158366

申请日：2018-10-12

Applicant: UNIVERSITY OF SOUTH CAROLINA ,  CLEMSON UNIVERSITY

Inventor： Fanglin Chen ,  Shumin Fang ,  Kyle Brinkman ,  Siwei Wang ,  Jian He ,  Yufei Liu

IPC: C01B3/50 ,  C04B35/50 ,  B01D71/02 ,  B01D67/00 ,  B01D53/22 ,  B01D53/32

Abstract: A hydrogen permeation membrane is provided that can include a carbon-based material (C) and a ceramic material (BZCYT) mixed together. The carbon-based material can include graphene, graphite, carbon nanotubes, or a combination thereof. The ceramic material can have the formula BaZr1-x-y-zCexYyTzO3-δ, where 0≤x≤0.5, 0≤y≤0.5, 0≤z≤0.5, (x+y+z)>0; 0≤δ≤0.5, and T is Yb, Sc, Ti, Nb, Ta, Mo, Mn, Fe, Co, Ni, Cu, Zn, Ga, In, or a combination thereof. In addition, the BZYCT can be present in the C-BZCYT mixture in an amount ranging from about 40% by volume to about 80% by volume. Further, a method of forming such a membrane is also provided. A method is also provided for extracting hydrogen from a feed stream.