公开(公告)号：US06448385B2

公开(公告)日：2002-09-10

申请号：US09821888

申请日：2001-03-30

申请人： Udo Herrmann ,  Lothar Weismantel ,  Frank Linke ,  Ronald Göbel ,  Bernhard Krumbach ,  Wolfgang Frank

发明人： Udo Herrmann ,  Lothar Weismantel ,  Frank Linke ,  Ronald Göbel ,  Bernhard Krumbach ,  Wolfgang Frank

IPC分类号： C09B4514

CPC分类号： C09B67/0033 ,  C09B45/14 ,  C09B67/0015

摘要： The invention relates to a process for preparing metal complexes of polyvalent metal ions with azo compounds of formula (I) or tautomeric structures, in which R and R′ are —OH, —NH2, —NH—CN, aryl-amino, acylamino, or p-chlorophenyl, and R1 and R1′ are independently —OH or —NH2, that intercalate an intercalate by (1) stirring an aqueous dispersion of an alkali metal salt of the azo compound with the polyvalent metal salt at 10 to 35° C., (2) admixing an aqueous solution, dispersion, or emulsion of the intercalate, (3) passing the mixture through a reaction zone at 85 to 140° C., while regulating the pH so that the product dispersion leaving the reaction zone has a pH of 0.5 to 3, (4) adjusting the pH of the mixture to at least pH 5, and (5) isolating the intercalated metal complex.

摘要翻译： 本发明涉及一种制备多价金属离子金属络合物与式（I）的偶氮化合物或互变异构结构的方法，其中R和R'是-OH，-NH 2，-NH-CN，芳基 - 氨基，酰基氨基， 或对氯苯基，R1和R1'独立地为-OH或-NH2，其通过以下步骤插入插层：（1）在10至35℃下，将偶氮化合物的碱金属盐的水分散体与多价金属盐一起搅拌 （2）将嵌入物的水溶液，分散液或乳液混合，（3）在85-140℃下使混合物通过反应区，同时调节pH，使离开反应区的产物分散体具有 pH为0.5至3，（4）将混合物的pH调节至至少pH 5，和（5）分离插入的金属络合物。

公开(公告)号：US07074364B2

公开(公告)日：2006-07-11

申请号：US10135500

申请日：2002-04-30

申请人： Peter Jähn ,  Georg Wiessmeier ,  Bernhard Krumbach ,  Reinhold Rose ,  Thomas Siebert ,  Rainer Krautkrämer

发明人： Peter Jähn ,  Georg Wiessmeier ,  Bernhard Krumbach ,  Reinhold Rose ,  Thomas Siebert ,  Rainer Krautkrämer

IPC分类号： G01N21/00

CPC分类号： B01L3/50851 ,  B01J19/0046 ,  B01J2219/00283 ,  B01J2219/00389 ,  B01J2219/00418 ,  B01J2219/00477 ,  B01J2219/00481 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/0059 ,  B01J2219/00601 ,  B01J2219/00698 ,  B01J2219/0072 ,  B01J2219/00722 ,  B01J2219/00745 ,  B01J2219/00747 ,  B01L7/00 ,  B01L2200/14 ,  B01L2300/04 ,  B01L2300/14 ,  C40B30/08 ,  C40B40/14 ,  C40B40/18 ,  C40B60/14 ,  Y10T436/11

摘要： Modular device and method for carrying out experiments in parallel on process substances to develop technical methods, comprising at least a multiplicity of individual reactors which are controllable independently of one another said reactors being comprised of pressure-tight chambers having separable sample vessels, and optionally, stirring devices, heating instruments, cooling instruments, or both, a monitoring unit for monitoring or controlling at least the pressure and the temperature in the individual reactors, pressure-tight lids having independent feed lines and optionally independent discharge lines for individual process substances; a plurality of the lids being simultaneously sealable upon the rectors by a common sealing means (11).

摘要翻译： 用于对工艺物质并行进行实验以开发技术方法的模块化装置和方法，包括至少多个独立于彼此控制的各个反应器，所述反应器包括具有可分离的样品容器的压力密封室， 搅拌装置，加热仪器，冷却仪器或两者，用于监测或控制各个反应器中的压力和温度的监测单元，具有独立进料管线的压力密封盖和用于各个加工物质的任选的独立排放管线; 多个盖可以通过共同的密封装置（11）同时密封在整流器上。