摘要:
A transparent, polycrystalline ceramic is described. The ceramic comprises crystallites of the formula AxCuByDvEzFw, whereby A and C are selected from the group consisting of Li+, Na+, Be2+, Mg2+, Ca2+, Sr2+, Ba2+, Al3+, Ga3+, In3+, C4+, Si4+, Ge4+, Sn2+/4+, Sc3+, Ti4+, Zn2+, Zr4+, Mo6+, Ru4+, Pd2+, Ag2+, Cd2+, Hf4+, W4+/6+, Re4+, Os4+, Ir4+, Pt2+/4+, Hg2+ and mixtures thereof, B and D are selected from the group consisting of Li+, Na+, K+, Mg2+, Al3+, Ga3+, In3+, Si4+, Ge4+, Sn4+, Sc3+, Ti4+, Zn2+, Y3+, Zr4+, Nb3+, Ru3+, Rh3+, La3+, Lu3+, Gd3+ and mixtures thereof, E and F are selected mainly from the group consisting of the divalent anions of S, Se and O and mixtures thereof, x, u, y, v, z and w satisfy the following formulae 0.125
摘要:
The refractive, transmissive or diffractive optical elements are made from a ceramic containing one or more oxides of the type X2O3, which is transmissive for visible light and/or for infrared radiation and which has a cubic crystal structure analogous to that of Y2O3. In preferred embodiments X is Y, Sc, In, or a lanthanide element, namely La to Lu, and in particular is Lu, Yb, Gd, or La. Also mixtures of oxides of the type X2O3 with oxides having different stoichiometries, such as HfO2 and/or ZrO2, may be present, as long as the cubic structure of the ceramic is maintained.
摘要翻译:折射,透射或衍射光学元件由含有一种或多种X 2 O 3的氧化物的陶瓷制成,该氧化物对于可见光和/或用于红外辐射是透射的,并且具有类似于Y 2 O 3的立方晶体结构。 在优选的实施方案中,X是Y,Sc,In或镧系元素,即La至Lu,特别是Lu,Yb,Gd或La,X2O3的氧化物与不同化学计量的氧化物的混合物,例如 可以存在HfO 2和/或ZrO 2,只要保持陶瓷的立方结构即可。
摘要:
The optoceramics are transparent to visible light and/or infrared radiation. The optoceramics each consist of a crystal matrix, i.e. of polycrystalline material, wherein at least 95% by weight, preferably at least 98% by weight, of the single crystallites have a cubic pyrochlore or a fluorite structure. Refractive, transmissive or diffractive optical elements made with the optoceramics, their uses and an optical imaging system comprising at least one of the optical elements are also disclosed. Methods of manufacturing the optoceramics are described.
摘要:
The transparent polycrystalline optoceramic has single grains with a symmetric cubic crystal structure and at least one optically active center. The optoceramic has the following formula: A2+xByDzE7, wherein 0≦x≦1.1, 0≦y≦3, 0≦z≦1.6, and 3x+4y+5z=8, and wherein A is at least one trivalent rare earth cation, B is at least one tetravalent cation, D is at least one pentavalent cation, and E is at least one divalent anion. The method of making the optoceramic includes preparing a powder mixture from starting materials, pre-sintering, sintering and then compressing to form the optoceramic. Scintillator media made from the optoceramic are also described.
摘要:
A transparent, polycrystalline ceramic is described. The ceramic comprises crystallites of the formula AxCuByDvEzFw, whereby A and C are selected from the group consisting of Li+, Na+, Be2+, Mg2+, Ca2+, Sr2+, Ba2+, Al3+, Ga3+, In3+, C4+, Si4+, Ge4+, Sn2+/4+, Sc3+, Ti4+, Zn2+, Zr4+, Mo6+, Ru4+, Pd2+, Ag2+, Cd2+, Hf4+W4+/6+, Re4+, Os4+, Ir4+,, Pt2+/4+, Hg2+ and mixtures thereof, B and D are selected from the group consisting of Li+, Na+, K+, Mg2+, Al3+, Ga3+, In3+, Si4+, Ge4+, Sn4+, Sc3+, Ti4+, Zn2+, Y3+, Zr4+, Nb3+, Ru3+, Rh3+, La3+, Lu3+, Gd3+ and mixtures thereof, E and F are selected mainly from the group consisting of the divalent anions of S, Se and O and mixtures thereof, x, u, y, v, z and w satisfy the following formulae 0.125
摘要:
The optoceramics are transparent to visible light and/or infrared radiation. The optoceramics each consist of a crystal matrix, i.e. of polycrystalline material, wherein at least 95% by weight, preferably at least 98% by weight, of the single crystallites have a cubic pyrochlore or a fluorite structure. Refractive, transmissive or diffractive optical elements made with the optoceramics, their uses and an optical imaging system comprising at least one of the optical elements are also disclosed. Methods of manufacturing the optoceramics are described.
摘要:
The opto-ceramics and optical elements of the present invention are transmissive to visible light and/or to infrared radiation. They consist of a crystal combination in which individual crystallites have a cubic structure of the type Y2O3 and are made from In2O3 or a mixture of oxides of the type X2O3 in which X=Y, Lu, Sc, Yb, In, Gd, or La. Also mixtures of X2O3 with oxides having different stoichiometries, such as zirconium and hafnium oxide, are possible, as long as the cubic structure of the opto-ceramic is maintained. The optical elements prepared from the opto-ceramics are particularly suitable for mapping optics, such as objectives having reduced chromatic aberrations, in particular with approximately apochromatic mapping behavior. The optical elements of the present invention may be used in lens systems in combination with lenses of glass, but also with other ceramic lenses.
摘要翻译:本发明的光学陶瓷和光学元件对可见光和/或对红外辐射是透射的。 它们由晶体组合组成,其中单个晶体具有Y 2 O 3 O 3类型的立方结构,并且由In 2 O 3, 或其中X = Y,Lu,Sc,Yb,In,Gd或其中的X 2 O 3 O 3的氧化物的混合物 La也可以是X 2 O 3 O 3与具有不同化学计量的氧化物的混合物,例如锆和氧化铪,只要光电陶瓷的立方结构 被维护。 从光学陶瓷制备的光学元件特别适合于映射光学元件,例如具有减小的色差的物镜,特别是具有近似的消色差映射行为。 本发明的光学元件可以与透镜系统结合使用,也可以与其它陶瓷透镜组合使用。
摘要:
The method for producing at least one rotationally symmetrical lens consisting of an opto-ceramic includes the step of moulding a ceramic green body for the lens, wherein the mould has a shaping surface, which is described by the following equation B: y 1 = cz 2 1 + 1 - ( k + 1 ) c 2 z 2 + a 1 z 2 + a 2 z 4 + a 3 z 6 + a 4 z 8 + … , ( B ) y1 gives a position on an optical axis; x designates a perpendicular distance from the optical axis to the surface; k, c, and a1, a2, a3, a4, . . . are constants describing a surface of the lens to be moulded and z=|x|+b, wherein b is a constant with a value greater than 0 and less than 0.3 mm, which is a measure of a deviation of the shaping surface from the surface of the lens.
摘要翻译:用于制造由光陶瓷构成的至少一个旋转对称透镜的方法包括模制用于透镜的陶瓷生坯的步骤,其中模具具有成形表面,其由下列等式B描述:y = cz 2 1 + 1 - (k + 1)c 2 z 2 + a 1 z 2 + a 2 z 4 + a 3 z 6 + a 4 z 8 + ...,(B)y1 给出光轴上的位置; x表示从光轴到表面的垂直距离; k,c和a1,a2,a3,a4,...。 。 。 是描述待模制透镜的表面的常数,z = | x | + b,其中b是具有大于0且小于0.3mm的常数,其是成形表面与 透镜表面。
摘要:
The moulding tool is a near-net-shape negative mould for shaping a ceramic green body for the lens. The mould has a shaping surface, which is described by the following equation B: y 1 = cz 2 1 + 1 - ( k + 1 ) c 2 z 2 + a 1 z 2 + a 2 z 4 + a 3 z 6 + a 4 z 8 + … , ( B ) y1 gives a position on an optical axis; x designates a perpendicular distance from the optical axis to the surface; k, c, and a1, a2, a3, a4, . . . are constants describing a surface of the lens to be moulded and z=|x|+b, wherein b is a constant with a value greater than 0 and less than 0.3 mm, which is a measure of a deviation of the shaping surface from the surface of the lens.
摘要翻译:成型工具是用于成形用于透镜的陶瓷生坯的近净形阴模。 模具具有成形表面,其由下面的等式B描述:y?1 1 = cz 2 1 + 1 - (k + 1)c 2 z 2 + a 1 z 2 + a 2 z 4 + a 3 z 6 + a 4 z 8 + ...,(B)y1给出光轴上的位置; x表示从光轴到表面的垂直距离; k,c和a1,a2,a3,a4,...。 。 。 是描述待模制透镜的表面的常数,z = | x | + b,其中b是具有大于0且小于0.3mm的常数,其是成形表面与 透镜表面。
摘要:
The transparent polycrystalline optoceramic has single crystallites and at least 95 percent by weight of the single crystallites have a cubic pyrochlore or fluorite structure. The optoceramic is composed of an oxide of stoichiometry: A2+xByDzE7 wherein 0