Reversible or irreversible production of an image
    1.
    发明授权
    Reversible or irreversible production of an image 失效
    可逆或不可逆转的图像制作

    公开(公告)号:US5418555A

    公开(公告)日:1995-05-23

    申请号:US975886

    申请日:1992-11-13

    摘要: In a novel process for the reversible or irreversible production of an image by the imagewise action of energy on a recording layer, resulting in a pattern of surface charges which corresponds to the imagewise action of the energy, on the surface of the recording layer, the recording layer used is one which contains or consists of an organic material which solidifies in glassy form, is nonphotoconductive or only slightly photoconductive and has permanent dipoles, wherein the pattern of surface charges is produced, without or almost without formation of free charge carriers, by reversible imagewise orientation of some or all of the permanent dipoles present in the recording layer, with the aid of an electric field applied imagewise. The novel process is advantageously carried out using a novel apparatus which comprises a suitable recording element, apparatus for the imagewise action of an electric field on the recording layer of the recording element and a counter-electrode which is in direct, non-frictional contact with the recording layer and can be removed again therefrom. The pattern of surface charges which is produced by the novel process can be treated with liquid or solid toners. The resulting toner image can then either be fixed on the recording layer or transferred from the recording layer to another surface, after which the pattern of surface charges can be deleted by uniform action of energy. Thereafter, a further image can be produced. In this way, it is possible to produce photocopies without the high voltage sources required in the conventional electrophotographic processes having to be used.

    摘要翻译: 在通过能量在记录层上的成像作用的可逆或不可逆的图像生成的新颖方法中,在记录层的表面上产生对应于能量的成像作用的表面电荷的图案, 使用的记录层是含有或由有机材料组成的材料,其以玻璃状固化,不受光导或仅具有光导电性并且具有永久偶极子,其中产生表面电荷的图案,没有或几乎不形成游离载流子,由 借助于成像的电场,存在于记录层中的一些或全部永久偶极子的可逆图像取向。 新颖的方法有利地使用新颖的装置进行,该装置包括合适的记录元件,用于在记录元件的记录层上的电场的成像作用的装置和与电极直接,非摩擦接触的对电极 记录层,并且可以从其再次移除。 通过新方法生产的表面电荷的图案可以用液体或固体调色剂处理。 所得到的调色剂图像然后可以固定在记录层上或从记录层转移到另一个表面,之后可以通过均匀的能量作用来删除表面电荷的图案。 此后,可以产生另外的图像。 以这种方式,可以在没有必须使用常规电子照相方法所需的高电压源的情况下生产复印件。

    Reversible or irreversible production of an image

    公开(公告)号:US5538824A

    公开(公告)日:1996-07-23

    申请号:US248552

    申请日:1994-05-24

    摘要: In a novel process for the reversible or irreversible production of an image by the imagewise action of energy on a recording layer, resulting in a pattern of surface charges which corresponds to the imagewise action of the energy, on the surface of the recording layer, the recording layer used is one which contains or consists of an organic material which solidifies in glassy form, is nonphotoconductive or only slightly photoconductive and has permanent dipoles, whereinthe pattern of surface charges is produced, without or almost without formation of free charge carriers, by reversible imagewise orientation of some or all of the permanent dipoles present in the recording layer, with the aid of an electric field applied imagewise.The novel process is advantageously carried out using a novel apparatus which comprises a suitable recording element, apparatus for the imagewise action of an electric field on the recording layer of the recording element and a counter-electrode which is in direct, non-frictional contact with the recording layer and can be removed again therefrom. The pattern of surface charges which is produced by the novel process can be treated with liquid or solid toners. The resulting toner image can then either be fixed on the recording layer or transferred from the recording layer to another surface, after which the pattern of surface charges can be deleted by uniform action of energy. Thereafter, a further image can be produced. In this way, it is possible to produce photocopies without the high voltage sources required in the conventional electrophotographic processes having to be used.

    Liquid-crystalline polymers of virtually uniform molecular weight
    3.
    发明授权
    Liquid-crystalline polymers of virtually uniform molecular weight 失效
    几乎均匀分子量的液晶聚合物

    公开(公告)号:US5332520A

    公开(公告)日:1994-07-26

    申请号:US880578

    申请日:1992-05-08

    CPC分类号: C09K19/3857 C08F20/30

    摘要: A liquid-crystalline polymer of virtually uniform molecular weight, obtainable by polymerizing identical or different monomers of the formula I ##STR1## where R is hydrogen, chlorine or methyl,A is a flexible, long-chain moiety which acts as a spacer, is a mesogenic moiety built up from at least two aromatic rings which are linked to one another in a linear or approximately linear manner, andC is an optically active, chiral moiety,in from 0.01 to 0.1 molar solution in an inert organic solvent in the presence of from 1 to 40 mol %, based on the monomers, of a free-radical initiator, at from 40.degree. to 60.degree. C. for from 100 to 140 hours, and subsequently isolating the polymerization product from the reaction mixture, and the use thereof for building up recording layers for laser-optical and electrical recording elements and for electrophotography and for building up liquid-crystalline display elements.

    摘要翻译: 通过聚合相同或不同的式I的单体得到的具有实质上均匀分子量的液晶聚合物,其中R是氢,氯或甲基,A是作为间隔基的柔性长链部分, 是由至少两个芳族环构成的介晶部分,其以线性或近似线性的方式彼此连接,C是光学活性的手性部分,在惰性有机溶剂中的0.01至0.1摩尔溶液 在40至60℃下,在100至140小时内,以单体为基础,存在1至40摩尔%的自由基引发剂,随后从反应混合物中分离出聚合产物, 其用于建立用于激光光学和电气记录元件的记录层和用于电子照相和用于构建液晶显示元件。

    Optically active phenoxypropionic esters
    4.
    发明授权
    Optically active phenoxypropionic esters 失效
    光学活性苯氧基丙酸酯

    公开(公告)号:US5455325A

    公开(公告)日:1995-10-03

    申请号:US231409

    申请日:1994-04-22

    摘要: Optically active compounds of the formula I ##STR1## where R is C.sub.1 -C.sub.12 -alkyl or -perfluoroalkyl in which one or two non-adjacent CH.sub.2 or CF.sub.2 groups can also be replaced by --O-- and/or --CO-- and/or --CO--O-- and/or --CH.dbd.CH-- and/or --CH-halogen- and/or --CHCN-- and/or --O--CO--CH-halogen- and/or --O--CO--CHCN--, or is C.sub.1 -C.sub.12 -alkyl which can have a terminal chemically reactive group and in which a CH.sub.2 group can be replaced by --O--,A.sup.1 and A.sup.2 are each, independently of one another, 1,4-phenylene which is unsubstituted or substituted by one or two F and/or Cl and/or Br atoms and/or CH.sub.3 groups and/or CN groups and in which one or two CH groups can also be replaced by N, 1,4-cyclohexylene in which one or two non-adjacent CH.sub.2 groups can also be replaced by --O-- and/or --S--, 1,4-piperidinediyl, 1,4-bicyclo[2.2.2]octylene, 2,6-naphthalenediyl, decahydro-2,6-naphthalenediyl or 1,2,3,4-tetrahydro-2,6-naphthalenediyl,A.sup.3 is unsubstituted or substituted phenyl,Z is --CO--O--, --O--CO--, --CH.sub.2 CH.sub.2 --, --OCH.sub.2 --, --CH.sub.2 O--, --C.tbd.C-- or a single bond andm is 0, 1, 2 or 3.

    摘要翻译: 其中R是具有一个或两个不相邻的CH2或CF2基团的C1-C12-烷基或全氟烷基的式I的光学活性化合物(I)也可以被-O-和/或-CO- 和/或-CO-O-和/或-CH = CH-和/或-CH-卤素 - 和/或-CHCN-和/或-O-CO-CH-卤素和/或-O-CO- CHCN-或可具有末端化学反应性基团并且其中CH 2基团可被-O-,A 1和A 2取代的C 1 -C 12 - 烷基彼此独立地为彼此独立的1,4-亚苯基,其为 未被取代或被一个或两个F和/或Cl和/或Br原子和/或CH 3基团和/或CN基团取代,并且其中一个或两个CH基团也可被N,1,4-亚环己基代替,其中一个或两个 或两个不相邻的CH 2基团也可以被-O-和/或-S-,1,4-哌啶二基,1,4-二环[2.2.2]亚辛基,2,6-萘二甲酸,十氢-2, 6-萘二基或1,2,3,4-四氢-2,6-萘二基,A3是未取代或取代的苯基,Z是-CO-O-,-O-CO-,-CH2CH2 - , - OCH2 - , - CH2O-,-C3OND C或单键,m为0,1,2或3。

    Optically active phenoxypropionic esters
    7.
    发明授权
    Optically active phenoxypropionic esters 失效
    光学活性苯氧基丙酸酯

    公开(公告)号:US5350873A

    公开(公告)日:1994-09-27

    申请号:US928568

    申请日:1992-08-13

    摘要: Optically active compounds of the formula I ##STR1## where R is C.sub.1 -C.sub.12 -alkyl or -perfluoroalkyl in which one or two non-adjacent CH.sub.2 or CF.sub.2 groups can also be replaced by --O-- and/or --CO-- and/or --CO--O-- and/or --CH.dbd.CH-- and/or --CH-halogen-- and/or --CHCN-- and/or --0--CO--CH-halogen-- and/or --O--CO--CHCN--, or is C.sub.1 -C.sub.12 -alkyl which can have a terminal chemically reactive group and in which a CH.sub.2 group can be replaced by --O--,A.sup.1 and A.sup.2 are each, independently of one another, 1,4-phenylene which is unsubstituted or substituted by one or two F and/or Cl and/or Br atoms and/or CH.sub.3 groups and/or CN groups and in which one or two CH groups can also be replaced by N, 1,4-cyclohexylene in which one or two non-adjacent CH.sub.2 groups can also be replaced by --O-- and/or --S--, 1,4-piperidinediyl, 1,4-bicyclo[2.2.2]octylene, 2,6-naphthalenediyl, decahydro-2,6-naphthalenediyl or 1,2,3,4-tetrahydro-2,6-naphthalenediyl,A.sup.3 is unsubstituted or substituted phenyl,Z is --CO--O--, --O--CO--, --CH.sub.2 CH.sub.2 --, --OCH.sub.2 --, --CH.sub.2 O--, --C.tbd.C-- or a single bond andm is 0, 1, 2 or 3.

    摘要翻译: 其中R是具有一个或两个不相邻的CH2或CF2基团的C1-C12-烷基或全氟烷基的式I的光学活性化合物(I)也可以被-O-和/或-CO- 和/或-CO-O-和/或-CH = CH-和/或-CH-卤素 - 和/或-CHCN-和/或-O-CO-CH-卤素 - 和/或-O-CO- CHCN-或可具有末端化学反应性基团并且其中CH 2基团可被-O-,A 1和A 2取代的C 1 -C 12 - 烷基彼此独立地为彼此独立的1,4-亚苯基,其为 未被取代或被一个或两个F和/或Cl和/或Br原子和/或CH 3基团和/或CN基团取代,并且其中一个或两个CH基团也可被N,1,4-亚环己基代替,其中一个或两个 或两个不相邻的CH 2基团也可以被-O-和/或-S-,1,4-哌啶二基,1,4-二环[2.2.2]亚辛基,2,6-萘二甲酸,十氢-2, 6-萘二基或1,2,3,4-四氢-2,6-萘二基,A3是未取代或取代的苯基,Z是-CO-O-,-O-CO-,-CH2CH2 - , - OCH2 - , - CH2O-,-C3OND C或单键,m为0,1,2或3。

    Polymerizable oligomesogenes
    8.
    发明授权
    Polymerizable oligomesogenes 失效
    可聚合低聚单体

    公开(公告)号:US06335462B1

    公开(公告)日:2002-01-01

    申请号:US09308634

    申请日:1999-05-27

    IPC分类号: C07C6976

    摘要: The compounds of the formula I X[—Y1—A1—Y2—M—Y3—A2—Z]n  I, wherein the variables are as defined in the specification. The compounds are suitable as alignment layers for liquid-crystalline materials, as photocrosslinkable adhesives, as monomers for the production of liquid-crystalline networks, as base material for the preparation of polymerizable liquid-crystal systems which can be doped by chiral compounds, as polymerizable matrix monomers for polymer-dispersed displays or as base material for polymerizable, liquid-crystalline materials for optical components, such as polarizers, retardation plates or lenses.

    摘要翻译: 变量中的式I化合物如本说明书中所定义。化合物适合作为液晶材料的取向层,作为可光致交联粘合剂,作为制备液晶网络的单体,用作制备 可由手性化合物掺杂的可聚合液晶体系,作为聚合物分散显示器的聚合性基体单体,或作为用于光学部件如偏振片,相位差板或透镜的可聚合液晶材料的基材。