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    Fluorine-containing polyamide
    3.
    发明授权
    Fluorine-containing polyamide 失效
    含氟聚酰胺

    公开(公告)号：US6103860A

    公开(公告)日：2000-08-15

    申请号：US332534

    申请日：1999-06-14

    申请人： Wataru Yamashita ,  Tomomi Yoshimura ,  Atsushi Shibuya ,  Yoshihiro Sakata ,  Hideaki Oikawa ,  Masahiro Ohta

    发明人： Wataru Yamashita ,  Tomomi Yoshimura ,  Atsushi Shibuya ,  Yoshihiro Sakata ,  Hideaki Oikawa ,  Masahiro Ohta

    IPC分类号： C08G69/42 ,  C08G69/12 ,  C08G69/32 ,  C08G69/40 ,  C08G73/10 ,  C08G69/02

    CPC分类号： C08G69/40 ,  C08G69/32 ,  C08G73/1039

    摘要： There is disclosed an organic optical component prepared from a resin essentially comprising one or more repetitive structural units selected from the group consisting of structures represented by general formula (1); ##STR1## wherein A is either of the groups below. ##STR2## This invention provides an organic optical component with excellent transparency, heat resistance and mechanical strength as well as a low birefringence. This invention also provides a novel aromatic polyamide with a low permitivity and excellent transparency, processability and thermal stability, besides excellent heat resistance inherent in an aromatic polyamide.

    摘要翻译： 公开了一种由基本上包含一个或多个重复结构单元的树脂制备的有机光学组件，所述重复结构单元选自由通式（1）表示的结构; 其中A是下面的组之一。 本发明提供了具有优异的透明性，耐热性和机械强度以及低双折射性的有机光学部件。 本发明还提供了芳香族聚酰胺固有的耐热性优异的低介电常数和优异的透明性，加工性和热稳定性的芳香族聚酰胺。

    Polyimide resin composition
    4.
    发明授权
    Polyimide resin composition 失效
    聚酰亚胺树脂组合物

    公开(公告)号：US5494996A

    公开(公告)日：1996-02-27

    申请号：US277568

    申请日：1994-07-20

    申请人： Shoji Tamai ,  Yuichi Okawa ,  Wataru Yamashita ,  Yoshihiro Sakata ,  Hideaki Oikawa ,  Keizaburo Yamaguchi ,  Tadashi Asanuma ,  Akihiro Yamaguchi ,  Mitsunori Matsuo

    发明人： Shoji Tamai ,  Yuichi Okawa ,  Wataru Yamashita ,  Yoshihiro Sakata ,  Hideaki Oikawa ,  Keizaburo Yamaguchi ,  Tadashi Asanuma ,  Akihiro Yamaguchi ,  Mitsunori Matsuo

    IPC分类号： C08L71/10 ,  C08G73/10 ,  C08L71/08 ,  C08L79/04 ,  C08L79/08

    CPC分类号： C08L79/08 ,  C08L79/04

    摘要： A polyimide resin composition substantially comprising 1 99.9.about.50 parts by weight of polyimide having recurring structural units of the formula ##STR1## and 2 0.1.about.50 parts by weight of a polyimide which improved melt flowability and is prepared by using 1,3-bis(3-aminophenoxy)benzene or 6,6'-bis(3-aminophenoxy)-3,3,3',3'-tetramethyl-1,1'-spirobiindane as essential diamine component, or polyether pyridine having recurring structural units of the formula: ##STR2## is disclosed. Further, a polyimide based resin composition comprising the polyimide resin composition or a polyimide copolymer obtained by using the above diamines and a fibrous reinforcement is disclosed. These compositions have remarkably good processability, excellent heat stability and repeated fatigue characteristics.

    摘要翻译： 一种聚酰亚胺树脂组合物，其基本上包含+ E，crc / 1 / 99.9差异50重量份具有式（1）的重复结构单元的聚酰亚胺和+ E，crc / 2 / 0.1差异50重量份的 通过使用1,3-双（3-氨基苯氧基）苯或6,6'-双（3-氨基苯氧基）-3,3,3'，3'-四甲基-1,1' - 螺环丁烷作为必需二胺组分，或具有下式重复结构单元的聚醚吡啶：。 此外，公开了一种聚酰亚胺系树脂组合物，其包含使用上述二胺和纤维增强剂而得到的聚酰亚胺树脂组合物或聚酰亚胺共聚物。 这些组合物具有非常好的加工性能，优异的热稳定性和重复的疲劳特性。

    Polyimide based resin composition
    6.
    发明授权
    Polyimide based resin composition 失效
    聚酰亚胺基树脂组合物

    公开(公告)号：US5763537A

    公开(公告)日：1998-06-09

    申请号：US577517

    申请日：1995-12-22

    申请人： Tomomi Yoshimura ,  Wataru Yamashita ,  Shoji Tamai ,  Akihiro Yamaguchi

    发明人： Tomomi Yoshimura ,  Wataru Yamashita ,  Shoji Tamai ,  Akihiro Yamaguchi

    IPC分类号： C08K5/3417 ,  C08L67/00 ,  C08L79/08

    CPC分类号： C08K5/3417

    摘要： A is a polyimide based resin molding composition comprising 100 parts by weight of crystalline polyimide having recurring structural units of the formula (1): ##STR1## and 1.about.50 parts by weight of crystallization accelerators selected from bisimide compounds of specific structure, a mixture of bisimide compounds, and imide based oligomer. The composition remarkably accelerates the crystallization velocity of polyimide of the formula (1), crystallization can be completed within a greatly reduced cooling time after melt processing, and the crystallized polyimide resin has excellent properties.

    摘要翻译： A是一种聚酰亚胺基树脂模制组合物，其包含100重量份具有式（1）的重复结构单元的结晶聚酰亚胺：1分钟和50分钟的选自特定结构的双酰亚胺化合物的结晶促进剂 ，双酰亚胺化合物和基于酰亚胺的低聚物的混合物。 该组合物显着加速式（1）的聚酰亚胺的结晶速度，在熔融加工后的冷却时间内可以结晶化，结晶化聚酰亚胺树脂具有优异的性能。

    Polyimide resin compositions for optical filters
    8.
    发明授权
    Polyimide resin compositions for optical filters 失效
    用于光学滤光片的聚酰亚胺树脂组合物

    公开(公告)号：US5868968A

    公开(公告)日：1999-02-09

    申请号：US965195

    申请日：1997-11-06

    申请人： Keisuke Takuma ,  Kazuhiro Seino ,  Tsutami Misawa ,  Shoji Tamai ,  Wataru Yamashita

    发明人： Keisuke Takuma ,  Kazuhiro Seino ,  Tsutami Misawa ,  Shoji Tamai ,  Wataru Yamashita

    IPC分类号： C08G73/10 ,  C08K5/00 ,  C09D11/10 ,  G02B5/20 ,  G02B5/22 ,  F21V9/04 ,  F21V9/00

    CPC分类号： G02B5/223 ,  C08G73/1039 ,  C08K5/0041 ,  C09D11/102 ,  G02B5/201

    摘要： A polyimide resin composition for an optical filter which includes a colorless transparent polyimide resin containing at least one perfluoroalkyl group in each recurring structural unit and having excellent solvent solubility, and at least one dyestuff soluble in said resin. The dyestuff has absorption in the visible range and/or the near infrared range. A printing ink for an optical filter is composed of the polyimide resin composition and a solvent while an optical filter formed from a transparent base material and the polyimide resin composition can also be provided.

    摘要翻译： 一种滤光器用聚酰亚胺树脂组合物，其包含在每个重复结构单元中含有至少一个全氟烷基并且溶剂溶解性优异的无色透明聚酰亚胺树脂和至少一种可溶于所述树脂的染料。 染料在可见光范围和/或近红外范围内具有吸收。 用于滤光器的印刷油墨由聚酰亚胺树脂组合物和溶剂构成，同时也可以提供由透明基材形成的滤光器和聚酰亚胺树脂组合物。

    Polyamic acid, polyimide, process for producing these, and film of the polyimide
    9.
    发明授权
    Polyamic acid, polyimide, process for producing these, and film of the polyimide 有权
    聚酰胺酸，聚酰亚胺，其制造方法和聚酰亚胺薄膜

    公开(公告)号：US06710160B2

    公开(公告)日：2004-03-23

    申请号：US10088481

    申请日：2002-03-20

    申请人： Wataru Yamashita ,  Katsuji Watanabe ,  Hideaki Oikawa ,  Hisato Ito

    发明人： Wataru Yamashita ,  Katsuji Watanabe ,  Hideaki Oikawa ,  Hisato Ito

    IPC分类号： C08G7310

    CPC分类号： G01N33/54346 ,  C08G73/10 ,  C08G73/1082

    摘要： Disclosed are a polyamic acid having repeating units represented by the formula (1): wherein the norbornane skeleton of comprises four components of and their contents satisfy the following: 1%≦2,5-[diexo]≦90%, 1%≦2,5-[exo,endo]≦90%, 1%≦2,6-[diexo]≦90%, 1% ≦2,6-[exo,endo]≦90%, provided that (2,5-[diexo])+(2,5-[exo,endo])+(2,6-[diexo])+(2,6-[exo,endo])=100%, R represents from 4 to 27 carbon atoms, and represents a tetravalent group selected from the group consisting of an aliphatic group, a monocyclic aliphatic group, a condensed polycyclic aliphatic group, a monocyclic aromatic group, a condensed polycyclic aromatic group, and a non-condensed polycyclic aliphatic or aromatic group which is composed of cycloaliphatic or aromatic groups mutually bonded to each other either directly or via a crosslinking member; and a polyimide which is obtained by imidizing the polyamic acid and which has good properties intrinsic to polyimides, or that is, thermal resistance, mechanical properties, slidability, low water absorption, electric properties and radiation resistance intrinsic thereto. By varying the composition ratio of the starting diamine isomers, various polyimides having controlled thermal resistance, melt flowability, optical properties, chemical resistance and electric properties and capable of forming films of various forms can be obtained.

    摘要翻译： 公开了具有由式（1）表示的重复单元的聚酰胺酸：其中含有四种成分及其含量的降冰片烷骨架满足以下条件：1％<= 2,5- [阴离子] <= 90％，1％<= 2,5- [外，内] <= 90％，1％<= 2,6- [阴离子] <= 90％，1％<= 2,6- [外，内] <= 90％ 表示4〜27个碳原子，表示选自脂肪族基团，单环脂族基团，缩合多环脂族基团，单环芳香族基团，缩合多环芳香族基团和未缩合的四价基团 由脂环族或芳族基团组成的多环脂肪族或芳香族基团直接或通过交联成分彼此相互结合; 和通过酰亚胺化聚酰胺酸而获得的聚酰亚胺，其具有聚酰亚胺所固有的良好性能，或者其本身具有的热阻，机械性能，滑动性，低吸水性，电性能和耐辐射性。 通过改变起始二胺异构体的组成比，可以获得具有受控热阻，熔体流动性，光学性能，耐化学性和电性能并且能够形成各种形式的膜的各种聚酰亚胺。

    Readily soluble, amorphous polyimide, and preparation process of same
    10.
    发明授权
    Readily soluble, amorphous polyimide, and preparation process of same 失效
    易溶，无定形聚酰亚胺及其制备方法相同

    公开(公告)号：US5480965A

    公开(公告)日：1996-01-02

    申请号：US280551

    申请日：1994-07-26

    申请人： Wataru Yamashita ,  Yuichi Okawa ,  Hideaki Oikawa ,  Tadashi Asanuma ,  Yuko Ishihara ,  Mitsunori Matsuo ,  Keizaburo Yamaguchi ,  Akihiro Yamaguchi ,  Shoji Tamai

    发明人： Wataru Yamashita ,  Yuichi Okawa ,  Hideaki Oikawa ,  Tadashi Asanuma ,  Yuko Ishihara ,  Mitsunori Matsuo ,  Keizaburo Yamaguchi ,  Akihiro Yamaguchi ,  Shoji Tamai

    IPC分类号： C07C201/12 ,  C07C205/45 ,  C07C221/00 ,  C07C225/22 ,  C08G73/10 ,  C08G73/12 ,  C08J5/18 ,  C08L79/08 ,  C08G69/26 ,  C08L77/00

    CPC分类号： C08G73/10 ,  C08G73/1007 ,  C08G73/1014 ,  C08G73/1017 ,  C08G73/1067 ,  Y10T428/31504 ,  Y10T428/31721

    摘要： This invention relates to a novel thermoplastic and amorphous polyimide which is readily soluble in organic solvent, a novel aromatic diamino compound used for the polyimide, a preparation process thereof, a polyimide-based resin composition comprising the thermoplastic polyimide and a fibrous reinforcement, a process for preparing the resin composition, an injection molded article of the resin composition, a polyimide-based composite obtained by molding the above soluble and thermoplastic polyimide in combination with a fibrous reinforcement, and a fibrous reinforcement having a surface modified with the above polyimide.The polyimide comprise a requisite structural unit having one or more recurring structural units of the formula: ##STR1## wherein m and n are individually an integer of 0 or 1, and R is ##STR2## The polyimide of the invention is essentially amorphous, excellent in melt flow stability in the decreased temperature as compared with conventionally known polyimide and has greatly improved processability.The polyimide of the invention obtained by using a novel aromatic diamino compound as a monomer can control various properties such as melt flow ability and solubility in solvents by side chains and not by principal chain of polyimide. Thus, excellent melt flow property and solubility in solvents can be obtained while maintaining high heat resistance and adhesive property which are derived from benzophenone structure of the diamino compound of the the invention.

    摘要翻译： 本发明涉及易溶于有机溶剂的新型热塑性和无定形聚酰亚胺，用于聚酰亚胺的新型芳族二氨基化合物及其制备方法，包含热塑性聚酰亚胺和纤维增强剂的聚酰亚胺基树脂组合物， 用于制备树脂组合物的树脂组合物的注塑制品，通过将上述可溶性和热塑性聚酰亚胺与纤维增强剂组合成型而获得的聚酰亚胺类复合材料和具有用上述聚酰亚胺改性的表面的纤维增强剂。 聚酰亚胺包含必需的结构单元，其具有一个或多个下式的重复结构单元：其中m和n分别为0或1的整数，R为本发明的聚酰亚胺基本上为 与常规已知的聚酰亚胺相比，在降低的温度下的熔体流动稳定性优异并且具有极大的改进的加工性。 通过使用新颖的芳族二氨基化合物作为单体获得的本发明的聚酰亚胺可以通过侧链而不是聚酰亚胺的主链来控制各种性能如熔体流动性和在溶剂中的溶解度。 因此，在保持由本发明的二氨基化合物的二苯甲酮结构得到的高耐热性和粘合性的同时，可以获得优异的熔体流动性和溶剂中的溶解性。