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1.发明授权
公开(公告)号：US4088705A
公开(公告)日：1978-05-09
申请号：US767716
申请日：1977-02-11
摘要： Catalyst and process for the production of chlorofluorinated hydrocarbons are disclosed by reacting a hydrocarbon with HCl, HF and oxygen-containing gas under oxychlorofluorination conditions in the presence of a catalytic composition comprising magnesium and copper ions each in combination with fluoride ions and an alkali metal ion, or mixtures thereof, in combination with chloride ions.
摘要翻译： 催化剂和制备氯氟烃的方法通过在氧氯氟化条件下，在含有镁和铜离子的催化组合物与氟离子和碱金属离子组合的存在下使烃与HCl，HF和含氧气体反应来进行公开 ，或其混合物，与氯离子组合。
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2.发明授权
公开(公告)号：US4194990A
公开(公告)日：1980-03-25
申请号：US869730
申请日：1978-01-16
摘要： Catalyst and process for the production of chlorofluorinated hydrocarbons are disclosed by reacting a hydrocarbon with HCl, HF and an oxygen-containing gas under oxychlorofluorination conditions in the presence of a catalytic composition comprising magnesium and copper ions each in combination with fluoride ions and an alkali metal ion, or mixtures thereof, in combination with chloride ions.
摘要翻译： 催化剂和制备氯氟烃的方法通过在含氟氯离子和碱金属的催化剂组合物存在下，在含氟氯氟化条件下，将烃与HCl，HF和含氧气体反应， 离子或其混合物，与氯离子组合。
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3.发明授权Pyrogenic silica or titania or alpha-alumina cuprous chloride catalyst of hydrogen chloride/oxygen reaction 失效热解二氧化硅或二氧化钛或α-氧化铝氯化亚铜催化剂的氯化氢/氧反应
公开(公告)号：US4123389A
公开(公告)日：1978-10-31
申请号：US765161
申请日：1977-02-02
IPC分类号： B01J23/72 , B01J27/122 , B01J37/02 , B01J27/06 , C07C17/00
CPC分类号： B01J27/122 , B01J23/72 , B01J37/024
摘要： Catalyst of cuprous chloride, as a first layer, on a carrier of particles of pyrogenic anhydrous silica or titania, or alpha-alumina produced from pyrogenic gamma-alumina, having as a second layer an alkali metal chloride especially KCl, and preferably also a rare earth metal chloride; especially LaCl.sub.3 ; formed by impregnation using non-aqueous solvents, especially CuCl in acetonitrile followed by KCl/LaCl.sub.3 in formic acid. The catalyst is effective at desirable reaction rates at temperatures well below 400.degree. C., such as 200.degree.-300.degree. C. and even below 200.degree. C., under certain conditions, for oxyhydrochlorination of organic materials such as methane; and is also effective for production of chlorine by the Deacon process at relatively low temperatures. Problems due to catalyst volatility and melting are substantially mitigated.
摘要翻译： 作为第一层的氯化亚铜催化剂在由热解的无水二氧化硅或二氧化钛的颗粒载体或由热解的γ-氧化铝产生的α-氧化铝的载体上，其中第二层为碱金属氯化物，特别是KCl，优选也是罕见的 地球金属氯化物; 特别是LaCl3; 通过使用非水溶剂，特别是在乙腈中的CuCl，随后在甲酸中的KCl / LaCl 3浸渍形成。 催化剂在一定条件下，在有机物质如甲烷的氢氯化处理下，在远低于400℃的温度，如200-300℃，甚至低于200℃下，以所需的反应速率有效。 并且在相对较低的温度下通过Deacon工艺生产氯也是有效的。 催化剂挥发性和熔融性引起的问题大为减轻。
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4.发明授权Catalyst of chlorination and combined chlorination/fluorination based on copper/calcium/fluoride 失效基于铜/钙/氟化物的氯化和联合氯化/氟化催化剂
公开(公告)号：US4113655A
公开(公告)日：1978-09-12
申请号：US791767
申请日：1977-04-28
摘要： The catalyst consists essentially of a calcium fluoride matrix and a thermally stable copper-containing phase as produced by coprecipitation of calcium fluoride and copper fluoride and/or calcium hydroxide and copper oxide, in presence of alkali metal or ammonium ion. The coprecipitate is thoroughly dried and heated at elevated temperature; followed, if the coprecipitate is in the form of hydroxide and/or oxide, by conversion of such hydroxide and oxide to fluoride.The preferred alkali metal ion is potassium.The most active and stable catalysts show by X-ray diffraction a pattern including lines characteristic of calcium fluoride and additional lines indicative of a face-centered cubic unit cell having unit dimension of about 8.1-8.4 A.The catalyst operates at about 200.degree.-550.degree. C. depending to some extent on the substrate.
摘要翻译： 催化剂基本上由氟化钙基质和通过在碱金属或铵离子存在下共沉淀氟化钙和氟化铜和/或氢氧化钙和氧化铜产生的热稳定的含铜相组成。 将共沉淀物彻底干燥并在高温下加热; 其次，如果共沉淀物是氢氧化物和/或氧化物的形式，则将这种氢氧化物和氧化物转化为氟化物。
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公开(公告)号：US4060499A
公开(公告)日：1977-11-29
申请号：US761561
申请日：1977-01-24
摘要： A catalyst consisting essentially of cuprous chloride intercalated in crystalline boron nitride, containing at least 10% copper, useful for substitution chlorination of organic substances in vapor phase at elevated temperature by action of chlorine or HCL and oxygen. Highly selective for chlorination versus oxidation and hydrolysis even at high conversions, using partially chlorinated organic material as reactant, in particular methyl chloride.
摘要翻译： 一种主要由氯化亚铜组成的催化剂，其插入结晶氮化硼中，含有至少10％的铜，可用于通过氯或HCL和氧的作用在升高的温度下进行有机物质的取代氯化。 即使在高转化率下，也可选择性地进行氯化与氧化和水解，使用部分氯化有机材料作为反应物，特别是氯甲烷。
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6.发明授权Catalyst of chlorination and combined chlorination/fluorination based on copper/calcium/fluoride 失效基于铜/钙/氟化物的氯化和联合氯化/氟化催化剂
公开(公告)号：US4039596A
公开(公告)日：1977-08-02
申请号：US683995
申请日：1976-05-06
摘要： The catalyst consists essentially of a calcium fluoride matrix and a thermally stable copper-containing phase as produced by coprecipitation of calcium fluoride and copper fluoride and/or calcium hydroxide and copper oxide, in presence of alkali metal or ammonium ion. The coprecipitate is thoroughly dried and heated at elevated temperature; followed, if the coprecipitate is in the form of hydroxide and/or oxide, by conversion of such hydroxide and oxide to fluoride.The preferred alkali metal ion is potassium.The most active and stable catalysts show by X-ray diffraction a pattern including lines characteristic of calcium fluoride and additional lines indicative of a face-centered cubic unit cell having unit dimension of about 8.1-8.4 A.The catalyst operates at about 200.degree.-550.degree. C. depending to some extent on the substrate.
摘要翻译： 催化剂基本上由氟化钙基质和通过在碱金属或铵离子存在下共沉淀氟化钙和氟化铜和/或氢氧化钙和氧化铜产生的热稳定的含铜相组成。 将共沉淀物彻底干燥并在高温下加热; 其次，如果共沉淀物是氢氧化物和/或氧化物的形式，则将这种氢氧化物和氧化物转化为氟化物。
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7.发明授权Catalyst and method of making same for oxidation of primary amines to oximes by elemental oxygen 失效通过元素氧将伯胺氧化成肟的催化剂及其制备方法
公开(公告)号：US4624939A
公开(公告)日：1986-11-25
申请号：US780857
申请日：1985-09-27
申请人： Jean Yamanis , Emery J. Carlson , John N. Armor
发明人： Jean Yamanis , Emery J. Carlson , John N. Armor
CPC分类号： B01J23/30 , B01J27/188 , B01J37/033
摘要： Improved processes for the conversion to oximes by selective oxidation, in the vapor phase, of saturated primary aliphatic or alicyclic amines having 2 to 12 carbon atoms especially cyclohexylamine to cyclohexanone oxime with elemental oxygen, in a reaction zone, in the presence of an effective amount of a catalyst comprising an oxygen-containing tungsten compound and alumina by (1) periodically regenerating the oxygen-containing tungsten catalyst by heating same at about 250.degree. C.-300.degree. C. in the presence of elemental oxygen, or (2) maintaining the temperature of the oxygen-containing tungsten catalyst in a range of about 100.degree. C.-145.degree. C. or (3) employing higher mol fractions of oxygen and of amine in a range of about 0.2-0.4 in the vapor phase are disclosed. An improved method of preparing an oxygen-containing tungsten on an alumina catalyst is also disclosed.
摘要翻译： 在有效量的存在下，在反应区中，通过在气相中选择性氧化具有2至12个碳原子的饱和伯脂族或脂环族胺，特别是环己胺与环己酮肟与元素氧的转化为肟的改进方法 包含含氧钨化合物和氧化铝的催化剂通过（1）在元素氧存在下，在约250℃-300℃下，通过加热氧化钨催化剂来定期再生含氧钨催化剂，或者（2）维持 公开了含氧钨催化剂在约100℃-145℃范围内的温度或（3）在汽相中使用较高摩尔分数的氧气和约0.2-0.4范围的胺的胺 。 还公开了一种在氧化铝催化剂上制备含氧钨的改进方法。
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公开(公告)号：US4281194A
公开(公告)日：1981-07-28
申请号：US125723
申请日：1980-02-28
申请人： John N. Armor , Emery J. Carlson
发明人： John N. Armor , Emery J. Carlson
IPC分类号： B01J21/12 , C07C131/04
CPC分类号： B01J21/12 , Y10S502/513
摘要： An amorphous silica/alumina gel catalyst obtained by coprecipitating orthosilicate tetraester and aluminate triester in about 2.5:1 mole ratio, via rapid addition of about 0.4 to 5 moles of water per molecular equivalent of total ester groups, and drying at not over about 275.degree. C. is an effective catalyst for vapor phase reaction of cyclohexanone, ammonia and oxygen to form cyclohexanone oxime. This oxime can be rearranged to caprolactam, the starting material for nylon-6.
摘要翻译： 通过以每分子当量的总酯基快速加入约0.4至5摩尔水，并以不超过约275℃干燥，以约2.5:1的摩尔比共聚原硅酸酯四酯和铝酸盐三酯获得的无定形二氧化硅/氧化铝凝胶催化剂 C.是环己酮，氨和氧的气相反应形成环己酮肟的有效催化剂。 该肟可重排为己内酰胺，即尼龙-6的原料。
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公开(公告)号：US4629652A
公开(公告)日：1986-12-16
申请号：US656820
申请日：1984-10-01
申请人： Emery J. Carlson , John N. Armor
发明人： Emery J. Carlson , John N. Armor
CPC分类号： B01J13/0052 , B01J13/0091 , B01J37/036 , Y10T428/249953 , Y10T428/249955 , Y10T428/249978 , Y10T428/259 , Y10T428/2991 , Y10T428/2993
摘要： A widely applicable and simple technique has been discovered for preparing aerogels in more durable forms. By the exposure of a variety of support structures to a pregel heated to hypercritical conditions, the resulting aerogel is produced and retained on the supporting structure. Thus, the aerogels are prepared and "pelletized" in one step.
摘要翻译： 已经发现了一种广泛应用和简单的技术来制备更耐用形式的气凝胶。 通过将各种支撑结构暴露于加热至超临界条件的预凝胶中，得到的气凝胶被产生并保留在支撑结构上。 因此，制备气凝胶并在一个步骤中“造粒”。
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公开(公告)号：US4615736A
公开(公告)日：1986-10-07
申请号：US729728
申请日：1985-05-01
申请人： John N. Armor , Emery J. Carlson
发明人： John N. Armor , Emery J. Carlson
CPC分类号： B22F1/0007 , B22F9/16 , B22F9/24 , B22F2998/00
摘要： A process is disclosed for the preparation of metallic products from metal salts admixed with solvent wherein at least one of the metal salt and the solvent is easily reducible. The admixture is heated under hypercritical conditions of temperature and pressure to produce metallic products and a hypercritical fluid. The hypercritical fluid is subsequently removed from the reaction zone and the metallic product is collected. The metallic product includes pure metals selected from the group of silver, gold, platinum, palladium, ruthenium, rhodium, mercury, arsenic, rhenium, tellurium, iridium, osmium, and copper, and alloys and mixtures thereof. The metallic product ordinarily exists as finely divided powders which may be highly porous.
摘要翻译： 公开了一种从与溶剂混合的金属盐制备金属产品的方法，其中至少一种金属盐和溶剂容易还原。 将混合物在超临界温度和压力条件下加热以产生金属产物和超临界流体。 随后从反应区中除去超临界流体，并收集金属产物。 金属产品包括选自银，金，铂，钯，钌，铑，汞，砷，铼，碲，铱，锇和铜的纯金属，以及它们的合金和混合物。 金属产品通常以细碎的粉末存在，其可以是高度多孔的。
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