摘要:
A method for the concentration of water-in-oil emulsions of water soluble vinyl addition polymers is disclosed. The process involves distilling the water-in-oil emulsion of the water soluble vinyl addition polymer under a vacuum while maintaining the water-oil phase ratio substantially equal to the starting latex. Maintaining this ratio allows latices of this type to be concentrated to as high as 70% by weight polymer.
摘要:
The use of falling-film evaporation and a concentration means such as centrifugal separation to dehydrate and concentrate a water-in-oil polymer emulsion or suspension is disclosed. In a preferred embodiment, a water-in-oil polymer composition containing less than about 25% active polymer solids is dehydrated in falling-film evaporator to produce an evaporator concentrate containing less than about 5.0% water. The evaporator concentrate then flows to a separation device such as a centrifuge, wherein oil is removed to produce a composition that is substantially a polymer and emulsifying surfactant-in-oil composition containing in excess of about 60 weight % polymer solids. The centrifuge raffinate may optionally be treated in a second separation means to capture additional polymer solids, with optional recycle of the oil-rich raffinate. The concentrated polymer composition is preferably stabilized with a steric stabilizer to produce a free flowing liquid product.
摘要:
The instant invention is directed to a method for preparing free-flowing, water-soluble polymer gels comprising:(a) reducing the size of water-soluble polymer gels by a size-reduction means, so as to produce polymer gel particles which are less than 1/2 inch in their longest dimension; and(b) adding to the size-reduced polymer gels of Step (a) 0.001 to 20 percent, by weight, of an amphipathic compound, thereby reducing the adhesion of said gel particles to themselves and other substances.The instant invention is also directed to a free-flowing, water-soluble polymer gel admixture comprising:(a) size-reduced, water-soluble polymer gel particles, wherein said gel particles are less than 1/2 inch in their longest dimension; and(b) an amphipathic compound.
摘要:
Continuous process for the preparation of water-soluble polymers in which highly concentrated monomer solutions may be polymerized by a combination of a visible light and a thermally initiated process.
摘要:
A composition comprising an aqueous cellulosic furnish, a high molecular weight cationic polymer, and an anionic polymer comprising a modified lignin wherein the ratio of the cationic polymer to the anionic polymer is from about 10:1 to 1:10 on an active basis is disclosed. A process employing this composition for making paper or paperboard having improved drainage, retention and formation properties is also provided.
摘要:
A method for clarifying phosphoric acid by flocculation or coagulation of solids wherein an effective amount of a carboxylic-type polymer having a portion of sulfonic functionality is used as the clarification aid. Preferred polymers are high molecular weight acrylic acid/acrylamido methylpropyl sulfonic acid-type polymers.
摘要:
A novel method of treating circulating water containing over-sprayed, water-borne paint, such as in a paint spray booth operation, comprises adjusting the alkalinity of the paint spray booth water to between about 20 and 600 ppm, on a calcium carbonate basis, by adding a designated alkalinity source thereto, adding a cationic potato starch to the water, contacting the over-sprayed, water-borne paint with the alkalinity-adjusted paint spray booth water after addition of the cationic potato starch, adding an effective amount of a polymer floccing agent to the paint spray booth water, and removing resulting sludge from the paint spray booth water.
摘要:
A method for improving gypsum slurry filtration in the production of wet process phosphoric acid wherein an effective amount of carboxylic-type polymer having a portion of sulfonic functionality is used as the filtration aid. Preferred polymers are high molecular weight polymers of acrylic acid and acrylamido methylpropyl sulfonic acid.
摘要:
The instant invention is directed to a method for preparing free-flowing, water-soluble polymer gels comprising:(a) reducing the size of water-soluble polymer gels by a size-reduction means, so as to produce polymer gel particles which are less than 1/2 inch in their longest dimension; and(b) adding to the size-reduced polymer gels of Step (a) 0.001 to 20 percent, by weight, of an amphipathic compound, thereby reducing the adhesion of said gel particles to themselves and other substances.
摘要:
Energetic materials, such as nitrocellulose, TNT, RDX, and combinations thereof, optionally in combination with chemical warfare agents, such as mustard gas, Lewisite, Tabun, Sarin, Toman, VX, and combinations thereof, are destroyed when chemically reacted according to the method of the invention. The method comprises reacting the energetic materials and chemical warfare agents, of present, with solvated electrons which are preferably produced by dissolving an active metal such as sodium in a nitrogenous base such as anhydrous liquid ammonia.