摘要:
New products having excellent sizing action, in particular on paper are obtained by reacting .alpha.,.beta.-unsaturated carboxylic acids or their reactive derivatives (such as, for example, esters or anhydrides) with amide-amines of higher carboxylic acids at temperatures above 120.degree. C.The new products are used in size formulations, preferably as aqueous alkaline and, in particular, aqueous ammoniacal, dispersions.
摘要:
Paper sizing agents in the form of an aqueous preparation of maleic acid anhydride copolymers of which the anhydride groups had been reacted either with organic or inorganic bases or with primary-tertiary diamines and the reaction products subsequently reacted with epichlorohydrin or with inorganic or organic acids to form salts, the copolymers being made up of polymerised units of(a) from 5 to 75%, by weight, of an aromatic vinyl compound;(b) from 10 to 75%, by weight, of acrylic and/or methacrylic acid C.sub.1 -C.sub.18 alkyl esters;(c) from 5 to 35%, by weight, of maleic acid anhydride;(d) from 0 to 25%, by weight, of other vinyl monomers; and(e) from 0.1 to 10%, by weight, based on the sum of monomers (a) to (d) (which amounts to 100%, by weight), of an unsaturated aldehyde or of an enol ether derived therefrom.The copolymers are produced by radical polymerisation preferably in the absence of solvents.
摘要:
The invention provides new sizing agents, in particular for paper, which contain chloroformic acid esters of ester alcohols and/or carboxamide alcohols.The chloroformic acid esters in question preferably have the following idealized structure:(RCOX).sub.n R'(OCOCL).sub.m (I)whereinX=an oxygen atom or an NH radical,R=an aliphatic, araliphatic or cycloaliphatic hydrocarbon radical having 8 to 28 carbon atoms,R'=the radical of an (n+m)-functional alcohol or amino alcohol having 2 to 10 carbon atoms, where the functionality refers to the total number of OH and NH.sub.2 groups,n=an integer from 1 to 4, andm=an integer from 1 to 3.
摘要:
Gel formers comprising acid aluminum phosphate and a reaction product of boric acid and an alkanolamine, and further comprising alkali metal compounds in the aluminum: alkali metal ratio of 1:1.3-2.5 require short gelling times, and form gels having improved melting resistance.
摘要:
Fireproofing gels based on amine salts of acid phosphates are characterised in that they comprise an aluminium component, a phosphorus component, an amine component and if appropriate water in proportions such that, at 5 to 30.degree. C. for more than 24 hours, they form a mixture which is capable of flow, and on heating to temperatures above 45.degree. C. they change into a transparent gel in less than 24 hours. In addition to other uses, such fireproofing gels are particularly suitable for the production of laminated glass constructions having a-fire protection action.
摘要:
Waterproofing and oil-proofing agents contain A. compounds containing a perfluoroalkyl group, and B. quaternization products of basic fatty acid amides.
摘要:
Flame-retarding sealing compounds based on hydraulic binders are described which are characterized by a content of dehydratable fillers and melamines.
摘要:
The present invention is concerned with a method for improving the water storage capacity of textile substrates, particularly fleece based artificial leathers by treatment with a hydrophilizing agent. This agent, once applied to the substrate is insoluble in but swellable in water. The agent in an uncross-linked state is water soluble and has a turbidity point of between about 25.degree. and 95.degree. C. in a 25% aqueous solution. The agent may be applied to the substrate from aqueous solution and then cross-linked or it may be applied to an inert carrier such as kaolin, cross-linked and applied to the substrate from an aqueous suspension. A particularly suitable agent is a polyether with a molecular weight of between 500 and 8500, an ethylene oxide content of about 35 to 80 wt. % and cross-linkable end groups. The end groups may be self cross-linking such as vinyl groups or they may be cross-linkable via a cross-linking promoter such as hexamethylol melamine. These end groups include the hydroxyl groups normally present in polyethers produced from polyalkylene oxides.
摘要:
The instant invention is directed to a suspension which is stable in storage comprising:(1) 0.5 to 80%, by weight, based on the total suspension, of an inorganic filler in(2) 20 to 99.5%, by weight, based on the total suspension, of polyhydroxyl compounds containing aliphatic or cycloaliphatic combined hydroxyl groups,wherein said polyhydroxyl compounds (2) contain from 0.05 to 10% by weight based on (1)+(2) of a graft polymer and stabilizer which was produced by the free radical polymerization of(a) from 1 to 35%, by weight, based on the graft polymer, of an olefinically unsaturated carboxylic acid and(b) from 0 to 60%, by weight, based on the graft polymer, of other olefinically unsaturated monomers, in the presence of(c) from 5 to 99%, by weight, based on the graft polymer, of polyhydroxyl compounds,wherein the carboxyl groups of the graft polymer are completely or partially neutralized by organic or inorganic bases.