Abstract:
Disclosed herein is a printing method for forming a three dimensional article. The method includes providing a first 3D structural material; depositing a metal nanoparticle ink composition on a surface of the first 3D structural material; annealing the metal nanoparticle ink composition at a temperature of between 60° C. and 100° C. to form the conductive article on the first 3D structural material; and optionally forming a second 3D structural material over the conductive article.
Abstract:
Methods for printing a conductive object are provided which may comprise dispensing one of a first ink composition and a second ink composition towards a substrate surface to form a deposition region on the substrate surface or on a previously printed object on the substrate surface, wherein the first ink composition comprises an aqueous solution of a metal compound and the second ink composition comprises an aqueous solution of a stable free radical; dispensing the other of the first and second ink compositions in the deposition region to mix the first and second ink compositions and induce chemical reduction of the metal compound by the stable free radical and precipitation of the metal of the metal compound; and removing solvent from the deposition region, thereby forming a conductive object comprising the precipitated metal.
Abstract:
A composite powder includes a core particle comprising a styrene/acrylate polymer resin, and a shell comprising a styrene/acrylate ionomer resin, wherein the styrene/acrylate ionomer resin comprises a metal ion acrylate monomer, and methods of making thereof. Various articles can be manufactured from such composite powders.
Abstract:
A composite filament includes a core particle comprising a styrene/acrylate polymer resin, and a shell comprising a styrene/acrylate ionomer resin, wherein the styrene/acrylate ionomer resin comprises a metal ion acrylate monomer, and methods of making thereof. Various articles can be manufactured from such composite filaments.
Abstract:
A color three-dimensional (3D) printing system includes (1) a solid build ink for each of a plurality of colors, each solid build ink includes (a) a solid acrylate in an amount from about 40 to about 70 percent by weight, (b) a non-curable wax in an amount from about 10 to about 45 percent by weight, (c) a curable wax in an amount from about 1 to about 15 percent by weight, (d) a photoinitiator, and (e) a colorant; each solid build ink has a curing speed adjusted by a ratio of the non-curable wax to curable wax such that the initial curing speed and final hardness of each solid build ink is approximately the same for each of the plurality of colors, and (2) a support material includes the non-curable wax used in each build ink, the support material providing a scaffold for deposition of each build ink.
Abstract:
An intermediate transfer member containing a blend of materials including a base polymer and a stimulus-responsive additive, an intermediate transfer member containing a first layer including a base polymer and a second layer grafted onto the first layer and including a stimulus-responsive additive, and a method of printing an image to a substrate.
Abstract:
The present disclosure provides an electron beam ink comprising a radiation curable material selected from the group consisting of a curable monomer, a curable oligomer, and mixtures thereof; and a surfactant, which is suitable for use in an indirect printing method. The present disclosure also provides a method of printing using an electron beam curable ink.
Abstract:
An aqueous latex ink includes a polymer latex having a particle size of less than about 100 nm. A method of making an aqueous latex ink includes emulsifying a polymer without the use of a surfactant to prepare a latex having a particle size of less than 100 nm. A method of printing an image on a substrate includes applying an aqueous latex ink to an intermediate receiving member using an inkjet printhead, spreading the ink onto the intermediate receiving member, inducing a property change of the ink, and transferring the ink to a substrate, wherein the ink comprises a latex having a particle size of less than about 100 nm.
Abstract:
A method of printing an image to a substrate includes applying an aqueous inkjet ink onto an intermediate receiving member using an inkjet printhead, optionally spreading the ink onto the intermediate receiving member, inducing a property change of the ink, and transferring the ink to a substrate, wherein the ink includes a curable oligomer. A method of printing an image to a substrate includes applying an aqueous inkjet ink onto an intermediate receiving member using an inkjet printhead, optionally spreading the ink onto the intermediate receiving member, inducing a property change of the ink, and transferring the ink to a substrate, wherein making the ink includes forming an aqueous mixture by adding a mixture of oligomers and a surfactant to a reactor containing a mixture of a humectant and an aqueous vehicle, heating and stirring the aqueous mixture, and homogenizing the aqueous mixture, forming the ink.
Abstract:
The present disclosure is directed to a hybrid conductive ink including: silver nanoparticles and eutectic low melting point alloy particles, wherein a weight ratio of the eutectic low melting point alloy particles and the silver nanoparticles ranges from 1:20 to 1:5. Also provided herein are methods of forming an interconnect including a) depositing a hybrid conductive ink on a conductive element positioned on a substrate, wherein the hybrid conductive ink comprises silver nanoparticles and eutectic low melting point alloy particles, the eutectic low melting point alloy particles and the silver nanoparticles being in a weight ratio from about 1:20 to about 1:5; b) placing an electronic component onto the hybrid conductive ink; c) heating the substrate, conductive element, hybrid conductive ink and electronic component to a temperature sufficient i) to anneal the silver nanoparticles in the hybrid conductive ink and ii) to melt the low melting point eutectic alloy particles, wherein the melted low melting point eutectic alloy flows to occupy spaces between the annealed silver nanoparticles, d) allowing the melted low melting point eutectic alloy of the hybrid conductive ink to harden and fuse to the electronic component and the conductive element, thereby forming an interconnect. Electrical circuits including conductive traces and, optionally, interconnects formed with the hybrid conductive ink are also provided.