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公开(公告)号：US5668076A
公开(公告)日：1997-09-16
申请号：US429345
申请日：1995-04-26
CPC分类号： B01J23/06 , B01J35/002 , B01J35/004 , B01J37/0226
摘要： A photocatalyst comprises, on the surface, a zinc oxide film which comprises zinc oxide fine particles formed by anodic oxidation of zinc and having a particle size of not more than 0.2 .mu.m and a method for preparing a photocatalyst comprises the step of anodically oxidizing the surface of a zinc metal substance or a substance mainly comprising zinc metal to form, on the surface, a zinc oxide film which comprises zinc oxide fine particles having a particle size of not more than 0.2 .mu.m. The photocatalyst permits quite efficient decomposition or destruction of gases or bacterial cells to be treated, can easily be adhered to faces to which the photocatalytic function is to be imparted to thus impart sterilization and/or deodorization functions thereto and can easily be fitted to various apparatuses to which a film has conventionally been applied with great difficulty. In particular, if the thickness of the metal substrate is not more than 1 mm, the photocatalyst can be processed by, for instance, cutting and/or bending so that it can be adhered to faces other than flat ones. Moreover, if the photocatalytic activity thereof is deteriorated due to, for instance, contamination, the used photocatalyst can easily be replaced with a fresh one.
摘要翻译： 光催化剂在表面上包含氧化锌膜，其包含通过阳极氧化锌并且具有不大于0.2μm的粒径形成的氧化锌微粒，以及制备光催化剂的方法包括以下步骤：阳极氧化 锌金属物质的表面或主要包含锌金属的物质，在表面上形成包含粒径不大于0.2μm的氧化锌微粒的氧化锌膜。 光催化剂可以很好地分解或破坏待处理的气体或细菌细胞，可以容易地粘附到赋予光催化功能的面上，从而赋予其消毒和/或除臭功能，并且可以容易地装配到各种装置 电影传统上很难应用于其中。 特别地，如果金属基板的厚度不大于1mm，则光催化剂可以通过例如切割和/或弯曲进行加工，使得其可以粘附到除平面以外的面上。 此外，如果由于例如污染导致的光催化活性劣化，则可以容易地用新鲜的光催化剂代替所使用的光催化剂。
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2.发明授权Organic-inorganic composite graded material, method for preparation thereof and use thereof 失效有机 - 无机复合分级材料，其制备方法和用途公开(公告)号：US06737145B1
公开(公告)日：2004-05-18
申请号：US09807904
申请日：2001-06-08
申请人： Toshiya Watanabe , Kazuhito Hashimoto , Akira Fujishima , Kazuyuki Takami , Norihiro Nakayama , Taro Suzuki , Naoki Tanaka , Eisuke Tachibana , Tatsuhiko Adachi
发明人： Toshiya Watanabe , Kazuhito Hashimoto , Akira Fujishima , Kazuyuki Takami , Norihiro Nakayama , Taro Suzuki , Naoki Tanaka , Eisuke Tachibana , Tatsuhiko Adachi
IPC分类号： B32B514
CPC分类号： C08F8/42 , Y10T428/31504 , Y10T428/31855 , Y10T428/31935
摘要： The present invention is concerned with an organic-inorganic composite graded material containing a composite material formed by chemically bonding an organic polymer compound and a metallic compound and having a component graded structure in which the content of the metallic compound continuously changes in the depth direction from the material surface, a process for the production of the above organic-inorganic composite graded material by forming a coating layer composed of a specific coating solution for forming the organic-inorganic composite film on an organic substrate and drying the coating layer under heat, a coating agent composed of the above organic-inorganic composite graded material for forming a coating film, and an article coated with the above coating agent.
摘要翻译： 本发明涉及含有通过化学键合有机高分子化合物和金属化合物形成的复合材料的有机 - 无机复合分级材料，并且具有其中金属化合物的含量在深度方向上连续变化的组分渐变结构 材料表面，通过在有机基材上形成有机无机复合膜的特定涂布溶液形成涂层并在加热下干燥涂层来生产上述有机 - 无机复合分级材料的方法， 由上述用于形成涂膜的有机 - 无机复合分级材料组成的涂布剂和涂覆有上述涂布剂的制品。
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3.发明授权Metal material having photocatalytic activity and method of manufacturing the same 失效具有光催化活性的金属材料及其制造方法
公开(公告)号：US6106955A
公开(公告)日：2000-08-22
申请号：US5584
申请日：1998-01-12
申请人： Takatoshi Ogawa , Toshio Saito , Sadatoshi Ohno , Atsumichi Kushibe , Fumio Kamikubo , Tatsuya Yasunaga , Takashi Kato , Yoshimasa Ito , Akira Fujishima , Kazuhito Hashimoto
发明人： Takatoshi Ogawa , Toshio Saito , Sadatoshi Ohno , Atsumichi Kushibe , Fumio Kamikubo , Tatsuya Yasunaga , Takashi Kato , Yoshimasa Ito , Akira Fujishima , Kazuhito Hashimoto
CPC分类号： B01J37/0244 , B01J35/002 , B01J35/004 , B01J37/0226 , C25D11/26 , Y10T428/252
摘要： A metal material having a photocatalytic activity which comprises an anodized layer and a thin layer containing titanium oxide powder which are heat treated are sequentially laminated on the surface of a substrate comprising metal material including titanium. By anodically oxidizing the metal material including titanium, an anodized layer is formed on the surface thereof. A thin layer containing titanium oxide powder is further coated on this surface, and heat treatment is carried out before and/or after forming this thin layer containing titanium oxide powder.
摘要翻译： 具有光催化活性的金属材料，其包含阳极氧化层和包含经过热处理的氧化钛粉末的薄层依次层压在包含钛的金属材料的基材的表面上。 通过阳极氧化包括钛的金属材料，在其表面上形成阳极氧化层。 在该表面上进一步涂布含有氧化钛粉末的薄层，在形成含有氧化钛粉末的薄层之前和/或之后进行热处理。
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公开(公告)号：US6099695A
公开(公告)日：2000-08-08
申请号：US910207
申请日：1997-08-13
申请人： Akira Fujishima , Kazuhito Hashimoto , Shuzo Moroto , Masao Ando , Masako Sakai
发明人： Akira Fujishima , Kazuhito Hashimoto , Shuzo Moroto , Masao Ando , Masako Sakai
CPC分类号： B01D53/864 , B01D53/86 , B01J23/60
摘要： A ZnO--Pd composite catalyst wherein Pd is dispersed and fixed on the surface of ZnO is produced by ion adsorption process having the steps of soaking ZnO in an acid solution of Pd to adsorb Pd ions (Pd.sup.2+) onto the surface of ZnO; and reducing the adsorbed Pd ions to metallic Pd particles so that the metallic Pd particles are substantially evenly deposited on the surface of ZnO. The ZnO--Pd composite catalyst provides a stable and continuing CO oxidizing capability, without light irradiation, even when the air to be treated contains sulfur compounds such as H.sub.2 S and SOx.
摘要翻译： 通过离子吸附法制备了Pd分散固定在ZnO表面的ZnO-Pd复合催化剂，其工序有：将ZnO浸入Pd的酸性溶液中，将Pd离子（Pd2 +）吸附到ZnO的表面上; 并将吸附的Pd离子还原成金属Pd颗粒，使得金属Pd颗粒基本上均匀地沉积在ZnO的表面上。 即使待处理的空气含有硫化合物如H 2 S和SO x，ZnO-Pd复合催化剂提供了稳定且持续的CO氧化能力，而不需要光照射。
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5.发明授权
公开(公告)号：US6090489A
公开(公告)日：2000-07-18
申请号：US91692
申请日：1998-06-19
申请人： Makoto Hayakawa , Eiichi Kojima , Keiichiro Norimoto , Mitsuyoshi Machida , Atsushi Kitamura , Toshiya Watanabe , Makoto Chikuni , Akira Fujishima , Kazuhito Hashimoto
发明人： Makoto Hayakawa , Eiichi Kojima , Keiichiro Norimoto , Mitsuyoshi Machida , Atsushi Kitamura , Toshiya Watanabe , Makoto Chikuni , Akira Fujishima , Kazuhito Hashimoto
CPC分类号： G02B1/105 , C03C17/23 , C03C17/256 , C09K3/18 , C03C2217/212 , C03C2217/229 , C03C2217/71 , C03C2218/113 , C03C2218/32 , Y10T428/31
摘要： A method for hydrophilifying the surface of a substrate by taking advantage of photocatalytic action. The substrate has a photocatalytic titania coating (10). The surface of the photocatalytic coating (10) bears the solid acid that increases a hydrogen bond component (.gamma..sub.S.sup.h) in the surface energy in the solid/gas interface of the coating. Photoexcitation of the photocatalyst enhances the hydrogen bond component (.gamma..sub.S.sup.h) in the surface energy of the photocatalytic coating (10), accelerating the physical adsorption of molecules of water in the atmosphere through a hydrogen bond (16) onto hydrogen atoms in a terminal OH group (12), bonded to a titanium atom, and a bridge OH group (14) on the surface of the coating. This results in the formation of a high density, physically adsorbed water layer (18) on the surface of the photocatalytic coating (10), thus permitting the surface of the substrate to be easily hydrophilified. The method is applicable to antifogging, antifouling, selfcleaning and cleaning of articles.
摘要翻译： 利用光催化作用亲水化底物表面的方法。 该基底具有光催化二氧化钛涂层（10）。 光催化涂层（10）的表面承载增加涂层固体/气体界面中表面能的氢键成分（γSh）的固体酸。 光催化剂的光激发增强了光催化涂层（10）的表面能中的氢键成分（γSh），通过氢键（16）加速了大气中的水分子在末端OH中的氢原子的物理吸附 与钛原子键合的基团（12）和涂层表面上的桥羟基（14）。 这导致在光催化涂层（10）的表面上形成高密度，物理吸附的水层（18），从而允许基底的表面容易亲水化。 该方法适用于防雾，防污，自清洁和清洁物品。
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公开(公告)号：US5939194A
公开(公告)日：1999-08-17
申请号：US987670
申请日：1997-12-09
申请人： Kazuhito Hashimoto , Akira Fujishima , Toshiya Watanabe , Mitsuhide Shimohigoshi , Makoto Hayakawa
发明人： Kazuhito Hashimoto , Akira Fujishima , Toshiya Watanabe , Mitsuhide Shimohigoshi , Makoto Hayakawa
IPC分类号： C03C17/245 , C03C17/25 , C09K3/18 , G02B1/10 , B32B9/04
CPC分类号： C03C17/256 , C03C17/2456 , C09K3/18 , G02B1/105 , C03C2217/212 , C03C2217/23 , C03C2217/71 , C03C2218/113 , C03C2218/151 , Y10T428/31504
摘要： A method for highly hydrophilifying the surface of an article by photoexcitation of a semiconductor photocatalyst and maintaining the hydrophilicity is disclosed. A layer containing a photocatalyst is formed on a substrate. Onto the surface of the layer are fixed a hydroxyl group upon photoexcitation of the photocatalyst and a physically adsorbed water molecule in the vicinity of the hydroxyl group upon photoexcitation of the photocatalyst. Thus, the surface is highly hydrophilified. Further, this surface, simultaneously with the hydrophilification, exhibits higher hydrophobicity.
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公开(公告)号：US07998562B2
公开(公告)日：2011-08-16
申请号：US10565121
申请日：2004-07-02
申请人： Kazuhiro Abe , Hiroshi Toyoda , Takayuki Nakata , Eiichi Okamoto , Akira Fujishima , Kazuhito Hashimoto
发明人： Kazuhiro Abe , Hiroshi Toyoda , Takayuki Nakata , Eiichi Okamoto , Akira Fujishima , Kazuhito Hashimoto
CPC分类号： D06N3/047 , B01J35/004 , B01J37/0244 , B05D5/083 , B05D7/56 , D06N3/0063 , Y10T428/24942 , Y10T428/269 , Y10T428/2904 , Y10T428/3154 , Y10T428/31544
摘要： The present invention provides a new photocatalyst sheet in which the substrates coated with fluorocarbon resin are readily weldable mutually, and also of the high antifouling and water-repellant property by coating the outermost surface of film/fabric structure with fluorocarbon resin containing a photocatalyst and a photocatalyst sheet comprises a substrate (2), a first fluorocarbon resin layer (3) coated on said substrate (2), a second fluorocarbon resin layer (4) coated on said first fluorocarbon resin layer (3), and a third fluorocarbon resin layer (5) containing photocatalyst coated on said second fluorocarbon resin layer (4). The melting point of the first fluorocarbon resin layer (3) may be higher than the melting points of the second and the third fluorocarbon resin layers (4), (5).
摘要翻译： 本发明提供了一种新的光催化剂片，其中涂覆有氟碳树脂的基材易于相互焊接，并且通过用含有光催化剂的氟碳树脂涂覆薄膜/织物结构的最外表面，并且还具有高防污和防水性能 光催化剂片材包括基材（2），涂覆在所述基材（2）上的第一氟碳树脂层（3），涂覆在所述第一氟碳树脂层（3）上的第二氟碳树脂层（4）和第三氟碳树脂层 （5）包含涂覆在所述第二氟碳树脂层（4）上的光催化剂。 第一氟树脂层（3）的熔点可以高于第二和第三氟树脂层（4），（5）的熔点。
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8.发明申请公开(公告)号：US20050019700A1
公开(公告)日：2005-01-27
申请号：US10924158
申请日：2004-08-23
申请人： Makoto Hayakawa , Eiichi Kojima , Keiichiro Norimoto , Mitsuyoshi Machida , Atsushi Kitamura , Toshiya Watanabe , Makoto Chikuni , Akira Fujishima , Kazuhito Hashimoto
发明人： Makoto Hayakawa , Eiichi Kojima , Keiichiro Norimoto , Mitsuyoshi Machida , Atsushi Kitamura , Toshiya Watanabe , Makoto Chikuni , Akira Fujishima , Kazuhito Hashimoto
CPC分类号： C09K3/18 , C03C17/23 , C03C17/2456 , C03C17/256 , C03C2217/212 , C03C2217/229 , C03C2217/23 , C03C2217/71 , C03C2218/113 , C03C2218/151 , C03C2218/32 , G02B1/105 , G02B1/18
摘要： A method of preventing or reducing fogging of a surface of a composite when subjected to humid conditions includes providing a composite with a surface. The composite includes a substrate and a photocatalytic surface layer. The photocatalytic surface layer includes a photocatalyst. The method further includes subjecting the photocatalyst to photoexcitation to render the surface of the composite hydrophilic, wherein, after the photoexcitation, the surface of the composite has a water wettability of less than 10° in terms of the contact angle with water. The method further includes subjecting the composite to humidity that is sufficient to induce fogging of the substrate if the photocatalytic surface layer were absent.
摘要翻译： 当经受潮湿条件时，防止或减少复合材料表面起雾的方法包括提供具有表面的复合材料。 复合材料包括基底和光催化表面层。 光催化表面层包括光催化剂。 该方法还包括使光催化剂进行光激发以使复合材料的表面具有亲水性，其中，在光激发后，复合材料的表面以与水的接触角为基准的水润湿性小于10°。 该方法还包括如果不存在光催化表面层，则使复合物经受足以引起底物起雾的湿度。
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公开(公告)号：US6139803A
公开(公告)日：2000-10-31
申请号：US119050
申请日：1998-07-20
CPC分类号： A61L9/205 , A61L9/16 , B01D53/86 , B01D53/8603 , B01D53/8606 , B01D53/8621 , B01D53/8634 , B01D53/885 , B01D2255/802 , B01D2259/804
摘要： A process for photocatalytically treating a hospital room contaminated by bacteria or an interior environment bearing airborne malodorous substances. A thin film of photocatalyst made of a semiconductor such as titanium dioxide is disposed on the inner wall of the hospital room or living space. The photocatalytic thin film is irradiated by a light source suitable for general lighting applications, such as a fluorescent lamp, and is photoexcited by the small amount of ultraviolet radiation included in the light of the fluorescent lamp. The wattage of the fluorescent lamp as well as the distance between the photocatalytic thin film and the lamp are selected such that the intensity of those UV wavelengths which have a higher energy than the band gap energy of the photo-catalyst is 0.001-1 mW/cm.sup.2, preferably, 0.01-0.1 mW/cm.sup.2. The bacteria and chemical compounds deposited on the photoexcited thin film are photodecomposed.
摘要翻译： 一种光催化处理被细菌污染的医院室或带有空气恶臭物质的室内环境的方法。 在医院室或生活空间的内壁上设置由诸如二氧化钛的半导体制成的光催化剂薄膜。 光催化薄膜由适用于一般照明应用的光源（例如荧光灯）照射，并且由包括在荧光灯的光中的少量紫外线照射而被光激发。 选择荧光灯的功率以及光催化薄膜和灯之间的距离，使得具有比光催化剂的带隙能量更高的能量的那些UV波长的强度为0.001-1mW / cm2，优选为0.01-0.1mW / cm 2。 沉积在光激发薄膜上的细菌和化学化合物被光分解。
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公开(公告)号：US6117568A
公开(公告)日：2000-09-12
申请号：US913167
申请日：1997-10-30
CPC分类号： H01F41/26 , C25D9/00 , H01F10/005
摘要： The invention provides a novel cyanochromium-complex-based magnetic material formed on an electrode, which is excellent in magnetic properties and of which magnetic properties are reversibly controllable, by impressing a reduction potential which electrochemically reduces Cr.sup.3+ into Cr.sup.2+ in a solution containing at least [Cr(CN).sub.6 ].sup.3- and Cr.sup.3+.
摘要翻译： PCT No.PCT / JP96 / 00577 Sec。 371 1997年10月30日第 102（e）1997年10月30日PCT 1996年3月8日PCT公布。 公开号WO96 / 28831 日期1996年9月19日本发明提供了一种形成在电极上的新颖的基于氰基铬络合物的磁性材料，其磁性能优异，磁性能可逆地控制，通过在电化学方法中减少Cr3 +的还原电位， 至少含有[Cr（CN）6] 3-和Cr3 +的溶液。
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