公开(公告)号：US20120029158A1

公开(公告)日：2012-02-02

申请号：US13193108

申请日：2011-07-28

申请人： Yasuo WAKATSUKI ,  Hiroaki Tetsuka

发明人： Yasuo WAKATSUKI ,  Hiroaki Tetsuka

IPC分类号： C08F4/70 ,  C08F30/08 ,  C08F32/08 ,  C08F2/04

CPC分类号： C08F4/70 ,  C08F30/08 ,  C08F32/08 ,  C08J5/18 ,  C08J2343/04

摘要： A method for preparing a cyclic olefin addition polymer of high gas permeability, which method including subjecting a specific type of cyclic olefin-functional siloxane and a mixture thereof with a specific type of cyclic olefin compound to addition polymerization in the presence of a multi-component catalyst containing (A) a zero-valent palladium compound, (B) an ionic boron compound, and (C) a phosphine compound having a substituent group selected from an alkyl group having 3 to 6 carbon atoms, a cycloalkyl group and an aryl group, to obtain a cyclic olefin addition polymer of high gas permeability wherein a ratio of the structural units derived from the cyclic olefin-functional siloxane is at 10 to 100 mole % of the addition polymer and a number average molecular weight (Mn) ranges from 100,000 to 2,000,000.

摘要翻译： 一种制备高透气性的环状烯烃加成聚合物的方法，该方法包括使特定类型的环状烯烃官能硅氧烷及其与特定类型环状烯烃化合物的混合物在多组分存在下进行加成聚合 含有（A）零价钯化合物的催化剂，（B）离子性硼化合物，（C）具有选自碳原子数3〜6的烷基的取代基的膦化合物，环烷基和芳基 得到环状烯烃官能性硅氧烷衍生的结构单元的比例为加成聚合物的10〜100摩尔％，数均分子量（Mn）为100,000以下的高透气性环状烯烃加成聚合物 至2,000,000。

公开(公告)号：US08158732B2

公开(公告)日：2012-04-17

申请号：US13193108

申请日：2011-07-28

申请人： Yasuo Wakatsuki ,  Hiroaki Tetsuka

发明人： Yasuo Wakatsuki ,  Hiroaki Tetsuka

IPC分类号： C08F4/609 ,  C08F4/70 ,  C08F30/08

CPC分类号： C08F4/70 ,  C08F30/08 ,  C08F32/08 ,  C08J5/18 ,  C08J2343/04

摘要： A method for preparing a cyclic olefin addition polymer of high gas permeability, which method including subjecting a specific type of cyclic olefin-functional siloxane and a mixture thereof with a specific type of cyclic olefin compound to addition polymerization in the presence of a multi-component catalyst containing (A) a zero-valent palladium compound, (B) an ionic boron compound, and (C) a phosphine compound having a substituent group selected from an alkyl group having 3 to 6 carbon atoms, a cycloalkyl group and an aryl group, to obtain a cyclic olefin addition polymer of high gas permeability wherein a ratio of the structural units derived from the cyclic olefin-functional siloxane is at 10 to 100 mole % of the addition polymer and a number average molecular weight (Mn) ranges from 100,000 to 2,000,000.

摘要翻译： 一种制备高透气性的环状烯烃加成聚合物的方法，该方法包括使特定类型的环状烯烃官能硅氧烷及其与特定类型环状烯烃化合物的混合物在多组分存在下进行加成聚合 含有（A）零价钯化合物的催化剂，（B）离子性硼化合物，（C）具有选自碳原子数3〜6的烷基的取代基的膦化合物，环烷基和芳基 得到环状烯烃官能性硅氧烷衍生的结构单元的比例为加成聚合物的10〜100摩尔％，数均分子量（Mn）为100,000以下的高透气性环状烯烃加成聚合物 至2,000,000。

公开(公告)号：US20140165838A1

公开(公告)日：2014-06-19

申请号：US14236301

申请日：2012-08-01

申请人： Yoshinobu Suzuki ,  Katsunori Iwase ,  Takehiro Kurata ,  Manabu Maeda ,  Yoshinori Yoneda ,  Hiroaki Tetsuka ,  Jyunya Ishida

发明人： Yoshinobu Suzuki ,  Katsunori Iwase ,  Takehiro Kurata ,  Manabu Maeda ,  Yoshinori Yoneda ,  Hiroaki Tetsuka ,  Jyunya Ishida

IPC分类号： B01D71/26

CPC分类号： B01D71/26 ,  B01D53/228 ,  B01D67/0088 ,  B01D69/02 ,  B01D69/12 ,  B01D71/64 ,  B01D71/70 ,  B01D2256/12 ,  B01D2257/104 ,  B01D2257/502 ,  B01D2257/504 ,  B01D2257/708 ,  B01D2258/06 ,  B01D2259/4566 ,  B01D2323/12 ,  B01D2323/21 ,  B60H1/3202 ,  B60H3/06 ,  B60H2003/0666 ,  C08F230/00 ,  C08F232/04 ,  C08K3/36 ,  C08L45/00 ,  F24F3/1603 ,  F24F13/28 ,  F24F2003/1435 ,  Y02C10/10 ,  Y02P20/152

摘要： As a permeable membrane of an air conditioning system that performs as supply to a space to be air conditioned through the permeable membrane and/or gas discharge from the space to be air conditioned through the permeable membrane, an asymmetric membrane is used. The asymmetric membrane is made of a cyclic olefin addition polymer obtained by addition polymerization of a cyclic olefin functionality siloxane, or by addition polymerization of the cyclic olefin functionality siloxane and a cyclic olefin compound, and in which a rate of a structural unit derived from the cyclic olefin functionality siloxane is 5 to 100 mol % of the addition polymer, and a number average molecular weight (Mn) is 10,000 to 2,000,000 in terms of polystyrene conversion measured by a GPC using tetrahydrofuran as a solvent.

摘要翻译： 作为空调系统的可渗透膜，其通过可渗透膜进行空调调节的空间和/或通过可渗透膜从空气调节的空间排出气体，使用非对称膜。 非对称膜由环烯烃官能团硅氧烷的加成聚合得到的环状烯烃加成聚合物，或环状烯烃官能团硅氧烷和环状烯烃化合物的加成聚合而成，其中衍生自 环烯烃官能团硅氧烷为5〜100摩尔％的加成聚合物，数均分子量（Mn）为聚乙烯换算换算为10,000〜200万，使用四氢呋喃作为溶剂通过GPC测定。

公开(公告)号：US20110301247A1

公开(公告)日：2011-12-08

申请号：US12980859

申请日：2010-12-29

申请人： Chihiro HAYAKAWA ,  Hiroaki Tetsuka ,  Mamoru Hagiwara ,  Yoshinori Yoneda

发明人： Chihiro HAYAKAWA ,  Hiroaki Tetsuka ,  Mamoru Hagiwara ,  Yoshinori Yoneda

IPC分类号： A61K47/30 ,  C08G77/18 ,  C08G77/04

CPC分类号： A61K8/891 ,  A61Q1/02 ,  A61Q1/04 ,  A61Q1/06 ,  A61Q1/08 ,  A61Q1/10 ,  A61Q1/12 ,  A61Q3/00 ,  A61Q3/02 ,  A61Q5/00 ,  A61Q15/00 ,  A61Q17/04 ,  A61Q19/00 ,  A61Q19/08 ,  C08F230/08 ,  C08F232/08

摘要： Disclosed herein is a cosmetic product which contains a polymer having the repeating unit represented by the following formula (1) or (2): wherein R1 is independently alkyl group having 1 to 12 carbon atoms, X is a group represented by the following formula (i), a is an integer of 1 to 3, and b is an integer of 0 to 2, wherein R2 is independently alkyl group having 1 to 12 carbon atoms and c is an integer of 1 to 5, wherein R1, R2, and b are defined as above, and d is an integer of 2 to 5.

摘要翻译： 本发明公开了含有具有下述式（1）或（2）所示的重复单元的聚合物的化妆品，其中，R 1独立地为碳原子数1〜12的烷基，X为下述式 i）中，a为1〜3的整数，b为0〜2的整数，R 2为碳原子数1〜12的烷基，c为1〜5的整数，其中，R 1，R 2， b定义如上，d为2〜5的整数。

公开(公告)号：US20050084691A1

公开(公告)日：2005-04-21

申请号：US10958251

申请日：2004-10-06

申请人： Akihiro Endo ,  Kunihiko Mita ,  Akio Nakano ,  Kunihiro Yamada ,  Hiroaki Kizaki ,  Hiroaki Tetsuka

发明人： Akihiro Endo ,  Kunihiko Mita ,  Akio Nakano ,  Kunihiro Yamada ,  Hiroaki Kizaki ,  Hiroaki Tetsuka

IPC分类号： C08L83/07 ,  C08K3/08 ,  C08K5/5419 ,  C08L83/04 ,  C08L83/05 ,  C09K5/14 ,  H01L23/36 ,  H01L23/373 ,  H01L21/60

CPC分类号： H01L23/3737 ,  C08G77/12 ,  C08G77/18 ,  C08G77/20 ,  C08K3/08 ,  C08K5/5419 ,  C08L83/04 ,  C08L2205/02 ,  C08L2205/03 ,  C09K5/14 ,  H01L2224/16 ,  H01L2224/73253 ,  Y10T428/31663 ,  C08L83/00

摘要： Provided is a curable organopolysiloxane composition which includes (A) an organopolysiloxane containing at least 2 alkenyl groups bonded to silicon atoms within each molecule, (B) an organohydrogenpolysiloxane containing at least 2 hydrogen atoms bonded to silicon atoms within each molecule, (C) gallium and/or an alloy thereof, with a melting point within a range from 0 to 70° C., optionally (D) a heat conductive filler with an average particle size within a range from 0.1 to 100 μm, (E) a platinum based catalyst, and (F) an addition reaction control agent. The composition is useful as a material capable of forming a layer with excellent thermal conductivity that is sandwiched between a heat generating electronic component and a heat radiating member.

摘要翻译： 提供了一种可固化的有机基聚硅氧烷组合物，其包含（A）在每个分子内含有至少2个与硅原子键合的烯基的有机聚硅氧烷，（B）含有与每个分子内的硅原子键合的至少2个氢原子的有机氢聚硅氧烷，（C）镓 和/或其合金，熔点在0-70℃的范围内，任选地（D）平均粒径在0.1-100μm范围内的导热填料，（E）铂基 催化剂，（F）加成反应控制剂。 该组合物可用作能够形成具有优异导热性的层的材料，其夹在发热电子部件和散热构件之间。

公开(公告)号：US07141273B2

公开(公告)日：2006-11-28

申请号：US10958251

申请日：2004-10-06

申请人： Akihiro Endo ,  Kunihiko Mita ,  Akio Nakano ,  Kunihiro Yamada ,  Hiroaki Kizaki ,  Hiroaki Tetsuka

发明人： Akihiro Endo ,  Kunihiko Mita ,  Akio Nakano ,  Kunihiro Yamada ,  Hiroaki Kizaki ,  Hiroaki Tetsuka

IPC分类号： B05D3/02

CPC分类号： H01L23/3737 ,  C08G77/12 ,  C08G77/18 ,  C08G77/20 ,  C08K3/08 ,  C08K5/5419 ,  C08L83/04 ,  C08L2205/02 ,  C08L2205/03 ,  C09K5/14 ,  H01L2224/16 ,  H01L2224/73253 ,  Y10T428/31663 ,  C08L83/00

摘要： Provided is a curable organopolysiloxane composition which includes (A) an organopolysiloxane containing at least 2 alkenyl groups bonded to silicon atoms within each molecule, (B) an organohydrogenpolysiloxane containing at least 2 hydrogen atoms bonded to silicon atoms within each molecule, (C) gallium and/or an alloy thereof, with a melting point within a range from 0 to 70° C., optionally (D) a heat conductive filler with an average particle size within a range from 0.1 to 100 μm, (E) a platinum based catalyst, and (F) an addition reaction control agent. The composition is useful as a material capable of forming a layer with excellent thermal conductivity that is sandwiched between a heat generating electronic component and a heat radiating member.

摘要翻译： 提供了一种可固化的有机基聚硅氧烷组合物，其包含（A）在每个分子内含有至少2个与硅原子键合的烯基的有机聚硅氧烷，（B）含有与每个分子内的硅原子键合的至少2个氢原子的有机氢聚硅氧烷，（C）镓 和/或其合金，熔点在0-70℃的范围内，任选地（D）平均粒径在0.1-100μm范围内的导热填料，（E）铂基 催化剂，（F）加成反应控制剂。 该组合物可用作能够形成具有优异导热性的层的材料，其夹在发热电子部件和散热构件之间。

公开(公告)号：US06940722B2

公开(公告)日：2005-09-06

申请号：US10347599

申请日：2003-01-22

申请人： Hiroaki Tetsuka ,  Kunihiko Mita ,  Kunihiro Yamada ,  Yoshitaka Aoki ,  Tsutomu Yoneyama

发明人： Hiroaki Tetsuka ,  Kunihiko Mita ,  Kunihiro Yamada ,  Yoshitaka Aoki ,  Tsutomu Yoneyama

IPC分类号： H01L23/427 ,  H05K7/20

CPC分类号： H01L23/427 ,  F28F2013/006 ,  H01L2924/0002 ,  Y10T428/31663 ,  H01L2924/00

摘要： A heat-dissipating member sandwiched between a heat dissipating electronic component which reaches a higher temperature than room temperature due to operation, and a heat-dissipating component for dissipating the heat produced from this heat dissipating electronic component. The heat-dissipating member of this invention has an interlayer comprising a metal foil and/or metal mesh having a thickness of 1-50 μm and heat conductivity of 10-500 W/mK, and a layer comprising a thermally-conducting composition containing 100 wt parts of a silicone resin and 1,000-3,000 wt parts of a thermally-conducting filler formed on both surfaces of the interlayer such that the overall thickness is within the range of 40-500 μm. This heat-dissipating member is non-fluid at room temperature, but due to the action of heat emitted when the electronic component operates, its viscosity decreases, and it softens or melts based on the phase transition of the resin and low melting point metal so that it is effectively in intimate contact with the boundary between the electronic component and heat-dissipating component without any gaps. The thermally-conducting filler contains a low melting point metal powder (1) having a melting temperature of 40-250° C. and a particle diameter of 0.1-100 μm, together with a thermally-conducting powder (2) having a melting temperature exceeding 250° C. and an average particle diameter of 0.1-100 μm, such that (1)/[(1)+(2)]=0.2-1.0.

摘要翻译： 夹在由于操作而达到比室温高的温度的散热电子部件之间的散热部件，以及用于散发由该散热电子部件产生的热量的散热部件。 本发明的散热构件具有中间层，其包含厚度为1-50μm，导热率为10-500W / mK的金属箔和/或金属网，以及包括含有100 重量份硅树脂和1000-3,000重量份形成在中间层的两个表面上的导热填料，使得总厚度在40-500μm的范围内。 该散热构件在室温下为非流体，但是由于电子部件运转时发出的热量的作用，其粘度降低，并且基于树脂和低熔点金属的相变而软化或熔化，因此 它有效地与电子部件和散热部件之间的边界紧密接触而没有任何间隙。 导热性填料含有熔融温度为40〜250℃，粒径为0.1〜100μm的低熔点金属粉末（1），以及具有熔融温度的导热性粉末（2） 超过250℃，平均粒径为0.1-100μm，使得（1）/ [（1）+（2）] = 0.2-1.0。

公开(公告)号：US08999043B2

公开(公告)日：2015-04-07

申请号：US14236301

申请日：2012-08-01

申请人： Yoshinobu Suzuki ,  Katsunori Iwase ,  Takehiro Kurata ,  Manabu Maeda ,  Yoshinori Yoneda ,  Hiroaki Tetsuka ,  Jyunya Ishida

发明人： Yoshinobu Suzuki ,  Katsunori Iwase ,  Takehiro Kurata ,  Manabu Maeda ,  Yoshinori Yoneda ,  Hiroaki Tetsuka ,  Jyunya Ishida

IPC分类号： B01D53/22 ,  B01D71/26 ,  B60H3/06 ,  B01D69/12 ,  B01D67/00 ,  B01D71/64 ,  B01D69/02 ,  C08K3/36 ,  C08L45/00 ,  F24F13/28 ,  F24F3/14

CPC分类号： B01D71/26 ,  B01D53/228 ,  B01D67/0088 ,  B01D69/02 ,  B01D69/12 ,  B01D71/64 ,  B01D71/70 ,  B01D2256/12 ,  B01D2257/104 ,  B01D2257/502 ,  B01D2257/504 ,  B01D2257/708 ,  B01D2258/06 ,  B01D2259/4566 ,  B01D2323/12 ,  B01D2323/21 ,  B60H1/3202 ,  B60H3/06 ,  B60H2003/0666 ,  C08F230/00 ,  C08F232/04 ,  C08K3/36 ,  C08L45/00 ,  F24F3/1603 ,  F24F13/28 ,  F24F2003/1435 ,  Y02C10/10 ,  Y02P20/152

摘要： As a permeable membrane of an air conditioning system that performs as supply to a space to be air conditioned through the permeable membrane and/or gas discharge from the space to be air conditioned through the permeable membrane, an asymmetric membrane is used. The asymmetric membrane is made of a cyclic olefin addition polymer obtained by addition polymerization of a cyclic olefin functionality siloxane, or by addition polymerization of the cyclic olefin functionality siloxane and a cyclic olefin compound, and in which a rate of a structural unit derived from the cyclic olefin functionality siloxane is 5 to 100 mol % of the addition polymer, and a number average molecular weight (Mn) is 10,000 to 2,000,000 in terms of polystyrene conversion measured by a GPC using tetrahydrofuran as a solvent.

摘要翻译： 作为空调系统的可渗透膜，其通过可渗透膜进行空调调节的空间和/或通过可渗透膜从空气调节的空间排出气体，使用非对称膜。 非对称膜由环烯烃官能团硅氧烷的加成聚合得到的环状烯烃加成聚合物，或环状烯烃官能团硅氧烷和环状烯烃化合物的加成聚合而成，其中衍生自 环烯烃官能团硅氧烷为5〜100摩尔％的加成聚合物，数均分子量（Mn）为聚乙烯换算换算为10,000〜200万，使用四氢呋喃作为溶剂通过GPC测定。

公开(公告)号：US20100190950A1

公开(公告)日：2010-07-29

申请号：US12694444

申请日：2010-01-27

申请人： Hiroaki Tetsuka ,  Mamoru Hagiwara ,  Shojiro Kaita

发明人： Hiroaki Tetsuka ,  Mamoru Hagiwara ,  Shojiro Kaita

IPC分类号： C08G77/06 ,  C08G77/04

CPC分类号： C08F4/70 ,  B01D71/44 ,  B01D71/70 ,  B01D71/82 ,  C08F30/08 ,  C08F32/08 ,  C08F232/08 ,  C08F230/08

摘要： A cycloolefin addition polymer is prepared by addition polymerization of a cycloolefin-functionalized siloxane and optionally norbornene in the presence of catalyst A which is a nickel or palladium complex having a cyclopentadienyl ligand and a methyl, triphenylphosphine or allyl ligand and co-catalyst B, typically tris(pentafluorophenyl)boron or trityltetra(pentafluorophenyl)borate. The polymer is easy to manufacture and has high thermal stability and mechanical strength as well as good gas permeability.

摘要翻译： 通过在催化剂A（其是具有环戊二烯基配体和甲基，三苯基膦或烯丙基配体和助催化剂B的镍或钯配合物）的存在下加成聚合环烯烃官能化的硅氧烷和任选的降冰片烯来制备环烯烃加成聚合物，通常 三（五氟苯基）硼或三苯甲基四（五氟苯基）硼酸盐。 聚合物易于制造，并且具有高热稳定性和机械强度以及良好的透气性。

公开(公告)号：US07538075B2

公开(公告)日：2009-05-26

申请号：US10996418

申请日：2004-11-26

申请人： Kunihiro Yamada ,  Hiroaki Tetsuka

发明人： Kunihiro Yamada ,  Hiroaki Tetsuka

IPC分类号： C10M169/04

CPC分类号： C08K3/08 ,  C08K3/22 ,  C08K2003/2227 ,  C08K2003/2296 ,  C08L83/04 ,  C10M169/02 ,  C10M2201/056 ,  C10M2201/0626 ,  C10M2203/102 ,  C10M2203/1025 ,  C10M2227/04 ,  C10M2227/045 ,  C10M2229/025 ,  C10M2229/0415 ,  C10N2210/02 ,  C10N2210/03 ,  C10N2230/02 ,  C10N2240/20 ,  C10N2240/201 ,  C10N2250/10 ,  C10N2250/121

摘要： A heat dissipating silicone grease composition comprising: (A) 3% to 30% by weight of an organo polysiloxane represented by the general formula, R1aSiO(4−a)/2(R1 is one or two or more groups selected from a group of saturated or unsaturated monovalent hydrocarbon groups containing one to eighteen carbon atoms, and a is a positive number defined by 1.8≦a≦2.2) having a dynamic viscosity at 25° C. of 50 mm2/s to 500,000 mm2/s; (B) 60% to 96.9% by weight of a thermally conductive filler having a thermal conductivity of at least 10 W/(m·K); and (C) 0.1% to 10% by weight of a solvent that disperses or dissolves component (A).

摘要翻译： 1.一种散热硅润滑脂组合物，其特征在于，含有：（A）3质量％〜30质量％的由通式R1aSiO（4-a）/ 2表示的有机聚硅氧烷（R1为1〜 饱和或不饱和的含有1至18个碳原子的一价烃基，a为在25℃下的动态粘度为1.8≤a≤2.2的正数，为50mm 2 / s至500,000mm 2 / s; （B）热导率为10W /（m·K）以上的导热性填料的60〜96.9重量％。 和（C）0.1〜10重量％的分散或溶解组分（A）的溶剂。